Zirconia-mullite-corundum composites were successfully prepared from fly ash,zircon and alumina powder by a reaction sintering process.The phase and microstructure evolutions of the composite synthesized at desired te...Zirconia-mullite-corundum composites were successfully prepared from fly ash,zircon and alumina powder by a reaction sintering process.The phase and microstructure evolutions of the composite synthesized at desired temperatures of 1 400,1 500 and 1 600°C for 4 h were characterized by X-ray diffractometry and scanning electronic microscopy,respectively.The influences of sintering temperature on shrinkage ratio,apparent porosity and bulk density of the synthesized composite were investigated.The formation process of the composites was discussed in detail.The results show that the zirconia-mullite-corundum composites with good sintering properties can be prepared at 1 600°C for 4 h.Zirconia particles can be homogeneously distributed in mullite matrix,and the zirconia particles are around 5μm.The formation process of zirconia-mullite-corundum composites consists of decomposition of zircon and mullitization process.展开更多
Decomposition kinetics of mullite and corundum in coal fly ash with highly alkaline solution was studied.The effects of the reaction temperature and reaction time on decomposition rates of mullite and corundum and alu...Decomposition kinetics of mullite and corundum in coal fly ash with highly alkaline solution was studied.The effects of the reaction temperature and reaction time on decomposition rates of mullite and corundum and alumina extraction efficiency were investigated.The results show that increasing reaction temperature and reaction time increases the decomposition rates of mullite and corundum and alumina extraction efficiency,with the decomposition temperature of mullite lower than that of corundum.After 90 min reaction at 220℃,more than 100 g alumina was extracted when recycling 1 L of alkaline solution.The decomposition processes of mullite and corundum corresponded with the shrinking unreacted core model,and the reaction rate was under chemical reaction control,with the activation energies of mullite and corundum being 67.46 and 161.82 kJ/mol,respectively.展开更多
Zirconia-mullite nano-composite ceramics were fabricated by in-situ controlled crystallization of Si-Al-Zr-O amorphous bulk, which were first treated at 900-1000 ℃ for nucleation, then treated at higher temperature f...Zirconia-mullite nano-composite ceramics were fabricated by in-situ controlled crystallization of Si-Al-Zr-O amorphous bulk, which were first treated at 900-1000 ℃ for nucleation, then treated at higher temperature for crystallization to obtain ultra-fine zirconia-mullite composite ceramics. The effects of treating temperature and ZrO2 addition on mechanical properties and microstructure were analyzed. A unique structure in which there are a lot of near equiaxed t-ZrO2 grains and fine yield-cracks has been developed in the samples with 15% zirconia addition treated at 1 150 ℃ . This specific microstructure is much more effective in toughening ceramics matrix and results in the best mechanical properties. The flexural strength and fracture toughness are 520 MPa and 5.13 MPa·m1/2, respectively. Either higher zirconia addition or higher crystallization temperature will produce large size rod-like ZrO2 and mullite grains, which are of negative effect on mechanical properties of this new composite ceramics.展开更多
Reaction sintered dense zirconia-mullite composites were prepared by isostatically pressing from zircon flour and reactive alumina with different proportions of TiO_2 and Cr_2O_3 additives. The pressed compacts were s...Reaction sintered dense zirconia-mullite composites were prepared by isostatically pressing from zircon flour and reactive alumina with different proportions of TiO_2 and Cr_2O_3 additives. The pressed compacts were sintered at different elevated temperatures with variable soaking times. Microstructures and phase development in the sintered compacts were analysed to assess the influence of the additives on the properties of the zirconia mullite composite.展开更多
Laboratory and industrial experiments were carried out to study the possibility of producing high purity purity mullite-corundumthermal insulating firebricks. The results show that by using industrial alumina. natuua...Laboratory and industrial experiments were carried out to study the possibility of producing high purity purity mullite-corundumthermal insulating firebricks. The results show that by using industrial alumina. natuual powder power, coal gangues and a small amountof additives. high purity mullite-corundum thermal insulating firebrieks can be produced The service. temperature of these brick can beup to 1780 with low. thermal conductivity' and good thermal shock resistance展开更多
Recently, ＂ Low Creep Ultra-high Temperature Corundum Mullite Kiln Fumature＂ developed by Sinosteel L1RR was listed in The National New Product Program in 2012 of The Ministry of Science and Technology of China.
In search of new mineral raw materials with industrial potential, we identified a deposit located in the southwest of Oujda (in the Northeastern Morocco). The physicochemical analyses indicate that the ore consists ma...In search of new mineral raw materials with industrial potential, we identified a deposit located in the southwest of Oujda (in the Northeastern Morocco). The physicochemical analyses indicate that the ore consists mainly of diaspore, topaz and quartz, and also secondary minerals. The presence of topaz in the ore is explained by hydrothermal action on the structure of diaspore. The investigation of structural transformations reveals complex reaction mechanisms that result in a mixture of corundum-mullite at 1200℃, which is of great industrial interest. Thus, the peculiarity of this ore is the presence of fluorine and secondary minerals.展开更多
In order to investigate the effect of zirconia corundum on the preparation of chrome corundum castables,samples were prepared using tabular corundum,white fused corundum,active alumina micropowder,chromium oxide micro...In order to investigate the effect of zirconia corundum on the preparation of chrome corundum castables,samples were prepared using tabular corundum,white fused corundum,active alumina micropowder,chromium oxide micropowder and fused ziconia corundum particles as the main raw materials,and pure calcium aluminate cement as the binder.The effects of the fused zirconia corundum particles addition(1-0.5 mm,0,4.5%,9%,and 18%,by mass)on the linear change rate,the apparent porosity,the cold modulus of rupture,and the thermal shock resistance of chrome corundum castables were studied,and the microstructure of the samples was analyzed.The results show that:(1)with the zirconia corundum addition increasing,the permanent linear change on heating of the samples gradually increases,the apparent porosity gradually increases,the cold modulus of rupture gradually decreases,and the thermal shock resistance gradually increases;(2)according to SEM,it can be found that the phase transformation of ZrO2 after heat treatment leads to a large number of microcracks in the material.On one hand,the cold modulus of rupture of the material is reduced;on the other hand,the thermal shock resistance of the material is improved.展开更多
基金Project(N100302002)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(20100471467)supported by the China Postdoctoral Science Foundation
文摘Zirconia-mullite-corundum composites were successfully prepared from fly ash,zircon and alumina powder by a reaction sintering process.The phase and microstructure evolutions of the composite synthesized at desired temperatures of 1 400,1 500 and 1 600°C for 4 h were characterized by X-ray diffractometry and scanning electronic microscopy,respectively.The influences of sintering temperature on shrinkage ratio,apparent porosity and bulk density of the synthesized composite were investigated.The formation process of the composites was discussed in detail.The results show that the zirconia-mullite-corundum composites with good sintering properties can be prepared at 1 600°C for 4 h.Zirconia particles can be homogeneously distributed in mullite matrix,and the zirconia particles are around 5μm.The formation process of zirconia-mullite-corundum composites consists of decomposition of zircon and mullitization process.
