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Isomerization and degradation of all-trans-β-carotene during in-vitro digestion 被引量:1
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作者 Wenyang Tao Xingqian Ye Yanping Cao 《Food Science and Human Wellness》 SCIE 2021年第3期370-374,共5页
To investigate the behavior of all-trans-β-carotene during digestion,in-vitro digestion coupled with HPLC-DAD,Raman spectroscopy and Fourier transform-infrared spectroscopy were used to monitor it.All-trans-β-carote... To investigate the behavior of all-trans-β-carotene during digestion,in-vitro digestion coupled with HPLC-DAD,Raman spectroscopy and Fourier transform-infrared spectroscopy were used to monitor it.All-trans-β-carotene reduced by 75%during the in-vitro digestion and had a highest degradation during intestinal digestion compared with oral and gastro digestion.All-trans-β-carotene occurred isomerization and degradation during oral digestion and occurred degradation during gastro and intestinal digestion.Isomers were identifi ed as 15-cis-β-carotene and 9-cis-β-carotene,degradation products were compounds with function group of C—O,C—O—C or C=C—C=C.The biological fate ofβ-carotene during digestion was clarifi ed,and one of the reasons for low bioavailability ofβ-carotene was explained by high degradation rate during digestion. 展开更多
关键词 β-carotene DIGESTION ISOMERIZATION cis-β-carotene degradation
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Removal of Carbonyl-Containing Effluents by Photodegradation Using β-Carotene Embedded onto Zinc Oxide Particles
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作者 Bakari Chaka Aloys Mosima Osano 《Journal of Health Science》 2019年第4期262-272,共11页
Environmental pollution especially in the form of effluent wastewater from industries has been a major challenge. Carbonyl-containing organic standards and sewage sample were effectively photo degraded. ZnO nanopartic... Environmental pollution especially in the form of effluent wastewater from industries has been a major challenge. Carbonyl-containing organic standards and sewage sample were effectively photo degraded. ZnO nanoparticles were prepared by emulsification of zinc-carbamate solution using 1 N NaOH and grafted chemically by Molecular Layer Doping method at 180 °C with β-carotene extracted using methanol by refluxing at 50 °C at varying concentrations. Intrinsic and grafted β-carotene ZnO were characterized using FTIR (Fourier transform infrared spectroscopy) and their spectra differed in an additional peak at around 1,435 nm corresponding to the organ metallic bond Zn-C. UV-Vis spectra of the two composites indicated a blue shift in the grafted samples. This translated to a reduced band gap from 3.5 eV to 3.4 eV. Comparison in the rates of photodegradation of pure organic compounds, organic effluents and color change of dyes was in the order 1% grafted, 0.5% grafted, intrinsic ZnO and blank sample. When 10.0 mL of sewerage water was photo degraded using both sunlight and UV-Lamp for 40 minutes, the amount of carbonyls present decreased by 28.5% for β-carotene grafted ZnO, 24.5% for intrinsic ZnO and 0.6% for a blank sample. 展开更多
关键词 Intrinsic ZnO β-carotene organic EFFLUENTS CARBONYLS PHOTO-degradation
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Inhibition of protein degradation increases the Bt protein concentration in Bt cotton 被引量:2
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作者 Yuting Liu Hanjia Li +6 位作者 Yuan Chen Tambel Leila.I.M Zhenyu Liu Shujuan Wu Siqi Sun Xiang Zhang Dehua Chen 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第6期1897-1909,共13页
Bacillus thuringiensis(Bt)cotton production is challenged by two main problems,i.e.,the low concentration of Bt protein at the boll setting stage and the lowest insect resistance in bolls among all the cotton plant’s... Bacillus thuringiensis(Bt)cotton production is challenged by two main problems,i.e.,the low concentration of Bt protein at the boll setting stage and the lowest insect resistance in bolls among all the cotton plant’s organs.Therefore,increasing the Bt protein concentration at the boll stage,especially in bolls,has become the main goal for increasing insect resistance in cotton.In this study,two protein degradation inhibitors(ethylene diamine tetra acetic acid(EDTA)and leupeptin)were sprayed on the bolls,subtending leaves,and whole cotton plants at the peak flowering stage of two Bt cultivars(medium maturation Sikang 1(SK1))and early maturation Zhongmian 425(ZM425)in 2019 and 2020.The Bt protein content and protein degradation metabolism were assessed.The results showed that the Bt protein concentrations were enhanced by 21.3 to 38.8%and 25.0 to 38.6%in the treated bolls of SK1 and ZM425 respectively,while they were decreased in the subtending leaves of these treated bolls.In the treated leaves,the Bt protein concentrations increased by 7.6 to 23.5%and 11.2 to 14.9%in SK1 and ZM425,respectively.The combined application of EDTA and leupeptin to the