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HKUST-1和Co-MOF-74颗粒的稳定性及其分离低浓度氙氪的实验研究 被引量:1
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作者 陈彬 傅钰 +7 位作者 户耀文 张文祥 马燕 伍岳 曹天 陈莉云 武山 马和平 《原子能科学技术》 EI CAS CSCD 北大核心 2023年第11期2170-2181,共12页
Xe和Kr的分离对放射性Xe同位素活度的准确测量具有重要意义。为研究HKUST-1和Co-MOF-74在核数据测量用气体源制备工况条件下的稳定性及其分离低浓度Xe和Kr的性能,本文首先使用粘结剂聚乙烯醇对HKUST-1和Co-MOF-74粉末样品进行造粒,并表... Xe和Kr的分离对放射性Xe同位素活度的准确测量具有重要意义。为研究HKUST-1和Co-MOF-74在核数据测量用气体源制备工况条件下的稳定性及其分离低浓度Xe和Kr的性能,本文首先使用粘结剂聚乙烯醇对HKUST-1和Co-MOF-74粉末样品进行造粒,并表征了造粒前后HKUST-1和Co-MOF-74样品的晶体结构,分析了造粒过程对晶体结构的影响;然后采用静态吸附法测定了N 2、Xe和Kr在粉末样品和颗粒样品上的吸附等温线;随后研究对比了粉末样品和颗粒样品的水稳定性、热循环稳定性和γ射线辐照稳定性;最后采用固定床吸附-脱附法开展了HKUST-1颗粒样品分离低浓度Xe和Kr的初步研究。结果表明:使用聚乙烯醇粘结剂造粒未对HKUST-1和Co-MOF-74粉末的晶体结构造成明显损伤,HKUST-1和Co-MOF-74颗粒样品的BET比表面积较造粒前分别减小11%和6%;HKUST-1和Co-MOF-74样品造粒前后在25℃时对低压下的Xe(Kr)吸附量基本相同,HKUST-1和Co-MOF-74颗粒样品的Xe/Kr亨利选择性分别为9.70和9.15;HKUST-1颗粒样品的水稳定性和热循环稳定性好于Co-MOF-74颗粒样品,HKUST-1和Co-MOF-74颗粒样品均具有良好的耐γ射线辐照性能;采用固定床吸附-脱附法,HKUST-1颗粒样品可将低浓度的Xe和Kr分离,Xe和Kr的柱分离度为0.96。 展开更多
关键词 HKUST-1 Co-MOF-74 颗粒 稳定性 吸附 分离
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Description of the shape coexistence in neutron-deficient ^(74,76)Kr with IBM2
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作者 DaLi Zhang ChengFu Mu 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2016年第8期43-49,共7页
The shape deformation and shape coexistence in ^(74,76) Kr isotopes are investigated within the framework of the proton-neutron interacting boson model(IBM2). By considering the relative energy of the d proton boson t... The shape deformation and shape coexistence in ^(74,76) Kr isotopes are investigated within the framework of the proton-neutron interacting boson model(IBM2). By considering the relative energy of the d proton boson to be different from that of the neutron boson, the low-lying energy spectrum is in good agreement with experimental results both qualitatively and quantitatively. In particular, the low-lying 0_2^+ states associated with the shape-coexistence phenomenon are reproduced quite well. The calculated key sensitive quantities of B(E2) transition branch ratios are fairly consistent with the experimental data except for R_4. The predicated deformation parameter is very similar for the ground states in ^(74)Kr and ^(76)Kr, showing good agreement with the experimental result,and the calculated deformation parameter for the second 0^+ state in ^(74)Kr is close to the experimental data. The calculated results of the triaxiality parameter indicated an almost purely prolate shape for the ground state of ^(76)Kr and a mostly prolate shape with a little triaxiality for the ground state of ^(74)Kr. The calculations also show an oblate triaxial shape for the second 0^+ state in ^(76)Kr and maximum triaxiality for the second 0^+ state in ^(74)Kr. These results confirm the importance of the triaxial deformation for the description of such shape coexistence. 展开更多
关键词 ^^(74)kr ^^(76)kr shape coexistence low-ling energy states IBM2
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