This work aims to compute stability derivatives in the Newtonian limit in pitch when the Mach number tends to infinity.In such conditions,these stability derivatives depend on the Ogive’s shape and not the Mach numbe...This work aims to compute stability derivatives in the Newtonian limit in pitch when the Mach number tends to infinity.In such conditions,these stability derivatives depend on the Ogive’s shape and not the Mach number.Generally,the Mach number independence principle becomes effective from M=10 and above.The Ogive nose is obtained through a circular arc on the cone surface.Accordingly,the following arc slopes are consideredλ=5,10,15,−5,−10,and−15.It is found that the stability derivatives decrease due to the growth inλfrom 5 to 15 and vice versa.Forλ=5 and 10,the damping derivative declines with an increase inλfrom 5 to 10.Yet,for the damping derivatives,the minimum location remains at a pivot position,h=0.75 for large values ofλ.Hence,whenλ=−15,the damping derivatives are independent of the cone angles for most pivot positions except in the early twenty percent of the leading edge.展开更多
A<sub>2</sub>FeCoO<sub>6-δ</sub> (A = Ca or Sr) is synthesized by the solid-state synthesis method and their specific heat capacities are evaluated at 40˚C using a heat flow meter. The effect ...A<sub>2</sub>FeCoO<sub>6-δ</sub> (A = Ca or Sr) is synthesized by the solid-state synthesis method and their specific heat capacities are evaluated at 40˚C using a heat flow meter. The effect of the A-cation size on the specific heat capacity of these compounds is observed. The specific heat capacity of Sr<sub>2</sub>FeCoO<sub>6-δ</sub> is found to be the highest, and that of Ca<sub>2</sub>FeCoO<sub>6-δ</sub> is the lowest while CaSrFeCoO<sub>6-δ</sub> shows the intermediate value. The specific heat capacity decreases with the decrease of the average A-site ionic radius, demonstrating the relationship between heat capacity and A-site ionic radius. The relationship between specific heat capacity and molar mass is also confirmed as the δ value decreases or molar mass increases from Ca<sub>2</sub>FeCoO<sub>6-δ</sub> to CaSrFeCoO<sub>6-δ</sub> to Sr<sub>2</sub>FeCoO<sub>6-δ</sub>.展开更多
The specific heat capacities of Cu60Zr20Hfl0Til0 bulk metallic glass (BMG) and crystallized alloys were measured from 2 to 101 K. The effect of crystallization on the specific heat capacity of the BMG was studied. T...The specific heat capacities of Cu60Zr20Hfl0Til0 bulk metallic glass (BMG) and crystallized alloys were measured from 2 to 101 K. The effect of crystallization on the specific heat capacity of the BMG was studied. The effects of crystallization and the relationship between local modes and boson peak in the BMG were discussed. The specific heat capacity deviates from the simple Debye behaviors, showing the presence of local harmonic modes (Einstein oscillator) in the BMG and the crystallized alloy. Model calculation includes the contribution of one Debye mode and two Einstein modes for the BMG, one Debye mode and one Einstein mode for the crystallized alloy, showing an adequate description of the experimental data.展开更多
Arrhenius law implicates that only those molecules which possess the internal energy greater than the activation energy Ea can react. However, the internal energy will not be proportional to the gas temperature if the...Arrhenius law implicates that only those molecules which possess the internal energy greater than the activation energy Ea can react. However, the internal energy will not be proportional to the gas temperature if the specific heat ratio y and the gas constant R vary during chemical reaction processes. The varying y may affect significantly the chemical reaction rate calculated with the Arrhenius law under the constant γ assumption, which has been widely accepted in detonation and combustion simulations for many years. In this paper, the roles of variable γ and R in Arrhenius law applications are reconsidered, and their effects on the chemical reaction rate are demonstrated by simulating one- dimensional C-J and two-dimensional cellular detonations. A new overall one-step detonation model with variable γ and R is proposed to improve the Arrhenius law. Numerical experiments demonstrate that this improved Arrhenius law works well in predicting detonation phenomena with the numerical results being in good agreement with experimental data.展开更多