whole cotton plant increased the Bt protein concentrations in both bolls and subtending leaves.The Bt protein concentrations in bolls were higher,increasing by 22.5 to 31.0%and 19.6 to 32.5%for SK1 and ZM425,respectively.The organs treated with EDTA or/and leupeptin showed reduced free amino acid contents,protease and peptidase activities and significant enhancements in soluble protein contents.These results indicated that inhibiting protein degradation could improve the protein content,thus increasing the Bt protein concentrations in the bolls or/and leaves of cotton plants.Therefore,the increase in the Bt protein concentration without yield reduction suggested that these two protein degradation inhibitors may be applicable for improving insect resistance in cotton production. 展开更多
关键词 Bt cotton Bt protein inhibition of protein degradation protein degradation metabolism
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Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe)octahedrons 被引量:1
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作者 Hao Yuan Xinhai Sun +2 位作者 Shuai Zhang Weilong Shi Feng Guo 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期298-309,共12页
The synergistic reaction of photocatalysis and advanced oxidation is a valid strategy for the degradation of harmful antibiotic wastewater.Herein,carbon dots(CDs)modified MIL-101(Fe)octahedrons to form CDs/MIL-101(Fe)... The synergistic reaction of photocatalysis and advanced oxidation is a valid strategy for the degradation of harmful antibiotic wastewater.Herein,carbon dots(CDs)modified MIL-101(Fe)octahedrons to form CDs/MIL-101(Fe)composite photocatalyst was synthesized for visible light-driven photocatalytic/persulfate(PS)-activated tetracycline(TC)degradation.The electron spin resonance(ESR)spectra,scavenging experiment and electrochemical analysis were carried out to reveal that the high visible light-driven photocatalytic degradation activity of TC over CDs/MIL-101(Fe)photocatalysts is not only ascribed to the production of free active radicals in the CDs/MIL-101(Fe)/PS system(·OH,·SO_(4-),^(1)O_(2),h^(+)and·O_(2)^(-))but also attributed to the consumption of electrons caused by the PS,which can suppress the recombination of photo-generated carriers as well as strong light scattering and electron trapping effects of CDs.Finally,the possible degradation pathways were proposed by analyzing intermediates via liquid chromatography-mass spectrometry technique.This research presents a rational design conception to construct a CDs/PS-based photocatalysis/advanced oxidation technology with high-efficient degradation activity for the remediation of organic antibiotic pollutant wastewater and for the improvement of carrier transport kinetics of photocatalysts. 展开更多
关键词 Carbon dots MIL-101(Fe) PHOTOCATALYTIC Persulfate activation Tetracycline degradation
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Carbon-doped CuFe_(2)O_(4) with C-O-M channels for enhanced Fenton-like degradation of tetracycline hydrochloride: From construction to mechanism 被引量:1
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作者 Hong Qin Yangzhuo He +9 位作者 Piao Xu Yuan Zhu Han Wang Ziwei Wang Yin Zhao Haijiao Xie Quyang Tian Changlin Wang Ying Zeng Yicheng Li 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第4期732-747,共16页
Carbon-doped copper ferrite(C–CuFe_(2)O_(4))was synthesized by a simple two-step hydrothermal method,which showed enhanced tetracycline hydrochloride(TCH)removal efficiency as compared to the pure CuFe_(2)O_(4) in Fe... Carbon-doped copper ferrite(C–CuFe_(2)O_(4))was synthesized by a simple two-step hydrothermal method,which showed enhanced tetracycline hydrochloride(TCH)removal efficiency as compared to the pure CuFe_(2)O_(4) in Fenton-like reaction.A removal efficiency of 94%was achieved with 0.2 g L^(-1) catalyst and 20 mmol L^(-1) H_(2)O_(2) within 90 min.We demonstrated that 5%C–CuFe_(2)O_(4) catalyst in the presence of H_(2)O_(2) was significantly efficient for TCH degradation under the near-neutral pH(5–9)without buffer.Multiple techniques,including SEM,TEM,XRD,FTIR,Raman,XPS M€ossbauer and so on,were conducted to investigate the structures,morphologies and electronic properties of as-prepared samples.The introduction of carbon can effectively accelerate electron transfer by cooperating with Cu and Fe to activate H_(2)O_(2) to generate·OH and·O_(2)^(-).Particularly,theoretical calculations display that the p,p,d orbital hybridization of C,O,Cu and Fe can form C–O–Cu and C–O–Fe bonds,and the electrons on carbon can transfer to metal Cu and Fe along the C–O–Fe and C–O–Cu channels,thus forming electron-rich reactive centers around Fe and Cu.This work provides lightful reference for the modification of spinel ferrites in Fenton-like application. 展开更多
关键词 Fenton-like reaction CuFe_(2)O_(4) Tetracycline hydrochloride degradation
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Dietary Supplementation of β-Carotene Reveals miRNAs Involved in the Regulation of Carotenoid Metabolism in Crassostrea gigas
