高效液相色谱法测定双黄连口服液中黄芩苷含量的比对实验

目的对14个实验室比对实验结果进行总结和分析。方法采用贝塞尔统计方法处理样本数据,用Z比分数衡量一个实验室的检测结果与平均值的偏离程度。结果14个实验室的|Z|<2,表明各实验室检测结果满意,其中85%以上的实验室|Z|≤1,检测结果离散较小。结论14个实验室质量管理较为严谨,比对实验数据准确、可靠。

A numerical study on water diversion ratio of the Changjiang(Yangtze)estuary in dry season

We studied the flood, ebb and tidal averaged along (net) water diversion ratio (WDR) during dry season in the Changjiang (Yangtze) estuary, China, along with the effects of northerly wind, river discharge, tide and their interactions on WDR using the improved version of three-dimensional numerical model ECOM. Using data for annual mean wind speed and river discharge during January, we determined that the flood, ebb, net WDR values in the North Branch of the estuary were 3.48%, 1.68%,-4.06% during spring tide, and 4.82%, 2.34%,-2.79% during neap tide, respectively. Negative net WDR values denote the transport of water from the North Branch into the South Branch. Using the same data, the corresponding ratios were 50.09%, 50.92%, 54.97%, and 52.33%, 50.15%, 43.86% in the North Channel and 38.56%, 44.78%, 103.96%, and 36.92%, 43.17%, 60.97% in the North Passage, respectively. When northerly wind speed increased, landward Ekman transport was enhanced in the North Branch, increasing the flood WDR, while the ebb WDR declined and the net WDR exhibited a significant decrease. Similarly, in the North Channel, the flood WDR is increased, the ebb WDR reduced, and the net WDR showed a marked decrease. In the North Passage, the flood WDR also increased while the ebb and net WDR declined. As the river discharge increased, the flood and ebb WDR of the North Branch increased slightly and the net WDR increased markedly. In the North Channel the flood and ebb WDR changed very slightly, while the net WDR declined during spring tides and increased during neap tides. The WDR in the North Passage changed slightly during flood and ebb tides while the net WDR showed a marked increase. The WDR values of different bifurcations and the responses to northerly wind, river discharge, and tide are discussed in comparison with variations in river topography, horizontal wind-induced circulation, and tidal-induced residual current.

Numerical Investigation on Effect of Vapor Split Ratio to Performance and Operability for Dividing Wall Column

Operability problem of dividing wall column (DWC) raised by vapor split was investigated by numerically analyzing four cases defined by different compositions of a three-component mixture. DWCs were firstly designed for each case by optimizing the vapor split to the two sides of the dividing wall, and then their feasibilities and total annual costs in operation were evaluated against different vapor split ratios. The analysis on the operability of the DWC for four cases was made based on two scenarios: (1) vapor split is shifted by the vapor resistance difference between the column sections in the two sides of the dividing wall and (2) the feed composition is changed. It was demonstrated that the positioning of the dividing wall and the decision on the vapor split may affect significantly the operability of a DWC.

Rate Coefficients and Branching Ratio for Multi-Channel Hydrogen Abstractions from CH3OH by F

The hydrogen abstraction reaction F+CH3OH has two possible reaction pathways: HF+CH3O and HF+CH2OH. Despite the absence of intrinsic barriers for both channels, the former has a branching ratio comparable to the latter, which is far from the statistical limit of 0.25 (one out of four available H atoms). Furthermore, the measured branching ratio of the two abstraction channels spans a large range and is not quantitatively reproduced by previous theoretical predictions based on the transition-state theory with the stationary point information calculated at the levels of MФller-Plesset perturbation theory and G2. This work reports a theoretical investigation on the kinetics and the associated branching ratio of the two competing channels of the title reaction using a quasi-classical trajectory approach on an accurate full-dimensional potential energy surface (PES) fitted by the permutation invariant polynomial-neural network approach to ca. 1.21x10^5 points calculated at the explicitly correlated (F12a) version of coupled cluster singles doubles and perturbative triples (CCSD(T)) level with the aug-cc-pVDZ basis set. The calculated room temperature rate coeffcient and branching ratio of the HF+CH3O channel are in good agreement with the available experimental data. Furthermore, our theory predicts that rate coeffcients have a slightly negative temperature dependence, consistent with barrierless nature of the reaction.

