On the basis of an investigation on σ phase in Ni-base cast superalloy K24 and the results about σ phase in other Ni-base superalloys,an embrittl- ing mechanism and a softening mechanism,by which platelike σ phase ...On the basis of an investigation on σ phase in Ni-base cast superalloy K24 and the results about σ phase in other Ni-base superalloys,an embrittl- ing mechanism and a softening mechanism,by which platelike σ phase weakens the Ni-base superalloys,have been proposed.It is considered that the platelike morphology and the habit precipi- tation along{111}of σ phase are necessary condi- tions for both mechanisms.The embrittling mecha- nism is dominant at room temperature and high strain rate,and the softening mechanism is domi- nant at high temperature and low strain rate.Ac- cording to the idea of the softening mechanism and the analyses of σ phase and alloy compositions,it is considered that Nb,Mo and W in the alloys may be resistant to the detrimental effect of σ phase on the stress-rupture properties of the alloys.展开更多
The nose temperature for σ-phase precipitation in super-duplex stainless steel （SDSS） UNS S32750 was evaluated by hardness method.Color-optical microscopy,scanning electron microscopy,energy spectrum analysis,impac...The nose temperature for σ-phase precipitation in super-duplex stainless steel （SDSS） UNS S32750 was evaluated by hardness method.Color-optical microscopy,scanning electron microscopy,energy spectrum analysis,impact and corrosion testing were carried out to investigate characteristics of microstructure and properties of the SDSS aged at the nose temperature.The experimental results indicate that the nose temperature of precipitation is 920℃ and aging at this temperature tiny σ phases can precipitate at phase interfaces or ferrite grain boundaries within 2min.Prolonging aging duration the amount ofσ-phase increases and a dual structure with σ and γ is obtained when aging for 120min.The precipitation ofσ-phase leads to severe deterioration in impact toughness （longitudinal/transverse direction） and corrosion resistance of SDSS.展开更多
The precipitation kinetics of σ phase in commercial HR3C heat-resistant steel during aging at 650–800 °C was studied in the paper. Through morphology, composition and structural analyzing on the second phase in...The precipitation kinetics of σ phase in commercial HR3C heat-resistant steel during aging at 650–800 °C was studied in the paper. Through morphology, composition and structural analyzing on the second phase in the HR3C steel, it was confi rmed that the precipitations after aging were mainly NbCrN, M23C6 and FeCr type σ phase. The time-dependent mass change of the three precipitated phases showed that the linearly increased σ phase after aging at 750 °C–2000 h was transformed from NbCrN phase or M23C6 phase. According to the calculation on the volume fraction of electrolytically dyed σ phase, the time–temperature transformation(TTT) curve for σ phase at 1 vol% in two kinds of commercial HR3C steel(different in grain size) was obtained and analyzed. The nose of the TTT curve was located at around 750 °C for the two kinds of HR3C steel, and the larger grain size HR3C steel displayed a inhibit effect on the precipitation of σ phase. The impact energy of the HR3C steel after aging at 700 °C decreased obviously with the fracture mechanism changing from ductile fracture to intergranular brittle fracture, which was considered to be related to the density of σ-brittle phase after aging.展开更多
Using the calculation of thermodynamic equilibria in multicomponent systems,two ternary phase diagrams,Ni-Cr-Mo and Ni-Cr-Co,have been calculated by optimizing the Gibbs free ener- gies with respect to phase diagrams ...Using the calculation of thermodynamic equilibria in multicomponent systems,two ternary phase diagrams,Ni-Cr-Mo and Ni-Cr-Co,have been calculated by optimizing the Gibbs free ener- gies with respect to phase diagrams and thermodynamic data.On the basis of this calcula- tion,the occurrence of σ-phase in the residual solid solution of commercial Ni-base superalloys, IN-713C and U-700,has been predicted.The re- sults show that the calculation of phase equilibria is successful in the prediction of the occurrence of the σ-phase.展开更多
The Co-Cr-W ternary system was critically assessed using the CALPHAD technique.The solution phases including the liquid,γ-Co,ε-Co and α-Cr were described by a substitutional solution model.The σ,μ and R phases we...The Co-Cr-W ternary system was critically assessed using the CALPHAD technique.The solution phases including the liquid,γ-Co,ε-Co and α-Cr were described by a substitutional solution model.The σ,μ and R phases were described by three-sublattice models of（Co,W）8（Cr,W）4（Co,Cr,W）18,（Co,Cr,W）7W2（Co,Cr,W）4 and（Co,W）27（Cr,W）14（Co,Cr,W）12,respectively,in order to reproduce their homogeneity ranges.A self-consistent set of thermodynamic parameters for each phase was derived.The calculated isothermal sections at 1 000,1 200 and 1 350 ℃ are in good agreement with the experimental data.A eutectoid reaction of R μ＋γ-Co＋σ in this ternary system was predicted to occur at 1 022 ℃.展开更多
文摘On the basis of an investigation on σ phase in Ni-base cast superalloy K24 and the results about σ phase in other Ni-base superalloys,an embrittl- ing mechanism and a softening mechanism,by which platelike σ phase weakens the Ni-base superalloys,have been proposed.It is considered that the platelike morphology and the habit precipi- tation along{111}of σ phase are necessary condi- tions for both mechanisms.The embrittling mecha- nism is dominant at room temperature and high strain rate,and the softening mechanism is domi- nant at high temperature and low strain rate.Ac- cording to the idea of the softening mechanism and the analyses of σ phase and alloy compositions,it is considered that Nb,Mo and W in the alloys may be resistant to the detrimental effect of σ phase on the stress-rupture properties of the alloys.