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作者 SUN Dongfang WAN Sai +2 位作者 YU Hong KONG Lingfeng LI Qi 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第4期1045-1053,共9页
Carotenoids play crucial physiological roles in animals.A comprehensive investigation into the mechanism of carotenoid metabolism in oysters will establish a theoretical foundation for further development of its carot... Carotenoids play crucial physiological roles in animals.A comprehensive investigation into the mechanism of carotenoid metabolism in oysters will establish a theoretical foundation for further development of its carotenoid-rich traits.However,the information on the function of miRNA in β-carotene metabolism in oysters is limited.To elucidate the mechanisms underlying miRNA regulation of carotenoid metabolism in oysters,we compared the expressions of miRNA in digestive gland tissues of Pacific oyster(Crassostrea gigas)fed with aβ-carotene supplemented diet and a normal diet,respectively.A total of 690 candidate miRNAs in the Pacific oyster digestive gland tissues were identified,including 590 known miRNAs and 111 unknown miRNAs.Three differentially expressed miRNAs were obtained in the carotenoid-fed and normal groups,associated to 137 differentially expressed target genes.Moreover,the GO enrichment analysis revealed that the differentially expressed target genes were mainly involved in transmembrane transport activity.KEGG enrichment showed that the differentially expressed target genes were involved in ABC transport.Analysis of the mRNA-miRNA network revealed that novel0025 played a central role in carotenoid metabolism,and it was negatively correlated with the expression of 46 mRNAs.In addition,down-regulated expression of novel0025 upregulated the expression of the lipoprotein gene LOC105342186,suggesting a potential regulatory role in carotenoid metabolism.Our results provide useful information for elucidating the miRNA regulation mechanism during carotenoids metabolism in the Pacific oyster. 展开更多
关键词 Crassostrea gigas β-carotene microRNA carotenoid metabolism
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Microbial Degradation of Organic Contaminants in Streambed/Floodplain Sediments in Passaic River—New Jersey Area
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作者 Taheim Evans English Meghann Trombetta +1 位作者 Alyssa Beres Yusuf Yildiz 《American Journal of Analytical Chemistry》 CAS 2024年第4期139-150,共12页
This paper is intended to explore soil organic matter and carbon isotope fractionation at three locations of the Passaic River to determine if microbial degradation of organic contaminants in soil is correlated to the... This paper is intended to explore soil organic matter and carbon isotope fractionation at three locations of the Passaic River to determine if microbial degradation of organic contaminants in soil is correlated to the surrounding physical environment. Microbial degradation of organic contaminants is important for the detoxification of toxic substances thereby minimizing stagnation in the environment and accumulating in the food chain. Since organic contaminants are not easily dissolved in water, they will penetrate sediment and end up enriching the adjacent soil. The hypothesis that we are testing is microbial activity and carbon isotope fractionation will be greater in preserved soils than urban soils. The reason why this is expected to be the case is the expectation of higher microbial activity in preserved environments due to less exposure to pollutants, better soil structure, higher organic matter content, and more favorable conditions for microbial growth. This is contrasted with urban soils, which are impacted by pollutants and disturbances, potentially inhibiting microbial activity. We wish to collect soil samples adjacent to the Passaic River at a pristine location, Great Swamp Wildlife Refuge, a suburban location, Goffle Brook Park, Hawthorne NJ, and an urban location, Paterson NJ. These soil samples will be weighed for soil organic matter (SOM) and weighed for isotope ratio mass spectrometry (IRMS) to test organic carbon isotopes. High SOM and δ13C depletion activity indicate microbial growth based on the characteristics of the soil horizon rather than the location of the soil sample which results in degradation of organic compounds. 展开更多
关键词 Organic Contaminant PCBS Microbial degradation Passaic River
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Photocatalytic Degradation of Plastic Waste: Recent Progress and Future Perspectives
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作者 Amra Bratovcic 《Advances in Nanoparticles》 CAS 2024年第3期61-78,共18页
