Shear hydrophobic flocculation and flotation of ultrafine Anshan hematite using sodium oleate

Effects of stirring speed and time, pH and sodium oleate concentration on the shear hydrophobic flocculation of ultrafine Anshan hematite with sodium oleate as the surfactant were discussed. The results show that these parameters significantly affect the shear hydrophobic flocculation of ultrafine hematite. The optimum conditions for the flocculation are： stirring speed 1 400 r/min, flocculation time 20 min, pH 9 and sodium oleate concentration 3.94×10-4 mol/L; the flotation recovery of hematite flocs is remarkably high compared with non flocculated ultrafine hematite. According to the extended DLVO theory, the total interaction potential of Anshan ultrafine hematite was determined. The calculation results indicate that the hydrophobic flocculation state of the ultrafine hematite-sodium oleate system is mainly dominated by electric double layer repulsive interaction potential and hydrophobic interaction potential. A mechanical agitation is required to impart particles a kinetic energy to overcome potential barrier between them due to the existence of electric double layer repulsive interaction potential. Those particles further approach to form flocs due to the significant increase of the hydrophobic interaction potential.

Dynamic experiments on flocculation and sedimentation of argillized ultrafine tailings using fly-ash-based magnetic coagulant

In order to accelerate the sedimentation of super-large-scale argillized ultrafine tailings with bad features such as low settling velocity, muddy overflow water, and large flocculant dosage, a fly-ash-based magnetic coagulant （FAMC） was used in a dynamic experimental device. To obtain the best possible combination of the impact factors （magnetic intensity, FAMC dosage, flocculant dosage, and feed speed） for minimum overflow turbidity, a response surface methodology test coupled with a four-factor five-level central composite design was conducted. The synergy mechanism of FAMC and flocculant was analyzed based on the potential measurement and scanning electron microscopy. The results show that the flocculant dosage, overflow turbidity, and solid content can be reduced by 50%, 90%, and 80%, while the handling capacity per unit and efficiency of backfill and dry stacking can be promoted by 20%, 17%, and 13%, respectively, with a magnetic intensity of 0.3 T, FAMC dosage of 200 mL/t, flocculant dosage of 30 g/t, and feed speed of 0.6 t/（m^2·h）. Therefore, synergy of FAMC and flocculant has obvious efficiency in saving energy and protecting the environment by allowing 70×10^6 t/a of argillized ultrafine tailings slurry to be disposed safely and efficiently with a cost saving of more than 53×106 Yuan/a, which gives it great promise for use in domestic and foreign mines.

Effects of water hardness on selective flocculation of diasporic bauxite

The effect of electrolyte on settling behavior of kaolinite was studied. Effects of hard water on selective flocculation of diasporic bauxite was tested and the measures were taken to eliminate the effects of Ca2＋ and Mg2＋ in hard water. The results indicated that, not only the concentration of electrolyte ions but also the ionic valence of the electrolyte ions affects the settling behavior of kaolinite; hard water significantly affects its selective flocculation owing to Ca2＋ and Mg2＋; general dispersants could not eliminate the effects of Ca2＋ and Mg2＋. Self-made softening agent in our lab could weaken or eliminate the effects of hard water on flocculation processes. The results of molecular dynamics simulation show that softening agent molecules could restrict Ca2＋ and prevent them from playing their roles, so as to eliminate the effects. The continuous pilot experiment results of bauxite flocculation were even better than those obtained in laboratory.

Screening of a Novel Bioflocculant-producing Strain and Research on Its Flocculation

[Objective] This study aimed to screen a bacterial strain capable of producing bioflocculant. [Method] A bacterial strain T-11 capable of producing bioflocculant was isolated from activated sludge. Detailed tests on the morphological, physiological and biochemical characteristics were carried out and identification was performed to identify the strain. Finally, the bioflocculant was isolated and purified, and the flocculating activity and chemical characteristics were measured. [Result] It was identified as Serratia plumuthica based on its morphological, physiological and biochemical characteristics. This strain secreted flocculant best in a culture medium which included sucrose and NaNO3. The maximal cell growth was achieved within 10 h and the flocculating activity paralleled to it. It was found to be effective for flocculation of kaolin suspension, when added at a final concentration of 0.7 mg/L, over a range of pHs （2-7）, and temperature （approximately 30-80 ℃）. Chemical analysis indicated that the bioflocculant was an acidic polysaccharide consisting of glucose, glucuronic acid and galactose, talose and altrose. Infrared spectrum analysis also revealed typical characteristics of polysaccharides. [Conclusion] The biofloccu- lants produced by strain T-11 can greatly improve the ability of activated sludge to settle.

