Microchannel reactors are widely used in different fields due to their intensive micromixing and, thus, high masstransfer efficiency. In this work, a single countercurrent-flow microchannel reactor(S-CFMCR) at the siz...Microchannel reactors are widely used in different fields due to their intensive micromixing and, thus, high masstransfer efficiency. In this work, a single countercurrent-flow microchannel reactor(S-CFMCR) at the size of ~1 mm was developed by steel micro-capillary and laser drilling technology. Utilizing the Villermaux/Dushman parallel competing reaction, numerical and experimental studies were carried out to investigate the micromixing performance(expressed as the segregation index XS) of liquids inside S-CFMCR at the low flow velocity regime.The effects of various operating conditions and design parameters of S-CFMCR, e.g., inlet Reynolds number(Re),volumetric flow ratio(R), inlet diameter(d) and outlet length(L), on the quality of micromixing were studied qualitatively. It was found that the micromixing efficiency was enhanced with increasing Re, but weakened with the increase of R. Moreover, d and L also have a significant influence on micromixing. CFD results were in good agreement with experimental data. In addition, the visualization of velocity magnitude, turbulent kinetic energy and concentration distributions of various ions inside S-CFMCR was illustrated as well. Based on the incorporation model, the estimated minimum micromixing time tmof S-CFMCR is ~2 × 10-4s.展开更多
Process characteristics of CO2 absorption using aqueous monoethanolamine (MEA) in a microchannel reactor were investigated experimentally in this work. A T-type rectangular microchannel with a hydraulic diameter of ...Process characteristics of CO2 absorption using aqueous monoethanolamine (MEA) in a microchannel reactor were investigated experimentally in this work. A T-type rectangular microchannel with a hydraulic diameter of 408μm was used. Operating parameters, i.e. temperature, pressure and molar ratio of MEA to CO2 were studied. Under 3 MPa pressure, the mole fraction of CO2 in gaslphase could decrease from 32.3% to 300×10-6 at least when gas hourly space velocity ranged from 14400 to 68600 h- and molar ratio of MEA to CO2 was kept at 2.2. In particular, the effects of temperature on CO2 absorption flux, mass transfer driving force, gas-liquid contact time and en- hancement factor were analyzed in detail and found that mass transfer enhancement by chemical reaction was a crucial factor for the orocess of CO9 absorotion.展开更多
Microchannel reactors are commonly used in micro-chemical technology. The performance of microreactors is greatly affected by the velocity field in the microchannel. The flow field is disturbed by the cylindrical etch...Microchannel reactors are commonly used in micro-chemical technology. The performance of microreactors is greatly affected by the velocity field in the microchannel. The flow field is disturbed by the cylindrical etch holes caused by air dust on the microchannel surface during its processing procedure. In this approach, a two-dimensional computational fluid dynamics (CFD) model is put forward to study the effect of etch holes on flow field. The influenced area of single or two concave etch holes is studied for the case of laminar flow. The hole diameter, the Reynolds number and the distance between the center of holes are found to have influences on the flow field. Numerical results indicate that the effects of etch hole on the flow field should be evaluated and the way of choosing the economic class of cleanroom for microreactor manufacture is presented.展开更多
The present paper is basically a synthesis resulting from incorporating Kerr spinning black hole geometry into E-infinity topology, then letting the result bares on the vacuum zero point Casimir effect as well as the ...The present paper is basically a synthesis resulting from incorporating Kerr spinning black hole geometry into E-infinity topology, then letting the result bares on the vacuum zero point Casimir effect as well as the cosmic dark energy and dark matter density. In E-infinity theory a quantum particle is represented by a Hausdorff dimension Φ where Φ =2/(√5+1) . The quantum wave on the other hand is represented by Φ2 . To be wave and a particle simultaneously intersection theory leads us to?(Φ) (Φ)2= Φ3 which will be shown here to be twice the value of the famous Casimir force of the vacuum for a massless scalar field. Thus in the present work a basically topological interpretation of the Casimir effect is given as a natural intrinsic property of the geometrical topological structure of the quantum-Cantorian micro spacetime. This new interpretation compliments the earlier conventional interpretation as vacuum fluctuation or as a Schwinger source and links the Casimir energy to the so called missing dark energy density of the cosmos. From the view point of the present work Casimir pressure is a local effect acting on the Casimir plates constituting the local boundary condition while dark energy is nothing but the global combined effect of infinitely many quantum waves acting on the Möbius-like boundary of the holographic boundary of the entire universe. Since this higher dimensional Möbius-like boundary is one sided, there is no outside to balance the internal collective Casimir pressure which then manifests itself as the force behind cosmic expansion, that is to say, dark energy. Thus analogous to the exact irrational value of ordinary energy density of spacetime E(O)=(Φ5/2) mc2 we now have P (Casimir) = (Φ3/2)(ch/d2) where c is the speed of light, m is the mass, h is the Planck constant and d is the plate separation. In addition the new emerging geometry combined with the topology of E-infinity theory leads directly to identifying dark matter with the quasi matter of the ergosphere. As a direct consequence of this new insight E=mc2 which can be written as E = E (O) + E (D)?where the exact rational approximation is E (O)=mc2/22 is?the ordinary energy density of the cosmos and the exact rational approximation E (D)=mc2/(21/22) is the corresponding dark energy which could be subdivided once more albeit truly approximately into E(D)=mc2/(5/22)?+mc2/(16/22)??where 5 is the Kaluza Klein spacetime dimension, 16 are the bosonic extra dimensions of Heterotic superstrings and 5/22 □?22% is approximately the density of the dark matter-like energy of the ergosphere of the Kerr geometry. As for the actual design of our nano reactor, this is closely related to branching clusters of polymer, frequently called lattice animals. In other words we will have Casimir spheres instead of Casimir plates and these spheres will be basically nano particles modelling lattice animals. Here D=?4 will be regarded as spacetime dimensionality while D=6 of percolations are the compactified super string dimensions and D=8 is the dimension of a corresponding super space.展开更多