Microplastics are persistent anthropogenic pollutants that have become a global concern due to their widespread distribution and unfamiliar threat to the environment and living organisms. Conventional technologies are... Microplastics are persistent anthropogenic pollutants that have become a global concern due to their widespread distribution and unfamiliar threat to the environment and living organisms. Conventional technologies are unable to fully decompose and mineralize plastic waste. Therefore, there is a need to develop an environmentally friendly, innovative and sustainable photocatalytic process that can destroy these wastes with much less energy and chemical consumption. In photocatalysis, various nanomaterials based on wide energy band gap semiconductors such as TiO2 and ZnO are used for the conversion of plastic contaminants into environmentally friendly compounds. In this work, the removal of plastic fragments by photocatalytic reactions using newly developed photocatalytic composites and the mechanism of photocatalytic degradation of microplastics are systematically investigated. In these degradation processes, sunlight or an artificial light source is used to activate the photocatalyst in the presence of oxygen. 展开更多
关键词 Plastic Waste Microplastics Photocatalytic Method degradation SEMICONDUCTORS Heterogeneous Photocatalysts
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Aβ-Carotene Ketolase Gene NfcrtO from Subaerial Cyanobacteria Confers Drought Tolerance in Rice
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作者 GAO Ningning YE Shuifeng +7 位作者 ZHANG Yu ZHOU Liguo MA Xiaosong YU Hanxi LI Tianfei HAN Jing LIU Zaochang LUO Lijun 《Rice science》 SCIE CSCD 2024年第1期62-76,共15页
Nostoc flagelliforme is a terrestrial cyanobacterium that can resist many types of stressors,including drought,ultraviolet radiation,and extreme temperatures.In this study,we identified the drought tolerance gene Nfcr... Nostoc flagelliforme is a terrestrial cyanobacterium that can resist many types of stressors,including drought,ultraviolet radiation,and extreme temperatures.In this study,we identified the drought tolerance gene NfcrtO,which encodes aβ-carotene ketolase,through screening the transcriptome of N.flagelliforme under water loss stress.Prokaryotic expression of NfcrtO under 0.6 mol/L sorbitol or under 0.3 mol/L NaCl stress significantly increased the growth rate of Escherichia coli.When NfcrtO was heterologously expressed in rice,the seedling height and root length of NfcrtO-overexpressing rice plants were significantly higher than those of the wild type(WT)plants grown on½Murashige and Skoog solid medium with 120 mmol/L mannitol at the seedling stage.Transcriptome analysis revealed that NfcrtO was involved in osmotic stress,antioxidant,and other stress-related pathways.Additionally,the survival rate of the NfcrtO-overexpression lines was significantly higher than that of the WT line under both hydroponic stress(24%PEG and 100 mmol/L H_(2)O_(2))and soil drought treatment at the seedling stage.Physiological traits,including the activity levels of superoxide dismutase,peroxidase,catalase,total antioxidant capacity,and the contents of proline,trehalose,and soluble sugar,were significantly improved in the NfcrtO-overexpression lines relative to those in the WT line under 20%PEG treatment.Furthermore,when water was withheld at the booting stage,the grain yield per plant of NfcrtO-overexpression lines was significantly higher than that of the WT line.Yeast two-hybrid analysis identified interactions between NfcrtO and Dna J protein,E3 ubiquitin-protein ligase,and pyrophosphate-energized vacuolar membrane proton pump.Thus,heterologous expression of NfcrtO in rice could significantly improve the tolerance of rice to osmotic stress,potentially facilitating the development of new rice varieties. 展开更多
关键词 antioxidant enzyme β-carotene ketolase drought resistance Nostoc flagelliforme osmotic stress RICE transcriptome analysis
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Biodegradation of Crystalline Chitin:A Review of Recent Advancement,Challenges,and Future Study Directions
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作者 SONG Jianlin SU Haipeng +1 位作者 SUN Jianan MAO Xiangzhao 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第5期1319-1328,共10页
Chitin is the second most abundant renewable polysaccharide on Earth.The degradation of chitin into soluble and bioactive N-acetyl chitooligosaccharides(NCOSs)and N-acetyl-D-glucosamine(GlcNAc)has emerged as a pivotal... Chitin is the second most abundant renewable polysaccharide on Earth.The degradation of chitin into soluble and bioactive N-acetyl chitooligosaccharides(NCOSs)and N-acetyl-D-glucosamine(GlcNAc)has emerged as a pivotal step in the efficient and sustainable utilization of chitin resources.However,because of its dense structure,high crystallinity,and poor solubility,chitin typically needs pretreatment via chemical,physical,and other methods before enzymatic conversion to enhance the accessibility between substrates and enzyme molecules.Consequently,there has been considerable interest in exploring the direct biological degradation of crystalline chitin as a cost-effective and environment-friendly technology.This review endeavors to present several biological methods for the direct degradation of chitin.We primarily focused on the importance of chitinase containing chitin-binding domain(CBD).Additionally,various modification strategies for increasing the degradation efficiency of crystalline chitin were introduced.Subsequently,the review systematically elucidated critical components of multi-enzyme catalytic systems,highlighting their potential for chitin degradation.Furthermore,the application of microorganisms in the degradation of crystalline chitin was also discussed.The insights in this review contribute to the explorations and investigations of enzymatic and microbial approaches for the direct degradation of crystalline chitin,thereby fostering advancements in biomass conversion. 展开更多