基金Project(2013CB632601)supported by the National Basic Research Program of China
文摘Decomposition kinetics of mullite and corundum in coal fly ash with highly alkaline solution was studied.The effects of the reaction temperature and reaction time on decomposition rates of mullite and corundum and alumina extraction efficiency were investigated.The results show that increasing reaction temperature and reaction time increases the decomposition rates of mullite and corundum and alumina extraction efficiency,with the decomposition temperature of mullite lower than that of corundum.After 90 min reaction at 220℃,more than 100 g alumina was extracted when recycling 1 L of alkaline solution.The decomposition processes of mullite and corundum corresponded with the shrinking unreacted core model,and the reaction rate was under chemical reaction control,with the activation energies of mullite and corundum being 67.46 and 161.82 kJ/mol,respectively.
基金Project supported by Foundation for Innovative Research Groups of ChinaProject(50634060) supported by the National Natural Science Founation of China
文摘Zirconia-mullite nano-composite ceramics were fabricated by in-situ controlled crystallization of Si-Al-Zr-O amorphous bulk, which were first treated at 900-1000 ℃ for nucleation, then treated at higher temperature for crystallization to obtain ultra-fine zirconia-mullite composite ceramics. The effects of treating temperature and ZrO2 addition on mechanical properties and microstructure were analyzed. A unique structure in which there are a lot of near equiaxed t-ZrO2 grains and fine yield-cracks has been developed in the samples with 15% zirconia addition treated at 1 150 ℃ . This specific microstructure is much more effective in toughening ceramics matrix and results in the best mechanical properties. The flexural strength and fracture toughness are 520 MPa and 5.13 MPa·m1/2, respectively. Either higher zirconia addition or higher crystallization temperature will produce large size rod-like ZrO2 and mullite grains, which are of negative effect on mechanical properties of this new composite ceramics.
文摘Reaction sintered dense zirconia-mullite composites were prepared by isostatically pressing from zircon flour and reactive alumina with different proportions of TiO_2 and Cr_2O_3 additives. The pressed compacts were sintered at different elevated temperatures with variable soaking times. Microstructures and phase development in the sintered compacts were analysed to assess the influence of the additives on the properties of the zirconia mullite composite.
文摘Laboratory and industrial experiments were carried out to study the possibility of producing high purity purity mullite-corundumthermal insulating firebricks. The results show that by using industrial alumina. natuual powder power, coal gangues and a small amountof additives. high purity mullite-corundum thermal insulating firebrieks can be produced The service. temperature of these brick can beup to 1780 with low. thermal conductivity' and good thermal shock resistance
文摘Recently, ＂ Low Creep Ultra-high Temperature Corundum Mullite Kiln Fumature＂ developed by Sinosteel L1RR was listed in The National New Product Program in 2012 of The Ministry of Science and Technology of China.
文摘In search of new mineral raw materials with industrial potential, we identified a deposit located in the southwest of Oujda (in the Northeastern Morocco). The physicochemical analyses indicate that the ore consists mainly of diaspore, topaz and quartz, and also secondary minerals. The presence of topaz in the ore is explained by hydrothermal action on the structure of diaspore. The investigation of structural transformations reveals complex reaction mechanisms that result in a mixture of corundum-mullite at 1200℃, which is of great industrial interest. Thus, the peculiarity of this ore is the presence of fluorine and secondary minerals.
文摘In order to investigate the effect of zirconia corundum on the preparation of chrome corundum castables,samples were prepared using tabular corundum,white fused corundum,active alumina micropowder,chromium oxide micropowder and fused ziconia corundum particles as the main raw materials,and pure calcium aluminate cement as the binder.The effects of the fused zirconia corundum particles addition(1-0.5 mm,0,4.5%,9%,and 18%,by mass)on the linear change rate,the apparent porosity,the cold modulus of rupture,and the thermal shock resistance of chrome corundum castables were studied,and the microstructure of the samples was analyzed.The results show that:(1)with the zirconia corundum addition increasing,the permanent linear change on heating of the samples gradually increases,the apparent porosity gradually increases,the cold modulus of rupture gradually decreases,and the thermal shock resistance gradually increases;(2)according to SEM,it can be found that the phase transformation of ZrO2 after heat treatment leads to a large number of microcracks in the material.On one hand,the cold modulus of rupture of the material is reduced;on the other hand,the thermal shock resistance of the material is improved.