A phase one design of a new free energy nano reactor is presented. The design is based on a basically topological interpretation of the Casimir effect as a natural intrinsic property of the geometrical topological str...A phase one design of a new free energy nano reactor is presented. The design is based on a basically topological interpretation of the Casimir effect as a natural intrinsic property of the geometrical topological structure of the quantum-Cantorian micro spacetime. In particular we view dark energy, Hawking negative energy, Unruh temperature and zero point vacuum energy as being different sides of the same multi-dimensional coin. This new interpretation compliments the earlier conventional interpretation as vacuum fluctuation or as a Schwinger source and links the Casimir energy to the so-called missing dark energy density of the cosmos. We start with a general outline of the theoretical principle and basic design concepts of a proposed Casimir dark energy nano reactor. In a nutshell the theory and consequently the actual design depend crucially upon the equivalence between the dark energy density of the cosmos and the faint local Casimir effect produced by two sides boundary condition quantum waves. This Casimir effect is then colossally amplified as a one internal quantum wave representing a Hartle-Hawking state vector of the universe pushing from the inside against the boundary of the universe with nothing balancing it from the non-existent outside. This strange situation becomes completely natural and logical when we remember that the boundary of the universe is a one sided Möbius like manifold. In view of the present theory, this is essentially what leads to the observed accelerated expansion of the cosmos. As in any reactor, the basic principle in the present design is to produce a gradient so that the excess energy on one side flows to the other side. Thus in principle we will restructure the local topology of space using material nanoscience technology to create an artificial local high dimensionality with a Dvoretzky theorem like 96 percent volume measure concentration. Without going into the intricate nonlinear dynamics and technological detail, it is fair to say that this would lead us to pure, clean, free energy obtained directly from the topology of spacetime via an artificial singularity. Needless to say, the entire design is based completely on the theory of quantum wave dark energy proposed by the present author for the first time in 2011 in a conference held in the Bibliotheca Alexandrina, Egypt and a little later in Shanghai, Republic of China. The quintessence of the present theory is easily explained as the Φ3 intrinsic Casimir topological energy where Φ=?(√5-1)/2 is produced from the zero set Φ of the quantum particle when we extract the empty set quantum wave Φ2 from it and find Φ-Φ2=Φ3 by restructuring space via conducting but uncharged plates similar to that of the classical Casimir experiments. Our proposed preliminary design of this Casimir-spacetime artificial singularity reactor follows in a natural way from the above.展开更多
Traditional preparation of magnetic microcapsules involves cumbersome processes and often results in irregular-shaped products. Due to the stable laminar flow of reaction solution and the moderate reaction conditions,...Traditional preparation of magnetic microcapsules involves cumbersome processes and often results in irregular-shaped products. Due to the stable laminar flow of reaction solution and the moderate reaction conditions, the T-shaped microchannel (T-MC) reactor is supposed to yield microcapsules with regular shape. In this paper, magnetic particles of ferroferric oxide modified by oleic acid (OA-Fe3O4) and dispersed in tetrachloroethylene were used as core material. Polymethyl methacrylate (PMMA) was used as shell material. Magnetic microcapsules were prepared by using a T-MC reactor. Factors that influenced the encapsulated reaction were investigated in details, which included the velocity ratio of aqueous phase to oil phase, the length and the inner diameter of the microchannel. The morphology, composition, and magnetic responsiveness of the magnetic microcapsules were analyzed and characterized by SEM, FTIR, XRD, TGA, and vibrating sample magnetometer (VSM). The results confirmed that magnetic microcapsules prepared by T-MC reactor were regular in shape.展开更多
Recently,there has been considerable interest in the use of microchannel reactors for hydrometallurgy of rare earths(REs).Here,a novel integrated microchannel reactor based on the hollow-strut SiC foam material is pre...Recently,there has been considerable interest in the use of microchannel reactors for hydrometallurgy of rare earths(REs).Here,a novel integrated microchannel reactor based on the hollow-strut SiC foam material is presented and demonstrated to extract Ce^(3+)and Pr^(3+)using 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester(P507)as the extractant.The typical three-dimensional reticulated structure of the hollow-strut SiC foam was characterized by scanning electron microscopy and X-ray micro computed tomography.Since the reactor’s structure plays a key role in fluid mixing and mass diffusion during the extraction process,the structure-performance relationship of the foam was studied by extraction experiments combined with numerical simulations.Using the foam with the optimal structure,the influence of the flow rate Q_(0) of the two liquid phases on the extraction efficiency η and overall volume mass transfer coefficient KLa was discussed.For both RE ions,with increasing Q_(0),η decreases while KLa increases.For the total flow rate of the two phases of 4 ml·min^(-1),the η values of Pr^(3+)and Ce^(3+)reached 98.7%and 97.0%,respectively.For the total flow rate of 36 ml·min^(-1) which was much higher than that of many other microchannel reactors reported in the literatures,the η values of Pr^(3+)and Ce^(3+)still reached 92.2%and 86.9%,respectively,and the KLa values of Pr^(3+)and Ce^(3+)were 0.198 and 0.161 s^(-1),respectively,similar to the high values reported for other microchannel reactors studied in previous work.These findings indicate that the hollow-strut SiC foam microchannel reactor is suitable for use in REs extraction.展开更多
