针对硝酸盐对地下水污染的严重性 ,介绍了用 Ca O除去 CO2 和 H2 O的测定氮同位素比值的燃烧管方法和利用 Ag NO3+C(石墨 )生成 CO2 的测定 NO-3 中氧同位素比值的燃烧法 ;研究了用 15N和 18O同位素分析地下水中 NO-3 的来源和判断硝化...针对硝酸盐对地下水污染的严重性 ,介绍了用 Ca O除去 CO2 和 H2 O的测定氮同位素比值的燃烧管方法和利用 Ag NO3+C(石墨 )生成 CO2 的测定 NO-3 中氧同位素比值的燃烧法 ;研究了用 15N和 18O同位素分析地下水中 NO-3 的来源和判断硝化作用和反硝化作用的发生机理。展开更多
High-resolution ro-vibrational spectroscopy of ^15N2^16O in 1650-3450 cm-1 region is studied using highly enriched isotopologue sample. The positions of more than 7300 lines of ^15N2^16O isotopologue were measured wit...High-resolution ro-vibrational spectroscopy of ^15N2^16O in 1650-3450 cm-1 region is studied using highly enriched isotopologue sample. The positions of more than 7300 lines of ^15N2^16O isotopologue were measured with a typical accuracy of 5.0×10-4 cm-1. The transitions were rovibrationally assigned on the basis of the global effective Hamiltonian model. The band by band analysis allowed for the determination of the rovibrational parameters of a total of 73 bands. 29 of them are newly reported and more rotational transitions have been observed for the others. The maximum deviation of the preidictions of the effective Hamiltonian model is up to 0.70 cm-1 for the ^15N2^16O species.展开更多
文摘针对硝酸盐对地下水污染的严重性 ,介绍了用 Ca O除去 CO2 和 H2 O的测定氮同位素比值的燃烧管方法和利用 Ag NO3+C(石墨 )生成 CO2 的测定 NO-3 中氧同位素比值的燃烧法 ;研究了用 15N和 18O同位素分析地下水中 NO-3 的来源和判断硝化作用和反硝化作用的发生机理。
基金This work is supported by the National Natural Science Foundation of China （No.20903085）, the NKBRSF 2010CB9230, and RFBR-Russia （No.06-05- 39016）. The support of the Groupement de Recherche International SAMIA （Spectroscopie d＇Absorption des Mol@cules d＇Interet Atmospherique） between CNRS （France）, RFBR （Russia） and CAS （China） is also acknowledged.
文摘High-resolution ro-vibrational spectroscopy of ^15N2^16O in 1650-3450 cm-1 region is studied using highly enriched isotopologue sample. The positions of more than 7300 lines of ^15N2^16O isotopologue were measured with a typical accuracy of 5.0×10-4 cm-1. The transitions were rovibrationally assigned on the basis of the global effective Hamiltonian model. The band by band analysis allowed for the determination of the rovibrational parameters of a total of 73 bands. 29 of them are newly reported and more rotational transitions have been observed for the others. The maximum deviation of the preidictions of the effective Hamiltonian model is up to 0.70 cm-1 for the ^15N2^16O species.