The gas temperature within hypersonic boundary layer flow is so high that the specific heat of gas is no longer a constant but relates to temperature. How variable specific heat influences on boundary layer flow stabi...The gas temperature within hypersonic boundary layer flow is so high that the specific heat of gas is no longer a constant but relates to temperature. How variable specific heat influences on boundary layer flow stability is worth researching. The effect of the variable specific heat on the stability of hypersonic boundary layer flows is studied and compared with the case of constant specific heat based on the linear stability theory. It is found that the variable specific heat indeed has some effects on the neutral curves of both the first-mode and the second-mode waves and on the maximum rate of growth also. Therefore, the relationship between specific heat and temperature should be considered in the study of the stability of the boundary layer.展开更多
On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the qua...On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the quasione-dimensional interehain coupling organic ferromagnets are presented. We find that an obvious feature is to present itself the round peak for the specific heat with the temperature. This indicates unambiguously the presence of the phase transition in the system. The transition temperature plays down with increasing of the interchain coupling t2 or decreasing of the electron repulsion u. The curves of charge density with the temperature debase monotonously. This result illustrates that the higher the temperature is, the more electrons are excited.展开更多
The thermal decomposition process was studied by the TG–DTA analyzer. The results show that the decomposition process of sodium hydroxyethyl sulfonate consisted of three stages: the mass loss for the first, the secon...The thermal decomposition process was studied by the TG–DTA analyzer. The results show that the decomposition process of sodium hydroxyethyl sulfonate consisted of three stages: the mass loss for the first, the second and third stages may be about the groups of CH_3CH_2OH, CH_3CHO and SO_2 volatilized, respectively. The decomposition residuum of three stages was analyzed by FT-IR, and the results of FT-IR agreed with the decomposition process predicted by theoretical weight loss. The specific heat capacity of sodium hydroxyethyl sulfonate was determined by differential scanning calorimetry(DSC). The melting temperature and melting enthalpy were obtained to be 465.41 K and 25.69 kJ·mol^(-1), respectively. The molar specific heat capacity of sodium hydroxyethyl sulfonate was determinated from 310.15 K to 365.15 K and expressed as a function of temperature.展开更多
Nanofluids are extensively applied in various heat transfer mediums for improving their heat transfer characteristics and hence their performance.Specific heat capacity of nanofluids,as one of the thermophysical prope...Nanofluids are extensively applied in various heat transfer mediums for improving their heat transfer characteristics and hence their performance.Specific heat capacity of nanofluids,as one of the thermophysical properties,performs principal role in heat transfer of thermal mediums utilizing nanofluids.In this regard,different studies have been carried out to investigate the influential factors on nanofluids specific heat.Moreover,several regression models based on correlations or artificial intelligence have been developed for forecasting this property of nanofluids.In the current review paper,influential parameters on the specific heat capacity of nanofluids are introduced.Afterwards,the proposed models for their forecasting and modeling are proposed.According to the reviewed works,concentration and properties of solid structures in addition to temperature affect specific heat capacity to large extent and must be considered as inputs for the models.Moreover,by using other effective factors,the accuracy and comprehensive of the models can be modified.Finally,some suggestions are offered for the upcoming works in the relevant topics.展开更多
The specific heat of superheated Al 10Sr melts was determined at different heating rates between 1 K/min and 20 K/min using a differential scanning calorimeter(DSC). As a whole, the specific heat increases with increa...The specific heat of superheated Al 10Sr melts was determined at different heating rates between 1 K/min and 20 K/min using a differential scanning calorimeter(DSC). As a whole, the specific heat increases with increasing temperature. A hump is observed on the specific heat curve at the temperature corresponding to the phase boundary temperature dependent on heating rate. Moreover, the hump shifts to higher temperature in the measured temperature range from about 840 ℃ to 890 ℃ with increasing heating rate. At certain temperature in the higher superheated zone, the specific heat of the melt as a function of temperature shows a sharp rise . The result indicates that disorder zone fraction begins to increase while atom clusters fraction decreases at the breaking temperature. [展开更多