Quantitative comparison of similarity measure and entropy for fuzzy sets

Comparison and data analysis with the similarity measures and entropy for fuzzy sets were carried out. The distance proportional value between the fuzzy set and the corresponding crisp set was considered by the fuzzy entropy. The relation between the similarity measure and the entropy for fuzzy set was also analyzed. The fuzzy entropy was reformulated as the dissimilarity measure. Furthermore, crisp set having the minimum uncertainty with respect to the corresponding fuzzy set was also proposed. Finally, derivation of a similarity measure from entropy with the help of total information property was derived. A simple example shows the relation between similarity measure and fuzzy entropy, in which the summation of similarity measure and fuzzy entropy represents a constant value.

Applications of Jacobi Elliptic Function Expansion Method for Nonlinear Differential-Difference Equations

The Jacobi elliptic function expansion method is extended to derive the explicit periodic wave solutions for nonlinear differential-difference equations. Three well-known examples are chosen to illustrate the application of the Jacobi elliptic function expansion method. As a result, three types of periodic wave solutions including Jacobi elliptic sine function, Jacobi elliptic cosine function and the third elliptic function solutions are obtained. It is shown that the shock wave solutions and solitary wave solutions can be obtained at their limit condition.

Analytical Algorithms for the Blend Ratios by Fibre-bundle Tensile Curves Part Ⅱ: Calculations of the Modulus Method and the Percentage Method

The principles for the modulus method and the percentage method are established and discussed in the part following Part Ⅰ of the series papers, in which we proposed the various algorithms of the strength method and the work method. The samples of Wool/PET blended fibre bundles, the method of fibre-bundle tensile tests and the typical specific stress-extension curves from the fibre bundles with different blend ratios are the same as in Part Ⅰ. It can be found that the theoretical results estimated by the modulus and percentage methods accord with the experimental values highly though the calculations of the two methods are slightly more complex than those of the strength and work methods. Especially, using the modulus method can not only avoid the influence of the error caused by the determination of the tensile curve of no fibre breaking in stretching, Y(e), but also need not to know the tensile curves of mono-component fibre bundles in certain calculation. The latter advantage of the modulus method exists in the percentage method too, but it should adopt the improved calculation of ones.

Repeating Fractions and Primes

In base-I 0 number system, the repeating fractions possess quite lot more properties than could be thought, including natures of primes.

Mechanical behaviour analysis and support system field experiment of confined concrete arches

Soft rock control is a big challenge in underground engineering.As for this problem,a high-strength support technique of confined concrete(CC)arches is proposed and studied in this paper.Based on full-scale mechanical test system of arch,research is made on the failure mechanism and mechanical properties of CC arch.Then,a mechanical calculation model of circular section is established for the arches with arbitrary section and unequal rigidity;a calculation formula is deduced for the internal force of the arch;an analysis is made on the influence of different factors on the internal force of the arch;and a calculation formula is got for the bearing capacity of CC arch through the strength criterion of bearing capacity.With numerical calculation and laboratory experiment,the ultimate bearing capacity and internal force distribution is analyzed for CC arches.The research results show that:1)CC arch is 2.31 times higher in strength than the U-shaped steel arch and has better stability;2)The key damage position of the arch is the two sides;3)Theoretical analysis,numerical calculation and laboratory experiment have good consistency in the internal force distribution,bearing capacity,and deformation and failure modes of the arch.All of that verifies the correctness of the theoretical calculation.Based on the above results,a field experiment is carried out in Liangjia Mine.Compared with the U-shaped steel arch support,CC arch support is more effective in surrounding rock deformation control.The research results can provide a basis for the design of CC arch support in underground engineering.

Study on dynamic response of embedded long span corrugated steel culverts using scaled model shaking table tests and numerical analyses

A series of scaled-model shaking table tests and its simulation analyses using dynamic finite element method were performed to clarify the dynamic behaviors and the seismic stability of embedded corrugated steel culverts due to strong earth-quakes like the 1995 Hyogoken-nanbu earthquake. The dynamic strains of the embedded culvert models and the seismic soil pressure acting on the models due to sinusoidal and random strong motions were investigated. This study verified that the cor-rugated culvert model was subjected to dynamic horizontal forces (lateral seismic soil pressure) from the surrounding ground, which caused the large bending strains on the structure; and that the structures do not exceed the allowable plastic deformation and do not collapse completely during strong earthquake like Hyogoken-nanbu earthquake. The results obtained are useful for design and construction of embedded long span corrugated steel culverts in seismic regions.

