A formula was proved for computing the zeroth-order general Randic index of a hexagonal system to explore the correlation between the zeroth-order general Randic index and the π-electronic energy of a hexagonal syste...A formula was proved for computing the zeroth-order general Randic index of a hexagonal system to explore the correlation between the zeroth-order general Randic index and the π-electronic energy of a hexagonal system.As a consequence,the extremal hexagonal systems with minimum or maximum zeroth-order general Randic index were completely characterized.Moreover,by using the least-square fit method and regression analysis,a new and close relation was found between the zeroth-order general Randic index and the π-electronic energy of a hexagonal system.So the zeroth-order general Randic index is a good measure of the π-electronic energies for benzenoid hydrocarbons.展开更多
Increasing the availability ofπ-electron in graphitic carbon nitride(g-C_(3)N_(4))can reduce the band gap and thus enhance the photocatalytic hydrogen(H_(2))generation activity upon exposure to visible light,However,...Increasing the availability ofπ-electron in graphitic carbon nitride(g-C_(3)N_(4))can reduce the band gap and thus enhance the photocatalytic hydrogen(H_(2))generation activity upon exposure to visible light,However,such strategy has not yet been largely applied to increase the H_(2)generation of g-C_(3)N_(4).Herein,we succes s fully increased the amount ofπ-electron in g-C_(3)N_(4)by incorporatingπ-electron-rich benzene rings through copolymerization of melamine and trimesic acid in air.The incorporation of benzene rings not only extends the light absorption of g-C_(3)N_(4)to 650 nm,but also improves the electrical conductivity due to delocalization ofπelectrons in benzene rings.As a result,a 3.4 times enhancement of photocatalytic H_(2)generation was achieved from the g-C_(3)N_(4)with benzene ring incorporation in comparing with that of pristine g-C_(3)N_(4).More interestingly,H_(2)generation still occurs under irradiation of the light ofλ≥490 nm,above the absorption edge of pristine g-C_(3)N_(4)(~460 nm),illustrating the positive effectiveness of incorporated benzene rings on enhancing the H_(2)generation capacity of g-C_(3)N_(4).The present work manifests the advantages of increasingπ-conjugated electrons on designing highly active g-C_(3)N_(4)photocatalysts.展开更多
Photocatalysis using polymeric carbon nitride(CN)materials is a constantly evolving field,where the variation of synthetic procedures allows the constant improvement of activity by tackling the intrinsic limitations o...Photocatalysis using polymeric carbon nitride(CN)materials is a constantly evolving field,where the variation of synthetic procedures allows the constant improvement of activity by tackling the intrinsic limitations of these materials(optical absorbance,specific surface area,charge migration,etc.).Amongst the possible photocatalytic reactions,the most popular application of CNs is the hydrogen evolution reaction(HER)from water.In this work,we design precisely-controlled carbon-doped porous CN rods with extended π-electron conjugation from supramolecular assemblies of melem and co-monomers,which partially substitute nitrogen for carbon atoms at the pyrimidine ring of the melem.Dense hydrogen bonds and good thermal stability of the melem-based supramolecular framework allow synthesizing a more ordered structure for improved charge migration;the control from the molecular level over the position of carbon-substituted nitrogen positions tailors the band alignment and photogenerated charge separation.The optimal photocatalyst shows an excellent HER rate(up to 10.16 mmol·h-1·g-1 under 100 W white light-emitting diode(LED)irradiation,with an apparent quantum efficiency of 20.0%at 405 nm,which is 23.2 times higher compared to a reference bulk CN).To fully harness the benefits of the developed metal-free CNs,selective oxidation reaction of aromatic alcohols is demonstrated with high conversion and selectivity.展开更多
基金National Natural Science Foundation of China (No. 10901034)Chenguang Program of Shanghai Education Development Foundation,China (No. 2008CG40)
文摘A formula was proved for computing the zeroth-order general Randic index of a hexagonal system to explore the correlation between the zeroth-order general Randic index and the π-electronic energy of a hexagonal system.As a consequence,the extremal hexagonal systems with minimum or maximum zeroth-order general Randic index were completely characterized.Moreover,by using the least-square fit method and regression analysis,a new and close relation was found between the zeroth-order general Randic index and the π-electronic energy of a hexagonal system.So the zeroth-order general Randic index is a good measure of the π-electronic energies for benzenoid hydrocarbons.