Acylation of 2-methylnaphthalene(2-MN) is a very important reaction in organic synthesis,and the effiency of the continuous reactor is more than one of the batch reactor.Considering that the Friedel–Crafts acylation ...Acylation of 2-methylnaphthalene(2-MN) is a very important reaction in organic synthesis,and the effiency of the continuous reactor is more than one of the batch reactor.Considering that the Friedel–Crafts acylation is a rapid exothermic reaction,in this study,we perform the acylation of 2-MN in a stainless steel microchannel flow reactor,which is characterized by high mass and heat transfer rates.The effect of reactant ratio,mixing temperature,reaction temperature,and reaction time on product yield and selectivity were investigated.Under the optimal conditions,2-methyl-6-propionylnaphthalene(2,6-MPN) was obtained in 85.8% yield with 87.5% selectivity.Compared with the conventional batch system,the continuous flow microchannel reactor provides a more efficient method for the synthesis of 2,6-MPN.展开更多
Building on the various manifestations of the forces latent in the quantum vacuum of spacetime such as Hawking’s radiation and Unruh temperature, we resolve a major paradox connected to an immensely important proposa...Building on the various manifestations of the forces latent in the quantum vacuum of spacetime such as Hawking’s radiation and Unruh temperature, we resolve a major paradox connected to an immensely important proposal by NASA scientists for constructing a practically fuelless spacecraft. In a nutshell, preliminary laboratory work shows that NASA’s electromagnetic drive project is viable and several experiments and measurements show it is real. Yet the proposal violates a fundamental principle of classical mechanics, namely Newton’s third law. The resolution of this paradox is quite straight forward in principle. It is simply the case that although the proposal seems to be based on classical mechanics and classical thinking it is only superficially so. Deep at the roots, the EM drive proposal of NASA is not classical physics but rather based on the vacuum forces of quantum cosmology and the theory of dark energy density of the universe. In fact the proposal is deeply linked to Hawking’s radiation and Unruh temperature, which is explained in some detail in the main body of the present short paper within the frame work of E-infinity Cantorian spacetime theory and D. Gross’ Heterotic superstring theory. In short the quintessence of our explanation is to regard the EM drive as a quasi electromagnetic cavity with an effective event horizon akin to that of a Hawking black hole emitting radiation causing ultimately the needed thrust to push the spacecraft forwards. In addition and by invoking fractal spacetime self similarity we show that a spacecraft will be subject to another cosmic thrust on the large scale of the entire cosmos.展开更多
In this study, a simple and effective technique for establishing an external mass transfer model in a recirculated packed-bed batch reactor (RPBBR) with an immobilized lipase enzyme and Jatropha oil system is presente...In this study, a simple and effective technique for establishing an external mass transfer model in a recirculated packed-bed batch reactor (RPBBR) with an immobilized lipase enzyme and Jatropha oil system is presented. The external mass transfer effect can be represented with a model in the form of Colburn factor JD = K Re-(1–n). The value of K and n were derived from experimental data at different mass flow rates.The experiment shows an average increment of 1.51% FFA for calcium alginate and 1.62% FFA for carrageenan after the hydrolysis took place. Based on different biopolymer material used in immobilized beads, JD = 1.674 Re-0.4 for calcium alginate and JD = 1.881 Re-0.3 for k-carrageenan were found to be adequate to predict the experimental data for external mass transfer in the reactor in the Reynolds number range of 0.2 to 1.2. The purposed model can be used for the design of industrial bioreactor and scale up. Besides, the external mass transfer coefficients for the hydrolysis of Jatropha oil reaction and the entrapment efficiency for the two biopolymer materials used were also investigated.展开更多
This article proposes to associate a Deuterium-Deuterium (D-D) fusion reactor with a PWR (fission Pressurized Water Reactor) in a hybrid reactor. Even if the mechanical gain (Q factor) of the D-D fusion reactor is bel...This article proposes to associate a Deuterium-Deuterium (D-D) fusion reactor with a PWR (fission Pressurized Water Reactor) in a hybrid reactor. Even if the mechanical gain (Q factor) of the D-D fusion reactor is below the unity and consequently consumes more energy than it supplies, due to the high energy amplification factor of the PWR fission reactor, the global yield is widely superior to 1. As the energy supplied by the fusion reactor is relatively low and as the neutrons supplied are mainly issued from D-D fusions (at 2.45 MeV), the problems of heat flux and neutrons damage connected with materials, as with D-T fusion reactors are reduced. Of course, there is no need to produce Tritium with this D-D fusion reactor. This type of reactor is able to incinerate any mixture of natural Uranium, natural Thorium and depleted Uranium (waste issued from enrichment plants), with natural Thorium being the best choice. No enriched fuel is needed. So, this type of reactor could constitute a source of energy for several thousands of years because it is about 90 more efficient than a standard fission reactor, such as a PWR or a Candu one, by extracting almost completely the energy from the fertile materials U238 and Th232. For the fission part, PWR technology is mature. For the fusion part, it is based on a reasonable hypothesis done on present Stellarators projects. The working of this reactor is continuous, 24 hours a day. In this paper, it will be targeted a reactor able to provide net electric power of about 1400 MWe, as a big fission power plant.展开更多
