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富氡地热水中δ^(34)S_(so4)^(2-)、δ^(13)C_(DIC)同位素特征及其意义——以息烽温泉为例 被引量:1
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作者 张中欣 罗腾 +3 位作者 陈正山 陈刚 杨晨 肖吉 《环境化学》 CAS CSCD 北大核心 2022年第2期643-652,共10页
贵州息烽温泉被誉为“亚洲第一氡泉”,富含多种有益元素。选取息烽地热水和与其有关的地表径流水及岩溶泉水为研究对象,利用水文地球化学、δ^(34)S_(SO_(4)^(2-))、δ^(13)C_(HCO_(3)^(-))同位素等方法对区内富氡地热水中硫、碳元素来... 贵州息烽温泉被誉为“亚洲第一氡泉”,富含多种有益元素。选取息烽地热水和与其有关的地表径流水及岩溶泉水为研究对象,利用水文地球化学、δ^(34)S_(SO_(4)^(2-))、δ^(13)C_(HCO_(3)^(-))同位素等方法对区内富氡地热水中硫、碳元素来源及水-岩作用过程进行研究。结果显示,地热水水化学类型为HCO_(3)·SO_(4)−Ca·Mg型,pH呈弱碱性,其阴离子主要为HCO_(3)^(−)和SO_(4)^(2−),阳离子主要Ca^(2+)和Mg^(2+),阴离子浓度变化范围为86—191.01 mg·L^(−1),阳离子浓度变化范围为20.7—57.4 mg·L^(−1)。地热水中δ^(13)C_(HCO_(3)^(−))值为−4.85‰—−9.12‰,计算得出CO_(2)的δ^(13)C_(CO_(2))值集中在−10.34‰—−13.99‰间,其参与水-岩反应的CO_(2)为幔源和土壤混合成因。δ^(34)S_(SO_(4)^(2-))值为25.41‰—27.53‰,与区内寒武系娄山关岩组中石膏中的δ^(34)S_(SO_(4)^(2-))值(26.73‰—29.57‰)一致。结合地热水中的阴阳离子含量、δ^(34)S_(SO_(4)^(2-))值和δ^(13)C_(HCO3)^(-)值的分析,可以认为大气降水入渗寒武系娄山关组碳酸盐岩地层发生的水岩反应主要为石膏的溶解,其次CO_(2)进入含水层与围岩发生水岩作用生成HCO_(3)^(−)。 展开更多
关键词 ^δ^(34)S_(SO_(4)^(2-)) ^δ^(13)C_(HCO_(3)^(-))水-岩作用 富氡地热水 贵州息烽
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Source identification of nitrate in the upper aquifer system of the Wadi Shueib catchment area in Jordan based on stable isotope composition 被引量:4
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作者 Mutawakil OBEIDAT Muheeb AWAWDEH +1 位作者 Noor AL-KHARABSHEH Ahmad AL-AJLOUNI 《Journal of Arid Land》 SCIE CSCD 2021年第4期350-374,共25页
Groundwater forms the main freshwater supply in arid and semi-arid areas,and contamination of this precious resource is complicated by the slow rate of recharge in these areas.Nitrate contamination of groundwater is a... Groundwater forms the main freshwater supply in arid and semi-arid areas,and contamination of this precious resource is complicated by the slow rate of recharge in these areas.Nitrate contamination of groundwater is a global water quality problem,as it entails threat to human health as well as aquatic ecosystems.Source identification of contamination is the cornerstone and a prerequisite for any effective management program of water quality.Stable isotope composition of the dissolved nitrate(δ^(15)N-NO_(3)-andδ^(18)O-NO_(3)-)has been applied to identify NO_(3)-sources and the main transformation processes in the upper aquifer system(A1/2,A4,and B2/A7 aquifers)in the Wadi Shueib catchment area,Jordan.Moreover,the stable isotope compositions of the groundwater(δ^(2)H-H_(2)O andδ^(18)O-H_(2)O)in conjunction with the groundwater hydrochemistry were integrated to investigate the origin and evolution of the groundwater.Results revealed that groundwater in the study area is fresh and hard-very hard water,and mainly a Ca-Mg-Cl type.NO_(3)-concentration was in the range of 7.0-74.0 mg/L with an average of 37.0 mg/L.Most of the samples showed concentration higher than the natural background concentration of NO_(3)-(5.0-10.0 mg/L).Theδ^(2)H-H_(2)O andδ^(18)O-H_(2)O values indicated that the groundwater is meteoric,and of Mediterranean origin,with a strong evaporation effect.Theδ^(15)N-NO_(3)-values ranged between 6.0‰and 11.3‰with an average of 8.7‰,and theδ^(18)O-NO_(3)-values ranged between 1.6‰and 5.9‰with an average of 3.4‰.These values are in conformity with the stable isotope composition of nitrate derived the nitrification of wastewater/manure,and soil NH4.Nitrification and denitrification are the main transformation processes affecting nitrogen species.Statistical analysis revealed no significant differences in theδ^(2)H-H_(2)O andδ^(18)OH_(2)O values,andδ^(15)N-NO_(3)-andδ^(18)O-NO_(3)-values for the three aquifers(A1/2,A4,and B2/A7),indicating that the groundwater of these aquifers has the same origin,and a common source of pollution. 展开更多
