1 Results Living free radical polymerization has undergone tremendous advancement in the past few years, particularly in the area of nitroxide mediated free radical polymerization. In 1980s, the use of nitroxyl free r...1 Results Living free radical polymerization has undergone tremendous advancement in the past few years, particularly in the area of nitroxide mediated free radical polymerization. In 1980s, the use of nitroxyl free radicals such as 2,2,6,6-tetramethylpiperidinyl-1-oxyl(TEMPO) to moderate free radical polymerizations was first reported by Rizzardo,et al[1], more and more people began to interested in the polymerization methods which controlled by nitroxide stable free radicals. Recently, some people int...展开更多
文摘1 Results Living free radical polymerization has undergone tremendous advancement in the past few years, particularly in the area of nitroxide mediated free radical polymerization. In 1980s, the use of nitroxyl free radicals such as 2,2,6,6-tetramethylpiperidinyl-1-oxyl(TEMPO) to moderate free radical polymerizations was first reported by Rizzardo,et al[1], more and more people began to interested in the polymerization methods which controlled by nitroxide stable free radicals. Recently, some people int...