The Fischer-Tropsch synthesis is an important step in coal liquefaction,natural gas liquefaction,and biomass liquefaction.In recent years,the use of microchannel reactors for Fischer-Tropsch synthesis has received wid...The Fischer-Tropsch synthesis is an important step in coal liquefaction,natural gas liquefaction,and biomass liquefaction.In recent years,the use of microchannel reactors for Fischer-Tropsch synthesis has received widespread attention.Since thermocouples and other sensors cannot be placed easily in a microchannel reactor,it is very vital to establish a model to provide calculated results highly compatible with the experimental data.This paper mainly introduces the establishment and solution of microchannel reactor models for Fischer-Tropsch synthesis.General mass transfer differential equations,heat transfer differential equations and related parameters(such as reaction rates,dispersion coefficient,and convective heat transfer coefficient)are listed.To solve the models,numerical solutions,such as the CFD simulation methods and the programming methods,are reviewed.It is recommended that a more accurate solution strategy is the combination of CFD simulation and programming methods.展开更多
In the past decade or so,AI(artificial intelligence)technology has been growing with such a mesmerizing speed that today its presence in almost any industry that deals with any huge sheer volume of data is taking adva...In the past decade or so,AI(artificial intelligence)technology has been growing with such a mesmerizing speed that today its presence in almost any industry that deals with any huge sheer volume of data is taking advantage of AI by integrating it into their day-to-day operation.Meanwhile,seven billion people worldwide shape the world’s energy system and directly impact the fundamental drivers of energy,both renewable and non-renewable sources,to meet the demand for electricity from them.These energy sources can be reached from nature such as solar,wind,etc.,and human-made such as NPPs(nuclear power plants)in the form of either fission as an old technology since the Manhattan project and in the near future as fusion in the form of magnetic or inertial confinements.Meanwhile,AI controlling nuclear reactors are about to happen.The basic idea is to apply AI with its two subset components as ML(machine learning),and DL(deep learning)techniques to go through the mountains of data that come from a reactor,spot patterns in it,and calling them to the unit’s human attention operators is not invadable either.Designers of such nuclear reactors will combine simulation and real-world data,comparing scenarios from each to develop“confidence[in]what they can predict and what is the range of uncertainty of their prediction”.Adding that,in the end,the operator will make the final decisions in order to keep these power plants safe while they are in operation and how to secure them against cyber-attack natural or human-made disasters.In this short communication article,we would like to see how we can prove some of these concepts;then a NPP manufacturer can pick it up and use it in their designs of a new generation of these reactors.展开更多
In this paper we outline a non-perturbative quantum relativity theory. Subsequently an actual design of a nanotech energy reactor is based on spacetime vacuum fluctuation of the said quantum relativity theory. Using a...In this paper we outline a non-perturbative quantum relativity theory. Subsequently an actual design of a nanotech energy reactor is based on spacetime vacuum fluctuation of the said quantum relativity theory. Using a compact heap of Fullerene nano particle moduli of a nano matrix device we propose that by maximizing the Casimir forces between these particles as a desirable effect, we can achieve a gradual rather than a sudden implosion pressure. We expect that this will result in a mini holographic universe from which energy can be extracted in a way to constitute a nano energy reactor and function effectively on a hybrid principle somewhere between a Casimir effect and a cold fusion process based on the fusion algebra of a highly structured golden ring quantum field theory. The present theory depends upon many concepts and results, in particular J. Schwinger’s source theory as well as the modern theory of quantum sets, nonlinear dynamics, chaos and chaotic fractals.展开更多
The most widely accepted model of Solar System formation, known as the Nebular hypothesis, does not solve the Angular Momentum problem—why is the orbital momentum of Jupiter larger than rotational momentum of the Sun...The most widely accepted model of Solar System formation, known as the Nebular hypothesis, does not solve the Angular Momentum problem—why is the orbital momentum of Jupiter larger than rotational momentum of the Sun? The present manuscript introduces a Rotational Fission model of creation and evolution of Macrostructures of the World (Superclusters, Galaxies, Extrasolar Systems), based on Overspinning Cores of the World’s Macroobjects, and the Law of Conservation of Angular Momentum. The Hypersphere World-Universe model is the only cosmological model in existence that is consistent with this Fundamental Law.展开更多
