1.27μm波段的氧分子近红外气辉是火星大气最重要的气辉辐射之一,该气辉高光谱分辨辐射传输模型的建立对于研制火星探测载荷,反演火星大气的风场温度场与臭氧浓度,以及研究火星空间物理,有重要的科学价值与工程意义.在研究火星大气O_(2)...1.27μm波段的氧分子近红外气辉是火星大气最重要的气辉辐射之一,该气辉高光谱分辨辐射传输模型的建立对于研制火星探测载荷,反演火星大气的风场温度场与臭氧浓度,以及研究火星空间物理,有重要的科学价值与工程意义.在研究火星大气O_(2)(a^(1)Δ_(g))气辉光化学反应模型的基础上,提出了O_(2)(a^(1)Δ_(g))气辉体辐射率的计算方法,并建立了火星大气气辉辐射传输理论;通过与用于研究火星大气特征的光谱学探测仪(Spectroscopy Spectrograph for the Investigation of Characteristics of the Atmosphere of Mars,SPICAM)的实测数据进行对比,验证了所建立的火星O_(2)(a^(1)Δ_(g))气辉高光谱分辨辐射传输模型的准确性;针对火星与地球大气的O_(2)(a^(1)Δ_(g))气辉,在体辐射率、自吸收效应,以及临边辐射光谱特性三个方面进行了系统深入的比较,对比结果表明,火星大气由于密度低、氧气丰度小,其自吸收效应可以忽略不计,但其O_(2)(a^(1)Δ_(g))气辉辐射强度与地球大气相当,可以用于火星大气的风场温度场与臭氧浓度的探测与反演.展开更多
Highly active solid superacid catalysts for n-butane isomerization, SZ/A1_2O_3-P, were prepared by supporting SO-(4-2)/ZrO2, (SZ) on y-A1_2O_3 carrier using a precipitation method. The activities of some catalysts wer...Highly active solid superacid catalysts for n-butane isomerization, SZ/A1_2O_3-P, were prepared by supporting SO-(4-2)/ZrO2, (SZ) on y-A1_2O_3 carrier using a precipitation method. The activities of some catalysts were enhanced significantly j The activity of the most active sample. 60%SZ/Al_2O3-P, was even about 2 times more active than that of the SZ catalyst.展开更多
Dynamic fluorescent materials play a crucial role in secure inks for data encryption;however,they are still plagued by issues such as photodegradation,poor latency,and susceptibility to unauthorized access.Herein,we p...Dynamic fluorescent materials play a crucial role in secure inks for data encryption;however,they are still plagued by issues such as photodegradation,poor latency,and susceptibility to unauthorized access.Herein,we propose a photochemically modulated dynamic fluorescent encryption system based on^(1)O_(2)sensitization of fluorescent composites,comprising a^(1)O_(2)-sensitive fluorophore(F2)and non-emissive polymers.After UV irradiation,in-situ generated^(1)O_(2)from the polymer effectively binds with F2 to form endoperoxides(F2EPO),resulting in a significant redshift in emission,up to 150 nm.The^(1)O_(2)concentration is closely related to the irradiation time,rendering different fluorescent colors in a time-gated fashion.Moreover,the emission of F2EPO can be regulated by polymer chemical structure,molecular weight,and crosslinking density.Relying on these merits,we develop a dynamic data encryption method with various non-emissive polymers as the data storage media,UV light irradiation as the data encoder,and F2 as the data decoder.UV light irradiation of diverse polymer solutions generates^(1)O_(2)at different concentrations,effectively encoding the data,which remains invisible under both UV and natural lights.The addition of F2 to these irradiated polymer solutions produces different redshifted fluorescence,enabling secure data decryption.Attributing to the non-emissive nature of the polymers,time-gated readout fashion,excellent latency of^(1)O_(2),and subtle interactions between^(1)O_(2)and F2,this data encryption is nearly undecipherable.This work offers an advantage data encryption approach beyond the reach of conventional fluorophores.展开更多