We investigate the particle-hole fluctuation correction to the specific heat of an ultracold Fermi gas at unitarity within the framework of the non-self-consistent T-matrix approximation in the normal phase. We find g...We investigate the particle-hole fluctuation correction to the specific heat of an ultracold Fermi gas at unitarity within the framework of the non-self-consistent T-matrix approximation in the normal phase. We find good agreement between our theoretical predictions and the experimental data measured by the MIT group, apart from discrepancies near the transition temperature. At high temperature, our calculated specific heat has the tendency to approach the specific heat of the Boltzmann gas.展开更多
The alloys of non-centrosymmetric superconductor, Re3W, which were reported to have an ^-Mn structure [P. Greenfield and P. A. Beck, J. Metals, N. Y. 8, 265 (1959)] with Tc = 9K, are prepared by arc melting. The val...The alloys of non-centrosymmetric superconductor, Re3W, which were reported to have an ^-Mn structure [P. Greenfield and P. A. Beck, J. Metals, N. Y. 8, 265 (1959)] with Tc = 9K, are prepared by arc melting. The values of ac susceptibility and the low-temperature specific heat of these alloys are measured. It is found that there are two superconducting phases coexisting in the samples with Tc1 ≈ 9 K and Tc2 ≈ 7K, which are both non-centrosymmetric in structure as reported previously. By analysing the specific heat data measured in various magnetic fields down to a temperature of 1.8 K, we find that the absence of the inversion symmetry does not lead to an obvious deviation from an s-wave pairing symmetry in Re3W.展开更多
The specific heats of both a two-layer ferromagnetic superlattice and a two-layer ferrimagnetic one arestudied.It is found that the spin quantum numbers,the interlayer and intralayer exchange couplings,the anisotropy,...The specific heats of both a two-layer ferromagnetic superlattice and a two-layer ferrimagnetic one arestudied.It is found that the spin quantum numbers,the interlayer and intralayer exchange couplings,the anisotropy,theapplied magnetic field,and the temperature all affect the specific heat of these superlattices.For both the ferromagneticand ferrimagnetic superlattices,the specific heat decreases with increasing the spin quantum number,the absolutevalue of interlayer exchange coupling,intralayer exchange coupling,and anisotropy,while it increases with increasingtemperature at low temperatures.When an applied magnetic field is enhanced,the specific heat decreases in the two-layerferromagnetic superlattice,while it is almost unchanged in the two-layer ferrimagnetic superlattice at low fieldrange at low temperatures.展开更多
A new compound, [(NH2)2C=NH2]+N(NO2)2-(GDN), was prepared by mixing ammonium dinitramide (ADN) and guanidine hydrochloride in water. The thermal behavior of GDN was studied under the non-isothermal conditions...A new compound, [(NH2)2C=NH2]+N(NO2)2-(GDN), was prepared by mixing ammonium dinitramide (ADN) and guanidine hydrochloride in water. The thermal behavior of GDN was studied under the non-isothermal conditions with DSC and TG/DTG methods. The apparent activation energy(E) and pre-exponential constant(A) of the exothermic decomposition stage of GDN were 118.75 kJ/mol and 10^10.86 s^-1, respectively. The critical temperature of the thermal explosion(Tb) of GDN was 164.09 ℃. The specific heat capacity of GDN was determined with the Micro-DSC method and the theoretical calculation method, and the standard molar specific heat capacity was 234.76 J·mol^-1·K^-1 at 298.15 K. The adiabatic time-to-explosion of GDN was also calculated to be a certain value between 404.80 and 454.95 s.展开更多
When the air temperature reaches 600 K or higher, vibration is excited. The specific heat is not a constant but a function of temperature. Under this condition, the transition position of hypersonic sharp wedge bounda...When the air temperature reaches 600 K or higher, vibration is excited. The specific heat is not a constant but a function of temperature. Under this condition, the transition position of hypersonic sharp wedge boundary layer is predicted by using the improved eN method considering variable specific heat. The transition positions with different Mach numbers of oncoming flow, half wedge angles, and wall conditions are computed condition, the nearer to the Mach number The results show that for the same oncoming flow condition and wall transition positions of hypersonic sharp wedge boundary layer move much leading edge than those of the flat plate. The greater the oncoming flow the closer the transition position to the leading edge.展开更多
