针对传统铝合金在激光粉末床融合技术(Laser Powder Bed Fusion,LPBF)中的高裂纹敏感性,总结了近年来通过微合金化方法改善LPBF铝合金成型性及力学性能的研究进展。综述了微合金元素在成型过程中的作用机理,重点讨论了Er、Zr元素对微观...针对传统铝合金在激光粉末床融合技术(Laser Powder Bed Fusion,LPBF)中的高裂纹敏感性,总结了近年来通过微合金化方法改善LPBF铝合金成型性及力学性能的研究进展。综述了微合金元素在成型过程中的作用机理,重点讨论了Er、Zr元素对微观组织的调控即晶粒细化,总结了LPBF微合金化铝合金的成型工艺研究,分析了微合金改性后热处理工艺诱导第二相弥散析出及对应力学性能的研究。对未来LPBF铝合金微合金化研究提出展望,开发新的微合金改性铝合金并探索适合工业生产的热处理工艺,获得低成本、高强度的LPBF铝合金。展开更多
The paper presents comparative kinetic characteristics of the decomposition of 2,4-dichlorophenol in a dielectric barrier discharge and a combined plasma-catalytic process. Vermiculite containing 5% zirconium was used...The paper presents comparative kinetic characteristics of the decomposition of 2,4-dichlorophenol in a dielectric barrier discharge and a combined plasma-catalytic process. Vermiculite containing 5% zirconium was used as a catalyst. The destruction processes of 2,4-DCP proceed efficiently, the degree of decomposition increases in the combined plasma-catalytic process by a factor of 1.33 and reaches 80%. The experimental results were processed according to the first-order kinetic law (R<sup>2</sup> > 0.97), according to which the effective constants (0.36 ± 0.04) and (0.51 ± 0.03) s<sup>-1</sup> and the decomposition rates of 2,4-DCP (106 and 123 μmol/l·s) when treating model solutions without a catalyst and with vermiculite + Zr 5%, respectively, and the energy costs are 0.012 and 0.017 molecules/100eV. The main decomposition products present in the solution have been determined to be carboxylic acids, aldehydes, the contribution of which does not exceed 2%, as well as chloride ions, and in the gas phase they are carbon dioxide and molecular chlorine (the share of which does not exceed 1.5% of total chlorine content in the system).展开更多
选用Zr-4、N18和N36锆合金,分别采用不同的热处理工艺获得析出相种类、尺寸和数量不同的样品,研究其在360℃/18.6 MPa/0.01 mol/L Li OH水溶液中的腐蚀吸氢行为。结果表明:吸氢与耐腐蚀性能之间并没有直接的对应关系,而是与析出相的种...选用Zr-4、N18和N36锆合金,分别采用不同的热处理工艺获得析出相种类、尺寸和数量不同的样品,研究其在360℃/18.6 MPa/0.01 mol/L Li OH水溶液中的腐蚀吸氢行为。结果表明:吸氢与耐腐蚀性能之间并没有直接的对应关系,而是与析出相的种类、尺寸和数量有关。含Cr的N18合金和Zr-4合金的吸氢分数高于不含Cr的N36合金,热处理对Zr-4合金腐蚀吸氢行为的影响比N18和N36合金的大。用锆合金的腐蚀吸氢行为与析出相可逆吸放氢能力相关的吸氢模型可合理解释本实验结果。展开更多
文摘针对传统铝合金在激光粉末床融合技术(Laser Powder Bed Fusion,LPBF)中的高裂纹敏感性,总结了近年来通过微合金化方法改善LPBF铝合金成型性及力学性能的研究进展。综述了微合金元素在成型过程中的作用机理,重点讨论了Er、Zr元素对微观组织的调控即晶粒细化,总结了LPBF微合金化铝合金的成型工艺研究,分析了微合金改性后热处理工艺诱导第二相弥散析出及对应力学性能的研究。对未来LPBF铝合金微合金化研究提出展望,开发新的微合金改性铝合金并探索适合工业生产的热处理工艺,获得低成本、高强度的LPBF铝合金。
文摘The paper presents comparative kinetic characteristics of the decomposition of 2,4-dichlorophenol in a dielectric barrier discharge and a combined plasma-catalytic process. Vermiculite containing 5% zirconium was used as a catalyst. The destruction processes of 2,4-DCP proceed efficiently, the degree of decomposition increases in the combined plasma-catalytic process by a factor of 1.33 and reaches 80%. The experimental results were processed according to the first-order kinetic law (R<sup>2</sup> > 0.97), according to which the effective constants (0.36 ± 0.04) and (0.51 ± 0.03) s<sup>-1</sup> and the decomposition rates of 2,4-DCP (106 and 123 μmol/l·s) when treating model solutions without a catalyst and with vermiculite + Zr 5%, respectively, and the energy costs are 0.012 and 0.017 molecules/100eV. The main decomposition products present in the solution have been determined to be carboxylic acids, aldehydes, the contribution of which does not exceed 2%, as well as chloride ions, and in the gas phase they are carbon dioxide and molecular chlorine (the share of which does not exceed 1.5% of total chlorine content in the system).
文摘选用Zr-4、N18和N36锆合金,分别采用不同的热处理工艺获得析出相种类、尺寸和数量不同的样品,研究其在360℃/18.6 MPa/0.01 mol/L Li OH水溶液中的腐蚀吸氢行为。结果表明:吸氢与耐腐蚀性能之间并没有直接的对应关系,而是与析出相的种类、尺寸和数量有关。含Cr的N18合金和Zr-4合金的吸氢分数高于不含Cr的N36合金,热处理对Zr-4合金腐蚀吸氢行为的影响比N18和N36合金的大。用锆合金的腐蚀吸氢行为与析出相可逆吸放氢能力相关的吸氢模型可合理解释本实验结果。
