EFFECTS OF DEFORMATION ON MICROSTRUCTURE AND σ-PHASE FORMATION IN Cr_(25)Ni_(20) STAINLESS STEEL

The microstructure of Cr_(25)Ni_(20)stainless steel under plastic deformation up to 50% has re- vealed an even distributed twins,micro-twins and deformation bands.The σ-phase formation in 800℃ aged specimens is accelerated by its nucleation at either deformation twins or recrystallized grain boundaries under less or more deformation respectively.In the recrystallized zone,the recrystallization is prior to the precipitation of σ-phase.Although recrystallization may accelerate the formation of σ-phase,it is not essential.The twins and micro-twins produced by deformation may also provide the additional nucleation sites.

σ-Phase Precipitation Mechanism of 15Cr–15Ni Titanium-Modified Austenitic Stainless Steel During Long-Term Thermal Exposure

The σ-phase precipitation in 20% cold-worked 15Cr-15Ni titanium-modified austenitic stainless steel was studied during long-term aging treatment.During the isothermal aging stage,the amount of a-phase was significantly increased at beginning and gradually became constant.The aging time only slightly affected the size and morphology of the σ-phase.Conversely,during the isochronal aging stage,the amount ofσ-phase grew rapidly with the increase in the aging temperature.The σ-phase with a large amount of stacking faults was prone to nucleate around the（Ti,Mo）C particles or at the grain boundaries.The（Ti,Mo）C particles can act as effective nucleation sites,where the σ-phase directly precipitates from the austenitic matrix.From this work,the growth of σ-phase is found to be influenced by the aging temperature,and a new mechanism of σ-phase precipitation from austenite has been proposed.

σ-Phase in Lean Duplex Stainless Steel Sheets

The precipitation kinetics of secondary phases in two austeno-ferritic lean duplex stainless steels（lean DSS）were examined after aging the materials at 800 ℃.Owing to the instability of ferrite,all DSS are known to be sensitive to solid-state phase transformations in the critical temperature range 600-1,000 ℃ and different secondary phases may form,depending on composition and microstructure.The performed thermodynamic simulations revealed the proneness to the precipitation of such phases also have been done in lean DSS,but only information on the equilibrium microstructures were achieved.Therefore,the materials were aged at various times,in order to verify the simulations and determine the precipitation kinetics.The occurred structural modifications were observed and quantified by scanning electron microscope and X-ray diffraction measurements,determining phase type,composition and volumetric fraction.At 800 ℃,grade 2101 was found to be only affected by Cr_2N nitrides precipitation,whereas a significant amount of σ-phase was found to form in LDX 2404 for treatment longer than 1 h,almost totally replacing ferrite after 50 h.Up to now,the intermetallic σ-phase has been observed only in the high alloyed DSS,and the unexpected precipitation in grade 2404 highlighted that the increased content of molybdenum in this steel might be considered as determinant for the formation.

Characterization of a 3-Phase a.c. Free Burning Arc Plasma

A 3-phase a.c. arc plasma reactor with large volume plasma has been developed for the synthesis of new carbon nano-structures. One of the main characteristics of the plasma system is related to the absence of a fixed neutral point. This gives rise to a rich and complex phenomenology related to instabilities and arc motion since the arcs are ＂burning＂ freely in the gas flow between the three electrodes. This paper is dedicated to the analysis of the behavior of such a system under typical conditions using argon and nitrogen as plasma gases. A classification of are configuration, arc commutating, arc interaction, arc motion and arc instabilities are discussed based on ultra high-speed cine camera analysis. A simple model describing the time evolution of the system is also presented and compared with the experimental measurements. The results show that an adequate control could allow the improvement of the overall system.

Coercive Force of γ-Phase in WC-Co Cemented Carbides

The influence of γ-phase composition in WC-Co cemented carbides on its specific coercive force H_(sc) hasbeen studied by analysing the imitative alloys of γ-phase. The results show that the H_(sc) of γ-phase is lower thanthat of pure cobalt, because the solute W can raise γ-phase H_(sc) but the carbon exhibits more intense negativeeffect on H_(sc). The effect is enhanced with raising the C solubilities in γ-phase.

