The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is u...The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is usually sensitive to climate change.The water resource management in the monsoon margin should be better planned by understanding the composition of precipitation isotope and its influencing factors.In this study,the precipitation samples were collected at five sampling sites(Baiyin City,Kongtong District,Maqu County,Wudu District,and Yinchuan City)of the monsoon margin in the northwest of China in 2022 to analyze the characteristics of stable hydrogen(δD)and oxygen(δ18O)isotopes.We analyzed the impact of meteorological factors(temperature,precipitation,and relative humidity)on the composition of precipitation isotope at daily level by regression analysis,utilized the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)-based backward trajectory model to simulate the air mass trajectory of precipitation events,and adopted the potential source contribution function(PSCF)and concentration weighted trajectory(CWT)to analyze the water vapor sources.The results showed that compared with the global meteoric water line(GMWL),the slope of the local meteoric water line(LMWL;δD=7.34δ^(18)O-1.16)was lower,indicating the existence of strong regional evaporation in the study area.Temperature significantly contributed toδ18O value,while relative humidity had a significant negative effect onδ18O value.Through the backward trajectory analysis,we found eight primary locations that were responsible for the water vapor sources of precipitation in the study area,of which moisture from the Indian Ocean to South China Sea(ITSC)and the western continental(CW)had the greatest influence on precipitation in the study area.The hydrogen and oxygen isotopes in precipitation are significantly influenced by the sources and transportation paths of air mass.In addition,the results of PSCF and CWT analysis showed that the water vapor source areas were primarily distributed in the south and northwest direction of the study area.展开更多
This paper presents an evaluation of different dose of Sodium Metabisulfite (0.01 M Na2S2O5), (Na2S2O5) + (0.1 HCl), and Distilled water for the removal of soil contaminated with Pb, Zn and Cr by the column mode. The ...This paper presents an evaluation of different dose of Sodium Metabisulfite (0.01 M Na2S2O5), (Na2S2O5) + (0.1 HCl), and Distilled water for the removal of soil contaminated with Pb, Zn and Cr by the column mode. The field soil contained concentrations of Pb (307.31 mg⋅kg−1), Zn (207.77 mg⋅kg−1) and Cr (447.50 mg⋅kg−1). Both (0.01 M Na2S2O5), (Na2S2O5) + (0.1 HCl), and Distilled water were found to be effective on removing (Na2S2O5) Pb, Cr and Zn respectively. (Na2S2O5) + (0.1 HCl) Cr, Zn and Pb respectively. Sulfur Pb, Cr and Zn respectively. The removal rate of Pb, Zn, and Cr varied from 10.35% - 26%, 3.4% - 21.60% and 4.97% - 23.88% for (0.01 M Na2S2O5 respectively. The removal rate of Pb, Zn, and Cr varied from 16.13% - 20.07%, 8.20% - 23.48%, 5.42% - 28.93% for (0.01 M Na2S2O5 + 0.1 M HCl) respectively. The removal rate of Pb, Zn, and Cr varied from 10.20% - 25.5%, 9.55% - 25.13% and 6.04% - 25.54% for (S) respectively.展开更多
Based on the theoretical modelling of water-rock δD-δ18O isotopic exchange process,the evolution and sources of ore-forming fluid in four metallogenic epochs of the Jinduicheng su-perlarge-scale porphyry-type molybd...Based on the theoretical modelling of water-rock δD-δ18O isotopic exchange process,the evolution and sources of ore-forming fluid in four metallogenic epochs of the Jinduicheng su-perlarge-scale porphyry-type molybdenum deposit were investigated. It was revealed that in thepre-metallogenic and early-metallogenic epehs, the ore-forming fluid was a residual fluid derived from magmatic water-wall rock interaction at middle to high temperatures (T = 250 -500℃) and lower W/R ratios (0. 1 > = W/R >0.001 ), while in the metallogenic and Post-metallogenic epochs, the ore-forming nuid was a residual fluid derived from meteoric water-wallrock interaction at midd1e to lower temperatures (T = 150 - 310℃ ) and relatively high W/Rratios (0. 5 >W/R≥0.1 ). The meteoric water played an important role in molybdenum min-eralization, and at the main metallogenic epoch the W/R ratio reached its maximum value.展开更多