The molecular-based magnetic materials AFe11 Fe111(C2O4)3 have a honeycomb structure in which FeII (S = 2) and FeIH (S= 5/2) occupy sites alternately. They can be described as mixed spin-2 and spin-5/2 Ising mod...The molecular-based magnetic materials AFe11 Fe111(C2O4)3 have a honeycomb structure in which FeII (S = 2) and FeIH (S= 5/2) occupy sites alternately. They can be described as mixed spin-2 and spin-5/2 Ising model with ferrimagnetic interlayer coupling. The influences of the transverse field on the internal energy and the specific heat of the molecalar-based magnetic system have been studied numerically by using the effective-field theory with self-spin correlations and the differential operator technique.展开更多
Superconducting thermal fluctuation(STF) plays an important role in both thermodynamic and transport properties in the vortex liquid phase of high Tsuperconductors.It was widely observed in the vicinity of the critica...Superconducting thermal fluctuation(STF) plays an important role in both thermodynamic and transport properties in the vortex liquid phase of high Tsuperconductors.It was widely observed in the vicinity of the critical transition temperature.In the framework of Ginz burg-Landau-La wrence-Doniach theory in magnetic field,a self-consistent analysis of STF including all Landau levels is given.Besides that,we calculate the contribution of STF to specific heat in vortex liquid phase for high Tcuprate superconductors,and the fitting results are in good agreement with experimental data.展开更多
Low-temperature specific heat in a dichalcogenide superconductor 2H-NbSe2 is measured in various magnetic fields. It is found that the specific heat can be described very well by a simple model concerning two componen...Low-temperature specific heat in a dichalcogenide superconductor 2H-NbSe2 is measured in various magnetic fields. It is found that the specific heat can be described very well by a simple model concerning two components corresponding to vortex normal core and ambient superconducting region, separately. For calculating the specific heat outside the vortex core region, we use the Bardeen-Cooper Schrieffer (BCS) formalism under the assumption of a narrow distribution of the superconducting gaps. The field-dependent vortex core size in the mixed state of 2H-NbSe2, determined by using this model, can explain the nonlinear field dependence of specific heat coefficient γ(H), which is in good agreement with the previous experimental results and more formal calculations. With the high-temperature specific heat data, we can find that, in the multi-band superconductor 2H-NbSe2, the recovered density of states (or Fermi surface) below Tc under a magnetic field seems not to be gapped again by the charge density wave (CDW) gap, which suggests that the superconducting gap and the CDW gap may open on different Fermi surface sheets.展开更多
Specific heat is a powerful tool to investigate the physical properties of condensed materials.Superconducting state is achieved through the condensation of paired electrons,namely,the Cooper pairs.The condensed Coope...Specific heat is a powerful tool to investigate the physical properties of condensed materials.Superconducting state is achieved through the condensation of paired electrons,namely,the Cooper pairs.The condensed Cooper pairs have lower entropy compared with that of electrons in normal metal,thus specific heat is very useful in detecting the low lying quasiparticle excitations of the superconducting condensate and the pairing symmetry of the superconducting gap.In this brief overview,we will give an introduction to the specific heat investigation of the physical properties of superconductors.We show the data obtained in cuprate and iron based superconductors to reveal the pairing symmetry of the order parameter.展开更多
In this paper,we report the measurements of the specific heat of the lanthanide oxides(La_2O_3,CeO_2, Pr_6O_(11),Nd_2O_3,Sm_2O_3,Eu_2O_3,Gd_2O_3,Tb_4O_7,Dy_2O_3,Ho_2O_3,Er_2O_3,Tm_2O_3,Yb_2O_3,Lu_2O_3)from-150℃ to 80...In this paper,we report the measurements of the specific heat of the lanthanide oxides(La_2O_3,CeO_2, Pr_6O_(11),Nd_2O_3,Sm_2O_3,Eu_2O_3,Gd_2O_3,Tb_4O_7,Dy_2O_3,Ho_2O_3,Er_2O_3,Tm_2O_3,Yb_2O_3,Lu_2O_3)from-150℃ to 800℃ by using adiabatic scanning calorimeter.We found that chemical reactions occur during the heating pro- cess of initial La_2O_3 and Nd_2O_3 materials by using DTA and X-ray diffraction.The results of specific heat measurement show that except CeO_2 and Tb_4O_7,other twelve lanthanide oxides were accompanied with endothermal change and weight loss to a certain degree during the heating process.展开更多