Fast reactors used lead-bismuth eutectic (LBE) and lead as coolants possess very high level of inherent self-protection and passive safety against severe accident. So, population radiophobia can be overcome. That type...Fast reactors used lead-bismuth eutectic (LBE) and lead as coolants possess very high level of inherent self-protection and passive safety against severe accident. So, population radiophobia can be overcome. That type of reactors can be simultaneously more safely and more cheaply. As all other coolants, LBE and lead coolant (LC) possess the certain virtues and shortcomings. The presented report includes the comparative analysis of characteristic properties of those coolants, their impact on reactor safety, reliability and operating characteristics. The conclusion is made about promising usage of FRs with these coolants in future NP after the experience in operating of the prototypes of such reactors has been obtained.展开更多
A new type of commercial reactor is first built up in China.This paper briefly describesits performances,working foundamentals and various possible uses.The reactor uses urani-um-zirconium hydride as fuel element and ...A new type of commercial reactor is first built up in China.This paper briefly describesits performances,working foundamentals and various possible uses.The reactor uses urani-um-zirconium hydride as fuel element and has a large prompt negative temperature coefficientof reactivity,featuring inherent safety and a fairly high pulsed-power capacity.展开更多
This article explores the transformative potential of nanotechnology and MMs(memory metals)in enhancing the design and operation of nuclear reactors,encompassing both fission and fusion technologies.Nanotechnology,wit...This article explores the transformative potential of nanotechnology and MMs(memory metals)in enhancing the design and operation of nuclear reactors,encompassing both fission and fusion technologies.Nanotechnology,with its ability to engineer materials at the atomic scale,offers significant improvements in reactor safety,efficiency,and longevity.In fission reactors,nanomaterials enhance fuel rod integrity,optimize thermal management,and improve in-core instrumentation.Fusion reactors benefit from nanostructured materials that bolster containment and heat dissipation,addressing critical challenges in sustaining fusion reactions.The integration of SMAs(shape memory alloys),or MMs,further amplifies these advancements.These materials,characterized by their ability to revert to a pre-defined shape under thermal conditions,provide self-healing capabilities,adaptive structural components,and enhanced magnetic confinement.The synergy between nanotechnology and MMs represents a paradigm shift in nuclear reactor technology,promising a future of cleaner,more efficient,and safer nuclear energy production.This innovative approach positions the nuclear industry to meet the growing global energy demand while addressing environmental and safety concerns.展开更多
基金Supported by the National Natural Science Foundation of China(21576012)the National Key Research and Development Program of China(2017YFB0307202)
文摘Microchannel reactors are widely used in different fields due to their intensive micromixing and, thus, high masstransfer efficiency. In this work, a single countercurrent-flow microchannel reactor(S-CFMCR) at the size of ~1 mm was developed by steel micro-capillary and laser drilling technology. Utilizing the Villermaux/Dushman parallel competing reaction, numerical and experimental studies were carried out to investigate the micromixing performance(expressed as the segregation index XS) of liquids inside S-CFMCR at the low flow velocity regime.The effects of various operating conditions and design parameters of S-CFMCR, e.g., inlet Reynolds number(Re),volumetric flow ratio(R), inlet diameter(d) and outlet length(L), on the quality of micromixing were studied qualitatively. It was found that the micromixing efficiency was enhanced with increasing Re, but weakened with the increase of R. Moreover, d and L also have a significant influence on micromixing. CFD results were in good agreement with experimental data. In addition, the visualization of velocity magnitude, turbulent kinetic energy and concentration distributions of various ions inside S-CFMCR was illustrated as well. Based on the incorporation model, the estimated minimum micromixing time tmof S-CFMCR is ~2 × 10-4s.
基金Supported by the National Natural Science Foundation of China (20911130358)the Ministry of Science and Technology of China (2009CB219903)the Fund of Dalian Institute of Chemical Physics,CAS (K2009D01)
文摘Process characteristics of CO2 absorption using aqueous monoethanolamine (MEA) in a microchannel reactor were investigated experimentally in this work. A T-type rectangular microchannel with a hydraulic diameter of 408μm was used. Operating parameters, i.e. temperature, pressure and molar ratio of MEA to CO2 were studied. Under 3 MPa pressure, the mole fraction of CO2 in gaslphase could decrease from 32.3% to 300×10-6 at least when gas hourly space velocity ranged from 14400 to 68600 h- and molar ratio of MEA to CO2 was kept at 2.2. In particular, the effects of temperature on CO2 absorption flux, mass transfer driving force, gas-liquid contact time and en- hancement factor were analyzed in detail and found that mass transfer enhancement by chemical reaction was a crucial factor for the orocess of CO9 absorotion.
基金Supported by the National Natural Science Foundation of China (20676093).
文摘Microchannel reactors are commonly used in micro-chemical technology. The performance of microreactors is greatly affected by the velocity field in the microchannel. The flow field is disturbed by the cylindrical etch holes caused by air dust on the microchannel surface during its processing procedure. In this approach, a two-dimensional computational fluid dynamics (CFD) model is put forward to study the effect of etch holes on flow field. The influenced area of single or two concave etch holes is studied for the case of laminar flow. The hole diameter, the Reynolds number and the distance between the center of holes are found to have influences on the flow field. Numerical results indicate that the effects of etch hole on the flow field should be evaluated and the way of choosing the economic class of cleanroom for microreactor manufacture is presented.