The effect of coupling coagulation and flocculation with membrane filtration in water treatment:A review

Water supply and sanitation demands are foreseen to face enormous challenges over the coming decades to meet the fast growing needs in a global perspective. Significant growth in the industry is predicted and membrane separation technologies have been identified as one of the possible solutions to meet future demands. Application and implementation of membrane technology is expected both in production of potable water as well as in treatment of wastewater. In potable water production membranes are substituting conventional separation technologies due to the superior performance, potential for less chemical use and sludge production, as well as the potential to fulfill hygienic barrier requirements. Membrane bio-reactor （MBR） technology is probably the membrane process which has had most success and has the best prospects for the future in wastewater treatment. Trends and developments indicate that this technology is becoming accepted and is rapidly becoming the best available technology for many wastewater treatment applications. A major drawback of MBR systems is membrane fouling. Studies have shown that fouling mitigation in MBR systems can potentially be done by coupling coagulation and flocculation to the process.

Features and mechanism for coagulation－flocculation processes of polyaluminum chloride

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Improving the sulfidation-flotation of fine cuprite by hydrophobic flocculation pretreatment

Hydrophobic flocculation pretreatment was performed to assess its effect on the recovery of fine cuprite in sulfidation-flotation. The results of the micro-flotation experiment showed that cuprite recovery is related to the particle size, and that an excessive content of fine particles(<18 μm) impacted the recovery of coarse particles. When hydrophobic flocculation pretreatment was used, the recovery of fine cuprite in sulfidation-flotation increased from 60.3% to 86.3% under optimum conditions(pH 9.5; sodium oleate concentration, 2 × 10^(-4) mol×L^(-1); stirring time, 6 min; stirring speed, 1600 r×min^(-1)). The laser particle size analysis and optical microscopy results indicate that hydrophobic flocculation pretreatment effectively reduces the content of fine cuprite, and augments the apparent particle size in the pulp. We performed the Derjaguin–Landau–Verwey–Overbeek(DLVO) theory and extended DLVO theory calculations to further support the interpretation of the results.

Temperature variation characteristics in flocculation settlement of tailings and its mechanism

Rapid flocculation and settlement(FS)of mine tailings is significant for the improvement and development of the filling process,whereas the settlement velocity(SV)of tailings in FS has been recognized as a key parameter to evaluate the settlement effect.However,the influence of temperature on the SV and its mechanism have not been studied.FS experiments on tailings with various ambient temperatures were carried out.The SVs of tailings with a solid waste content of 10wt%and an anionic polyacrylamide content of 20 g·t^−1 were measured at different temperatures.The SV presented an“N”-shaped variation curve as the temperature changed from 5 to 40℃.The mechanism of these results can be explained from the perspective of the electric double-layer repulsive force,molecular dynamics,and the polymer flocculation principle,as revealed from the scanning electron microscopy of floc particles.The findings will be beneficial in the design of tailings dewatering processes and save costs in the production of cemented paste backfill.

Evaluation of flocculation characteristics of kaolinite dispersion system using guar gum:A green flocculant

This paper reports the systematic investigation on the flocculation,sedimentation and consolidation characteristics of kaolinite using guar gum as a green flocculant.In-situ flocculation behavior of kaolinite at various pH,guar gum dosages,and ionic strength were studied using a light scattering technique.The effect of these parameters on the settling rate,solid consolidation,and supernatant liquid clarity was recorded.The morphology of kaolinite and flocculated kaolinite aggregates were analyzed using FESEM.The morphology studies suggest that it is poorly crystalline with multiple steps on edge,broken edge;laminar with high aspect ratio and have rough basal surface.The complex irregularity on the basal surface and the presence of multiple steps in the edges,broken edges(hydroxyl groups)have facilitated the guar gum adsorption.The isoelectric point of kaolinite is pH 3.96.The pH,ionic strength and flocculant dosage have a significant effect on the kaolinite settling rate.The guar gum has exhibited excellent turbidity removal efficiency at pH 5.The turbidity removal is inefficient at pH 10.However,guar gum has shown high turbidity removal with 80%transmission at pH 10 in the presence of a KNO3 electrolyte.

Numerical study of flocculation settling and thickening of whole-tailings in deep cone thickener using CFD approach

Deep cone thickener (DCT) is the key equipment in cemented paste backfill (CPB), so it is essential to study the flocculation settling and thickening characteristics of the whole-tailings in DCT. Coupled with population balance model (PBM), computational fluid dynamics (CFD) was used to study the characteristics, namely particle size distribution (PSD) and underflow concentration in DCT. Based on actual production, the effects of rake rotational speed, feed rate and tailings slurry concentration were simulated and analyzed in a certain range. The PSD varied with rake rational speed, feed rate and tailings slurry concentration almost in the same trend, but the influence of feed rate was less than that of rake rational speed and tailings slurry concentration. The underflow concentration increased at first and then declined with rake rational speed and feed rate, but it rose and fell with the tailings slurry concentration. Finally, the optimal key parameters on the flocculation settling and thickening of the whole-tailings in DCT were obtained: rake rotational speed of 17 r/min, feed rate of 3.25 m^3/h and tailings slurry concentration of 20%, giving the reference values to the industrial production in Baishitamu Copper Mine.

