Molybdenum trioxide(MoO_(3))can be employed as an excellent host for intercalation due to its 2D lay-ered structure that connected by van der Waals interactions.Herein,a series of polyoxometalate-based MoO_(3) composi...Molybdenum trioxide(MoO_(3))can be employed as an excellent host for intercalation due to its 2D lay-ered structure that connected by van der Waals interactions.Herein,a series of polyoxometalate-based MoO_(3) composites(Al_(13)@MoO_(3))were successfully prepared by interpolating the Keggin-type polycationic AlO_(4)Al_(12)(OH)_(24)H_(2)O_(12)^(7+)(Al_(13))into MoO_(3)gallery.These composites can be applied to rapidly adsorb the anionic dye methyl orange(MO)through strong electrostatic interactions lead to compact and sta-ble gathering in the surrounding of the numerous charged Al_(13).Adsorption behaviors of composites with the different amount of Al_(13) were determined,these results revealed that Al_(13)-3.34%@MoO_(3)exhibited the most remarkable adsorption capacity.More importantly,the composite maintains superior adsorption capacity for five consecutive adsorption/desorption cycles,suggesting that Al_(13)@MoO_(3)can be an efficient and durable adsorbent.展开更多
Bismuth titanate (Bi_(4)Ti_(3)O_(12),BIT)piezoelectric materials have attracted increasing attention due to their high-temperature applications.However,it is quite challenging to simultaneously achieve outstanding pie...Bismuth titanate (Bi_(4)Ti_(3)O_(12),BIT)piezoelectric materials have attracted increasing attention due to their high-temperature applications.However,it is quite challenging to simultaneously achieve outstanding piezoelectric properties and high Curie temperature in BIT-based systems.In this study,oxygen vacancy defects tailoring strategy was utilized to solve this problem,excellent piezoelectric coefficient(32.1 pC/N),and ultrahigh Curie temperature(659℃)are gotten in Bi_(4)Ti_(3)-x(Mn_(1/3)Nb_(2/3))xO_(12)(BTMN)ceramics,which are among the top values in the BIT-based ceramics.More importantly,the(Mn_(1/3)Nb_(2/3))(4+d)+complex-ion modified Bi_(4)Ti_(3)O_(12)-based ceramics are characterized with excellent piezoelectric stability up to 500℃(d33>30.0 pC/N at 500℃))and significantly reduced conductivity(only~10^(-7)U-1 cm^(-1)at 500℃).Moreover,enhanced ferroelectricity and good dielectric stability were also obtained.The better comprehensive properties can be ascribed to two aspects.First,the concentration of oxygen vacancy defects is obviously reduced,and their distribution is effectively controlled in BITMN ceramics.Second,the introduction of(Mn_(1/3)Nb_(2/3))^((4+δ)+)complex-ion gives rise to the antiphase boundaries and massive ferroelectric domain walls.This works not only reveal the high potential of BITMN ceramics for high-temperature piezoelectric applications but also deepen the understanding of the structure-properties relationship in BIT-based materials.展开更多
基金jointly supported by the National Natural Science Foundation of China(No.22273093,No.41905018,No.21903080)the Ministry of Science and Technology of China(No.2022YFF0606500)。
基金the National Natural Science Foundation of China(Nos.21872021,21671033,22172022 and 22071019).
文摘Molybdenum trioxide(MoO_(3))can be employed as an excellent host for intercalation due to its 2D lay-ered structure that connected by van der Waals interactions.Herein,a series of polyoxometalate-based MoO_(3) composites(Al_(13)@MoO_(3))were successfully prepared by interpolating the Keggin-type polycationic AlO_(4)Al_(12)(OH)_(24)H_(2)O_(12)^(7+)(Al_(13))into MoO_(3)gallery.These composites can be applied to rapidly adsorb the anionic dye methyl orange(MO)through strong electrostatic interactions lead to compact and sta-ble gathering in the surrounding of the numerous charged Al_(13).Adsorption behaviors of composites with the different amount of Al_(13) were determined,these results revealed that Al_(13)-3.34%@MoO_(3)exhibited the most remarkable adsorption capacity.More importantly,the composite maintains superior adsorption capacity for five consecutive adsorption/desorption cycles,suggesting that Al_(13)@MoO_(3)can be an efficient and durable adsorbent.
基金supported by the National Natural Science Foundation of China,China(Grant No.51932010)by the National Natural Science Foundation of Shanghai,China(Grant No.19ZR1464600).
文摘Bismuth titanate (Bi_(4)Ti_(3)O_(12),BIT)piezoelectric materials have attracted increasing attention due to their high-temperature applications.However,it is quite challenging to simultaneously achieve outstanding piezoelectric properties and high Curie temperature in BIT-based systems.In this study,oxygen vacancy defects tailoring strategy was utilized to solve this problem,excellent piezoelectric coefficient(32.1 pC/N),and ultrahigh Curie temperature(659℃)are gotten in Bi_(4)Ti_(3)-x(Mn_(1/3)Nb_(2/3))xO_(12)(BTMN)ceramics,which are among the top values in the BIT-based ceramics.More importantly,the(Mn_(1/3)Nb_(2/3))(4+d)+complex-ion modified Bi_(4)Ti_(3)O_(12)-based ceramics are characterized with excellent piezoelectric stability up to 500℃(d33>30.0 pC/N at 500℃))and significantly reduced conductivity(only~10^(-7)U-1 cm^(-1)at 500℃).Moreover,enhanced ferroelectricity and good dielectric stability were also obtained.The better comprehensive properties can be ascribed to two aspects.First,the concentration of oxygen vacancy defects is obviously reduced,and their distribution is effectively controlled in BITMN ceramics.Second,the introduction of(Mn_(1/3)Nb_(2/3))^((4+δ)+)complex-ion gives rise to the antiphase boundaries and massive ferroelectric domain walls.This works not only reveal the high potential of BITMN ceramics for high-temperature piezoelectric applications but also deepen the understanding of the structure-properties relationship in BIT-based materials.
