Mercurous chloride catalyzed Mannich condensation of terminal alkynes with secondary amines and aldehydes has been developed. The reaction generated β-aminoalkynes in good yields.
基金Project supported by the National Natural Science Foundation of China (No. 20372024), the Excellent Scientist Foundation of Anhui Province (No.04046080), the Natural Science Foundation of the Education Department of Anhui Province (No. 2002kj254zd), the Scientific Research Foundation for the Returned 0verseas Chinese Scholars, the Ministry of Education of China (No. 2002247), the Excellent Young Teacher Program of the Ministry of Education of China (No. 2024) and the Key Project of Science and Technology of the Ministry of Education of China (No. 0204069).
文摘Mercurous chloride catalyzed Mannich condensation of terminal alkynes with secondary amines and aldehydes has been developed. The reaction generated β-aminoalkynes in good yields.