Chemical and isotopic data were measured for 51 leached brine springs in the Changdu-Lanping-Simao Basin(CD-LP-SM),China.The predominance of Cl and Na,saturation indices of carbonate minerals,and Na/Cl and Ca/SO4 rati...Chemical and isotopic data were measured for 51 leached brine springs in the Changdu-Lanping-Simao Basin(CD-LP-SM),China.The predominance of Cl and Na,saturation indices of carbonate minerals,and Na/Cl and Ca/SO4 ratios of^1 suggest that halite,sulphate,and carbonate are the solute sources.Integration of geochemical,δ18 O,andδD values suggests that springs are mainly derived from meteoric water,ice-snow melt,and water-rock interactions.B concentrations range from 0.18 to 11.9 mg/L,withδ11 B values of-4.37‰to+32.39‰,indicating a terrestrial source.Theδ11 B-B relationships suggest B sources of crustal origin(marine carbonates with minor crust-derived volcanics);we did not identify a marine or deep mantle origin.Theδ11 B values of saline springs(+4.61‰to+32.39‰)exceed those of hot(-4.37‰to+4.53‰)and cold(-3.47‰to+14.84‰)springs;this has contributed to strong water-rock interactions and strong saturation of dissolved carbonates.Conversely,the global geothermalδ11 B-Cl/B relationship suggests mixing of marine and non-marine sources.Theδ11 B-Cl/B relationships of the CD-LP-SM are similar to those of the Tibet geothermal belt and the Nangqen Basin,indicating the same B origin.These differ from thermal waters controlled by magmatic fluids and seawater,suggesting that B in CD-LP-SM springs has a crustal origin.展开更多
Pesticides provide the primary means for controlling organisms that compete with man for food and fibre or cause injury to man, livestock and crops. They played a vital role in the economic production of wide ranges o...Pesticides provide the primary means for controlling organisms that compete with man for food and fibre or cause injury to man, livestock and crops. They played a vital role in the economic production of wide ranges of vegetable, fruit, cereal, forage, fibre and oil crops which now constitute a large part of successful agricultural industry in many countries. After application to the target areas, pesticide residues are removed from applicators by rinsing with water which results in the formation of a toxic wastewater that represents a disposal problem for many farmers. Pesticides can adversely affect people, pets, livestock and wildlife in addition to the pests they are intended to destroy. The phenomenon of biomagnification of some pesticides has resulted in reproductive failure of some fish species and egg shell thinning of birds such as peregrine falcons, sparrow hawk and eagle owls. Pesticide toxicity to humans include skin and eye irritation and skin cancer. Therefore, care must be exercised in the application, disposal and treatment of pesticides. Currently, disposal of pesticide wastewater is carried out by: 1) land cultivation, 2) dumping in soil pits, plastic pits and concrete pits or on land and in extreme cases in streams near the rinsing operation, 3) use of evaporation beds and 4) land filling. These methods of disposal are unsafe as the surface run off will reach streams, rivers and lakes and the infiltration of the wastewater into the local soil will eventually reach ground water. The treatment methods currently used for pesticide wastewater include: 1) incineration (incinerators and open burning), 2) chemical treatments (O3/UV, hydrolysis, Fenton oxidation and KPEG), 3) physical treatments (inorganic, organic absorbents and activated carbon) and 4) biological treatments (composting, bioaugmentation and phytoremediation). Therefore, the choice of safe, on farm disposal techniques for agricultural pesticides is very important. A comparative analysis was performed on 18 methods of pesticide disposal/treatment using six criteria: containment, detoxification ability, cost, time, suitability for on farm use, size and evaporation efficiency. The results indicated that of the 18 methods evaluated, 9 scored above 80/100 and can be used on farm. They were organic absorbents (97), composting (94), bioaugmentation (92), inorganic absorbents (90), Fenton oxidation (86), O3/UV (83), activated carbon (82), hydrolysis (82), and land cultivation (80). The other methods are not suitable for on farm use as they suffered from containment problems, high cost and variability of effectiveness.展开更多