Theoretical Investigations on Photodissociation Dynamics of Deuterated Alkyl Halides CD_(3)CH_(2)F

The product branching ratio between different products in multichannel reactions is as important as the overall rate of reaction,both in terms of practical applications(e.g.models of combustion or atmosphere chemistry)in understanding the fundamental mechanisms of such chemical reactions.A global ground state potential energy surface for the dissociation reaction of deuterated alkyl halide CD_(3)CH_(2)F was computed at the CCSD(T)/CBS//B3 LYP/aug-cc-p VDZ level of theory for all species.The decomposition of CD_(3)CH_(2)F is controversial concerning C-F bond dissociation reaction and molecular(HF,DF,H_(2),D_(2),HD)elimination reaction.RiceRamsperger-Kassel-Marcus(RRKM)calculations were applied to compute the rate constants for individual reaction steps and the relative product branching ratios for the dissociation products were calculated using the steady-state approach.At the different energies studied,the RRKM method predicts that the main channel for DF or HF elimination from1,2-elimination of CD_(3)CH_(2)F is through a four-center transition state,whereas D_(2) or H_(2) elimination from 1,1-elimination of CD_(3)CH_(2)F occurs through a direct three-center elimination.At 266,248,and 193 nm photodissociation,the main product CD_(2)CH_(2)+DF branching ratios are computed to be 96.57%,91.47%,and 48.52%,respectively;however,at 157 nm photodissociation,the product branching ratio is computed to be 16.11%.Based on these transition state structures and energies,the following photodissociation mechanisms are suggested:at 266,248,193 nm,CD_(3)CH_(2)F→absorption of a photon→TS5→the formation of the major product CD_(2)CH_(2)+DF;at 157 nm,CD_(3)CH_(2)F→absorption of a photon→D/F interchange of TS1→CDH_(2)CDF→H/F interchange of TS2→CHD_(2)CHDF→the formation of the major product CHD_(2)+CHDF.

Semileptonic Decays of B_s^(**) Mesons into D_(s1) and D_(s2)~* in HQET

In the framework of the heavy quark effective theory, the leading order Isgur-Wise functions relevant to semileptonie decays of the orbitally P-wave excited Bs meson states Bs＊, including the newly found narrow Bs1 （5830） andBs2（5840） states, into the （Ds1（2536）, Ds2（2573）） doublet are calculated from QCD sum rules. With these universal form factors, the decay rates and branching ratios are also estimated.

Crustal Thickness and Velocity Ratio beneath National Seismic Stations in the Sichuan-Yunnan Area Based on Receiver Function Analysis

By using the teleseismic receiver function method, this paper analyzes the crustal thickness and Vp/Vs ratios beneath the 4 National seismic stations （KMI, TNC, CD2 and PZH） in the Sichuan-Yunnan area. This study gives the variance of Moho depths and velocity ratios of the 4 stations in different directions. The results show that the Moho depth beneath the Kunming station is around 50km, and the vdocity ratio varies between 1.62 and 1.69. The thickness of crust and the velocity ratio do not change much with the direction. The crust beneath Tengchong station shows clear directivity, being 40.7km thick in the northeast and 49.7km thick in the southeast. The difference of the Vp/Vs values is remarkable between the two directions, reaching 0.2. The Chengdu station also has shallow Moho, about 40km, but is 8km deeper in the northeast and southwest and the vdocity ratio has a change of 0.13 between the two directions. The crust beneath the Panzhihua station is stable. In all directions, the Moho depth is around 60km and the Vp/Vs ratio doesn＇t change significantly.

Re-study of Nucleon Pole Contribution in J/ψ → NN^-π Decay

We re-study nucleon pole contribution in J/ψ → NN^-π decays by including the imaginary part for the propagator of the off-shell nucleon with energy above π N threshold. It is found that when including the imaginary part in the propagator, the branching ratio of the decay width will descend about 11% compared with the result without including the imaginary part, no matter whether including the off-shell form factors or not. It also leads to a phase of up to 25° for the off-shell nucleon propagator at invariant mass around 1400 MeV. This effect needs to be considered for detailed partial wave analysis of N^＊ resonances around this mass region.