关键词 crystalline chitin CHITINASE biological degradation engineering MICROORGANISMS
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BiOBr nanosheets coupling with biomass carbon derived from locust leaves for enhanced photocatalytic degradation of rhodamine B
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作者 Hongtao Wang Xiangrui Fan +4 位作者 Mingming Yan Tianyu Guo Xingfa Li Chao Chen Yu Qi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第10期31-43,共13页
A series of BiOBr@biomass carbon derived from locust leaves materials(BiOBr@BC)were fabricated and the photocatalytic property was investigated for photocatalytic degradation of rhodamine B(RhB)under visible light.The... A series of BiOBr@biomass carbon derived from locust leaves materials(BiOBr@BC)were fabricated and the photocatalytic property was investigated for photocatalytic degradation of rhodamine B(RhB)under visible light.The morphology,structure and photoelectrochemical properties of the photocatalysts were characterized by means of SEM,TEM,XRD,XPS,FT-IR,BET,PL,UV-vis/DRS,and EIS techniques.The results showed that the introduction of BC significantly enhanced the photocatalytic activity.When the content of biomass carbon(BC)in a composite is 3%(based on the mass of BiOBr),the obtained BiOBr@BC-3 exhibits excellent photocatalytic activity,degrading 99%of RhB within 20 min.The excellent degradation efficiency after the introduction of BC can be attributed to the enhanced visible light absorption,narrower band gap,and fast electron-hole pair separation rate.The photocatalytic mechanism on the degradation of RhB was illustrated based on the radicals'trapping experiments and semiconductor energy band position.The proposed material is expected to be of significant application value in the field of wastewater treatment. 展开更多
关键词 degradation Rhodamine B ADSORPTION BiOBr Renewable energy
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Achieving high strength and rapid degradation in Mg-Gd-Ni alloys by regulating LPSO phase morphology combined with extrusion
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作者 Kai Ma Jingfeng Wang +7 位作者 Yinhong Peng Chaoneng Dai Yuanlang Pan Ye Wang Danqian Wang Jinxing Wang Yanlong Ma Fusheng Pan 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第6期2312-2326,共15页
In this study,Mg-13.2Gd-4.3Ni alloys containing continuous bulk-shaped long-period stacking ordered(LPSO),lamellar LPSO,and a small amount of eutectic phase were prepared,and the evolution of microstructure at differe... In this study,Mg-13.2Gd-4.3Ni alloys containing continuous bulk-shaped long-period stacking ordered(LPSO),lamellar LPSO,and a small amount of eutectic phase were prepared,and the evolution of microstructure at different extrusion temperatures and its influence on mechanical and degradation properties as well as corrosion mechanism were investigated.Preheating before extrusion can effectively promote the precipitation of lamellar LPSO in matrix.EX400 with higher volume fraction of non-DRXed grains exhibited higher strength,which was mainly due to strong texture,high dislocation density,and high volume fraction of lamellar LPSO.The EX420 with higher volume fraction of DRXed grains showed higher degradation rate,which was mainly due to the higher density of grain boundary.The EX400 exhibited excellent comprehensive properties with tensile yield strength(TYS)of 334 MPa,ultimate tensile strength(UTS)of 484 MPa and elongation(EL)of 7.4%,ultimate compressive strength(UCS)of 638 MPa and compressive yield strength(CYS)of 443 MPa,degradation rate of 86.1 mg/cm^(2)/h at 93℃in 3 wt.%KCl solution. 展开更多
关键词 Mg-Gd-Ni alloys LPSO Mechanical properties degradation rate
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Molecular Dynamics-Based Simulation of Polyethylene Pipe Degradation in High Temperature and High Pressure Conditions
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作者 Guowei Feng Qing Li +5 位作者 Yang Wang Nan Lin Sixi Zha Hang Dong Ping Chen Minjun Zheng 《Fluid Dynamics & Materials Processing》 EI 2024年第9期2139-2161,共23页
