An efficient, convenient and green method has been introduced for the preparation of 14-aryl（alkyl）-14H-dibenzo[a,j]xanthene and 1,8-dioxooctahydroxanthene derivatives by the reaction of aldehydes with 2-naphthol an...An efficient, convenient and green method has been introduced for the preparation of 14-aryl（alkyl）-14H-dibenzo[a,j]xanthene and 1,8-dioxooctahydroxanthene derivatives by the reaction of aldehydes with 2-naphthol and 5,5-dimethyl-1,3-cyclohexanedione, respectively, in the presence of ZrO（OTf）2 as a reusable catalyst under solvent-free conditions. In addition, very short reaction times, excellent yields, straightforward procedure, and relatively non-toxicity of the catalyst are other noteworthy advantages of the present method.展开更多
基金the Center of Excellence of Chemistry and Research Council of University of Isfahan for financial support of this work
文摘An efficient, convenient and green method has been introduced for the preparation of 14-aryl（alkyl）-14H-dibenzo[a,j]xanthene and 1,8-dioxooctahydroxanthene derivatives by the reaction of aldehydes with 2-naphthol and 5,5-dimethyl-1,3-cyclohexanedione, respectively, in the presence of ZrO（OTf）2 as a reusable catalyst under solvent-free conditions. In addition, very short reaction times, excellent yields, straightforward procedure, and relatively non-toxicity of the catalyst are other noteworthy advantages of the present method.