Specific heat(Cp)and effective thermal conductivity(λ)of native maize starch(NS)were measured by DSC and transient heat transfer method,respectively,at different moisture contents and temperatures.The dependency of t...Specific heat(Cp)and effective thermal conductivity(λ)of native maize starch(NS)were measured by DSC and transient heat transfer method,respectively,at different moisture contents and temperatures.The dependency of temperature(T)and moisture content(W)on the two parameters were investigated.The thermophysical properties of treated starch(TS)by four hydrothermal processes(RP-HMT,IV-HMT,DV-HMT and FV-HMT)were measured and compared to native strach.Hydrothermal treatments were performed at 3 bars(133°C)for 10 min.For Cp andλmeasurements,moisture content varied for NS from 5 to 21.5%d.b.and from 8.8 to 25%d.b.,respectively,and was fixed at 6%d.b.for TS.Empirical models were developed to specific heat and effective thermal conductivity,using a multiple regression algorithm with subsequent statistical analysis.The proposed models for NS based on T and W predict Cp andλwith a mean absolute error of 3.5%and 1.3%,respectively.Large differences in specific heat were observed between TS and NS.In a temperature range of 40 to 160°C,Cp values varied from 1.964 to 2.699 for NS and 1.380 to 2.085(J.g-1.°C-1)for TS.In contrast,the conductivity of NS was almost identical to that of treated starch by FV-HMT,followed in an increasing order by those treated by DV-HMT,RP-HMT,and IV-HM processes.展开更多
文摘This work aims to compute stability derivatives in the Newtonian limit in pitch when the Mach number tends to infinity.In such conditions,these stability derivatives depend on the Ogive’s shape and not the Mach number.Generally,the Mach number independence principle becomes effective from M=10 and above.The Ogive nose is obtained through a circular arc on the cone surface.Accordingly,the following arc slopes are consideredλ=5,10,15,−5,−10,and−15.It is found that the stability derivatives decrease due to the growth inλfrom 5 to 15 and vice versa.Forλ=5 and 10,the damping derivative declines with an increase inλfrom 5 to 10.Yet,for the damping derivatives,the minimum location remains at a pivot position,h=0.75 for large values ofλ.Hence,whenλ=−15,the damping derivatives are independent of the cone angles for most pivot positions except in the early twenty percent of the leading edge.
文摘A<sub>2</sub>FeCoO<sub>6-δ</sub> (A = Ca or Sr) is synthesized by the solid-state synthesis method and their specific heat capacities are evaluated at 40˚C using a heat flow meter. The effect of the A-cation size on the specific heat capacity of these compounds is observed. The specific heat capacity of Sr<sub>2</sub>FeCoO<sub>6-δ</sub> is found to be the highest, and that of Ca<sub>2</sub>FeCoO<sub>6-δ</sub> is the lowest while CaSrFeCoO<sub>6-δ</sub> shows the intermediate value. The specific heat capacity decreases with the decrease of the average A-site ionic radius, demonstrating the relationship between heat capacity and A-site ionic radius. The relationship between specific heat capacity and molar mass is also confirmed as the δ value decreases or molar mass increases from Ca<sub>2</sub>FeCoO<sub>6-δ</sub> to CaSrFeCoO<sub>6-δ</sub> to Sr<sub>2</sub>FeCoO<sub>6-δ</sub>.
基金Project(082102230035)supported by the Foundation of Science and Technology Department of Henan Province,China
文摘The specific heat capacities of Cu60Zr20Hfl0Til0 bulk metallic glass (BMG) and crystallized alloys were measured from 2 to 101 K. The effect of crystallization on the specific heat capacity of the BMG was studied. The effects of crystallization and the relationship between local modes and boson peak in the BMG were discussed. The specific heat capacity deviates from the simple Debye behaviors, showing the presence of local harmonic modes (Einstein oscillator) in the BMG and the crystallized alloy. Model calculation includes the contribution of one Debye mode and two Einstein modes for the BMG, one Debye mode and one Einstein mode for the crystallized alloy, showing an adequate description of the experimental data.
文摘Arrhenius law implicates that only those molecules which possess the internal energy greater than the activation energy Ea can react. However, the internal energy will not be proportional to the gas temperature if the specific heat ratio y and the gas constant R vary during chemical reaction processes. The varying y may affect significantly the chemical reaction rate calculated with the Arrhenius law under the constant γ assumption, which has been widely accepted in detonation and combustion simulations for many years. In this paper, the roles of variable γ and R in Arrhenius law applications are reconsidered, and their effects on the chemical reaction rate are demonstrated by simulating one- dimensional C-J and two-dimensional cellular detonations. A new overall one-step detonation model with variable γ and R is proposed to improve the Arrhenius law. Numerical experiments demonstrate that this improved Arrhenius law works well in predicting detonation phenomena with the numerical results being in good agreement with experimental data.