Various water samples were collected for electrical conductivity (EC) and δ^18O analysis,and the proportion and contribution of atmospheric precipitation,glacier ice and shallow groundwater to discharge in the Koxkar...Various water samples were collected for electrical conductivity (EC) and δ^18O analysis,and the proportion and contribution of atmospheric precipitation,glacier ice and shallow groundwater to discharge in the Koxkar glacier basin at the south slope of the Tianshan Mountains were studied.The results show that glacial ice-water recharge was dominant,accounting for 72.11% of the annual runoff.It also had a significant positive correlation with temperature during the warm season (from May to September).However,glacier ice ablation replenishment still existed when the temperature in the cold season was below the critical temperature of 0 ℃.This could be that the heat generated by the friction between the ice body and the ice bed during the subglacial ice sliding process led ice to melt,what's more,the stored water in the geometric passages inside and below the glacier could slowly release.Groundwater recharge accounted for 16.38% of the total runoff.The supplement was small and its variation range was relatively small in the cold season.But in the warm season,the amount of groundwater recharge increased and changed drastically.It might be that the seasonal frozen soil in the basin was widely developed and was affected by temperature changes.Atmospheric precipitation replenishment only accounted for 11.51%.The daily precipitation recharge river water had a significant response to regional precipitation,but there was hysteresis in time,and there was still precipitation recharge runoff even in the absence of precipitation.展开更多
基金supported by the National Natural Science Foundation of China(42161007)the Scientific Research Program for Higher Education Institutions of Gansu Province(2021B-081)the Natural Science Foundation of Gansu Province(22JR5RA074).
文摘The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is usually sensitive to climate change.The water resource management in the monsoon margin should be better planned by understanding the composition of precipitation isotope and its influencing factors.In this study,the precipitation samples were collected at five sampling sites(Baiyin City,Kongtong District,Maqu County,Wudu District,and Yinchuan City)of the monsoon margin in the northwest of China in 2022 to analyze the characteristics of stable hydrogen(δD)and oxygen(δ18O)isotopes.We analyzed the impact of meteorological factors(temperature,precipitation,and relative humidity)on the composition of precipitation isotope at daily level by regression analysis,utilized the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)-based backward trajectory model to simulate the air mass trajectory of precipitation events,and adopted the potential source contribution function(PSCF)and concentration weighted trajectory(CWT)to analyze the water vapor sources.The results showed that compared with the global meteoric water line(GMWL),the slope of the local meteoric water line(LMWL;δD=7.34δ^(18)O-1.16)was lower,indicating the existence of strong regional evaporation in the study area.Temperature significantly contributed toδ18O value,while relative humidity had a significant negative effect onδ18O value.Through the backward trajectory analysis,we found eight primary locations that were responsible for the water vapor sources of precipitation in the study area,of which moisture from the Indian Ocean to South China Sea(ITSC)and the western continental(CW)had the greatest influence on precipitation in the study area.The hydrogen and oxygen isotopes in precipitation are significantly influenced by the sources and transportation paths of air mass.In addition,the results of PSCF and CWT analysis showed that the water vapor source areas were primarily distributed in the south and northwest direction of the study area.
