The manipulation of rectifying contact of Co and nitrogen-doped carbon hierarchical superstructures toward high-performance oxygen reduction reaction

Rational design and construction of oxygen reduction reaction(ORR)electrocatalysts with high activity,good stability,and low price are essential for the practical applications of renewable energy conversion devices,such as metal-air batteries.Electronic modification through constructing metal/semiconductor Schottky heterointerface represents a powerful strategy to enhance the electrochemical performance.Herein,we demonstrate a concept of Schottky electrocatalyst composed of uniform Co nanoparticles in situ anchored on the carbon nanotubes aligned on the carbon nanosheets(denoted as Co@N-CNTs/NSs hereafter)toward ORR.Both experimental findings and theoretical simulation testify that the rectifying contact could impel the voluntary electron flow from Co to N-CNTs/NSs and create an internal electric field,thereby boosting the electron transfer rate and improving the intrinsic activity.As a consequence,the Co@N-CNTs/NSs deliver outstanding ORR activity,impressive long-term durability,excellent methanol tolerance,and good performance as the air-cathode in the Zn-air batteries.The design concept of Schottky contact may provide the innovational inspirations for the synthesis of advanced catalysts in sustainable energy conversion fields.

Igneous intrusion contact metamorphic system and its reservoir characteristics:A case study of Paleogene Shahejie Formation in Nanpu sag of Bohai Bay Basin,China

Taking the Paleogene Shahejie Formation in Nanpu sag of Bohai Bay Basin as an example,this study comprehensively utilizes seismic,mud logging,well logging,physical property analysis and core thin section data to investigate the metamorphic reservoir formed by contact metamorphism after igneous rock intrusion.(1)A geological model of the igneous intrusion contact met amorphic system is proposed,which can be divided into five structural layers vertically:the intrusion,upper metamorphic aureole,lower metamorphic aureole,normal sedimentary layers on the roof and floor.(2)The intrusion is characterized by xenoliths indicating intrusive facies at the top,regular changes in rock texture and mineral crystallization from the center to the edge on a microscopic scale,and low-angle oblique penetrations of the intrusion through sedimentary strata on a macroscopic scale.The metamorphic aureole has characteristics such as sedimentary rocks as the host rock,typical palimpsest textures developed,various low-temperature thermal metamorphic minerals developed,and medium-low grade thermal metamorphic rocks as the lithology.(3)The reservoir in contact metamorphic aureole has two types of reservoir spaces:matrix pores and fractures.The matrix pores are secondary"intergranular pores"distributed around metamorphic minerals after thermal metamorphic transformation in metasandstones.The fractures are mainly structural fractures and intrusive compressive fractures in metamudstones.The reservoirs generally have three spatial distribution characteristics:layered,porphyritic and hydrocarbon impregnation along fracture.(4)The distribution of reservoirs in the metamorphic aureole is mainly controlled by the intensity of thermal baking.Furthermore,the distribution of favorable reservoirs is controlled by the coupling of favorable lithofacies and thermal contact metamorphism,intrusive compression and hydrothermal dissolution.The proposal and application of the geological model of the intrusion contact metamorphic system are expected to promote the discovery of exploration targets of contact metamorphic rock in Nanpu sag,and provide a reference for the study and exploration of deep contact metamorphic rock reservoirs in the Bohai Bay Basin.

Validation of a Questionnaire to Diagnose the Baumann Skin Type in All Ethnicities and in Various Geographic Locations

The Baumann Skin Typing System diagnoses patients as having one of 16 skin types based on their answers to a validated questionnaire [i] known as the Baumann Skin Type Indicator [ii]. The BSTI questionnaire has been tested over the last decade on over 200,000 people of various ages and ethnicities in different geographic locations around the world. In this study, data were collected from 52,862 patients to compare skin type prevalence between those who presented to doctor’s offices and those who took the quiz without supervision online. The most common skin types varied only slightly between patients that took the quiz online and those that completed the questionnaire in their doctor’s office. This indicates that the prevalence of skin types seen in the doctor’s office is similar to that in the general population and that supervision is not necessary to get an accurate result on the BSTI. [iii] In addition, comparison of data gathered in China, Korea, and the US did not show a significant difference in skin type prevalence between Asian and Caucasian skin types. [iv] This study demonstrates that the English version of the BSTI is valid for English speaking patients online, and in doctors’ offices in the US, China and Korea.