基金Project supported by the National Natural Science Foundation of China (Nos. 10772134 and90716007)
文摘The gas temperature within hypersonic boundary layer flow is so high that the specific heat of gas is no longer a constant but relates to temperature. How variable specific heat influences on boundary layer flow stability is worth researching. The effect of the variable specific heat on the stability of hypersonic boundary layer flows is studied and compared with the case of constant specific heat based on the linear stability theory. It is found that the variable specific heat indeed has some effects on the neutral curves of both the first-mode and the second-mode waves and on the maximum rate of growth also. Therefore, the relationship between specific heat and temperature should be considered in the study of the stability of the boundary layer.
基金National Natural Science Foundation of China under Grant Nos.10574047 and 20490210
文摘On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the quasione-dimensional interehain coupling organic ferromagnets are presented. We find that an obvious feature is to present itself the round peak for the specific heat with the temperature. This indicates unambiguously the presence of the phase transition in the system. The transition temperature plays down with increasing of the interchain coupling t2 or decreasing of the electron repulsion u. The curves of charge density with the temperature debase monotonously. This result illustrates that the higher the temperature is, the more electrons are excited.
文摘The thermal decomposition process was studied by the TG–DTA analyzer. The results show that the decomposition process of sodium hydroxyethyl sulfonate consisted of three stages: the mass loss for the first, the second and third stages may be about the groups of CH_3CH_2OH, CH_3CHO and SO_2 volatilized, respectively. The decomposition residuum of three stages was analyzed by FT-IR, and the results of FT-IR agreed with the decomposition process predicted by theoretical weight loss. The specific heat capacity of sodium hydroxyethyl sulfonate was determined by differential scanning calorimetry(DSC). The melting temperature and melting enthalpy were obtained to be 465.41 K and 25.69 kJ·mol^(-1), respectively. The molar specific heat capacity of sodium hydroxyethyl sulfonate was determinated from 310.15 K to 365.15 K and expressed as a function of temperature.
基金This work was supported by College of Engineering and Technology,the American University of the Middle East,Kuwait.Homepage:https://www.aum.edu.kw.
文摘Nanofluids are extensively applied in various heat transfer mediums for improving their heat transfer characteristics and hence their performance.Specific heat capacity of nanofluids,as one of the thermophysical properties,performs principal role in heat transfer of thermal mediums utilizing nanofluids.In this regard,different studies have been carried out to investigate the influential factors on nanofluids specific heat.Moreover,several regression models based on correlations or artificial intelligence have been developed for forecasting this property of nanofluids.In the current review paper,influential parameters on the specific heat capacity of nanofluids are introduced.Afterwards,the proposed models for their forecasting and modeling are proposed.According to the reviewed works,concentration and properties of solid structures in addition to temperature affect specific heat capacity to large extent and must be considered as inputs for the models.Moreover,by using other effective factors,the accuracy and comprehensive of the models can be modified.Finally,some suggestions are offered for the upcoming works in the relevant topics.
文摘The specific heat of superheated Al 10Sr melts was determined at different heating rates between 1 K/min and 20 K/min using a differential scanning calorimeter(DSC). As a whole, the specific heat increases with increasing temperature. A hump is observed on the specific heat curve at the temperature corresponding to the phase boundary temperature dependent on heating rate. Moreover, the hump shifts to higher temperature in the measured temperature range from about 840 ℃ to 890 ℃ with increasing heating rate. At certain temperature in the higher superheated zone, the specific heat of the melt as a function of temperature shows a sharp rise . The result indicates that disorder zone fraction begins to increase while atom clusters fraction decreases at the breaking temperature. [
基金Supported by the Research Fund for Advanced Talents of Jiangsu University under Grant No 14JDG174the National Natural Science Foundation of China under Grants Nos 11447126,11275097,11475085 and 11535005the Natural Science Foundation of Jiangsu Province of China under Grant No BK20130078
文摘We investigate the particle-hole fluctuation correction to the specific heat of an ultracold Fermi gas at unitarity within the framework of the non-self-consistent T-matrix approximation in the normal phase. We find good agreement between our theoretical predictions and the experimental data measured by the MIT group, apart from discrepancies near the transition temperature. At high temperature, our calculated specific heat has the tendency to approach the specific heat of the Boltzmann gas.