文摘The present paper is basically a synthesis resulting from incorporating Kerr spinning black hole geometry into E-infinity topology, then letting the result bares on the vacuum zero point Casimir effect as well as the cosmic dark energy and dark matter density. In E-infinity theory a quantum particle is represented by a Hausdorff dimension Φ where Φ =2/(√5+1) . The quantum wave on the other hand is represented by Φ2 . To be wave and a particle simultaneously intersection theory leads us to?(Φ) (Φ)2= Φ3 which will be shown here to be twice the value of the famous Casimir force of the vacuum for a massless scalar field. Thus in the present work a basically topological interpretation of the Casimir effect is given as a natural intrinsic property of the geometrical topological structure of the quantum-Cantorian micro spacetime. This new interpretation compliments the earlier conventional interpretation as vacuum fluctuation or as a Schwinger source and links the Casimir energy to the so called missing dark energy density of the cosmos. From the view point of the present work Casimir pressure is a local effect acting on the Casimir plates constituting the local boundary condition while dark energy is nothing but the global combined effect of infinitely many quantum waves acting on the Möbius-like boundary of the holographic boundary of the entire universe. Since this higher dimensional Möbius-like boundary is one sided, there is no outside to balance the internal collective Casimir pressure which then manifests itself as the force behind cosmic expansion, that is to say, dark energy. Thus analogous to the exact irrational value of ordinary energy density of spacetime E(O)=(Φ5/2) mc2 we now have P (Casimir) = (Φ3/2)(ch/d2) where c is the speed of light, m is the mass, h is the Planck constant and d is the plate separation. In addition the new emerging geometry combined with the topology of E-infinity theory leads directly to identifying dark matter with the quasi matter of the ergosphere. As a direct consequence of this new insight E=mc2 which can be written as E = E (O) + E (D)?where the exact rational approximation is E (O)=mc2/22 is?the ordinary energy density of the cosmos and the exact rational approximation E (D)=mc2/(21/22) is the corresponding dark energy which could be subdivided once more albeit truly approximately into E(D)=mc2/(5/22)?+mc2/(16/22)??where 5 is the Kaluza Klein spacetime dimension, 16 are the bosonic extra dimensions of Heterotic superstrings and 5/22 □?22% is approximately the density of the dark matter-like energy of the ergosphere of the Kerr geometry. As for the actual design of our nano reactor, this is closely related to branching clusters of polymer, frequently called lattice animals. In other words we will have Casimir spheres instead of Casimir plates and these spheres will be basically nano particles modelling lattice animals. Here D=?4 will be regarded as spacetime dimensionality while D=6 of percolations are the compactified super string dimensions and D=8 is the dimension of a corresponding super space.
文摘A phase one design of a new free energy nano reactor is presented. The design is based on a basically topological interpretation of the Casimir effect as a natural intrinsic property of the geometrical topological structure of the quantum-Cantorian micro spacetime. In particular we view dark energy, Hawking negative energy, Unruh temperature and zero point vacuum energy as being different sides of the same multi-dimensional coin. This new interpretation compliments the earlier conventional interpretation as vacuum fluctuation or as a Schwinger source and links the Casimir energy to the so-called missing dark energy density of the cosmos. We start with a general outline of the theoretical principle and basic design concepts of a proposed Casimir dark energy nano reactor. In a nutshell the theory and consequently the actual design depend crucially upon the equivalence between the dark energy density of the cosmos and the faint local Casimir effect produced by two sides boundary condition quantum waves. This Casimir effect is then colossally amplified as a one internal quantum wave representing a Hartle-Hawking state vector of the universe pushing from the inside against the boundary of the universe with nothing balancing it from the non-existent outside. This strange situation becomes completely natural and logical when we remember that the boundary of the universe is a one sided Möbius like manifold. In view of the present theory, this is essentially what leads to the observed accelerated expansion of the cosmos. As in any reactor, the basic principle in the present design is to produce a gradient so that the excess energy on one side flows to the other side. Thus in principle we will restructure the local topology of space using material nanoscience technology to create an artificial local high dimensionality with a Dvoretzky theorem like 96 percent volume measure concentration. Without going into the intricate nonlinear dynamics and technological detail, it is fair to say that this would lead us to pure, clean, free energy obtained directly from the topology of spacetime via an artificial singularity. Needless to say, the entire design is based completely on the theory of quantum wave dark energy proposed by the present author for the first time in 2011 in a conference held in the Bibliotheca Alexandrina, Egypt and a little later in Shanghai, Republic of China. The quintessence of the present theory is easily explained as the Φ3 intrinsic Casimir topological energy where Φ=?(√5-1)/2 is produced from the zero set Φ of the quantum particle when we extract the empty set quantum wave Φ2 from it and find Φ-Φ2=Φ3 by restructuring space via conducting but uncharged plates similar to that of the classical Casimir experiments. Our proposed preliminary design of this Casimir-spacetime artificial singularity reactor follows in a natural way from the above.
基金Fundamental Research Funds for the Central Universities,China(No.2011D10543,No.2013D110525)
文摘Traditional preparation of magnetic microcapsules involves cumbersome processes and often results in irregular-shaped products. Due to the stable laminar flow of reaction solution and the moderate reaction conditions, the T-shaped microchannel (T-MC) reactor is supposed to yield microcapsules with regular shape. In this paper, magnetic particles of ferroferric oxide modified by oleic acid (OA-Fe3O4) and dispersed in tetrachloroethylene were used as core material. Polymethyl methacrylate (PMMA) was used as shell material. Magnetic microcapsules were prepared by using a T-MC reactor. Factors that influenced the encapsulated reaction were investigated in details, which included the velocity ratio of aqueous phase to oil phase, the length and the inner diameter of the microchannel. The morphology, composition, and magnetic responsiveness of the magnetic microcapsules were analyzed and characterized by SEM, FTIR, XRD, TGA, and vibrating sample magnetometer (VSM). The results confirmed that magnetic microcapsules prepared by T-MC reactor were regular in shape.
基金This work was supported by the National Key Research and Development Program of China(2017YFB0310405)the Shenyang National Laboratory for Materials Science(SYNL)Program for Youth Talent(L2019F45).