Investigation of the Relation between Rolling Contact Fatigue Property and Microstructure on the Surface Layer of D2 Wheel Steel

Through the rolling contact fatigue experiment under the condition of the lubricating oil, this article investigated the relation between contact fatigue property and microstructure on the surface layer of D2 wheel steel. The results showed that although the roughness of the original specimen induced by mechanical processing would diminish to some extent in the experiment, the 0.5 - 1.5 μm thick layer of ultrafine microstructure on the original mechanically-processed specimen surface would still become micro-cracks and small spalling pits due to spalling, and would further evolve into fatigue crack source. Additionally, even under the impact of the load that was not adequate to make the material reach fatigue limit, the ferrite in the microstructure underwent plastic deformation, which led the refinement of proeutectoid ferrite grains. During the experiment, the hardening and the refinement caused by plastic deformation consisted with the theory that dislocation gave rise to plastic deformation and grain refinement. The distribution laws of hardness and ferrite grain sizes measured could be explained by the distribution law of the shearing stress in the subsurface.

Existence and numerical approximation of a solution to frictional contact problem for electro-elastic materials

In this paper,a frictional contact problem between an electro-elastic body and an electrically conductive foundation is studied.The contact is modeled by normal compliance with finite penetration and a version of Coulomb’s law of dry friction in which the coefficient of friction depends on the slip.In addition,the effects of the electrical conductivity of the foundation are taken into account.This model leads to a coupled system of the quasi-variational inequality of the elliptic type for the displacement and the nonlinear variational equation for the electric potential.The existence of a weak solution is proved by using an abstract result for elliptic variational inequalities and a fixed point argument.Then,a finite element approximation of the problem is presented.Under some regularity conditions,an optimal order error estimate of the approximate solution is derived.Finally,a successive iteration technique is used to solve the problem numerically and a convergence result is established.

MMPI-2评估应激障碍的效果

目的:采用MMPI-2评估应激障碍(SD)患者的病理心理特征,并探讨其辅助诊断的应用价值。方法:实验组为入院治疗的29名急性应激障碍(ASD)患者及14名创伤后应激障碍(PTSD)患者,对照组为44名适应良好的应激创伤幸存者,在不影响测验症状的情况下完成MMPI-2测试。结果:ASD患者MMPI-2的F、Fb、Fp、Pa、Pt、Sc和Ma的因子得分高于对照组,K和S低于对照组,差异有统计学显著性(P<0.05-0.001);PTSD患者F、Fb、Fp、Hs、D、Hy、Pa、Pt和Sc高于对照组,S低于对照组,差异有统计学显著性(P<0.05-0.001);ASD患者Hs、D和Hy低于PTSD患者,差异有统计学显著性(P<0.05-0.001)。两组患者剖面图均呈M678型。Pa和Sc进入判别函数,该函数在训练样本和验证样本中的预测符合率分别为83.9%和72.0%。结论:SD患者和适应良好的创伤幸存者的心理病理表现明显不同,ASD患者和PTSD患者的症状特征也有所差异;MMPI-2对应激失常症状比较敏感,Pa和Sc具有较好的鉴别能力。

Three-Dimensional Thermo-Elastic-Plastic Finite Element Method Modeling for Predicting Weld-Induced Residual Stresses and Distortions in Steel Stiffened-Plate Structures

The objective of the present paper is to develop nonlinear finite element method models for predicting the weld-induced initial deflection and residual stress of plating in steel stiffened-plate structures. For this purpose, three-dimensional thermo-elastic-plastic finite element method computations are performed with varying plate thickness and weld bead length (leg length) in welded plate panels, the latter being associated with weld heat input. The finite element models are verified by a comparison with experimental database which was obtained by the authors in separate studies with full scale measurements. It is concluded that the nonlinear finite element method models developed in the present paper are very accurate in terms of predicting the weld-induced initial imperfections of steel stiffened plate structures. Details of the numerical computations together with test database are documented.