The present study reported fabrication of novel carbon quantum dots-MnFe_(2)O_(4)@ZIF-8(CQDs-MFO@ZIF-8)by using co-precipitation hydrothermal method for activation of peroxydisulfate(PDS)to degrade bisphenol A(BPA),on...The present study reported fabrication of novel carbon quantum dots-MnFe_(2)O_(4)@ZIF-8(CQDs-MFO@ZIF-8)by using co-precipitation hydrothermal method for activation of peroxydisulfate(PDS)to degrade bisphenol A(BPA),one of important emerging organic pollutants in water environment.CQDs-MFO@ZIF-8 served as a highly efficient thermal activated PDS catalyst with high catalytic degradation efficiency,reusability and stability.The catalyst achieved almost completely removal of 20.0 mg/L BPA within 5.0 min,and the degradation efficiency remained higher than 83%after 5 consecutive cycles.Free radicals(^(·)OH,SO_(4)^(·-)and^(·)O_(2)^(-))and non-free radicals((1)O_(2))were generated in the thermal PDS-activation system,in which singlet oxygen((1)O_(2))played a dominant role in the degradation of BPA.The potential toxicity of BPA degradation intermediates was analyzed upon the culture of E.coli and Chlorella sorokiniana by using Ecological Structure-Activity Relationship Model(ECOSAR)program.The catalytic performances of BPA degradation by CQDs-MFO@ZIF-8 were evaluated for treatment of different practical water samples to further verify the feasibility of practical applications.This study provides proof-in-concept demonstration of new nanomaterials for enhanced catalytic water decontamination.展开更多
Ⅰ. INTRODUCTIONHypocrellins are 3, 10-dihydroxyl-4, 9-perylenequinone derivatives. They are potent inhibitors of cancer cells. Besides <sup>1</sup>O<sub>2</sub> and O<sub>2</sub>&l...Ⅰ. INTRODUCTIONHypocrellins are 3, 10-dihydroxyl-4, 9-perylenequinone derivatives. They are potent inhibitors of cancer cells. Besides <sup>1</sup>O<sub>2</sub> and O<sub>2</sub><sup>,</sup> other radicals could also be involved in the effects of Hypocrellins on the photosensitization of erythrocyte membranes. The ESR signal with hyperfine structures could be obtained after illumination of Hypocrellin A, B (HA,展开更多
Bismuth titanate (Bi_(4)Ti_(3)O_(12),BIT)piezoelectric materials have attracted increasing attention due to their high-temperature applications.However,it is quite challenging to simultaneously achieve outstanding pie...Bismuth titanate (Bi_(4)Ti_(3)O_(12),BIT)piezoelectric materials have attracted increasing attention due to their high-temperature applications.However,it is quite challenging to simultaneously achieve outstanding piezoelectric properties and high Curie temperature in BIT-based systems.In this study,oxygen vacancy defects tailoring strategy was utilized to solve this problem,excellent piezoelectric coefficient(32.1 pC/N),and ultrahigh Curie temperature(659℃)are gotten in Bi_(4)Ti_(3)-x(Mn_(1/3)Nb_(2/3))xO_(12)(BTMN)ceramics,which are among the top values in the BIT-based ceramics.More importantly,the(Mn_(1/3)Nb_(2/3))(4+d)+complex-ion modified Bi_(4)Ti_(3)O_(12)-based ceramics are characterized with excellent piezoelectric stability up to 500℃(d33>30.0 pC/N at 500℃))and significantly reduced conductivity(only~10^(-7)U-1 cm^(-1)at 500℃).Moreover,enhanced ferroelectricity and good dielectric stability were also obtained.The better comprehensive properties can be ascribed to two aspects.First,the concentration of oxygen vacancy defects is obviously reduced,and their distribution is effectively controlled in BITMN ceramics.Second,the introduction of(Mn_(1/3)Nb_(2/3))^((4+δ)+)complex-ion gives rise to the antiphase boundaries and massive ferroelectric domain walls.This works not only reveal the high potential of BITMN ceramics for high-temperature piezoelectric applications but also deepen the understanding of the structure-properties relationship in BIT-based materials.展开更多