Influence of coarse tailings on flocculation settlement

The composition of tailings particles in mines plays a key role in the flocculation settlement of slurries.To study the influence of coarse particle tailings(CPTs)on the flocculation settlement of tailings slurries(TSs),static flocculent settling tests,scanning electron microscopy observations,and laser particle size analyses were conducted using the tailings obtained from a copper mine.The results demonstrate that(i)in the accelerated and free settling process,CPTs did not directly settle at the bottom of graduated cylinders;instead,they were netted by the flocculent structures(FSs)and settled together more quickly.The CPTs accelerate the rapid settlement of TSs;the acceleration effect is more obvious when the CPTs content is greater than 50 wt%.(ii)The most appropriate flocculant unit consumption(FUC)is 20 g·t-1,and no substantial increase is observed in the flocculant settling velocity with an increase in the flocculant because the effective FSs did not substantially change and thus did not lead to a notable increase in the settling velocity of the solid–liquid interface(SLI).(iii)In the effective settling space of the thickening facility,free water quickly flowed from the pores of FSs,which is reflected in the period from 0 to 1 min.

Hydrophobic flocculation flotation of rutile fines in presence of styryl phosphonic acid

The hydrophobic flocculation flotation of rutile fines in the presence of styryl phosphonic acid（SPA） was investigated by flotation tests, zeta-potential measurement, optical microscope observation, laser-based particle size analysis, adsorption measurements and DLVO theory. The flotation tests indicated that rutile fines could be flocculated by SPA, and pH, shear force（stirring speed） and stirring time played significant roles in flocculation. The isoelectric point（IEP） and zeta-potential in whole range all moved to negative values as SPA was added according to the results from zeta-potential measurement. It was demonstrated that the primary reason for above was chemical adsorption. The laser-based particle size results showed the particle size at a stirring speed of 1800 r/min and 1000 mg/L SPA was the largest in all experiments. Furthermore, using the optical microscope observation and flotation tests, it was important for flotation of rutile fines to produce the flocculant. In the light of above-mentioned facts, floc flotation of rutile fines could be induced in the form of chemical adsorption by SPA to increase particle size. The data calculated from DLVO theory also indicated that chemical adsorption was the main reason for the formation of flocculant.

Synthesis and Flocculation Property of Chitosan-Acrylamide Graft Copolymer

Chitosan, as a kind of natural polymer, has many advantages, such as abundant sources, biological degradation, no secondary contamination and facile modification. In this work, we prepared modified chitosan flocculants with double electrical behavior via polymerizing chitosan, acrylamide and sodium carboxymethyl cellulose together by using ammonium persulfate as the indicator in water. The product is a comb-type of chitosan copolymer and a polymeric ampholyte. And then we studied the product by FTIR, UV-Vis, TG, DSC spectrometeries and viscometry, etc. We also performed CACM′s water treat experiment. The effects of pH values, reaction time and dose of the new floccalant on treating various of waste water have been investigated, too.

Flocculation of flotation tailings in presence of silicate gel and polymer

Flotation tailings were successfully flocculated in the presence of cationic polyacrylamide and silica gel.The effects of various parameters such as polymer weight,charge density,and pH on the rate of flocculation were also investigated in the current study.The flocculation mechanism of the flocculant on tailings was investigated using zeta potential and Fourier transform infrared(FTIR)measurements.The results obtained reveal that 1)sodium silicate gel,used as a binder for the consolidation of tailings form primary flocs,acts as an anchor and the adsorption of polymer flocculant on these anchors results in the formation of larger flocs and,consequently,enhanced settling rate;2)flocculation in the presence of silica gel and polymer has a faster settling rate than single-polymer flocculation owing to the mechanisms of charge neutralization and bridging as identified using zeta potential and FTIR measurements.A pilot level study was conducted to investigate the influence of processed water on the flotation of scheelite.The results show that the proposed tailing disposal method could improve scheelite recovery by 2%(approximately)and could reduce the daily operation costs of the plant by approximately 108.57 USD.

Comparison of selective flocculation of low grade goethitic iron ore fines using natural and synthetic polymers and a graft copolymer

This study aims to beneficiate low grade goethitic iron ore fines using a selective flocculation process. Selective flocculation studies were conducted using different polymers such as starch amylopectin(AP), poly acrylic acid(PAA), and a graft copolymer(AP-g-PAA). The obtained results were analyzed; they indicate the enhancement of the iron ore grade from 58.49% to 67.52% using AP-g-PAA with a recovery of 95.08%. In addition, 64.45% Fe with a recovery of 88.79% was obtained using AP. Similarly, using PAA, the grade increased to 63.46% Fe with a recovery of 82.10%. The findings are also supported by characterizing concentrates using X-ray diffraction(XRD) and electron probe microanalysis(EPMA) techniques.

