BASICITY ON ZEOLITE NAX AFTER WATER HANDLING STUDIED BY TPD OF ORGANIC ACID

In this paper the effect of ion-exchange simplified as water handling on basic zeolitewas studied.It was foond that the interaction between chemisorbed water and Na+-O2- couplewould increase the total number of basic sites, while weaken the intensity of each basic sites.Theprocess can be explained by the adsorb model of organic acid on NaX presented before.

Physicochemical regeneration of high silica zeolite Y used to clean-up water polluted with sulfonamide antibiotics

High silica zeolite Y has been positively evaluated to clean-up water polluted with sulfonamides, an antibiotic family which is known to be involved in the antibiotic resistance evolution. To define possible strategies for the exhausted zeolite regeneration,the efficacy of some chemico-physical treatments on the zeolite loaded with four different sulfonamides was evaluated. The evolution of photolysis, Fenton-like reaction, thermal treatments, and solvent extractions and the occurrence in the zeolite pores of organic residues eventually entrapped was elucidated by a combined thermogravimetric（TGA–DTA）, diffractometric（XRPD）, and spectroscopic（FT-IR） approach. The chemical processes were not able to remove the organic guest from zeolite pores and a limited transformation on embedded molecules was observed. On the contrary, both thermal treatment and solvent extraction succeeded in the regeneration of the zeolite loaded from deionized and natural fresh water. The recyclability of regenerated zeolite was evaluated over several adsorption/regeneration cycles, due to the treatment efficacy and its stability as well as the ability to regain the structural features of the unloaded material.

Contribution to the Modeling of a Solar Adsorption Refrigerator under the Climatic Conditions of Burkina Faso

This work concerns a dynamic modeling and a numerical simulation of the operation of an adsorption solar refrigeration system using the zeolite-water couple. For this, a mathematical model representing the evolution of heat and mass transfer at each component of the solar adsorption refrigerator has been developed. We have adopted the Dubinin-Astakhov model for the adsorption kinetics of the zeolite/water pair. This model allows to describe the phenomenon of adsorption and to calculate the rate of adsorbate (water) in the zeolite (adsorbent) as a function of the temperature and the pressure. The equations governing the operation of the solar adsorption refrigerator, deduced from the thermal and mass balances established at the collector adsorber, condenser and evaporator components, were solved by an implicit finite difference scheme and Gauss Seidel’s iterative method. We have validated the model established by applying it to the model of Allouhi et al. 2014. We analyzed the influence of the adsorbate/adsorbent couples, the solar flux, the ambient temperature on the adsorption and desorption process. The temperature profiles obtained representing the temperature evolution of the glass, the absorbent plate, the zeolite-water mixture, the condenser, the evaporator, as well as the pressure and the adsorbed mass allowed us to evaluate the performance of the solar adsorption refrigerator. SCOP is higher the higher the solar flux captured by the collector-adsorber.

Evaluation of Performance of Thermal and Electrical Hybrid Adsorption Chiller Cycles with Mechanical Booster Pumps

Large amounts of waste heat below 100oC from the industrial sector are re-leased into the atmosphere. It has been suggested that energy system efficiency can be increased with adsorption chillers. However, the cooling power and coefficient of performance (COP) of conventional adsorption chillers significantly decrease with the desorption temperature. In this paper, we proposed a mechanical booster pump (MBP)-assisted adsorption chiller cycle, and evaluated its performances. In the cycle, a MBP was incorporated into a zeolite-water-type adsorption chiller for facilitating water vapor transportation between an adsorber and an evaporator/condenser. We have experimentally studied the effect of the input electrical power of MBP on the performances of adsorption chiller cycle. It has been demonstrated that the heat input achieved by using MBP at the desorption temperature of 50oC was 1.6 times higher than that of without MBP at the desorption temperature of 60oC. And the increase of pump power was found to be effective in increasing the heat input. Therefore, it was confirmed that the operation range of desorption temperature, which can be generated by using the waste heat, was extended and the cooling power was increased directly by using MBP.