The tri(o-chlorobenzyl)tin ester of 2-indolylcarboxylic acid has been synt hesized and characterized by elemental analysis, IR and 1H NMR. The crystal stru cture has been determined by X-ray single crystal diffraction...The tri(o-chlorobenzyl)tin ester of 2-indolylcarboxylic acid has been synt hesized and characterized by elemental analysis, IR and 1H NMR. The crystal stru cture has been determined by X-ray single crystal diffraction. The crystal belon gs to triclinic with space group P1, a=1.020 0(16) nm, b=1.125 9(18) nm, c=1.321 (2) nm, 8)穖-3,展开更多
The tri(o-bromobenzyl)abstract:tin bromide was tr eated with aqueous solution of NaOH to formed theμ-oxygen-bis[tri(o-bromoben zyl)abstract:tin].The crystal structures of compound was determined by X-ray diffraction ...The tri(o-bromobenzyl)abstract:tin bromide was tr eated with aqueous solution of NaOH to formed theμ-oxygen-bis[tri(o-bromoben zyl)abstract:tin].The crystal structures of compound was determined by X-ray diffraction .The crystal belongs to triclinic,space group with a=1.0544(4)abstract:nm,b=1.1029(4)abstract:nm,c =1.1309(4)abstract:nm,α=117.031(5)abstract:°,β=107.685(6)abstract:°,γ=98.523(6)abstract:°,V=1.0506(6)abstract:nm 3 ,Z=1,D x =2.013g·cm -3 ,μ(MoKα)abstract:=69.25cm -1 ,F(000)abstract:=606,R 1 =0.0524,wR 2 =0.1196.In the struture the tin atom has a distorted tetrahedral geometry.CC DC:220514.展开更多
The tetra(2, 4-dichlorobenzyl)tin was synthesized and characterized by elementary analysis, IR and 1H NMR. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal of the ti...The tetra(2, 4-dichlorobenzyl)tin was synthesized and characterized by elementary analysis, IR and 1H NMR. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to triclinic, space group P1 with a=1.089 7(3) nm, b=1.050 33(4) nm, c=1.858 5(4) nm, α=96.822(4)°, β=94.477(4)°, γ=94.636(3)°, V=3.001 3(12) nm3, Z=4, Dc=1.679 Mg·m-3, μ(Mo Kα)=1.582 mm-1, S=1.005, F(000)=1 496, R1=0.040 7, wR2=0.076 3. In compound, the tin atom has a distorted tetrahedral coordination configuration. The molecules are packed in one-dimensional chain polymer through a weak interaction between the chlorine atoms from adjacent molecules, respectively. CCDC: 286106.展开更多
文摘The tri(o-chlorobenzyl)tin ester of 2-indolylcarboxylic acid has been synt hesized and characterized by elemental analysis, IR and 1H NMR. The crystal stru cture has been determined by X-ray single crystal diffraction. The crystal belon gs to triclinic with space group P1, a=1.020 0(16) nm, b=1.125 9(18) nm, c=1.321 (2) nm, 8)穖-3,
文摘The tri(o-bromobenzyl)abstract:tin bromide was tr eated with aqueous solution of NaOH to formed theμ-oxygen-bis[tri(o-bromoben zyl)abstract:tin].The crystal structures of compound was determined by X-ray diffraction .The crystal belongs to triclinic,space group with a=1.0544(4)abstract:nm,b=1.1029(4)abstract:nm,c =1.1309(4)abstract:nm,α=117.031(5)abstract:°,β=107.685(6)abstract:°,γ=98.523(6)abstract:°,V=1.0506(6)abstract:nm 3 ,Z=1,D x =2.013g·cm -3 ,μ(MoKα)abstract:=69.25cm -1 ,F(000)abstract:=606,R 1 =0.0524,wR 2 =0.1196.In the struture the tin atom has a distorted tetrahedral geometry.CC DC:220514.
文摘The tetra(2, 4-dichlorobenzyl)tin was synthesized and characterized by elementary analysis, IR and 1H NMR. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to triclinic, space group P1 with a=1.089 7(3) nm, b=1.050 33(4) nm, c=1.858 5(4) nm, α=96.822(4)°, β=94.477(4)°, γ=94.636(3)°, V=3.001 3(12) nm3, Z=4, Dc=1.679 Mg·m-3, μ(Mo Kα)=1.582 mm-1, S=1.005, F(000)=1 496, R1=0.040 7, wR2=0.076 3. In compound, the tin atom has a distorted tetrahedral coordination configuration. The molecules are packed in one-dimensional chain polymer through a weak interaction between the chlorine atoms from adjacent molecules, respectively. CCDC: 286106.