文摘Recently,there has been considerable interest in the use of microchannel reactors for hydrometallurgy of rare earths(REs).Here,a novel integrated microchannel reactor based on the hollow-strut SiC foam material is presented and demonstrated to extract Ce^(3+)and Pr^(3+)using 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester(P507)as the extractant.The typical three-dimensional reticulated structure of the hollow-strut SiC foam was characterized by scanning electron microscopy and X-ray micro computed tomography.Since the reactor’s structure plays a key role in fluid mixing and mass diffusion during the extraction process,the structure-performance relationship of the foam was studied by extraction experiments combined with numerical simulations.Using the foam with the optimal structure,the influence of the flow rate Q_(0) of the two liquid phases on the extraction efficiency η and overall volume mass transfer coefficient KLa was discussed.For both RE ions,with increasing Q_(0),η decreases while KLa increases.For the total flow rate of the two phases of 4 ml·min^(-1),the η values of Pr^(3+)and Ce^(3+)reached 98.7%and 97.0%,respectively.For the total flow rate of 36 ml·min^(-1) which was much higher than that of many other microchannel reactors reported in the literatures,the η values of Pr^(3+)and Ce^(3+)still reached 92.2%and 86.9%,respectively,and the KLa values of Pr^(3+)and Ce^(3+)were 0.198 and 0.161 s^(-1),respectively,similar to the high values reported for other microchannel reactors studied in previous work.These findings indicate that the hollow-strut SiC foam microchannel reactor is suitable for use in REs extraction.
基金Supported by the National Natural Science Foundation of China(91634101)The Project of Construction of Innovative Teams and Teacher Career Development for Universities and Colleges under Beijing Municipality(IDHT20180508)
文摘Acylation of 2-methylnaphthalene(2-MN) is a very important reaction in organic synthesis,and the effiency of the continuous reactor is more than one of the batch reactor.Considering that the Friedel–Crafts acylation is a rapid exothermic reaction,in this study,we perform the acylation of 2-MN in a stainless steel microchannel flow reactor,which is characterized by high mass and heat transfer rates.The effect of reactant ratio,mixing temperature,reaction temperature,and reaction time on product yield and selectivity were investigated.Under the optimal conditions,2-methyl-6-propionylnaphthalene(2,6-MPN) was obtained in 85.8% yield with 87.5% selectivity.Compared with the conventional batch system,the continuous flow microchannel reactor provides a more efficient method for the synthesis of 2,6-MPN.
文摘Building on the various manifestations of the forces latent in the quantum vacuum of spacetime such as Hawking’s radiation and Unruh temperature, we resolve a major paradox connected to an immensely important proposal by NASA scientists for constructing a practically fuelless spacecraft. In a nutshell, preliminary laboratory work shows that NASA’s electromagnetic drive project is viable and several experiments and measurements show it is real. Yet the proposal violates a fundamental principle of classical mechanics, namely Newton’s third law. The resolution of this paradox is quite straight forward in principle. It is simply the case that although the proposal seems to be based on classical mechanics and classical thinking it is only superficially so. Deep at the roots, the EM drive proposal of NASA is not classical physics but rather based on the vacuum forces of quantum cosmology and the theory of dark energy density of the universe. In fact the proposal is deeply linked to Hawking’s radiation and Unruh temperature, which is explained in some detail in the main body of the present short paper within the frame work of E-infinity Cantorian spacetime theory and D. Gross’ Heterotic superstring theory. In short the quintessence of our explanation is to regard the EM drive as a quasi electromagnetic cavity with an effective event horizon akin to that of a Hawking black hole emitting radiation causing ultimately the needed thrust to push the spacecraft forwards. In addition and by invoking fractal spacetime self similarity we show that a spacecraft will be subject to another cosmic thrust on the large scale of the entire cosmos.
文摘In this study, a simple and effective technique for establishing an external mass transfer model in a recirculated packed-bed batch reactor (RPBBR) with an immobilized lipase enzyme and Jatropha oil system is presented. The external mass transfer effect can be represented with a model in the form of Colburn factor JD = K Re-(1–n). The value of K and n were derived from experimental data at different mass flow rates.The experiment shows an average increment of 1.51% FFA for calcium alginate and 1.62% FFA for carrageenan after the hydrolysis took place. Based on different biopolymer material used in immobilized beads, JD = 1.674 Re-0.4 for calcium alginate and JD = 1.881 Re-0.3 for k-carrageenan were found to be adequate to predict the experimental data for external mass transfer in the reactor in the Reynolds number range of 0.2 to 1.2. The purposed model can be used for the design of industrial bioreactor and scale up. Besides, the external mass transfer coefficients for the hydrolysis of Jatropha oil reaction and the entrapment efficiency for the two biopolymer materials used were also investigated.
文摘This article proposes to associate a Deuterium-Deuterium (D-D) fusion reactor with a PWR (fission Pressurized Water Reactor) in a hybrid reactor. Even if the mechanical gain (Q factor) of the D-D fusion reactor is below the unity and consequently consumes more energy than it supplies, due to the high energy amplification factor of the PWR fission reactor, the global yield is widely superior to 1. As the energy supplied by the fusion reactor is relatively low and as the neutrons supplied are mainly issued from D-D fusions (at 2.45 MeV), the problems of heat flux and neutrons damage connected with materials, as with D-T fusion reactors are reduced. Of course, there is no need to produce Tritium with this D-D fusion reactor. This type of reactor is able to incinerate any mixture of natural Uranium, natural Thorium and depleted Uranium (waste issued from enrichment plants), with natural Thorium being the best choice. No enriched fuel is needed. So, this type of reactor could constitute a source of energy for several thousands of years because it is about 90 more efficient than a standard fission reactor, such as a PWR or a Candu one, by extracting almost completely the energy from the fertile materials U238 and Th232. For the fission part, PWR technology is mature. For the fusion part, it is based on a reasonable hypothesis done on present Stellarators projects. The working of this reactor is continuous, 24 hours a day. In this paper, it will be targeted a reactor able to provide net electric power of about 1400 MWe, as a big fission power plant.