该研究中一种钌(Ⅱ)基配合物[Ru(phen)_(3)][PF_(6)]_(2)(phen=1,10-phenanthroline)被成功合成,用^(1)H NMR、FTIR和UV-vis表征其结构,并研究其在可见光下催化降解盐酸四环素(TC·HCl)的性能和影响因素。结果表明,该配合物在可见...该研究中一种钌(Ⅱ)基配合物[Ru(phen)_(3)][PF_(6)]_(2)(phen=1,10-phenanthroline)被成功合成,用^(1)H NMR、FTIR和UV-vis表征其结构,并研究其在可见光下催化降解盐酸四环素(TC·HCl)的性能和影响因素。结果表明,该配合物在可见光下能有效催化TC·HCl的降解,影响TC·HCl降解的主要因素是体系的pH值和溶解氧含量。在20℃、辐照强度50 mW/cm^(2)、[Ru(phen)_(3)][PF_(6)]_(2)和TC·HCl浓度分别为6.4 mg/L和20 mg/L的条件下,pH值由4增加到10,5 h TC·HCl降解率由7.8%增至88.9%。pH值为7.5时,去除体系溶解氧,5 h TC·HCl降解率由61.9%降至10.7%。TC·HCl降解过程复杂,主要涉及的活性种为单线态氧。展开更多
文摘1.27μm波段的氧分子近红外气辉是火星大气最重要的气辉辐射之一,该气辉高光谱分辨辐射传输模型的建立对于研制火星探测载荷,反演火星大气的风场温度场与臭氧浓度,以及研究火星空间物理,有重要的科学价值与工程意义.在研究火星大气O_(2)(a^(1)Δ_(g))气辉光化学反应模型的基础上,提出了O_(2)(a^(1)Δ_(g))气辉体辐射率的计算方法,并建立了火星大气气辉辐射传输理论;通过与用于研究火星大气特征的光谱学探测仪(Spectroscopy Spectrograph for the Investigation of Characteristics of the Atmosphere of Mars,SPICAM)的实测数据进行对比,验证了所建立的火星O_(2)(a^(1)Δ_(g))气辉高光谱分辨辐射传输模型的准确性;针对火星与地球大气的O_(2)(a^(1)Δ_(g))气辉,在体辐射率、自吸收效应,以及临边辐射光谱特性三个方面进行了系统深入的比较,对比结果表明,火星大气由于密度低、氧气丰度小,其自吸收效应可以忽略不计,但其O_(2)(a^(1)Δ_(g))气辉辐射强度与地球大气相当,可以用于火星大气的风场温度场与臭氧浓度的探测与反演.
文摘Highly active solid superacid catalysts for n-butane isomerization, SZ/A1_2O_3-P, were prepared by supporting SO-(4-2)/ZrO2, (SZ) on y-A1_2O_3 carrier using a precipitation method. The activities of some catalysts were enhanced significantly j The activity of the most active sample. 60%SZ/Al_2O3-P, was even about 2 times more active than that of the SZ catalyst.
基金supported by the National Natural Science Foundation of China(22275193 and 52303355)the Natural Science Foundation of Fujian Province(2021J06034)+2 种基金Self-deployment Project Research Program of Haixi Institutes,Chinese Academy of Science,CXZX-2022-GH09(E255KF0101)Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences(E055AJ01)the STS Project of Fujian-CAS(Grant No.:2023T3027).
文摘Dynamic fluorescent materials play a crucial role in secure inks for data encryption;however,they are still plagued by issues such as photodegradation,poor latency,and susceptibility to unauthorized access.Herein,we propose a photochemically modulated dynamic fluorescent encryption system based on^(1)O_(2)sensitization of fluorescent composites,comprising a^(1)O_(2)-sensitive fluorophore(F2)and non-emissive polymers.After UV irradiation,in-situ generated^(1)O_(2)from the polymer effectively binds with F2 to form endoperoxides(F2EPO),resulting in a significant redshift in emission,up to 150 nm.The^(1)O_(2)concentration is closely related to the irradiation time,rendering different fluorescent colors in a time-gated fashion.Moreover,the emission of F2EPO can be regulated by polymer chemical structure,molecular weight,and crosslinking density.Relying on these merits,we develop a dynamic data encryption method with various non-emissive polymers as the data storage media,UV light irradiation as the data encoder,and F2 as the data decoder.UV light irradiation of diverse polymer solutions generates^(1)O_(2)at different concentrations,effectively encoding the data,which remains invisible under both UV and natural lights.The addition of F2 to these irradiated polymer solutions produces different redshifted fluorescence,enabling secure data decryption.Attributing to the non-emissive nature of the polymers,time-gated readout fashion,excellent latency of^(1)O_(2),and subtle interactions between^(1)O_(2)and F2,this data encryption is nearly undecipherable.This work offers an advantage data encryption approach beyond the reach of conventional fluorophores.