High-density polyethylene(HDPE)pipes have gradually become the first choice for gas networks because of their excellent characteristics.As the use of pipes increases,there will unavoidably be a significant amount of w... High-density polyethylene(HDPE)pipes have gradually become the first choice for gas networks because of their excellent characteristics.As the use of pipes increases,there will unavoidably be a significant amount of waste generated when the pipes cease their operation life,which,if improperly handled,might result in major environmental contamination issues.In this study,the thermal degradation of polyethylene materials is simulated for different pressures(10,50,100,and 150 MPa)and temperatures(2300,2500,2700,and 2900 K)in the framework of Reactive Force Field(ReaxFF)molecular dynamics simulation.The main gas products,density,energy,and the mean square displacement with temperature and pressure are also calculated.The findings indicate that raising the temperature leads to an increase in the production of gas products,while changing the pressure has an impact on the direction in which the products are generated;the faster the temperature drops,the less dense the air;both temperature and pressure increase impact the system’s energy conversion or distribution mechanism,changing the system’s potential energy as well as its total energy;the rate at which molecules diffuse increases with temperature,and decreases with pressure.The results of this investigation provide a theoretical basis for the development of the pyrolytic treatment of polyethylene waste materials. 展开更多
关键词 ReaxFF MD high-density polyethylene degradation TEMPERATURE PRESSURE
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Defect mediated losses and degradation of perovskite solar cells:Origin impacts and reliable characterization techniques
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作者 Himangshu Baishy Ramkrishna Das Adhikari +5 位作者 Mayur Jagdishbhai Patel Deepak Yadav Tapashi Sarmah Mizanur Alam Manab Kalita Parameswar Krishnan lyer 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期217-253,共37页
The rapid advancement of halide-based hybrid perovskite materials has garnered significant research attention,particularly in the domain of photovoltaic technology.Owing to their exceptional optoelec-tronic properties... The rapid advancement of halide-based hybrid perovskite materials has garnered significant research attention,particularly in the domain of photovoltaic technology.Owing to their exceptional optoelec-tronic properties,they demonstrated power conversion efficiency(PcE)of over 25%in single junction solar cells.Despite the notable progress in PCE over the past decade,the inherent high defect density pre-senting in perovskite materials gives rise to several loss mechanisms and associated ion migration in per-ovskite solar cells(PsCs)during operational conditions.These factors collectively contribute to a significant stability challenge in PsCs,placing their longevity far behind for commercialization.While numerous reports have explored defects,ion migration,and their impacts on device performance,a com-prehensive correlation between the types of defects and the degradation kinetics of perovskite materials and PsCs has been lacking.In this context,this review aims to provide a comprehensive overview of the origins of defects and ion migration,emphasizing their correlation with the degradation kinetics of per-ovskite materials and PsCs,leveraging reliable characterization techniques.Furthermore,these charac-terization techniques are intended to comprehend loss mechanisms by different passivation approaches to enhance the durability and PCE of PSCs. 展开更多
关键词 Perovskite solar cells Defects lon migration degradation Stability
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Genome Sequencing,Probiotic Analysis,and Oxalate Degradation Modification of Limosilactobacillus reuteri Q35
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作者 NIU Dong-Yu KONG Ling-Hui +1 位作者 LIU Xiang-Yong QIN Jia-Yang 《中国生物化学与分子生物学报》 CAS CSCD 北大核心 2024年第11期1585-1595,共11页
Limosilactobacillus reuteri is a microbe intricately linked to humans and animal health.A thorough assessment of its safety and potential benefits is imperative prior to its application in human and animals.In this in... Limosilactobacillus reuteri is a microbe intricately linked to humans and animal health.A thorough assessment of its safety and potential benefits is imperative prior to its application in human and animals.In this investigation,we performed a comprehensive analysis encompassing genome sequencing,genomic analysis,and phenotypic characterization of L.reuteri Q35,an exceptionally proficient producer of reuterin.The whole genome sequencing results showed that the complete genome sequence spans 2145158 bp with a GC content of 38.9%and encompasses 2121 genes.Initial identification of antibiotic-resistant genes,virulence factors,and toxin-coding genes in the genome substantiated the strain’s low-risk status.Subsequent tests for antibiotic resistance,acute oral toxicology,and hemolysis further confirmed its elevated safety level.The genome of L.reuteri Q35 was found to contain