ε-Caprolactam(CL or CPL) is one of the most important intermediates used in polymer industry for the production of several million tons of nylon-6 every year^[1]. All current commercial processes for the production...ε-Caprolactam(CL or CPL) is one of the most important intermediates used in polymer industry for the production of several million tons of nylon-6 every year^[1]. All current commercial processes for the production of caprolactam are based on either benzene or tolueneI21. Caprolactam is synthesized by the Beckmann rearrangement of cyclohexanone oxime with fuming sulfuric acid or sulfuric acid as the reaction medium, and cyclohexanone oxime is produced by the reaction between cyclohexanone and hydro- xylamine(only one exception is the Toray PNC process).展开更多
基金Supported by the National Natural Science Foundation of China(Nos 20233040 and 20572021)
文摘ε-Caprolactam(CL or CPL) is one of the most important intermediates used in polymer industry for the production of several million tons of nylon-6 every year^[1]. All current commercial processes for the production of caprolactam are based on either benzene or tolueneI21. Caprolactam is synthesized by the Beckmann rearrangement of cyclohexanone oxime with fuming sulfuric acid or sulfuric acid as the reaction medium, and cyclohexanone oxime is produced by the reaction between cyclohexanone and hydro- xylamine(only one exception is the Toray PNC process).
基金supported by the Program for New Century Excellent Talents in University(NCET-10-0168)the National Natural Science Foundation of China(20976148,21006081)+1 种基金the Scientific Research Fund of Hunan Provincial Education Department(09CY007,CX2010B257)Project of Hunan Provincial Science and Technology Department(2010WK2008,2010GK3169)~~