The effect of abiotic stresses on plant C:N:P homeostasis and their mitigation by silicon

In crop plants, various environmental stresses affect the balance of carbon, nitrogen, and phosphorus(C:N:P), leading to biochemical and physiological alterations and reductions in yield. Silicon(Si) is a beneficial element that alleviates plant stress. Most studies involving silicon have focused on physiological responses, such as improvements in photosynthetic processes, water use efficiency, and antioxidant defense systems. But recent research suggests that stressed plants facing either limited or excessive resources(water, light, nutrients, and toxic elements), strategically employ Si to maintain C:N:P homeostasis, thereby minimizing biomass losses. Understanding the role of Si in mitigating the impact of abiotic stresses on plants by regulating C:N:P homeostasis holds great potential for advancing sustainable agricultural practices in crop production. This review presents recent advances in characterizing the influence of environmental stresses on C:N:P homeostasis, as well as the role of Si in preserving C:N:P equilibrium and attenuating biological damage associated with abiotic stress. It underscores the beneficial effects of Si in sustaining C:N:P homeostasis and increasing yield via improved nutritional efficiency and stress mitigation.

Novel nervous and multi-system regenerative therapeutic strategies for diabetes mellitus with mTOR

Throughout the globe,diabetes mellitus（DM） is increasing in incidence with limited therapies presently available to prevent or resolve the significant complications of this disorder.DM impacts multiple organs and affects all components of the central and peripheral nervous systems that can range from dementia to diabetic neuropathy.The mechanistic target of rapamycin（m TOR） is a promising agent for the development of novel regenerative strategies for the treatment of DM.m TOR and its related signaling pathways impact multiple metabolic parameters that include cellular metabolic homeostasis,insulin resistance,insulin secretion,stem cell proliferation and differentiation,pancreatic β-cell function,and programmed cell death with apoptosis and autophagy.m TOR is central element for the protein complexes m TOR Complex 1（m TORC1） and m TOR Complex 2（m TORC2） and is a critical component for a number of signaling pathways that involve phosphoinositide 3-kinase（PI 3-K）,protein kinase B（Akt）,AMP activated protein kinase（AMPK）,silent mating type information regulation 2 homolog 1（Saccharomyces cerevisiae）（SIRT1）,Wnt1 inducible signaling pathway protein 1（WISP1）,and growth factors.As a result,m TOR represents an exciting target to offer new clinical avenues for the treatment of DM and the complications of this disease.Future studies directed to elucidate the delicate balance m TOR holds over cellular metabolism and the impact of its broad signaling pathways should foster the translation of these targets into effective clinical regimens for DM.

Neuroprotective potential for mitigating ischemia-reperfusion-induced damage

Reperfusion following cerebral ischemia causes both structural and functional damage to brain tissue and could aggravate a patient's condition;this phenomenon is known as cerebral ischemia-reperfusion injury.Current studies have elucidated the neuroprotective role of the sirtuin protein family(Sirtuins)in modulating cerebral ischemia-reperfusion injury.However,the potential of utilizing it as a novel intervention target to influence the prognosis of cerebral ischemia-reperfusion injury requires additional exploration.In this review,the origin and research progress of Sirtuins are summarized,suggesting the involvement of Sirtuins in diverse mechanisms that affect cerebral ischemia-reperfusion injury,including inflammation,oxidative stress,blood-brain barrier damage,apoptosis,pyroptosis,and autophagy.The therapeutic avenues related to Sirtuins that may improve the prognosis of cerebral ischemia-reperfusion injury were also investigated by modulating Sirtuins expression and affecting representative pathways,such as nuclear factor-kappa B signaling,oxidative stress mediated by adenosine monophosphate-activated protein kinase,and the forkhead box O.This review also summarizes the potential of endogenous substances,such as RNA and hormones,drugs,dietary supplements,and emerging therapies that regulate Sirtuins expression.This review also reveals that regulating Sirtuins mitigates cerebral ischemia-reperfusion injury when combined with other risk factors.While Sirtuins show promise as a potential target for the treatment of cerebral ischemiareperfusion injury,most recent studies are based on rodent models with circadian rhythms that are distinct from those of humans,potentially influencing the efficacy of Sirtuinstargeting drug therapies.Overall,this review provides new insights into the role of Sirtuins in the pathology and treatment of cerebral ischemia-reperfusion injury.

