Some high T_c superconductors REBa_2Cu_3O_(7-x)(RE=Sm,Eu,Gd,Dy,Ho,Er,Tm) with zero resist- ance temperatures were about 90K have been prepared.The effect of magnetic rare earth ions on the transi- tion temperatures is...Some high T_c superconductors REBa_2Cu_3O_(7-x)(RE=Sm,Eu,Gd,Dy,Ho,Er,Tm) with zero resist- ance temperatures were about 90K have been prepared.The effect of magnetic rare earth ions on the transi- tion temperatures is not very great,but their magnetic behaviours are different from each other.The magnetization loops of these compounds have been measured at 77K.The coexistence of superconductivity with magnetic ordering (COSM) found in the samples with RE=Gd,Dy,Ho,Er,Tm,indicates that there are two possible ways of coexistence in the samples.These expertments show that the relation of paramagnetism to the atomtc number of rare earth elements for these superconductors is similar to that of rare earth ions in some paramagnetic salt crystals,which indicates that the magnetism of the samples origi- nates from the local magnetic moments of rare earth ions.In some samples there is antiferromagnetie ordering at low temperatures,and the effective Bohr magneton numbers are consistent with that of free rare earth ions. Some superconducting parameters including the critical current density are calculated according to Ginzburg-Landau theory and the critical state model.展开更多
The Eu^3＋/Ag co-doped rare earth disilicate Y2Si2O7 microcrystal was synthesized by sol-gel method. Through controlling the thermal treatment process of YzSi2OT：EU3＋/Ag precursor, various phases （amorphous, α, ...The Eu^3＋/Ag co-doped rare earth disilicate Y2Si2O7 microcrystal was synthesized by sol-gel method. Through controlling the thermal treatment process of YzSi2OT：EU3＋/Ag precursor, various phases （amorphous, α, β, γ, δ） were prepared. White light emis- sion was observed under UV light excitation in the samples heavily doped with Ag. The white light was realized by combining the intense red emission of Eu3＋, the green emission attributed to the very small molecule-like, non-plasmonic Ag particles （ML-Ag-particles）, and the blue emission due to Ag ions. Results demonstrated that Eu3＋/Ag co-doped Y2Si207 microcrystal could be potentially applied as white light emission phosphors for UV LED chips.展开更多
基金Supported by the Chinese National Science Foundation and originally published in J.Chin.RE Soc.(Chin.ed.),1989,7(2),63.
文摘Some high T_c superconductors REBa_2Cu_3O_(7-x)(RE=Sm,Eu,Gd,Dy,Ho,Er,Tm) with zero resist- ance temperatures were about 90K have been prepared.The effect of magnetic rare earth ions on the transi- tion temperatures is not very great,but their magnetic behaviours are different from each other.The magnetization loops of these compounds have been measured at 77K.The coexistence of superconductivity with magnetic ordering (COSM) found in the samples with RE=Gd,Dy,Ho,Er,Tm,indicates that there are two possible ways of coexistence in the samples.These expertments show that the relation of paramagnetism to the atomtc number of rare earth elements for these superconductors is similar to that of rare earth ions in some paramagnetic salt crystals,which indicates that the magnetism of the samples origi- nates from the local magnetic moments of rare earth ions.In some samples there is antiferromagnetie ordering at low temperatures,and the effective Bohr magneton numbers are consistent with that of free rare earth ions. Some superconducting parameters including the critical current density are calculated according to Ginzburg-Landau theory and the critical state model.
基金Project supported by the National Natural Science Foundation of China(11074232,11274288,21002097,11304300)the National Basic Research Program of China(2011CB932801,2012CB933702)Ministry of Education of China(20123402110034)
文摘The Eu^3＋/Ag co-doped rare earth disilicate Y2Si2O7 microcrystal was synthesized by sol-gel method. Through controlling the thermal treatment process of YzSi2OT：EU3＋/Ag precursor, various phases （amorphous, α, β, γ, δ） were prepared. White light emis- sion was observed under UV light excitation in the samples heavily doped with Ag. The white light was realized by combining the intense red emission of Eu3＋, the green emission attributed to the very small molecule-like, non-plasmonic Ag particles （ML-Ag-particles）, and the blue emission due to Ag ions. Results demonstrated that Eu3＋/Ag co-doped Y2Si207 microcrystal could be potentially applied as white light emission phosphors for UV LED chips.