基金Founded by the Special Project of Shaanxi Education Department(07JK309)Xi'an University of Architecture and Technology (JC0714)
文摘The nose temperature for σ-phase precipitation in super-duplex stainless steel （SDSS） UNS S32750 was evaluated by hardness method.Color-optical microscopy,scanning electron microscopy,energy spectrum analysis,impact and corrosion testing were carried out to investigate characteristics of microstructure and properties of the SDSS aged at the nose temperature.The experimental results indicate that the nose temperature of precipitation is 920℃ and aging at this temperature tiny σ phases can precipitate at phase interfaces or ferrite grain boundaries within 2min.Prolonging aging duration the amount ofσ-phase increases and a dual structure with σ and γ is obtained when aging for 120min.The precipitation ofσ-phase leads to severe deterioration in impact toughness （longitudinal/transverse direction） and corrosion resistance of SDSS.
基金financials support by National Natural Science Foundation of China (No. U1610256)the National High Technology Research and Development Program of China (The 863 Program) (No. 2015AA034402)the Dalian University of Technology Fundamental Research Fund (No. DUT17RC(3)010)
文摘The precipitation kinetics of σ phase in commercial HR3C heat-resistant steel during aging at 650–800 °C was studied in the paper. Through morphology, composition and structural analyzing on the second phase in the HR3C steel, it was confi rmed that the precipitations after aging were mainly NbCrN, M23C6 and FeCr type σ phase. The time-dependent mass change of the three precipitated phases showed that the linearly increased σ phase after aging at 750 °C–2000 h was transformed from NbCrN phase or M23C6 phase. According to the calculation on the volume fraction of electrolytically dyed σ phase, the time–temperature transformation(TTT) curve for σ phase at 1 vol% in two kinds of commercial HR3C steel(different in grain size) was obtained and analyzed. The nose of the TTT curve was located at around 750 °C for the two kinds of HR3C steel, and the larger grain size HR3C steel displayed a inhibit effect on the precipitation of σ phase. The impact energy of the HR3C steel after aging at 700 °C decreased obviously with the fracture mechanism changing from ductile fracture to intergranular brittle fracture, which was considered to be related to the density of σ-brittle phase after aging.
文摘Using the calculation of thermodynamic equilibria in multicomponent systems,two ternary phase diagrams,Ni-Cr-Mo and Ni-Cr-Co,have been calculated by optimizing the Gibbs free ener- gies with respect to phase diagrams and thermodynamic data.On the basis of this calcula- tion,the occurrence of σ-phase in the residual solid solution of commercial Ni-base superalloys, IN-713C and U-700,has been predicted.The re- sults show that the calculation of phase equilibria is successful in the prediction of the occurrence of the σ-phase.
基金Project(50771027)supported by the National Basic Research Program of ChinaProject(50771027)supported by the National Natural Science Foundation of China
文摘The Co-Cr-W ternary system was critically assessed using the CALPHAD technique.The solution phases including the liquid,γ-Co,ε-Co and α-Cr were described by a substitutional solution model.The σ,μ and R phases were described by three-sublattice models of（Co,W）8（Cr,W）4（Co,Cr,W）18,（Co,Cr,W）7W2（Co,Cr,W）4 and（Co,W）27（Cr,W）14（Co,Cr,W）12,respectively,in order to reproduce their homogeneity ranges.A self-consistent set of thermodynamic parameters for each phase was derived.The calculated isothermal sections at 1 000,1 200 and 1 350 ℃ are in good agreement with the experimental data.A eutectoid reaction of R μ＋γ-Co＋σ in this ternary system was predicted to occur at 1 022 ℃.