基金supported by the National Natural Science Foundation of Chinathe National Basic Research Program of China (Grant Nos 2006CB601000, 2006CB921802 and 2006CB921300)the Knowledge Innovation Program of the Chinese Academy of Sciences (ITSNEM)
文摘The alloys of non-centrosymmetric superconductor, Re3W, which were reported to have an ^-Mn structure [P. Greenfield and P. A. Beck, J. Metals, N. Y. 8, 265 (1959)] with Tc = 9K, are prepared by arc melting. The values of ac susceptibility and the low-temperature specific heat of these alloys are measured. It is found that there are two superconducting phases coexisting in the samples with Tc1 ≈ 9 K and Tc2 ≈ 7K, which are both non-centrosymmetric in structure as reported previously. By analysing the specific heat data measured in various magnetic fields down to a temperature of 1.8 K, we find that the absence of the inversion symmetry does not lead to an obvious deviation from an s-wave pairing symmetry in Re3W.
基金Supported by the Natural Science Foundation of Liaoning Province of China under Grant No.20062040
文摘The specific heats of both a two-layer ferromagnetic superlattice and a two-layer ferrimagnetic one arestudied.It is found that the spin quantum numbers,the interlayer and intralayer exchange couplings,the anisotropy,theapplied magnetic field,and the temperature all affect the specific heat of these superlattices.For both the ferromagneticand ferrimagnetic superlattices,the specific heat decreases with increasing the spin quantum number,the absolutevalue of interlayer exchange coupling,intralayer exchange coupling,and anisotropy,while it increases with increasingtemperature at low temperatures.When an applied magnetic field is enhanced,the specific heat decreases in the two-layerferromagnetic superlattice,while it is almost unchanged in the two-layer ferrimagnetic superlattice at low fieldrange at low temperatures.
基金Supported by the National Natural Science Foundation of China(No.20803058)Xi’an Scientific and Technical Plan Foundation, China(No.YF07106).
文摘A new compound, [(NH2)2C=NH2]+N(NO2)2-(GDN), was prepared by mixing ammonium dinitramide (ADN) and guanidine hydrochloride in water. The thermal behavior of GDN was studied under the non-isothermal conditions with DSC and TG/DTG methods. The apparent activation energy(E) and pre-exponential constant(A) of the exothermic decomposition stage of GDN were 118.75 kJ/mol and 10^10.86 s^-1, respectively. The critical temperature of the thermal explosion(Tb) of GDN was 164.09 ℃. The specific heat capacity of GDN was determined with the Micro-DSC method and the theoretical calculation method, and the standard molar specific heat capacity was 234.76 J·mol^-1·K^-1 at 298.15 K. The adiabatic time-to-explosion of GDN was also calculated to be a certain value between 404.80 and 454.95 s.
基金supported by the National Natural Science Foundation of China(Nos.11172203 and91216111)the National Basic Research Program of China(No.2009CB724103)
文摘When the air temperature reaches 600 K or higher, vibration is excited. The specific heat is not a constant but a function of temperature. Under this condition, the transition position of hypersonic sharp wedge boundary layer is predicted by using the improved eN method considering variable specific heat. The transition positions with different Mach numbers of oncoming flow, half wedge angles, and wall conditions are computed condition, the nearer to the Mach number The results show that for the same oncoming flow condition and wall transition positions of hypersonic sharp wedge boundary layer move much leading edge than those of the flat plate. The greater the oncoming flow the closer the transition position to the leading edge.
基金Supported by the Natural Science Foundation of Liaoning Province under Grant No.20041021the Scientific Foundation of the Educational Department of Liaoning Province under Grant Nos.20060638 and 2008533
文摘The molecular-based magnetic materials AFe11 Fe111(C2O4)3 have a honeycomb structure in which FeII (S = 2) and FeIH (S= 5/2) occupy sites alternately. They can be described as mixed spin-2 and spin-5/2 Ising model with ferrimagnetic interlayer coupling. The influences of the transverse field on the internal energy and the specific heat of the molecalar-based magnetic system have been studied numerically by using the effective-field theory with self-spin correlations and the differential operator technique.