基金supported by the National Natural Science Foundation of China(Nos.52270074,52170039 and U22A20241)the National Key Research and Development Plan“Intergovernmental International Science and Technology Innovation Cooperation”(No.2022YFE0135700)+1 种基金the Heilongjiang Provincial Natural Science Foundation of China(No.LH2021E117)the financial support by the University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province(No.UNPYSCT-2020068)。
文摘The present study reported fabrication of novel carbon quantum dots-MnFe_(2)O_(4)@ZIF-8(CQDs-MFO@ZIF-8)by using co-precipitation hydrothermal method for activation of peroxydisulfate(PDS)to degrade bisphenol A(BPA),one of important emerging organic pollutants in water environment.CQDs-MFO@ZIF-8 served as a highly efficient thermal activated PDS catalyst with high catalytic degradation efficiency,reusability and stability.The catalyst achieved almost completely removal of 20.0 mg/L BPA within 5.0 min,and the degradation efficiency remained higher than 83%after 5 consecutive cycles.Free radicals(^(·)OH,SO_(4)^(·-)and^(·)O_(2)^(-))and non-free radicals((1)O_(2))were generated in the thermal PDS-activation system,in which singlet oxygen((1)O_(2))played a dominant role in the degradation of BPA.The potential toxicity of BPA degradation intermediates was analyzed upon the culture of E.coli and Chlorella sorokiniana by using Ecological Structure-Activity Relationship Model(ECOSAR)program.The catalytic performances of BPA degradation by CQDs-MFO@ZIF-8 were evaluated for treatment of different practical water samples to further verify the feasibility of practical applications.This study provides proof-in-concept demonstration of new nanomaterials for enhanced catalytic water decontamination.
基金Project supported by the National Natural Science Foundation of China
文摘Ⅰ. INTRODUCTIONHypocrellins are 3, 10-dihydroxyl-4, 9-perylenequinone derivatives. They are potent inhibitors of cancer cells. Besides <sup>1</sup>O<sub>2</sub> and O<sub>2</sub><sup>,</sup> other radicals could also be involved in the effects of Hypocrellins on the photosensitization of erythrocyte membranes. The ESR signal with hyperfine structures could be obtained after illumination of Hypocrellin A, B (HA,
基金supported by the National Natural Science Foundation of China,China(Grant No.51932010)by the National Natural Science Foundation of Shanghai,China(Grant No.19ZR1464600).
文摘Bismuth titanate (Bi_(4)Ti_(3)O_(12),BIT)piezoelectric materials have attracted increasing attention due to their high-temperature applications.However,it is quite challenging to simultaneously achieve outstanding piezoelectric properties and high Curie temperature in BIT-based systems.In this study,oxygen vacancy defects tailoring strategy was utilized to solve this problem,excellent piezoelectric coefficient(32.1 pC/N),and ultrahigh Curie temperature(659℃)are gotten in Bi_(4)Ti_(3)-x(Mn_(1/3)Nb_(2/3))xO_(12)(BTMN)ceramics,which are among the top values in the BIT-based ceramics.More importantly,the(Mn_(1/3)Nb_(2/3))(4+d)+complex-ion modified Bi_(4)Ti_(3)O_(12)-based ceramics are characterized with excellent piezoelectric stability up to 500℃(d33>30.0 pC/N at 500℃))and significantly reduced conductivity(only~10^(-7)U-1 cm^(-1)at 500℃).Moreover,enhanced ferroelectricity and good dielectric stability were also obtained.The better comprehensive properties can be ascribed to two aspects.First,the concentration of oxygen vacancy defects is obviously reduced,and their distribution is effectively controlled in BITMN ceramics.Second,the introduction of(Mn_(1/3)Nb_(2/3))^((4+δ)+)complex-ion gives rise to the antiphase boundaries and massive ferroelectric domain walls.This works not only reveal the high potential of BITMN ceramics for high-temperature piezoelectric applications but also deepen the understanding of the structure-properties relationship in BIT-based materials.
文摘该研究中一种钌(Ⅱ)基配合物[Ru(phen)_(3)][PF_(6)]_(2)(phen=1,10-phenanthroline)被成功合成,用^(1)H NMR、FTIR和UV-vis表征其结构,并研究其在可见光下催化降解盐酸四环素(TC·HCl)的性能和影响因素。结果表明,该配合物在可见光下能有效催化TC·HCl的降解,影响TC·HCl降解的主要因素是体系的pH值和溶解氧含量。在20℃、辐照强度50 mW/cm^(2)、[Ru(phen)_(3)][PF_(6)]_(2)和TC·HCl浓度分别为6.4 mg/L和20 mg/L的条件下,pH值由4增加到10,5 h TC·HCl降解率由7.8%增至88.9%。pH值为7.5时,去除体系溶解氧,5 h TC·HCl降解率由61.9%降至10.7%。TC·HCl降解过程复杂,主要涉及的活性种为单线态氧。