基金the financial support from the SINOPEC(No.119001)。
文摘The Fischer-Tropsch synthesis is an important step in coal liquefaction,natural gas liquefaction,and biomass liquefaction.In recent years,the use of microchannel reactors for Fischer-Tropsch synthesis has received widespread attention.Since thermocouples and other sensors cannot be placed easily in a microchannel reactor,it is very vital to establish a model to provide calculated results highly compatible with the experimental data.This paper mainly introduces the establishment and solution of microchannel reactor models for Fischer-Tropsch synthesis.General mass transfer differential equations,heat transfer differential equations and related parameters(such as reaction rates,dispersion coefficient,and convective heat transfer coefficient)are listed.To solve the models,numerical solutions,such as the CFD simulation methods and the programming methods,are reviewed.It is recommended that a more accurate solution strategy is the combination of CFD simulation and programming methods.
文摘In the past decade or so,AI(artificial intelligence)technology has been growing with such a mesmerizing speed that today its presence in almost any industry that deals with any huge sheer volume of data is taking advantage of AI by integrating it into their day-to-day operation.Meanwhile,seven billion people worldwide shape the world’s energy system and directly impact the fundamental drivers of energy,both renewable and non-renewable sources,to meet the demand for electricity from them.These energy sources can be reached from nature such as solar,wind,etc.,and human-made such as NPPs(nuclear power plants)in the form of either fission as an old technology since the Manhattan project and in the near future as fusion in the form of magnetic or inertial confinements.Meanwhile,AI controlling nuclear reactors are about to happen.The basic idea is to apply AI with its two subset components as ML(machine learning),and DL(deep learning)techniques to go through the mountains of data that come from a reactor,spot patterns in it,and calling them to the unit’s human attention operators is not invadable either.Designers of such nuclear reactors will combine simulation and real-world data,comparing scenarios from each to develop“confidence[in]what they can predict and what is the range of uncertainty of their prediction”.Adding that,in the end,the operator will make the final decisions in order to keep these power plants safe while they are in operation and how to secure them against cyber-attack natural or human-made disasters.In this short communication article,we would like to see how we can prove some of these concepts;then a NPP manufacturer can pick it up and use it in their designs of a new generation of these reactors.
文摘In this paper we outline a non-perturbative quantum relativity theory. Subsequently an actual design of a nanotech energy reactor is based on spacetime vacuum fluctuation of the said quantum relativity theory. Using a compact heap of Fullerene nano particle moduli of a nano matrix device we propose that by maximizing the Casimir forces between these particles as a desirable effect, we can achieve a gradual rather than a sudden implosion pressure. We expect that this will result in a mini holographic universe from which energy can be extracted in a way to constitute a nano energy reactor and function effectively on a hybrid principle somewhere between a Casimir effect and a cold fusion process based on the fusion algebra of a highly structured golden ring quantum field theory. The present theory depends upon many concepts and results, in particular J. Schwinger’s source theory as well as the modern theory of quantum sets, nonlinear dynamics, chaos and chaotic fractals.
文摘The most widely accepted model of Solar System formation, known as the Nebular hypothesis, does not solve the Angular Momentum problem—why is the orbital momentum of Jupiter larger than rotational momentum of the Sun? The present manuscript introduces a Rotational Fission model of creation and evolution of Macrostructures of the World (Superclusters, Galaxies, Extrasolar Systems), based on Overspinning Cores of the World’s Macroobjects, and the Law of Conservation of Angular Momentum. The Hypersphere World-Universe model is the only cosmological model in existence that is consistent with this Fundamental Law.
文摘Fast reactors used lead-bismuth eutectic (LBE) and lead as coolants possess very high level of inherent self-protection and passive safety against severe accident. So, population radiophobia can be overcome. That type of reactors can be simultaneously more safely and more cheaply. As all other coolants, LBE and lead coolant (LC) possess the certain virtues and shortcomings. The presented report includes the comparative analysis of characteristic properties of those coolants, their impact on reactor safety, reliability and operating characteristics. The conclusion is made about promising usage of FRs with these coolants in future NP after the experience in operating of the prototypes of such reactors has been obtained.
基金the Commission of Science,Technology and Industry for National Defence
文摘A new type of commercial reactor is first built up in China.This paper briefly describesits performances,working foundamentals and various possible uses.The reactor uses urani-um-zirconium hydride as fuel element and has a large prompt negative temperature coefficientof reactivity,featuring inherent safety and a fairly high pulsed-power capacity.
文摘This article explores the transformative potential of nanotechnology and MMs(memory metals)in enhancing the design and operation of nuclear reactors,encompassing both fission and fusion technologies.Nanotechnology,with its ability to engineer materials at the atomic scale,offers significant improvements in reactor safety,efficiency,and longevity.In fission reactors,nanomaterials enhance fuel rod integrity,optimize thermal management,and improve in-core instrumentation.Fusion reactors benefit from nanostructured materials that bolster containment and heat dissipation,addressing critical challenges in sustaining fusion reactions.The integration of SMAs(shape memory alloys),or MMs,further amplifies these advancements.These materials,characterized by their ability to revert to a pre-defined shape under thermal conditions,provide self-healing capabilities,adaptive structural components,and enhanced magnetic confinement.The synergy between nanotechnology and MMs represents a paradigm shift in nuclear reactor technology,promising a future of cleaner,more efficient,and safer nuclear energy production.This innovative approach positions the nuclear industry to meet the growing global energy demand while addressing environmental and safety concerns.