Contact Stress Reliability Analysis Model for Cylindrical Gear with Circular Arc Tooth Trace Based on an Improved Metamodel

Although there is currently no unified standard theoretical formula for calculating the contact stress of cylindrical gears with a circular arc tooth trace(referred to as CATT gear),a mathematical model for determining the contact stress of CATT gear is essential for studying how parameters affect its contact stress and building the contact stress limit state equation for contact stress reliability analysis.In this study,a mathematical relationship between design parameters and contact stress is formulated using the KrigingMetamodel.To enhance the model’s accuracy,we propose a new hybrid algorithm that merges the genetic algorithm with the Quantum Particle Swarm optimization algorithm,leveraging the strengths of each.Additionally,the“parental inheritance+self-learning”optimization model is used to fine-tune the KrigingMetamodel’s parameters.Following this,amathematicalmodel for calculating the contact stress of Variable Hyperbolic Circular-Arc-Tooth-Trace(VH-CATT)gears using the optimized Kriging model was developed.We then examined how different gear parameters affect the VH-CATT gears’contact stress.Our simulation results show:(1)Improvements in R2,RMSE,and RMAE.R2 rose from0.9852 to 0.9974(a 1.22%increase),nearing 1,suggesting the optimized Kriging Metamodel’s global error is minimized.Meanwhile,RMSE dropped from3.9210 to 1.6492,a decline of 57.94%.The global error of the GA-IQPSO-Kriging algorithm was also reduced,with RMAE decreasing by 58.69%from 0.1823 to 0.0753,showing the algorithm’s enhanced precision.In a comparison of ten experimental groups selected randomly,the GA-IQPSO-Kriging and FEM-based contact analysis methods were used to measure contact stress.Results revealed a maximum error of 12.11667 MPA,which represents 2.85%of the real value.(2)Several factors,including the pressure angle,tooth width,modulus,and tooth line radius,are inversely related to contact stress.The descending order of their impact on the contact stress is:tooth line radius>modulus>pressure angle>tooth width.(3)Complex interactions are noted among various parameters.Specifically,when the tooth line radius interacts with parameters such as pressure angle,tooth width,and modulus,the resulting stress contour is nonlinear,showcasing amultifaceted contour plane.However,when tooth width,modulus,and pressure angle interact,the stress contour is nearly linear,and the contour plane is simpler,indicating a weaker coupling among these factors.

电针抗抑郁研究的模型探讨

目的:探讨电针抗抑郁研究适宜模型的选择。方法:选用药物实验方法,观察去甲肾上腺素毒性实验小鼠的死亡率、5 羟色胺酸甩头实验小鼠甩头次数。用改变环境条件的方法,观察悬尾实验小鼠悬尾的不动时间和通过慢性应激模型观察开野实验大鼠的活动性及检测糖水实验糖水的摄入量。结果:与空白对照组相比,电针不能降低去甲肾上腺素毒性实验小鼠的死亡率,不能减少5 羟色胺酸甩头实验小鼠的甩头次数;但能减少悬尾实验小鼠悬尾的不动时间;慢性应激模型中,与模型组及模型束缚组相比,电针组和百优解组可明显增加开野实验的垂直运动次数及糖水的摄入量。结论:针刺对抑郁症的实验研究应选择改变环境条件诱发的抑郁动物模型进行,药物诱发的抑郁模型可能是不适宜的。

Changes of China’s Status in the Global System and Its Influencing Factors:A Multiple Contact Networks Perspective