genes associated with adhesion and stress tolerance.Following exposure to artificial gastric juice and bile salt,the strain exhibited a higher survival rate and demonstrated a strong scavenging ability for hydroxyl free radicals in antioxidant capacity tests.These findings suggested that L.reuteri Q35 possesses unique probiotic properties.Additionally,the genome of strain Q35 harbors three truncated oxaloyl-CoA decarboxylase genes(oxc1,oxc2 and oxc3),overexpression of which resulted in a significant increase in ammonium oxalate degradation from 29.5%to 48.8%.These findings highlight that L.reuteri Q35 exhibits both favorable safety characteristics alongside beneficial properties,making it a promising candidate for treating metabolic disorders such as hyperoxaluria. 展开更多
关键词 Limosilactobacillus reuteri genomic analysis SAFETY probiotic oxalate degradation
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Equivalent linear model for seismic damage evaluation of single-degree-of-freedom systems representing reinforced concrete structures considering cyclic degradation behavior
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作者 Lulu Yan Ding-Hao Yu 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第3期637-648,共12页
In this study,a novel equivalent damping ratio model that is suitable for reinforced concrete(RC)structures considering cyclic degradation behavior is developed,and a new equivalent linearization analysis method for i... In this study,a novel equivalent damping ratio model that is suitable for reinforced concrete(RC)structures considering cyclic degradation behavior is developed,and a new equivalent linearization analysis method for implementing the proposed equivalent damping ratio model for use in seismic damage evaluation is presented.To this end,Ibarra’s peak-oriented model,which incorporates an energy-based degradation rule,is selected for representing hysteretic behavior of RC structure,and the optimized equivalent damping for predicting the maximum displacement response is presented by using the empirical method,in which the effect of cyclic degradation is considered.Moreover,the relationship between the hysteretic energy dissipation of the inelastic system and the elastic strain energy of the equivalent linear system is established so that the proposed equivalent linear system can be directly integrated with the Park-Ang seismic model to implement seismic damage evaluation.Due to the simplicity of the equivalent linearization method,the proposed method provides an efficient and reliable way of obtaining comprehensive insight into the seismic performance of RC structures.The verification demonstrates the validity of the proposed method. 展开更多
关键词 degrading system equivalent linear system equivalent damping seismic damage RC structures
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Facilitated Prediction of Micropollutant Degradation via UV-AOPs in Various Waters by Combining Model Simulation and Portable Measurement
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作者 Yanyan Huang Mengkai Li +3 位作者 Zhe Sun Wentao Li James R.Bolton Zhimin Qiang 《Engineering》 SCIE EI CAS CSCD 2024年第6期87-95,共9页
The degradation of micropollutants in water via ultraviolet(UV)-based advanced oxidation processes(AOPs)is strongly dependent on the water matrix.Various reactive radicals(RRs)formed in UV-AOPs have different reaction... The degradation of micropollutants in water via ultraviolet(UV)-based advanced oxidation processes(AOPs)is strongly dependent on the water matrix.Various reactive radicals(RRs)formed in UV-AOPs have different reaction selectivities toward water matrices and degradation efficiencies for target micropollutants.Hence,process selection and optimization are crucial.This study developed a facilitated prediction method for the photon fluence-based rate constant for micropollutant degradation(K′_(p,MP))in various UV-AOPs by combining model simulation with portable measurement.Portable methods for measuring the scavenging capacities of the principal RRs(RRSCs)involved in UV-AOPs(i.e.,HO^(·),SO_(4)^(·-),and Cl^(·))using a mini-fluidic photoreaction system were proposed.The simulation models consisted of photochemical,quantitative structure–activity relationship,and radical concentration steady-state approximation models.The RRSCs were determined in eight test waters,and a higher RRSC was found to be associated with a more complex water matrix.Then,by taking sulfamethazine,caffeine,and carbamazepine as model micropollutants,the k′_(p,MP) values in various UV-AOPs were predicted and further verified experimentally.A lower k′_(p,MP) was found to be associated with a higher RRSC for a stronger RR competition;for example,k′_(p,MP) values of 130.9 and 332.5 m^(2) einstein^(–1),respectively,were obtained for carbamazepine degradation by UV/H_(2)O_(2) in the raw water(RRSC=9.47×10^(4) s^(-1))and sand-filtered effluent(RRSC=2.87×10^(4) s^(-1))of a drinking water treatment plant.The developed method facilitates process selection and optimization for UV-AOPs,which is essential for increasing the efficiency and cost-effectiveness of water treatment. 展开更多