ON THE PRIMARY η-PHASE IN A HIGH-Ti Ni-Fe-Cr BASED SUPERALLOY

The precipitation and dissolution together with their control of the primary η-phase in a high-Ti Ni-Fe-Cr base superalloy have been investigated.The precipitation of primary η-phase was found to be closely related to Ti or Al content and solidification rate of the alloy. The aggregation of blocky η-phase may remarkably reduce the tensile strength,ductility and rupture life of the alloy.The temperature-time relation of dissolution of the primary η-phase obeys T=1370-86.1 lgt for as-cast superalloy.The formation of primary η-phase may be prevented by the reasonable control of Ti or Al content and smelting process.The adoption of treatment under large hot deformation and homogenization may be the remedy for unfavorable influence of η-phase.

A new design of stator magnetic system for 3-phase & 12-pole HB stepper

A new design of stato magnetic System is Proposed for 3-phase & 12-pole HB stepper, and it features bet-ter distribution of magntic lield to incare Pullou tope and bopmve Operaonal stability of moor and minimummutual inductance between phase windimp to make design of control circuit easier, and application proved it is as good as expected.

Numerical Method for Heat and Mass Transfer in Air Washer——3.Two-phase Flow in Eliminator

Numerical simulation method is applied in the study oftwo - phase flow dynamics in the eliminator of air wash-er. The carrier phase (air) is treated in Eulerian frame,the water droplets are tracked in the Lagrangian frame.A three - dimensional unsteady two - phase flow model isdeveloped. With the help of FLUENT software, air-stream velocity field and water droplets trajectories havebeen illustrated when their mixture passing through tra-ditional folded eliminator. The result of the simulationcan be used to investigate the mechanism of

Improvement of β-phase crystal formation in a BaTiO3-modified PVDF membrane

In this paper,low temperature plasma is used to modify the surface of barium titanate（BaTiO3）nanoparticles in order to enhance the interfacial compatibility between ferroelectric poly（vinylidene fluoride）（PVDF） and BaTiO3 nanoparticles.The results demonstrate that oxygenic groups are successfully attached to the BaTiO3 surface,and the quantity of the functional groups increases with the treatment voltage.Furthermore,the effect of modified BaTiO3 nanoparticles on the morphology and crystal structure of the PVDF/BaTiO3 membrane is investigated.The results reveal that the dispersion of BaTiO3 nanoparticles in the PVDF matrix was greatly improved due to the modification of the BaTiO3 nanoparticles by air plasma.It is worth noting that the formation of a β-phase in a PVDF/modified BaTiO3 membrane is observably promoted,which results from the strong interaction between PVDF chains and oxygenic groups fixed on the BaTiO3 surface and the better dispersion of BaTiO3 nanoparticles in the PVDF matrix.Besides,the PVDF/modified BaTiO3 membrane at the treatment voltage of 24 k V exhibits a lower water contact angle（≈68.4°） compared with the unmodified one（≈86.7°）.Meanwhile,the dielectric constant of PVDF/BaTiO3 nanocomposites increases with the increase of working voltage.

EFFECT OF Mg AND δ-PHASE ON MECHANICAL PROPERTIES OF ALLOY GH169(INCONEL718)

Micro-alloying of Mg,ranged from 30 to 70 ppm,may improve the high temperature ductility,stress rupture,especially,certain important mechanical properties,such as cyclic stress rupture,creep/fatigue interaction and crack propagation rate.The quantity, morphology and distribution of δ-phase may obviously influence the notched cyclic stress rup- ture life.The relevant microstructure shows that the Mg may also influence to certain extent on the feature of δ-phase.Thus,to keep the Mg and δ-phase under control may further im- prove the mechanical properties of alloy GH169.