文摘This paper presents an evaluation of different dose of Sodium Metabisulfite (0.01 M Na2S2O5), (Na2S2O5) + (0.1 HCl), and Distilled water for the removal of soil contaminated with Pb, Zn and Cr by the column mode. The field soil contained concentrations of Pb (307.31 mg⋅kg−1), Zn (207.77 mg⋅kg−1) and Cr (447.50 mg⋅kg−1). Both (0.01 M Na2S2O5), (Na2S2O5) + (0.1 HCl), and Distilled water were found to be effective on removing (Na2S2O5) Pb, Cr and Zn respectively. (Na2S2O5) + (0.1 HCl) Cr, Zn and Pb respectively. Sulfur Pb, Cr and Zn respectively. The removal rate of Pb, Zn, and Cr varied from 10.35% - 26%, 3.4% - 21.60% and 4.97% - 23.88% for (0.01 M Na2S2O5 respectively. The removal rate of Pb, Zn, and Cr varied from 16.13% - 20.07%, 8.20% - 23.48%, 5.42% - 28.93% for (0.01 M Na2S2O5 + 0.1 M HCl) respectively. The removal rate of Pb, Zn, and Cr varied from 10.20% - 25.5%, 9.55% - 25.13% and 6.04% - 25.54% for (S) respectively.
文摘Based on the theoretical modelling of water-rock δD-δ18O isotopic exchange process,the evolution and sources of ore-forming fluid in four metallogenic epochs of the Jinduicheng su-perlarge-scale porphyry-type molybdenum deposit were investigated. It was revealed that in thepre-metallogenic and early-metallogenic epehs, the ore-forming fluid was a residual fluid derived from magmatic water-wall rock interaction at middle to high temperatures (T = 250 -500℃) and lower W/R ratios (0. 1 > = W/R >0.001 ), while in the metallogenic and Post-metallogenic epochs, the ore-forming nuid was a residual fluid derived from meteoric water-wallrock interaction at midd1e to lower temperatures (T = 150 - 310℃ ) and relatively high W/Rratios (0. 5 >W/R≥0.1 ). The meteoric water played an important role in molybdenum min-eralization, and at the main metallogenic epoch the W/R ratio reached its maximum value.
基金funded by the National Key Basic Research Project of China(973 program,No.2011CB403004)
文摘Chemical and isotopic data were measured for 51 leached brine springs in the Changdu-Lanping-Simao Basin(CD-LP-SM),China.The predominance of Cl and Na,saturation indices of carbonate minerals,and Na/Cl and Ca/SO4 ratios of^1 suggest that halite,sulphate,and carbonate are the solute sources.Integration of geochemical,δ18 O,andδD values suggests that springs are mainly derived from meteoric water,ice-snow melt,and water-rock interactions.B concentrations range from 0.18 to 11.9 mg/L,withδ11 B values of-4.37‰to+32.39‰,indicating a terrestrial source.Theδ11 B-B relationships suggest B sources of crustal origin(marine carbonates with minor crust-derived volcanics);we did not identify a marine or deep mantle origin.Theδ11 B values of saline springs(+4.61‰to+32.39‰)exceed those of hot(-4.37‰to+4.53‰)and cold(-3.47‰to+14.84‰)springs;this has contributed to strong water-rock interactions and strong saturation of dissolved carbonates.Conversely,the global geothermalδ11 B-Cl/B relationship suggests mixing of marine and non-marine sources.Theδ11 B-Cl/B relationships of the CD-LP-SM are similar to those of the Tibet geothermal belt and the Nangqen Basin,indicating the same B origin.These differ from thermal waters controlled by magmatic fluids and seawater,suggesting that B in CD-LP-SM springs has a crustal origin.