关键词 UV-AOPs Micropollutant degradation Reactive radicals Water matrix Model simulation
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Photocatalytic degradation of methylene blue over MIL-100(Fe)/GO composites: a performance and kinetic study
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作者 Yuxue Wei Zhiyuan Fu +6 位作者 Yingzi Meng Chun Li Fu Yin Xue Wang Chenghua Zhang Lisheng Guo Song Sun 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第3期208-222,共15页
Adsorption coupled with photocatalytic degradation is proposed to fulfill the removal and thorough elimination of organic dyes.Herein,we report a facile hydrothermal synthesis of MIL-100(Fe)/GO photocatalysts.The adso... Adsorption coupled with photocatalytic degradation is proposed to fulfill the removal and thorough elimination of organic dyes.Herein,we report a facile hydrothermal synthesis of MIL-100(Fe)/GO photocatalysts.The adsorption and photocatalytic degradation process of methylene blue(MB)on MIL‐100(Fe)/GO composites were systematically studied from performance and kinetic perspectives.A possible adsorption‐photocatalytic degradation mechanism is proposed.The optimized 1M8G composite achieves 95%MB removal(60.8 mg/g)in 210 min and displays well recyclability over ten cycles.The obtained MB adsorption and degradation results are well fitted onto Langmuir isotherm and pseudo‐second order kinetic model.This study shed light on the design of MOFs based composites for water treatment. 展开更多
关键词 Graphene oxide Metal organic frameworks Methylene blue ADSORPTION Photocatalytic degradation
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Hydrodynamic Cavitation Enhanced SR-Aops Degradation of Organic Pollutants in Water:A Review
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作者 Xiufeng Zhu Jingying Wang 《Fluid Dynamics & Materials Processing》 EI 2024年第4期671-692,共22页
SR-AOP(sulfate radical advanced oxidation process)is a novel water treatment method able to eliminate refractory organic pollutants.Hydrodynamic cavitation(HC)is a novel green technology,that can effectively produce s... SR-AOP(sulfate radical advanced oxidation process)is a novel water treatment method able to eliminate refractory organic pollutants.Hydrodynamic cavitation(HC)is a novel green technology,that can effectively produce strong oxidizing sulfate radicals.This paper presents a comprehensive review of the research advancements in these fields and a critical discussion of the principal factors influencing HC-enhanced SR-AOP and the mechanisms of synergistic degradation.Furthermore,some insights into the industrial application of HC/PS are also provided.Current research shows that this technology is feasible at the laboratory stage,but its application on larger scales requires further understanding and exploration.In this review,some attention is also paid to the design of the hydrodynamic cavitation reactor and the related operating parameters. 展开更多
关键词 Hydrodynamic cavitation organic pollutant PERSULFATE degradation influence factor
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The misalignment between degradation rate and mechanical integrity of Mg-Zn-Y-Nd alloy during the degradation evaluation in modified Hanks’solutions
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作者 Di Mei Qingyuan Zhang +7 位作者 Yaqian Li Mengyao Liu Wenkai Li Pingli Jiang Ruiqing Hou Shijie Zhu Liguo Wang Shaokang Guan 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第9期3661-3674,共14页
The degradation behavior of biodegradable Mg alloys has become a research hotspot in the fields about biodegradable metallic materials.While the most of the related publications mainly focused on the degradation rate ... The degradation behavior of biodegradable Mg alloys has become a research hotspot in the fields about biodegradable metallic materials.While the most of the related publications mainly focused on the degradation rate of Mg-based materials,but rare to care about the changes of their mechanical properties during the immersion period,which can significantly affect their service performance.The link between residual strength and Mg degradation is not appreciated enough.In this work,a series media were constructed based on Hanks’solution,the effects of inorganic ions on the degradation rate and mechanical integrity of Mg-Zn-Y-Nd alloy were investigated.The results indicated that the degradation behavior of Mg alloy was mainly controlled by degradation products and there is no direct correspondence between the degradation rate change and mechanical integrity of Mg alloy.The relevant findings are beneficial for selecting the monitoring index in Mg corrosion tests and evaluating the service reliability of Mg alloys for biomedical applications. 展开更多
关键词 Magnesium alloy degradation rate Mechanical integrity Hanks’solution
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