Hyperbranched phthalocyanine enabling black-phase formamidinium perovskite solar cells processing and operating in humidity open air

The extreme instability of pureα-phase FAPbI_(3) under high humidity conditions restricts the highthroughput fabrication in unmodified air environments,resulting in poor performance ofα-phase FAPbI_(3) perovskite devices obtained by scalable fabrication methods.Here we synthesized hyperbranched copper phthalocyanine(HCuPc)as a supramolecular additive with twisted phthalocyanine units to realize the molecular-level encapsulation at the grain boundaries through supramolecular interaction,which greatly broadened the processing window of FAPbI_(3) under high humidity.At the same time,unlike traditional encapsulation layer that carrier can only be collected by tunneling effect,the twisted phthalocyanine ring of HCu Pc in perovskite films is more conducive to hole extraction.Finally,a record efficiency was achieved in pure FAPbI_(3) based inverted structured solar cell by blade-coating to the best of our knowledge,even under unmodified humid air conditions(relative humidity of 65%–85%).The best operational stability of 3D pure FAPbI_(3) devices can also be achieved at the same time and unencapsulated HCuPc-FAPbI_(3) device can even operate with negligible degradation for 100 h in the open air(RH 30%–40%).

THE INITIAL CORROSION MECHANISM OFα-PHASE ALUMINIUM BRONZE IN NaCI SOLUTION

The polarization curves of theα-PHASE aluminium bronze measured in 5%NaCl electrochemically show that the corrosion process of the alloy is controlled by the diffusion of oxygen.The corrosion surface of theα-PHASE A1 bronze in NaCl solution for a short time was analysed by X-ray Photoelectron Spectroscopy(XPS).The results indicate that the initial corrosion product of the A1 bronze consists of a simple Cu20 phase.A1 and Ni are incorporated in Cu20 lattice structure in the form of ions,and none of the aluminium compound can be detected.The authors propose that the initial corrosion mechanism ofα-PHASE A1 bronzes in NaCl solution should include oxidation,reduction and diffusion.

Effect of Injection Position on In-Flight Melting Behavior of Granular Alkali-Free Glass Raw Material in 12-Phase AC Arc Plasma

An innovative in-flight glass melting technology with a multi-phase AC arc plasma was developed to save energy and reduce emissions for the glass industry. The effect of the injection position on the in-flight melting behavior of granulated powders was investigated. Results show that the injection position has a strong effect on the melting behavior of alkali-free glass raw material. With the increase in injection distance, the vitrification, decomposition, and particle shrinkage of initial powders are improved. Longer injection distance causes much energy to transfer to particles due to a longer residence time of powder in the high temperature zone. The high vitrification and decomposition degrees indicate that the new in-flight melting technology with 12-phase AC arc can substantially reduce the melting and refining time for glass production.

Fault diagnosis algorithm for 3-phase passive rectifiers based on frequency-domain analysis for acceleration grid power supply in CFETR NBI system

The acceleration grid power supply(AGPS) is a crucial part of the Negative-ion Neutral Beam Injection system in the China Fusion Engineering Test Reactor,which includes a 3-phase passive(diode) rectifier.To diagnose and localize faults in the rectifier,this paper proposes a frequencydomain analysis-based fault diagnosis algorithm for the rectifier in AGPS.First,time-domain expressions and spectral characteristics of the output voltage of the TPTL-NPC inverter-based power supply are analyzed.Then,frequency-domain analysis-based fault diagnosis and frequency-domain analysis-based sub-fault diagnosis algorithms are proposed to diagnose open circuit(OC) faults of diode(s),which benefit from the analysis of harmonics magnitude and phase-angle of the output voltage.Only a fundamental period is needed to diagnose and localize exact faults,and a strong Variable-duration Fault Detection Method is proposed to identify acceptable ripple from OC faults.Detailed simulations and experimental results demonstrate the effectiveness,quickness,and robustness of the proposed algorithms,and the diagnosis algorithms proposed in this article provide a significant method for the fault diagnosis of other rectifiers and converters.