基金financially supported by the National Natural Science Foundation of China(Nos.51872003 and 51572003)the University Natural Science Research Project of Anhui Province(No.KJ2017A299)+1 种基金the Anhui Provincial Natural Science Foundation(Nos.1908085J21 and 1908085QB83)the Research Start-up Fund of Anhui University(No.S020118002/011)。
文摘Increasing the availability ofπ-electron in graphitic carbon nitride(g-C_(3)N_(4))can reduce the band gap and thus enhance the photocatalytic hydrogen(H_(2))generation activity upon exposure to visible light,However,such strategy has not yet been largely applied to increase the H_(2)generation of g-C_(3)N_(4).Herein,we succes s fully increased the amount ofπ-electron in g-C_(3)N_(4)by incorporatingπ-electron-rich benzene rings through copolymerization of melamine and trimesic acid in air.The incorporation of benzene rings not only extends the light absorption of g-C_(3)N_(4)to 650 nm,but also improves the electrical conductivity due to delocalization ofπelectrons in benzene rings.As a result,a 3.4 times enhancement of photocatalytic H_(2)generation was achieved from the g-C_(3)N_(4)with benzene ring incorporation in comparing with that of pristine g-C_(3)N_(4).More interestingly,H_(2)generation still occurs under irradiation of the light ofλ≥490 nm,above the absorption edge of pristine g-C_(3)N_(4)(~460 nm),illustrating the positive effectiveness of incorporated benzene rings on enhancing the H_(2)generation capacity of g-C_(3)N_(4).The present work manifests the advantages of increasingπ-conjugated electrons on designing highly active g-C_(3)N_(4)photocatalysts.
基金grateful for the financial support from the National Natural Science Foundation of China(Nos.22078028 and 21978026)the Special Program for Introducing Foreign Talents of Changzhou(No.CQ20214032)+1 种基金the joint Israel Science Foundation-National Science Foundation of China(ISF-NSFC)(No.2969/19 and the ISF No.601/21)The authors thank Jonathan Tzadikov,Rotem Geva,Liel Abisdris,Junyi Li,and Ayelet Tashakory(Ben-Gurion University of the Negev)for technical support and Dr.Laurent Chabanne for fruitful discussion.
文摘Photocatalysis using polymeric carbon nitride(CN)materials is a constantly evolving field,where the variation of synthetic procedures allows the constant improvement of activity by tackling the intrinsic limitations of these materials(optical absorbance,specific surface area,charge migration,etc.).Amongst the possible photocatalytic reactions,the most popular application of CNs is the hydrogen evolution reaction(HER)from water.In this work,we design precisely-controlled carbon-doped porous CN rods with extended π-electron conjugation from supramolecular assemblies of melem and co-monomers,which partially substitute nitrogen for carbon atoms at the pyrimidine ring of the melem.Dense hydrogen bonds and good thermal stability of the melem-based supramolecular framework allow synthesizing a more ordered structure for improved charge migration;the control from the molecular level over the position of carbon-substituted nitrogen positions tailors the band alignment and photogenerated charge separation.The optimal photocatalyst shows an excellent HER rate(up to 10.16 mmol·h-1·g-1 under 100 W white light-emitting diode(LED)irradiation,with an apparent quantum efficiency of 20.0%at 405 nm,which is 23.2 times higher compared to a reference bulk CN).To fully harness the benefits of the developed metal-free CNs,selective oxidation reaction of aromatic alcohols is demonstrated with high conversion and selectivity.
基金financially supported by the National Natural Science Foudation of China(Grants No.22103009,22025101,22222103,22173015,21871039,21801037,91961114,and 22071017)financial support by the Fundamental Research Funds for the Central Universities of China(Grants No.PA2021GDSK0063 and PA2020GDJQ0028)。
基金This work is financially supported by the National Natural Science Foundation of China(No.21827804 and No.21773221)the National Key R&D Program of China(No.2017YFA0303502).