文摘Pesticides provide the primary means for controlling organisms that compete with man for food and fibre or cause injury to man, livestock and crops. They played a vital role in the economic production of wide ranges of vegetable, fruit, cereal, forage, fibre and oil crops which now constitute a large part of successful agricultural industry in many countries. After application to the target areas, pesticide residues are removed from applicators by rinsing with water which results in the formation of a toxic wastewater that represents a disposal problem for many farmers. Pesticides can adversely affect people, pets, livestock and wildlife in addition to the pests they are intended to destroy. The phenomenon of biomagnification of some pesticides has resulted in reproductive failure of some fish species and egg shell thinning of birds such as peregrine falcons, sparrow hawk and eagle owls. Pesticide toxicity to humans include skin and eye irritation and skin cancer. Therefore, care must be exercised in the application, disposal and treatment of pesticides. Currently, disposal of pesticide wastewater is carried out by: 1) land cultivation, 2) dumping in soil pits, plastic pits and concrete pits or on land and in extreme cases in streams near the rinsing operation, 3) use of evaporation beds and 4) land filling. These methods of disposal are unsafe as the surface run off will reach streams, rivers and lakes and the infiltration of the wastewater into the local soil will eventually reach ground water. The treatment methods currently used for pesticide wastewater include: 1) incineration (incinerators and open burning), 2) chemical treatments (O3/UV, hydrolysis, Fenton oxidation and KPEG), 3) physical treatments (inorganic, organic absorbents and activated carbon) and 4) biological treatments (composting, bioaugmentation and phytoremediation). Therefore, the choice of safe, on farm disposal techniques for agricultural pesticides is very important. A comparative analysis was performed on 18 methods of pesticide disposal/treatment using six criteria: containment, detoxification ability, cost, time, suitability for on farm use, size and evaporation efficiency. The results indicated that of the 18 methods evaluated, 9 scored above 80/100 and can be used on farm. They were organic absorbents (97), composting (94), bioaugmentation (92), inorganic absorbents (90), Fenton oxidation (86), O3/UV (83), activated carbon (82), hydrolysis (82), and land cultivation (80). The other methods are not suitable for on farm use as they suffered from containment problems, high cost and variability of effectiveness.
基金Supported by the National Natural Science Foundation of China(41471060,41401084,41730751 and 41871055)
文摘Various water samples were collected for electrical conductivity (EC) and δ^18O analysis,and the proportion and contribution of atmospheric precipitation,glacier ice and shallow groundwater to discharge in the Koxkar glacier basin at the south slope of the Tianshan Mountains were studied.The results show that glacial ice-water recharge was dominant,accounting for 72.11% of the annual runoff.It also had a significant positive correlation with temperature during the warm season (from May to September).However,glacier ice ablation replenishment still existed when the temperature in the cold season was below the critical temperature of 0 ℃.This could be that the heat generated by the friction between the ice body and the ice bed during the subglacial ice sliding process led ice to melt,what's more,the stored water in the geometric passages inside and below the glacier could slowly release.Groundwater recharge accounted for 16.38% of the total runoff.The supplement was small and its variation range was relatively small in the cold season.But in the warm season,the amount of groundwater recharge increased and changed drastically.It might be that the seasonal frozen soil in the basin was widely developed and was affected by temperature changes.Atmospheric precipitation replenishment only accounted for 11.51%.The daily precipitation recharge river water had a significant response to regional precipitation,but there was hysteresis in time,and there was still precipitation recharge runoff even in the absence of precipitation.
文摘采用室内培养方法,选取两个土壤空隙含水量(water-filled pore space,WFPS)(55%和65%WFPS)和3个p H(5.5、6.5、7.5),研究p H和含水量对设施菜地土壤N_2O排放的影响.结果表明,含水量为55%WFPS时,p H值为5.5、6.5、7.5处理的N_2O累积排放量分别为1219.95±24.16、522.96±13.88、209.84±13.86μg·kg^(-1).含水量为65%WFPS时,p H值为5.5、6.5、7.5处理的N_2O累积排放量分别为1448.57±5.63、831.90±10.41、432.65±12.69μg·kg^(-1).除55%WFPS+p H 6.5处理与65%WFPS+p H 7.5处理间的N_2O累积排放量差异不显著(P>0.05),其它各处理间均存在显著性差异(P<0.05).65%WFPS+p H 5.5处理的N_2O累积排放量显著高于其他处理(P<0.05),比55%WFPS+p H 7.5处理的增加了5.9倍.同一含水量下,土壤p H值在5.5—7.5内N_2O累积排放量随p H值的降低而增加.同一p H下,含水量在55%—65%WFPS内土壤含水量越高N_2O累积排放量越大.p H和含水量是影响设施菜地土壤N_2O排放的重要因素.