FORMATION OFδ-PHASE IN AUSTENITIC STEELS

The relationship between the γ/(γ+δ) boundary temperature Tδ of austenitic steels and the equivalent weights of [Crl and [Ni] and the variation rule of the δ phase volume with the temperature are studied With the aid of computer,the regressives expression derived from the experimental results are Tδ(℃) = T4 -21.2[Cr] +15.8[Ni]-223. Vδ(%)=0.715 exp 0.015(T-Tδ).

3-Phase Modeling for the Origin of Chinese Lithium-Rich Brines

There are significantly different origins and mineralizations among various lithium-rich brines of the world.As for Clayton Valley,Nevada,the data and interpretations recently presented suggest that the model

A Device for Measuring 3-Phase Alternating Current at a Distance

We have made a preliminary study on a possibility to build a device, which could measure three-phase alternating current at a distance. This report gives a brief look at the theoretical background related with such a device and derives several mathematical results associated with the theory and the structure of the device. Our results suggest that such a device can be built, assuming the distances between the three current-carrying wires and the two sensors of the device are known accurately enough. There are ways to measure these distances, but this article does not concentrate on them.

ON A UNIVERSAL INEQUALITY FOR APPROXIMATE PHASE ISOMETRIES

Let X and Y be two normed spaces.Let U be a non-principal ultrafilter on N.Let g:X→Y be a standard ε-phase isometry for someε≥ 0,i.e.,g(0)=0,and for all u.v ∈ X,||‖g(u)+g(v)‖±‖g(u)-g(v)‖|-|‖u+v‖±‖u-v‖| |≤ε.The mapping g is said to be a phase isometry provided that ε=0.In this paper,we show the following universal inequality of g:for each u^(*) ∈ w^(*)-exp ‖u^(*)‖B_(x^(*)),there exist a phase function σ_(u^(*)):X→{-1,1} and φ ∈ Y^(*) with ‖φ‖=‖u^(*)‖≡α satisfying that|(u^(*),u)-σ_(u^(*))(u)<φ,g(u)>)|≤5/2εα,for all u ∈ X.In particular,let X be a smooth Banach space.Then we show the following:(1) the universal inequality holds for all u^(*) ∈ X^(*);(2) the constant 5/2 can be reduced to 3/2 provided that Y~*is strictly convex;(3) the existence of such a g implies the existence of a phase isometryΘ:X→Y such that■ provided that Y^(**) has the w^(*)-Kadec-Klee property(for example,Y is both reflexive and locally uniformly convex).

π-phase-shifted two-plus-one method for non-diffuse surface

We propose a method for reconstructing non-diffuse surfaces based on theπ-phase-shifted two-plus-one phase-shifting method.First,we introduce a 2fH+a+2fM+2f_(L)method for unwrapped phase extraction.Subsequently,we introduce a new set ofπ-phase-shifted 2fH+a/2+2fM+2f_(L)fringe patterns with halved background intensity.The saturated pixels will be replaced with the unsaturated pixels in theπ-phase-shifted fringe patterns.Finally,we analyze eight fringe replacement cases and give the corresponding phase calculation,and further give the general formulas.Experiments confirm that the sum of the phase error of the proposed method is 81.4%lower than that of the traditional method,and 61.5%lower than that of the adaptive fringe projection method.

时效温度和时间对一种铁基合金组织和性能的影响

本文研究了GH35A合金在650—750℃,100—10000h时效过程中性能和组织的变化。结果表明,合金室温拉伸强度基本不受时效温度和时间的影响,而室温塑性、韧性及700℃持久寿命在时效至某一时间后开始降低,但下降速度缓慢,直到10000h仍有较高的水平。同时,随时效温度提高,性能降低的开始时间缩短。合金性能的变化主要取决于σ相析出的时间、形态、分布以及σ相的特征。