Estimating the yield stress of soft materials via laser-induced breakdown spectroscopy

Taking three typical soft samples prepared respectively by loose packings of 77-,95-,and 109-μm copper grains as examples,we perform an experiment to investigate the energy-dependent laser-induced breakdown spectroscopy(LIBS)of soft materials.We discovered a reversal phenomenon in the trend of energy dependence of plasma emission intensity:increasing initially and then decreasing separated by a well-defined critical energy.The trend reversal is attributed to the laser-induced recoil pressure at the critical energy just matching the sample's yield strength.As a result,a one-to-one correspondence can be well established between the samples'yield stress and the critical energy that is easily obtainable from LIBS measurements.This allows us to propose an innovative method for estimating the yield stress of soft materials via LIBS with attractive advantages including in-situ remote detection,real-time data collection,and minimal destructive to sample.

Stresses in the Scapular Fossa Do Not Exceed the Yield Stress When Elevated up to 135 Degrees of Abduction after Reverse Shoulder Arthroplasty

Reverse shoulder arthroplasty (RSA) is an effective treatment for rotator cuff tears. Despite its advantages, complications occur at a high rate. Complications requiring revision include a high rate of base plate failure, 38% of which are due to instability. The primary stability the base plate ensures is a crucial factor and, thus, is the subject of much debate in clinical studies and biomechanical research. This study is aimed to provide data that will contribute to the base plate’s pri-mary stability and glenoid longevity by clarifying the stresses at the scapular fossa and base plate interface associated with elevation after RSA. A 3D finite element model was created from the DICOM data for the scapulohumeral joint and SMR shoulder system. For loading conditions, 30 N was applied for each posi-tion with abduction angles of 0, 45, 90, and 135 degrees. A three-dimensional fi-nite element analysis was performed using the static implicit method with LS-DYNA. The von Mises stresses in the scapular fossa were found not to exceed the yield stress on the bone even after elevation to an abduction angle of 135 de-grees after RSA. It is rough to uniformly compare the yield stress and the von Mises stress, but it was inferred that the possibility of fracture is low unless a large external force is applied. A maximum von Mises stress showed 0 degrees of abduction, suggesting that the lowered position is in a more severe condition than the elevated position. If better improvement is desired, it may be necessary to devise ways to reduce the stress on the upper screw. .

Effect of particle gradation characteristics on yield stress of cemented paste backfill

Along with slurry concentration and particle density,particle size distribution(PSD)of tailings also exerts a significant influence on the yield stress of cemented paste,a non-Newtonian fluid.In this work,a paste stability coefficient(PSC)was proposed to characterize paste gradation and better reveal its connection to yield stress.This coefficient was proved beneficial to the construction of a unified rheological model,applicable to different materials in different mines,so as to promote the application of rheology in the pipeline transportation of paste.From the results,yield stress showed an exponential growth with increasing PSC,which reflected the proportion of solid particle concentration to the packing density of granular media in a unit volume of slurry,and could represent the properties of both slurry and granular media.It was found that slurry of low PSC contained extensive pores,generally around 20μm,encouraging free flow of water,constituting a relatively low yield stress.In contrast,slurry of high PSC had a compact and quite stable honeycomb structure,with pore sizes generally<5μm,causing the paste to overcome a higher yield stress to flow.

Changes in underflow solid fraction and yield stress in paste thickeners by circulation

The trouble-free and efficient operation of paste thickeners requires an optimal design and the cooperation of each component.When underflow discharging is suspended,alleviating the vast torque that the remaining solids within the thickeners may place on rakes mainly lies in the circulation unit.The mechanism of this unit was analyzed,and a mathematical model was developed to describe the changes in underflow solid content and yield stress.The key parameters of the circulation unit,namely,the height and flow rate,were varied to test its performance in the experiments with a self-designed laboratorial thickening system.Results show that the circulation unit is valid in reducing underflow solid fraction and yield stress to a reasonable extent,and the model could be used to describe its efficiency at different heights and flow rates.A suitable design and application of the circulation unit contributes to a cost-effective operation of paste thickeners.