基金supported by the National Natural Science Foundation of China(Grant No.11274018)
文摘Superconducting thermal fluctuation(STF) plays an important role in both thermodynamic and transport properties in the vortex liquid phase of high Tsuperconductors.It was widely observed in the vicinity of the critical transition temperature.In the framework of Ginz burg-Landau-La wrence-Doniach theory in magnetic field,a self-consistent analysis of STF including all Landau levels is given.Besides that,we calculate the contribution of STF to specific heat in vortex liquid phase for high Tcuprate superconductors,and the fitting results are in good agreement with experimental data.
基金Project supported by the National Natural Science Foundation of China(Grant Nos 10221002/A0402 and 10774170/A0402)the State Key Development for Basic Research of China (Grant Nos 2006CB601000, 2006CB921802 and 2006CB921300)+1 种基金the Knowledge Innovation Project of Chinese Academy of Sciences (International Team on Superconductivity and Novel Electronic Materials, ITSNEM)the U.S. National Science Foundation (Grant No DMR-0605748)
文摘Low-temperature specific heat in a dichalcogenide superconductor 2H-NbSe2 is measured in various magnetic fields. It is found that the specific heat can be described very well by a simple model concerning two components corresponding to vortex normal core and ambient superconducting region, separately. For calculating the specific heat outside the vortex core region, we use the Bardeen-Cooper Schrieffer (BCS) formalism under the assumption of a narrow distribution of the superconducting gaps. The field-dependent vortex core size in the mixed state of 2H-NbSe2, determined by using this model, can explain the nonlinear field dependence of specific heat coefficient γ(H), which is in good agreement with the previous experimental results and more formal calculations. With the high-temperature specific heat data, we can find that, in the multi-band superconductor 2H-NbSe2, the recovered density of states (or Fermi surface) below Tc under a magnetic field seems not to be gapped again by the charge density wave (CDW) gap, which suggests that the superconducting gap and the CDW gap may open on different Fermi surface sheets.
文摘Specific heat is a powerful tool to investigate the physical properties of condensed materials.Superconducting state is achieved through the condensation of paired electrons,namely,the Cooper pairs.The condensed Cooper pairs have lower entropy compared with that of electrons in normal metal,thus specific heat is very useful in detecting the low lying quasiparticle excitations of the superconducting condensate and the pairing symmetry of the superconducting gap.In this brief overview,we will give an introduction to the specific heat investigation of the physical properties of superconductors.We show the data obtained in cuprate and iron based superconductors to reveal the pairing symmetry of the order parameter.
文摘In this paper,we report the measurements of the specific heat of the lanthanide oxides(La_2O_3,CeO_2, Pr_6O_(11),Nd_2O_3,Sm_2O_3,Eu_2O_3,Gd_2O_3,Tb_4O_7,Dy_2O_3,Ho_2O_3,Er_2O_3,Tm_2O_3,Yb_2O_3,Lu_2O_3)from-150℃ to 800℃ by using adiabatic scanning calorimeter.We found that chemical reactions occur during the heating pro- cess of initial La_2O_3 and Nd_2O_3 materials by using DTA and X-ray diffraction.The results of specific heat measurement show that except CeO_2 and Tb_4O_7,other twelve lanthanide oxides were accompanied with endothermal change and weight loss to a certain degree during the heating process.
文摘Specific heat(Cp)and effective thermal conductivity(λ)of native maize starch(NS)were measured by DSC and transient heat transfer method,respectively,at different moisture contents and temperatures.The dependency of temperature(T)and moisture content(W)on the two parameters were investigated.The thermophysical properties of treated starch(TS)by four hydrothermal processes(RP-HMT,IV-HMT,DV-HMT and FV-HMT)were measured and compared to native strach.Hydrothermal treatments were performed at 3 bars(133°C)for 10 min.For Cp andλmeasurements,moisture content varied for NS from 5 to 21.5%d.b.and from 8.8 to 25%d.b.,respectively,and was fixed at 6%d.b.for TS.Empirical models were developed to specific heat and effective thermal conductivity,using a multiple regression algorithm with subsequent statistical analysis.The proposed models for NS based on T and W predict Cp andλwith a mean absolute error of 3.5%and 1.3%,respectively.Large differences in specific heat were observed between TS and NS.In a temperature range of 40 to 160°C,Cp values varied from 1.964 to 2.699 for NS and 1.380 to 2.085(J.g-1.°C-1)for TS.In contrast,the conductivity of NS was almost identical to that of treated starch by FV-HMT,followed in an increasing order by those treated by DV-HMT,RP-HMT,and IV-HM processes.