关键词 ^δ^(15)N-NO_(3)– ^δ^(18)O-NO_(3)– nitrate sources pollution meteoric origin AQUIFER JORDAN
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Helium and Oxygen isotopic evidence on exchange of waters betweenthe western Pacific Ocean and the South China Sea
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作者 Ren Jianguo Wang Xianbin 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2000年第4期73-79,共7页
The composition and distribution of helium and oxygen isotopes in samples of seawater ob-tained at depths from surface to 300 m in the western Pacific Ocean (7°-26°N, 122° - 130°E) were discussed ... The composition and distribution of helium and oxygen isotopes in samples of seawater ob-tained at depths from surface to 300 m in the western Pacific Ocean (7°-26°N, 122° - 130°E) were discussed in detail. The results shaw that both δ18O and δ3He isoline extend eastward in the Pacific side of the Bashi Channel, which may suggest that the South China Sea water intrudes into the western Pacific by the Bashi Channel. 展开更多
关键词 The western Pacific Ocean ^δ^(18)O ^δ^(3)He distribution MIXING
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氮氧同位素示踪北京冬季大气硝酸盐来源
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作者 曹林 张忠义 《环境科学与技术》 CAS CSCD 北大核心 2021年第12期39-45,共7页
硝酸盐是大气细颗粒物(PM_(2.5))主要的二次无机组分之一,探究颗粒物硝酸盐的形成机制及NOx排放源结构对治理PM_(2.5)污染和改善空气质量至关重要。为此,该研究收集并分析了北京市实施清洁空气行动计划前后(2013-2018年)冬季大气硝酸盐... 硝酸盐是大气细颗粒物(PM_(2.5))主要的二次无机组分之一,探究颗粒物硝酸盐的形成机制及NOx排放源结构对治理PM_(2.5)污染和改善空气质量至关重要。为此,该研究收集并分析了北京市实施清洁空气行动计划前后(2013-2018年)冬季大气硝酸盐同位素组成特征。结果显示,北京市实施清洁空气行动期间,冬季大气PM_(2.5)中硝酸盐氮同位素(δ^(15)N-NO_(3)^(-))没有发生显著变化;δ^(15)N-NO_(3)^(-)平均值分别为+13.10‰±4.67‰(2013)、+12.65‰±4.08‰(2014)、+12.4‰±3.5‰(2017)、+11.54‰±4.22‰(2018)。通过剖析影响硝酸盐氮同位素的主要因素,研究认为该期间NOx排放源结构并没有显著变化。结合同位素组成和贝叶斯混合模型发现,2013-2018年期间机动车尾气对冬季NO_(x)的平均贡献值均保持在75%左右,表明机动车尾气可能是北京市冬季PM_(2.5)中硝酸盐的主要来源。由此可见,加强机动车尾气排放标准管理,是降低北京地区硝酸盐浓度和改善空气质量的有力途径。 展开更多
关键词 硝酸盐 ^δ^(15)N-NO_(3)^(-) 氮氧化物 贝叶斯混合模型 北京
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漓江流域碳氮同位素组成特征及其来源初探 被引量:8
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作者 任梦梦 黄芬 +2 位作者 胡晓农 曹建华 张鹏 《地球科学》 EI CAS CSCD 北大核心 2020年第5期1830-1843,共14页
以漓江流域境内地表河和地下河为研究对象,通过测定、分析水体中的水化学组成以及δ13CDIC、δ15N-NO3-、δ18O-NO3-等,利用同位素质量平衡混合模型,初步探讨了漓江流域境内DIC、硝酸盐的分布特征及其来源.结果表明:漓江流域DIC(即HCO3-... 以漓江流域境内地表河和地下河为研究对象,通过测定、分析水体中的水化学组成以及δ13CDIC、δ15N-NO3-、δ18O-NO3-等,利用同位素质量平衡混合模型,初步探讨了漓江流域境内DIC、硝酸盐的分布特征及其来源.结果表明:漓江流域DIC(即HCO3-)浓度和无机碳稳定同位素(δ13CDIC)分别在12.20~402.60 mg·L-1和-17.29‰^-10.01‰,平均值分别为140.3 mg·L-1和-13.06‰.NO3-浓度在2.37~35.38 mg·L-1,δ15N-NO3-在0.99‰~11.09‰,均展现出明显的空间变异特征.有机肥和污水对漓江流域硝酸盐的贡献最为显著,贡献比达57.00%.其次是化肥、降雨中的NH4+和土壤N,贡献比分别是36.45%,6.55%.流域内DIC主要来源于碳酸盐岩的风化和土壤CO2的溶解,同时也受硝酸溶蚀碳酸盐岩和大气CO2的影响.结果可为定制有效的控制硝酸盐的输入途径,净化水质测略提供依据. 展开更多
关键词 漓江 ^δ^(13)C_(DIC) 溶解性无机碳(DIC) ^δ^(15)N-NO_(3)^(-) ^δ^(18)O-NO_(3)^(-) 硝酸盐 水文地质
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