Synergistic effect of magnetic field and nanocomposite pour point depressant on the yield stress of waxy model oil

Yield stress,as the key parameter to characterize the network strength of waxy oil,is important to the petroleum pipeline safety.Reducing the yield stress of waxy oil is of great significance for flow assurance.In this study,the effect of alternating magnetic field(intensity,frequency)on the yield stress of a waxy model oil with nanocomposite pour point depressant(NPPD)is systematically investigated.An optimum magnetic field intensity and frequency is found for the reduction in yield stress.When adding with NPPD,the heterogeneous nucleation of NPPD contributes to the reduction in yield stress for waxy model oil.Interestingly,the magnetic field is helpful for the modification of yield stress at a lower frequency and intensity before the optimal value;however,the modification is found to be weakened when the magnetic field is further increased after the optimal value.Possible explanation is proposed that the aggregation morphology of wax crystal would be altered and results in the release of wrapped oil phase from the network structure under the magnetic field.

Influence of chemical reaction on heat and mass transfer of non-Newtonian fluid with yield stress by free convection from vertical surface in porous medium considering Soret effect

The effect of chemical reaction on free convection heat and mass transfer for a non-Newtonian power law fluid over a vertical flat plate embedded in a fluid-saturated porous medium has been studied in the presence of the yield stress and the Soret effect. The governing boundary layer equations and boundary conditions are cast into a dimen- sionless form by similarity transformations, and the resulting system of equations is solved by a finite difference method. The results are preSented and discussed for concentration profiles, as well as the Nusselt number and the Sherwood number for various values of the parameters, which govern the problem. The results obtained show that the flow field is influenced appreciably by the presence of the chemical reaction parameter γ the order of.the chemical reaction parameter m, the Soret number St, the buoyancy ratio N, the Lewis number Le, and the dimensionless rheological parameter Ω.

Characterization of Yield Stress Development of Cement Paste by Electrical Resistivity

Yield stress development of cement paste is potentially governed by percolation of 3-dimensional links formed by hydration products on the surface of the particles. It rises steadily at a gradual rate before a sudden increase in rate of growth. In this study, a method was proposed to predict the yield stress development based on the diameter of spread（D） of mini slump cone test and gradient from electrical resistivity measurement（Km）. To evaluate the significance of（D） and（Km） in terms of yield stress, they were quantitatively compared to the initial yield stress（τ0） and rate of yield stress growth（K） obtained from a rheometer. A mathematical relationship between the yield stress of cement paste, diameter of spread and electrical resistivity characteristic gradient was developed. The equation developed can be used as an alternative method to estimate yield stress of cement paste.

Inherent relations between yield stress and stability of bubble petroleum coke water slurry

The stability of petroleum coke water slurry（PCWS） is currently a hot topic. The inherent relationship between yield stress and stability of bubble-PCWS was studied through orthogonal experiments and range analysis in this work. The results showed that the stability of bubble-PCWS was positively related to the yield stress and that the yield stress could be greatly impacted by the operation conditions during preparation of bubble-PCWS. The main factors affecting the yield stress of bubble-PCWS were solid concentration, aeration time and dosage of frother. However, the effects of aperture size of air distribution plates and type of frother on the yield stress were slight within the experimental range. The optimal conditions for the greatest yield stress were as follows： aeration time of 30 min, solid concentration of 65 wt%, frother dosage of0.030 wt% of the air-dried pulverized petroleum coke, aperture size of air distribution plate of 2-5 lm and AOS frother.The yield stress and the pour rate of bubble-PCWS under this optimum operation condition could reach maxima of more than 0.4 Pa and 96%, respectively.

Stacking fault energy,yield stress anomaly, and twinnability of Ni_3Al:A first principles study

Using first principles calculations combined with the quasiharmonic approach, we study the effects of temperature on the elastic constants, generalized stacking fault energies, and generalized planar fault energies of Ni3Al. The antiphase boundary energies, complex stacking fault energies, superlattice intrinsic stacking fault energies, and twinning energies decrease slightly with temperature. Temperature dependent anomalous yield stress of Ni3Al is predicted by the energybased criterion based on elastic anisotropy and antiphase boundary energies. It is found that p increases with temperature and this can give a more accurate description of the anomalous yield stress in Ni3Al. Furthermore, the predicted twinnablity of Ni3Al is also decreasing with temperature.

QUANTITATIVE RELATIONSHIP BETWEEN YIELD STRESS AND r-VALUE OF Ti SHEET

Based on the experimental data,it was clarified that the plastic strain ratio R-value is not equal to Hill's r-value for Ti sheet.From the non-quadratic orthotropic yield function pro- posed recently by the author,an optimal expression between yield stress and r-value for Ti sheet was developed on overall investigation.The suitable value of exponent in the function seems to be 6—8.Thus,an equation was suggested to estimate strength for the pressure vessel made of Ti sheet.