Evaluation of Landsat 7 ETM＋ Data for Spectral Discrimination and Classification of Sugarcane Varieties in Colombia

The identification of sugarcane varieties through remote sensing is studied to reduce the time taken to identify in the field, also is useful to identify non-certified varieties and to monitor the adoption of new varieties. The purpose of this study is to evaluate the Landsat 7 ETM＋ images to discriminate varieties CC85-92 and CC84-75 in the Cauca river valley in Colombia. The method used to measure the spectral separability between varieties was Jeffries-Matusita. The results indicated that the only period where a clear discrimination of the varieties is between 4th and 5th months, with a global precision of 80.8% and kappa index 0.62. The proposed methodology and preliminary results show that remote sensing is a useful tool for monitoring and identification of varieties and could be used for identification of varieties already registered and planted in other countries without the consent of their true creators.

Solving Nonlinear Wave Equations by Elliptic Equation

The elliptic equation is taken as a transformation and applied to solve nonlinear wave equations. It is shown that this method is more powerful to give more kinds of solutions, such as rational solutions, solitary wave solutions,periodic wave solutions and so on, so it can be taken as a generalized method.

Uncertainty Study of B_d(B_s)→γv Decays

B^0(B+s)→γvv decays are useful to determining the decay constants f_B(f_B_s) and B(B_s) meson wavefunction.Using the B meson wave function determined in hadronic B(Bs) decays,we study the uncertainties due tothe types of B meson wave functions.We find that the branching ratios are sensitive to the type of wave functions andinput parameters,but the energy spectrum is independent.The predicted branching ratios are (0.45-1.04) ×10^(-9) and(2.14-3.27) × 10^(-8) for B^0 and B_s decay,respectively.

Performance of an Improved One-Way Error Reconciliation Protocol Based on Key Redistribution

In data post-processing for quantum key distribution, it is essential to have a highly efficient error reconciliation protocol. Based on the key redistribution scheme, we analyze a one-way error reconciliation protocol by data simulation. The relationship between the error correction capability and the key generation efficiency of three kinds of Hamming code are demonstrated. The simulation results indicate that when the initial error rates are （0,1.5%], （1.5,4%], and （4,11%], using the Hamming （31,26）, （15,11）, and （7,4） codes to correct the error, respectively, the key generation rate will be maximized. Based on this, we propose a modified one-way error reconciliation protocol which employs a mixed Hamming code concatenation scheme. The error correction capability and key generation rate are verified through data simulation. Using the parameters of the posterior distribution based on the tested data, a simple method for estimating the bit error rate （BER） with a given confidence interval is estimated. The simulation results show that when the initial bit error rate is 10.00%, after 7 rounds of error correction, the error bits are eliminated completely, and the key generation rate is 10.36%; the BER expectation is 2.96×10^-10, and when the confidence is 95% the corresponding BER upper limit is 2.17×10^-9. By comparison, for the single （7,4） Hamming code error reconciliation scheme at a confidence of 95%,the key generation rate is only 6.09%, while the BER expectation is 5.92x 10＂9, with a BER upper limit of 4.34×10^-8. Hence, our improved protocol is much better than the original one.

Analysis of fouling characteristic in enhanced tubes using multiple heat and mass transfer analogies

This paper provides a comprehensive analysis on cooling tower fouling data taken from seven 15.54 mm I.D. helically ribbed, copper tubes and a plain tube at Re = 16000. There are two key processes during fouling formation： fouling deposition and fouling removal, which can be determined by mass transfer and fluid friction respectively. The mass transfer coefficient can be calculated through three analogies： Prandtl analogy, VonKarman analogy, and Chilton-Colburn analogy. Based on our analyses, Von-Karman analogy is the optimized analogy, which can well predict the formation of cooling tower fouling. Series of semi-theoretical fouling correlations as a function of the product of area indexes and efficiency indexes were developed, which can be applicable to different internally ribbed geometries. The correlations can be directly used to assess the fouling ootential of enhanced tubes in actual coolinu tower water situations.

Predictive Functional Controller with a Similar Proportional Integral Optimal Regulator Structure:Comparison with Traditional Predic-tive Functional Controller and Application to Heavy Oil Coking Equipment

By extending the system's state variables,a novel predictive functional controller has been developed.The structure of this controller is similar to that of classical proportional integral(PI)optimal controller and in-cludes a control block that can perform a feed-forward control of future P-step set points.It considers both the state variables and the output errors in its cost function,which results in enhanced control performance compared with traditional state space predictive functional control(TSSPFC)methods that consider only the predictive output er-rors.The predictive functional controller(PFC)has been compared with TSSPFC in terms of tracking ability,dis-turbance rejection,and also based on its application to heavy oil coking equipment.The results obtained show the effectiveness of the controller.