Low energy gamma radiation （0.2-10.0） MeV near the Earth＇s surface has several origins. Primary and secondary cosmic radiations with interactions of very high energy protons （〉 1 GeV） in terrestrial atmosphere a...Low energy gamma radiation （0.2-10.0） MeV near the Earth＇s surface has several origins. Primary and secondary cosmic radiations with interactions of very high energy protons （〉 1 GeV） in terrestrial atmosphere are the main sources. The second most important source near the surface of the Earth and in the tropical and equatorial regions is the radon gas （Rn-222） that decays in alpha particles and gamma rays in this energy range. Also the telluric radionuclides 238U, 235U, 40K and 232Th in decays produce gamma radiation with different intensities at different locations on the surface of the Earth. Other sources less present are electrical discharges （lightning strikes） and man-made radioactive sources for medical, dental and industrial applications. In this work, it is shown that measurements of these components during all year 2016 are carried out at the ITA （Technological Institute of Aeronautics） campus in Sao Jose dos Campos, SP, Brazil and their possible correlations with atmospheric phenomena.展开更多
Manganese-catalyzed C—C bond cleavage of cyclobutanols has attracted great attention due to the high abundance and cheap and eco-friendly behaviour.A manganese-catalyzed ring-opening C—C bond fluorination of cyclobu...Manganese-catalyzed C—C bond cleavage of cyclobutanols has attracted great attention due to the high abundance and cheap and eco-friendly behaviour.A manganese-catalyzed ring-opening C—C bond fluorination of cyclobutanols is reported.Under mild conditions,the reaction provides a straightforward access to γ-fluorinated ketones using 10 mol% Mn(OAc)_(2) as catalyst and electrophilic fluorination reagent,which was generated in situ from HF·Et 3N and PhIO,as fluorine source.The reaction has an excellent functional-group tolerance and displays a broad substrate scope,affording the corresponding products in 50%~76%yields.展开更多
文摘Low energy gamma radiation （0.2-10.0） MeV near the Earth＇s surface has several origins. Primary and secondary cosmic radiations with interactions of very high energy protons （〉 1 GeV） in terrestrial atmosphere are the main sources. The second most important source near the surface of the Earth and in the tropical and equatorial regions is the radon gas （Rn-222） that decays in alpha particles and gamma rays in this energy range. Also the telluric radionuclides 238U, 235U, 40K and 232Th in decays produce gamma radiation with different intensities at different locations on the surface of the Earth. Other sources less present are electrical discharges （lightning strikes） and man-made radioactive sources for medical, dental and industrial applications. In this work, it is shown that measurements of these components during all year 2016 are carried out at the ITA （Technological Institute of Aeronautics） campus in Sao Jose dos Campos, SP, Brazil and their possible correlations with atmospheric phenomena.
基金Project supported by the National Natural Science Foundation of China(Nos.92156008,22161142016)the Taishan Scholar Program at Shandong Provincethe Natural Science Foundation of Shandong Province(No.ZR2020QB018)。
文摘Manganese-catalyzed C—C bond cleavage of cyclobutanols has attracted great attention due to the high abundance and cheap and eco-friendly behaviour.A manganese-catalyzed ring-opening C—C bond fluorination of cyclobutanols is reported.Under mild conditions,the reaction provides a straightforward access to γ-fluorinated ketones using 10 mol% Mn(OAc)_(2) as catalyst and electrophilic fluorination reagent,which was generated in situ from HF·Et 3N and PhIO,as fluorine source.The reaction has an excellent functional-group tolerance and displays a broad substrate scope,affording the corresponding products in 50%~76%yields.