A New Modified Conductivity Model for Prediction of Shear Yield Stress of Electrorheological Fluids Based on Face-center Square Structure

A new modified conductivity model was established to predict the shear yield stress of electrorheological fluids (ERF). By using a cell equivalent method, the present model can deal with the face-center square structure of ERF. Combining the scheme of the classical conductivity model for the single-chain structure, a new formula for the prediction of the shear yield stress of ERF was set up. The influences of the separation distance of the particles, the volume fraction of the particles and the applied electric field on the shear yield stress were investigated.

QUANTITATIVE RELATION BETWEEN YIELD STRESS AND R-VALUE OF Ti PLATE ALONG PARALLEL AND PERPENDICULAR TO ROLLING DIRECTION

An attempt was made on the quantitative prediction of the relationship hetween the yield stress and R-value along the parallel and perpendicular to the rolling direction of Ti plate based on analysis of the previous experimental data.It is shown that the yield stress along one direction and another is quite synchronized with the R—value.According to the plasticity theo- ry,an formular of σ_(1s)/σ_(2s)=[(1+1/R_2)/(1+1/R_1)/^(1 2) was proposed,In statistic estima- tion.the calculated results are in good agreement with the experimental data.The availability of this formula was briefly discussed also.

Correlation Between Yield Stress of Silty Mud Sediments and Continuous Oscillatory Shearing Properties

Analyzing the rheological properties of silty beds subjected to continuous oscillatory shear loading is crucial for understanding the morphological deformation of the seabed and ensuring safety in geological and marine engineering applications.In this study,the effects of oscillatory shearing properties on the yield stress(S_(u))of silty sediments were quantitatively investigated.The effects of oscillatory shear strength(0-3),water content(26.6%-70.84%),and particle diameter(8.79-50μm)were examined extensively through a series of laboratory tests.The results indicated that the three aforementioned parameters were the major factors that affected the rheological characteristics of silty sediments.Furthermore,their effects could be elucidated using the yield stress of cohesive sediments as the indicator parameter.The ratio of yield stress(S_(u)/S_(u0))varied as the oscillatory shear strength increased up to a critical value,Λ_(cr).S_(u)bsequently,the ratio remained at a constant value.It was deduced that the yield stress decreased with increasing oscillatory shear strength forΛ<Λ_(cr),when the sediments were in a non-equilibrium fluidization stage.WhenΛ>Λ_(cr),the sediments entered an equilibrium fluidization stage,and the yield stress remained almost constant,irrespective of the oscillatory shear strength.Furthermore,during the equilibrium fluidization stage,it was observed that the ratio S_(u)/S_(u0)did not vary with water content but decreased as the particle diameter increased.Finally,based on regression analysis of the experimental data for non-equilibrium and equilibrium fluidization stages,a correlation between yield stress of silty sediments and continuous oscillatory shearing properties was proposed.This correlation can aid in understanding the changes in solid resistance and assessing safety in piling engineering.Furthermore,it can provide a theoretical guidance for reducing soil resistance in marine structures using mechanical vibrations.

Static Yield Stress of Cement-based Grouting Material under Different Rheological Modes

To quantitatively estimate the workability of cement-based grouting material,from the perspective of rheology,the result of the static yield stress evaluated using the rate-controlled and stress-controlled modes,respectively,was compared using the Rheowin rheometer.Also,the correlation of workability and solid concentration of slurry with static yield stress was studied.Results show that the static yield stress of cement-based grouting slurry relates to the established slurry structure,and is the shear stress corresponding to the transformation of elastics to plastics;In rate-controlled mode,the static yield stress of the slurry is related to the shear rate.The higher the shear rate,the greater the yield stress of the slurry.For the stress-controlled mode,the result is more accurate and suitable for testing static yield stress under different water-cement ratios.Since the water-cement ratio has a good correspondence with the static yield stress and the static yield stress has a good correspondence with the slump flow of the slurry,the static yield stress is the minimum stress to be overcome when the slurry begins to flow and it reflects the yield behavior and structural stability of the cement.