Clarifying China’s position in the global system is an important logical basis for developing national diplomacy.Although much research has been done on China’s development status,most studies have been based on country comparisons or institutional en-vironment.In today’s networked era in which the global economy,trade,personnel,and information are closely connected,studies on China’s global position and its status changes and influencing factors in multiple contact networks are still insufficient.In this study,from the perspective of diverse global contact networks,we constructed economic,cultural,and political influence indices to explore the changes and influencing factors on China’s status in the global system from 2005 to 2018.The results show that during the study period,China’s global influence in the fields of economic ties,cultural exchanges,and political contacts increased significantly,but its influ-ence in the fields of cultural exchanges and political contacts lagged far economic ties.The pattern of China’s economic influence on various economies around the world has shown a transformation from an‘upright pyramid’to an‘inverted pyramid’structure.The proportion of these economies in low-influence zones has decreased from more than 60%in 2005 to less than 20%in 2018.China’s cultural and political influence on various economies around the world has increased significantly;however,for the former,the percentage of high-influence areas is still less than 20%,whereas for the latter the percentage of these economies in medium-and high-influence areas is still less than 50%.Analyses such as a scatter plot matrix show that geographical proximity,economic globalization,close cooperation with developing countries,and a proactive and peaceful foreign policy are important factors in improving China’s status in the diverse global network system.

不同剂量甜菜碱对热应激肉鸡组织器官发育的影响

选择将1日龄肉用仔鸡200只,随机分成3组,在试验期内,环境温度为28～31℃,湿度为83～87%。对照组仅喂基础日粮,试验1组、试验2组分别在基础日粮添中加0.1%、0.3%的甜菜碱。结果表明:试验1组鸡在38～47日龄甲状腺的重量和肾上腺重量显著增加(P<0.05),在48～57日龄试验1组鸡胸腺、胃、肝脏、心脏的重量显著增加(P<0.05),睾丸的重量极显著增加。在试验期内,与对照组相比较,试验1组鸡胰、脾、法氏囊、肺和肾重量差异都不显著(P>0.05)。试验2组鸡除了在48～57日龄睾丸重量极显著增加(P<0.01)以外,其它器官重量差异均不显著(P>0.05)。试验2组与试验1组鸡在整个试验期内各器官重量差异均不显著(P>0.05)。组织学观察表明,在高温环境中,对照组鸡肾、心脏、肺、肝、胃、脾、胸腺等器官出现不同程度病理变化,但试验1组鸡上述组织器官未见有明显变化,这说明,甜菜碱具有一定的抗热应激作用。

Transient Heat Transfer Study of Direct Contact Condensation of Steam in Spray Cooling Water

We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 1045 mm. We applied a new analysis method for the steam state equation to analyze the molar quantity change in steam over the course of the experiment and determined the transient steam variation. We also investigated the influence of flow rates and temperatures ofcooling water on the efficiency ofsteam condensation. Our experimental results show that appropriate increasing of the cooling water flow rate can significantly accelerate the steam condensation. We achieved a rapid increase in the total volumetric heat transfer coefficient by increasing the flow rate of cooling water, which indicated a higher thermal convection between the steam and the cooling water with higher flow rates. We found that the temperature ofcooling water did not play an important role on steam condensation. This method was confirmed to be effective for rapid recovering ofsteam.

Heterogeneities of grain boundary contact for simulation of laboratoryscale mechanical behavior of granitic rocks

From a practical point of view,grain structure heterogeneities are key parameters that control the rock response and still remains a challenge to incorporate in a quantitative manner.One of the less discussed topics in the context of the grain-based model(GBM)in the particle flow code(PFC)is the contact heterogeneities and the appropriate contact model to mimic the grain boundary behavior.Generally,the smooth joint(SJ)model and linear parallel bond(LPB)model are used to simulate the grain boundary behavior.However,the literature does not document the suitability of different models for specific problems.Another challenge in implementing GBM in PFC is that only a single bonding parameter is used at the grain boundaries.The aim of this study is to investigate the responses of a laboratory-scale specimen with SJ and LPB models,considering grain boundary heterogeneous and homogeneous contact parameters.Uniaxial and biaxial compression tests are performed to calibrate the response of Creighton granite.The stressestrain curves,volumetric dilation,inter-crack(crack in the grain boundary),and intra-crack(crack within the grain)development,and failure patterns associated with different contact models are examined.It was found that both the SJ and LPB models can reproduce the pre-peak behavior observed for a granitic rock type.However,the LPB model is unable to reproduce the post-peak behavior.Due to the large interlocking effect originating from the balls in contact and the ball size in the LPB model,local dilation is induced at the grain boundaries.This overestimates the volumetric dilation and residual shear strength.The LPB model tends to result in discontinuous inter-cracks and stress localization in the rock specimen,resulting in fine fragments at the rock surface during failure.

