采用光学显微镜、扫描电子显微镜、电子探针和X射线衍射仪,研究了Al-8%Mn合金熔体中添加稀土Y质量分数对合金微观组织的作用机制,并分析了稀土Y添加量对合金力学性能和耐蚀性能的影响规律.结果表明:稀土Y能有效细化Al-8%Mn合金中的Al_(6...采用光学显微镜、扫描电子显微镜、电子探针和X射线衍射仪,研究了Al-8%Mn合金熔体中添加稀土Y质量分数对合金微观组织的作用机制,并分析了稀土Y添加量对合金力学性能和耐蚀性能的影响规律.结果表明:稀土Y能有效细化Al-8%Mn合金中的Al_(6)Mn化合物相和α-Al相.当Y的添加质量分数为3%时,细化效果最佳,使Al6Mn相的形貌由粗大板条状和块状转变为细小块状,平均尺寸由未细化前的67.4μm减小到36.5μm,α-Al由粗大的柱状晶细化成等轴晶,其平均尺寸减小至48μm.稀土Y添加后Al-8%Mn合金的抗拉强度和延伸率分别由组织未细化前的126 MPa和1.47%增加到141 MPa和2.26%,分别提高了12.0%和76.9%.此外,在30 g NaCl+10 mL HCl+1 L H_(2)O溶液中的腐蚀研究表明,随着Al-8%Mn合金中稀土Y添加量的增加,合金的抗蚀性能逐渐变差.展开更多
An AA3003 aluminum alloy prepared by twin-roll casting was modified by a small amount of zirconium. Annealing at 450 °C led to precipitation of coherent Al3Zr phase and a simultaneous co-precipitation of Mn-rich...An AA3003 aluminum alloy prepared by twin-roll casting was modified by a small amount of zirconium. Annealing at 450 °C led to precipitation of coherent Al3Zr phase and a simultaneous co-precipitation of Mn-richα-Al(Mn,Fe)Si phase. Severe plastic deformation by equal channel angular pressing resulted in the grain refinement and increase of microhardness. Observation by electron back-scatter diffraction and in-situ transmission electron microscopy revealed influence of pre-annealing on microstructure changes during post-deformation heat treatment. Dislocation recovery and precipitation ofα-Al(Mn,Fe)Si particles preceded recrystallization at 450 °C in material which was not annealed before deformation. The pre-deformation annealing enabled dynamic recovery during deformation as it depleted the solid solution from Mn atoms. Recrystallization was enhanced by Al3Zr precipitates.展开更多
基金financially supported by the Fundamental Research Funds for the Central Universities,China(No.2020CDJDPT001)the Chongqing Natural Science Foundation,China(No.cstc2021jcyj-msxm X0699)。
文摘采用光学显微镜、扫描电子显微镜、电子探针和X射线衍射仪,研究了Al-8%Mn合金熔体中添加稀土Y质量分数对合金微观组织的作用机制,并分析了稀土Y添加量对合金力学性能和耐蚀性能的影响规律.结果表明:稀土Y能有效细化Al-8%Mn合金中的Al_(6)Mn化合物相和α-Al相.当Y的添加质量分数为3%时,细化效果最佳,使Al6Mn相的形貌由粗大板条状和块状转变为细小块状,平均尺寸由未细化前的67.4μm减小到36.5μm,α-Al由粗大的柱状晶细化成等轴晶,其平均尺寸减小至48μm.稀土Y添加后Al-8%Mn合金的抗拉强度和延伸率分别由组织未细化前的126 MPa和1.47%增加到141 MPa和2.26%,分别提高了12.0%和76.9%.此外,在30 g NaCl+10 mL HCl+1 L H_(2)O溶液中的腐蚀研究表明,随着Al-8%Mn合金中稀土Y添加量的增加,合金的抗蚀性能逐渐变差.
基金The financial supports of grants GACR P107-12-0921 and SVV-2015-260213
文摘An AA3003 aluminum alloy prepared by twin-roll casting was modified by a small amount of zirconium. Annealing at 450 °C led to precipitation of coherent Al3Zr phase and a simultaneous co-precipitation of Mn-richα-Al(Mn,Fe)Si phase. Severe plastic deformation by equal channel angular pressing resulted in the grain refinement and increase of microhardness. Observation by electron back-scatter diffraction and in-situ transmission electron microscopy revealed influence of pre-annealing on microstructure changes during post-deformation heat treatment. Dislocation recovery and precipitation ofα-Al(Mn,Fe)Si particles preceded recrystallization at 450 °C in material which was not annealed before deformation. The pre-deformation annealing enabled dynamic recovery during deformation as it depleted the solid solution from Mn atoms. Recrystallization was enhanced by Al3Zr precipitates.