Flocculation performance of a novel synthesized flocculant with low ecological risk

Combined flocculants with low ecological risk are urgently required in water supply and wastewater treatment in China. A novel flocculant was thus developed under the condition of low ecological risk(noted as CAS). The experiments to examine wastewater treatment performance of the new product showed that there was favourable performance in the flocculation process in contrast to commercial flocculants in treating kaolin suspensions, municipal effluent and domestic wastewater. Flocculation performance included the turbidity removal rate, sediment character and a decrease in COD(chemical oxygen demand). The sediment time of flocculation is short and the removal rate of turbidity treated by CAS is high compared with PAC(polyaluminum chloride), PAM(polyacrylamide) and the combined addition of PAC and PAM. The optimal concentration required to affect flocculation processes is dependent on kaolin concentration and the character of the wastewater within the range examined. It also showed that CAS is effective to treat wastewater with high turbidity.

Chemical and biological flocculation process to treat municipal sewage and analysis of biological function

The pilot scale experimental apparatus and the procedure of the chemical and biological flocculation process to verify the feasibility in treating Shanghai municipal sewage were introduced in this paper. In addition, the biological function of the process was discussed. The results of optimal running showed that in the reaction tank, the concentration of mixed liquor suspended solid(MLSS) was 2 g/L, hydraulic retention time(HRT) was 35 min, dosage of liquid polyaluminium chloride(PAC) was 60 mg/L, and the concentration of polyacrylamide(PAM) was 0 5 mg/L. The effluent average concentrations of COD Cr , TP, SS and BOD 5 were 50 mg/L, 0 62 mg/L, 18 mg/L, and 17 mg/L, respectively. These were better than the designed demand. In addition, the existence of biological degradation in this system was proven by several methods. The removal efficiencies of the chemical and biological flocculation process were 20% higher than that of the chemical flocculation process above at the same coagulant dosage. The treatment process under different situations was evaluated on a pilot scale experiment, and the results provided magnificent parameters and optimal condition for future operation of the plant.

Impact of dynamic distribution of floc particles on flocculation effect

Polyaluminum chloride （PAC） was used as coagulant and suspended particles in kaolin water. Online instruments including turbidimeter and particle counter were used to monitor the flocculation process. An evaluation model for demonstrating the impact on the flocculation effect was established based on the multiple linear regression analysis method. The parameter of the index weight of channels quantitatively described how the variation of floc particle population in different size ranges cause the decrement of turbidity. The study showed that the floc particles in different size ranges contributed differently to the decrease of turbidity and that the index weight of channel could excellently indicate the impact degree of floc particles dynamic distribution on flocculation effect. Therefore, the parameter may significantly benefit the development of coagulation and sedimentation techniques as well as the optimal coagulant selection.

Particle size distribution and removal by a chemical-biological flocculation process

The particle characterization from the influent and effluent of a chemical-biological flocculation （CBF） process was studied with a laser diffraction device. Water samples from a chemically enhanced primary treatment （CEPT） process and a primary sediment tank process were also analyzed for comparison. The results showed that CBF process was not only effective for both the big size particles and small size particles removal, but also the best particle removal process in the three processes. The results also indicated that CBF process was superior to CEPT process in the heavy metals removal. The high and non-selective removal for heavy metals might be closely related to its strong ability to eliminate small particles. Samples from different locations in CBF reactors showed that small particles were easier to aggregate into big ones and those disrupted flocs could properly flocculate again along CBF reactor because of the biological flocculation.

Recovering limonite from Australia iron ores by flocculation-high intensity magnetic separation

Successful recovery of limonite from iron fines was achieved by using flocculation-high intensity magnetic separation （FIMS） and adding hydrolyzed and causticized flocculants according to the characteristic of iron fines. The separation results of the three iron samples are as follows： iron grade 66.77%- 67.98% and the recovery of iron 69.26%-70.70% by the FIMS process with flocculants. The comparative results show that under the same separation conditions the F1MS process can effectively increase the recovery of iron by 10. 97%- 15.73%. The flowsheet results confirm the reliability of the process in a SHP high intensity magnetic separator. The concentrate product can he used as raw materials for direct reduction iron-smelting. The hydrolyzed and causticized flocculants can selectively flocculate fine feebly-magnetic iron mineral particles to increase their apparent separation sizes. The larger the separation size, the stronger the magnetic force. By comparing the separation results of the three samples it is found that among the three samples the higher the limonite content, the better the separation result. This means that the separation result relates closely to the flocculation process and the adding pattern of the flocculant.