Alleviation for contact stresses in curvic attachments

This paper studied the contact stresses in curvic attachments.The principal purpose of this research is to employ a method of alleviating the fluctuating hoop stresses which can be considered to be a major contribution to fatigue failure in curvic attachments.This method entails novel precision geometry of the contacting flat on curvic which is a tactic to get appropriate arc heights in in-plane direction as well as vary radius in out-of-plane direction.The dimensional finite elements in both directions were analyzed.These analysis results indicated that significant reduction in fluctuating hoop stresses can be achieved by the proposed method,provided that the precision geometry is controlled sufficiently precisely.

The Mathematical Modelling for Studying the Influence of the Initial Stresses and Relaxation Times on Reflection and Refraction Waves in Piezothermoelastic Half-Space

The present paper concentrates on the study of reflection and refraction phenomena of waves in pyroelectric and piezo-electric media under initial stresses and two relaxation times influence by apply suitable conditions. The generalized theories of linear piezo-thermoelasticity have been employed to investigate the problem. In two-dimensional model of transversely isotropic piezothermoelastic medium, there are four types of plane waves quasi-longitudinal (qP), quasi-transverse (qSV), thermal wave (T-mode), and potential electric waves (φ-mode) The amplitude ratios of reflection and refraction waves have been obtained. Finally, the results in each case are presented graphically.

光纤光栅传感器在大体积混凝土基础温度监测中的应用

光纤光栅传感器具有体积小、质量轻、灵敏度高、耐腐蚀、抗电磁干扰、传输频带较宽、易于进行分布式测量等诸多其他传感器所不具备的优点,更适用于现场的长期健康监测。大体积混凝土在施工过程中的温度问题如处理不当将会引起混凝土开裂。利用温度计、热电耦等作为传感器的传统的检测手段已经大大的制约了数据的准确性与精度。寻求一种高精度温度检测手段已经成为用于现场结构监测的前提。本文结合具体的工程实例介绍了光纤光栅传感器在基础混凝土温度监测中的应用,介绍了监测系统的组成,传感器的构造和标定,并利用实测温度预测基础混凝土底板中温度应力,及时采取措施防止混凝土的开裂。

AHFO-based soil water content sensing technology considering soil-sensor thermal contact resistance

The actively heated fiber-optic(AHFO)technology has become emerged as a research focus due to its advantages of distributed,real-time measurement and good durability.These attributes have led to the gradual application of AHFO technology to the water content measurement of in situ soil.However,all existing in situ applications of AHFO technology fail to consider the effect of soilesensor contact quality on water content measurements,limiting potential for the wider application of AHFO technology.To address this issue,the authors propose a method for determining the soilesensor thermal contact resistance based on the principle of an infinite cylindrical heat source.This is then used to establish an AHFO water content measurement technology that considers the thermal contact resistance.The reliability and validity of the new measurement technology are explored through a laboratory test and a field case study,and the spatial-temporal evolution of the soil water content in the case is revealed.The results demonstrate that method for determining the soilesensor thermal contact resistance is highly effective and applicable to all types of soils.This method requires only the moisture content,dry density,and thermal response of the in situ soil to be obtained.In the field case,the measurement error of soil water content between the AHFO method,which takes into account the thermal contact resistance,and the neutron scattering method is only 0.011.The water content of in situ soil exhibits a seasonal variation,with an increase in spring and autumn and a decrease in summer and winter.Furthermore,the response of shallow soils to precipitation and evaporation is significant.These findings contribute to the enhancement of the accuracy of the AHFO technology in the measurement of the water content of in situ soils,thereby facilitating the dissemination and utilization of this technology.