The Effect of Grain Size on the Viscosity and Yield Stress of Fine-Grained Sediments

In debris flow modelling,the viscosity and yield stress of fine-grained sediments should be determined in order to better characterize sediment flow.In particular,it is important to understand the effect of grain size on the rheology of fine-grained sediments associated with yielding.When looking at the relationship between shear stress and shear rate before yielding,a high-viscosity zone(called pseudoNewtonian viscosity) towards the apparent yield stress exists.After yielding,plastic viscosity(called Bingham viscosity) governs the flow.To examine the effect of grain size on the rheological characteristics of fine-grained sediments,clay-rich materials(from the Adriatic Sea,Italy; Cambridge Fjord,Canada; and the Mediterranean Sea,Spain),silt-rich debris flow materials(from La Valette,France) and silt-rich materials(iron tailings from Canada) were compared.Rheological characteristics were examined using a modified Bingham model.The materials examined,including the Canadian inorganic and sensitive clays,exhibit typical shear thinning behavior and strong thixotropy.In the relationships between the liquidity index and rheological values(viscosity and apparent yield stress),the effect of grain size on viscosity and yield stress is significant at a given liquidity index.The viscosity and yield stress of debris flow materials are higher than those of low-activity clays at the same liquid state.However the viscosity and yield stress of the tailings,which are mainly composed of silt-sized particles,are slightly lower than those of low-activity clays.

Estimation of the Yield Stress of Stainless Steel from the Vickers Hardness Taking Account of the Residual Stress

In this paper, a method that uses the Vickers hardness to estimate the yield stress of a metallic material with taking account of residual stress is proposed. Although the yield stress of bulk metal can be evaluated by a tensile test, it cannot be applied to local yield stress varied by surface modification methods, such as the peening technique which introduces high compressive residual stress at the surface. Therefore, to evaluate the local yield stress employing a relatively easy way, the Vickers hardness test was conducted in this paper. Since the Vickers hardness depends on both the residual stress and the yield stress, the relationship between the residual stress and the Vickers hardness was experimentally examined. It was concluded that the yield stress of the surface treated by several peening techniques can be estimated from the Vickers hardness once this has been corrected for residual stress.

Variation of yield stress of Daqing crude oil with pipelining history

The yield stress of waxy crude oil is a fundamental parameter in the calculation of pipelining technique and analysis of flow safety for the heated oil transported through pipeline.Daqing crude oil was studied and the variation of yield stress with shear history was explored through simulation experiment of pipelining.It is found that the effect of throughput variation or shear rate on yield stress is not obvious.With the decrease of final dynamic cooling temperature,the yield stress of waxy crude oil decreases,but there exists a little increase at the beginning.The prediction model of yield stress for waxy crude oil under the condition of shutdown is developed and it can be used to predict the yield stress of Daqing crude oil at certain heating temperature,final dynamic cooling temperature and measurement temperature.For the 139 groups of yield stress data of Daqing crude oil from the simulation experiment of pipelining,the result of prediction with this model shows that the average relative deviation between the yield stress measured and predicted is 30.27%,and the coefficient of correlation is 0.962 3.

Effects of PVA and PEG on pH Dependent Shear Yield Stress of Concentrated Alumina Suspensions

The pH dependence of the extrapolated shear yield stress for Alcoa A16 α-Al2O3 suspensions at the powder volume fraction of 0.27 with and without addition of both polyvinyl alcohol (PVA) and polyethylene glycol (PEG) each at fixed 0.18% of the powder mass was studied. Whith the polymer added, the full deflocculation of the suspension shifts from about pH=4 to around pH=1.5, at which the minimum value of shear yied stress is higher than that at pH=4. The addition of both PVA and PEG was found to prevent the filter cake from cracking.

Influence of Humidity on Yield Stress Determination by Slump Test of Slip-Prone Clayey Soils and Their Relation with the Chemical Properties

In this work, the yield stress evaluation as a function of water content for slip-prone clayey soils is studied in order to understand how yield stress decreases as water content increases, and their relation with the chemical properties. The clayey soil samples were taken from the region of Teziutlán-Puebla-Mexico. Yield stress was calculated using the slump test in cylindrical geometry. Results show three zones. The first one shows an exponential decrement on yield stress due to lower water content in accord with clayey soils with high content of illita, followed by a second region where yield stress decreases dramatically at a certain critical water concentration, and the third one where yield stress dependence is not well-defined since the clayey soil flow is seen. Finally, it is discussed how yield stress variation due to the water increment influences the landslide risk increment.