“Click”运动高升力机制

研究了具有“Click”运动的模型翼在三维流场中的气动特性.采用计算流体力学方法求解三维非定常不可压缩Navier-Stokes方程,对比了简谐和“Click”运动所产生的升力与阻力,研究了升力最大时的前缘涡特性和展向流动.结果表明,在下拍过程的升力最大处,“Click”和简谐运动的前缘涡能够分别维持至翼展的80%和60%处.两种运动都会在翼展方向存在维持展向流动的压力梯度,而“Click”运动具有更显著的展向压力梯度,对展向涡度的能量输运效率更高,因此其前缘涡能够保持更完整的形态.在上拍过程中,两种运动的前缘涡形态差异不明显,“Click”运动快速上拍的运动特点使其能够快速地摆脱尾涡的干扰,从而维持升力.

Click chemistry-based enrichment strategy for tracing cellular fatty acid metabolism by LC-MS/MS

Fatty acids(FAs),which were initially recognized as energy sources and essential building blocks of biomembranes,serve as the precursors of important signaling molecules.Tracing FA metabolism is essential to understanding the biochemical activity and role of FAs in physiological and pathological events.Inspired by the advances in click chemistry for protein enrichment,we herein established a click chemistry-based enrichment(CCBE)strategy for tracing the cellular metabolism of eicosapentaenoic acid(EPA,20:5 n-3)in neural cells.Terminal alkyne-labeled EPA(EPAA)used as a surrogate was incubated with N2a,mouse neuroblastoma cells,and alkyne-labeled metabolites(ALMs)were selectively captured by an azide-modified resin via a Cu(I)-catalyzed azide-alkyne cycloaddition reaction for enrichment.After removing unlabeled metabolites,ALMs containing a triazole moiety were cleaved from solid-phase resins and subjected to liquid chromatography mass spectrometry(LC-MS)analysis.The proposed CCBE strategy is highly selective for capturing and enriching alkyne-labeled metabolites from the complicated matrices.In addition,this method can overcome current detection limits by enhancing MS sensitivity of targets,improving the chromatographic separation of sn-position glycerophospholipid regioisomers,facilitating structural characterization of ALMs by a specific MS/MS fragmentation signature,and providing versatile fluorescence detection of ALMs for cellular distribution.This CCBE strategy might be expanded to trace the metabolism of other FAs,small molecules,or drugs.

MXenes: Versatile 2D materials with tailored surface chemistry and diverse applications

MXenes,the most recent addition to the 2D material family,have attracted significant attention owing to their distinctive characteristics,including high surface area,conductivity,surface characteristics,mechanical strength,etc.This review begins by presenting MXenes,providing insights into their structural characteristics,synthesis methods,and surface functional groups.The review covers a thorough analysis of MXene surface properties,including surface chemistry and termination group impacts.The properties of MXenes are influenced by their synthesis,which can be fluorine-based or fluorinedependent.Fluorine-based synthesis techniques involve etching with fluorine-based reagents,mainly including HF or LiF/HCl,while fluorine-free methods include electrochemical etching,chemical vapor deposition(CVD),alkaline etching,Lewis acid-based etching,etc.These techniques result in the emergence of functional groups such as-F,-O,-OH,-Cl,etc.on the MXenes surface,depending on the synthesis method used.Properties of MXenes,such as electrical conductivity,electronic properties,catalytic activity,magnetic properties,mechanical strength,and chemical and thermal stability,are examined,and the role of functional groups in determining these properties is explored.The review delves into the diverse applications of MXenes,encompassing supercapacitors,battery materials,hydrogen storage,fuel cells,electromagnetic interference(EMI) shielding,pollutant removal,water purification,flexible electronics,sensors,additive manufacturing,catalysis,biomedical and healthcare fields,etc.Finally,this article outlines the challenges and opportunities in the current and future development of MXenes research,addressing various aspects such as synthesis scalability,etching challenges,and multifunctionality,and exploring novel applications.The review concludes with future prospects and conclusions envisioning the impact of MXenes on future technologies and innovation.

Exploration of Ideological and Political Materials for the Course of Inorganic and Analytical Chemistry for Environmental and Ecological Engineering Major

Integrating ideological and political theories teaching into the whole process of classroom teaching construction is a new requirement for implementing the fundamental task of cultivating people by virtue and playing the role of collaborative education.In order to realize the seamless integration of inorganic and analytical chemistry courses and ideological and political education,this paper summarizes the current situation of ideological and political research on inorganic and analytical chemistry courses in three major databases in China(VIP,CNKI and Wanfang),and sorts out the knowledge points,ideological and political elements and educational goals according to the content of the course chapters,to provide a basic guarantee for the ideological and political education construction of the course.

Identified the hydrochemical and the sulfur cycle process in subsidence area of Pingyu mining area using multi-isotopes combined with hydrochemistry methods

Groundwater serves as an important water source for residents in and around mining areas.To achieve scientific planning and efficient utilization of water resources in mining areas,it is essential to figure out the chemical formation process and the ground water sulfur cycle that transpire after the coal mining activities.Based on studies of hydrochemistry and D,^(18)O-H_(2)O,^(34)S-SO_(4)isotopes,this study applied principal component analysis,ion ratio and other methods in its attempts to reveal the hydrogeochemical action and sulfur cycle in the subsidence area of Pingyu mining area.The study discovered that,in the studied area,precipitation provides the major supply of groundwater and the main water chemistry effects are dominated by oxidation dissolution of sulfide minerals as well as the dissolution of carbonate and silicate rocks.The sulfate in groundwater primarily originates from oxidation and dissolution of sulfide minerals in coal-bearing strata and human activities.The mixed sulfate formed by the oxidation of sulfide minerals and by human activities continuously recharges the groundwater,promoting the dissolution of carbonate rock and silicate rock in the process.

基于文化自信的中外合作办学学科基础课“General Chemistry”课程思政建设探索与实践

“General Chemistry”是面向中外合作办学工科专业学生开设的一门学科基础课。为了提升教学质量,课程引入国外经典教材,在教学过程中面临外来文化的冲击和文化自信缺失的风险。因此,必须通过“General Chemistry”课程思政教学提升学生对自身文化的深度认同。本文中,“General Chemistry”课程思政建设坚持文化自信理念,积极挖掘中国思政元素,将中外思政元素合理融入到教学的每一个环节,不断助推课程思政教学内涵式发展,打造课程思政高效课堂,取得了较好的育人成效。

Click Chemistry合成1,2,3-三唑氨基酸衍生物

通过W ong叠氮转化和亲核取代反应,分别合成了叠氮苯丙氨酸、叠氮丙氨酸、苄基叠氮,采用上述叠氮化物与L-炔丙基甘氨酸进行C lick反应,合成了3个1,4-取代1,2,3-三唑氨基酸衍生物:2-氨基-3-[1-(1-羧基-2-苯乙基)-1H-1,2,3-三唑-4-基]丙酸、3,3-′(1H-1,2,3-三唑-1,4-基)双(2-氨基丙酸)和2-氨基-3-(1H-1,2,3-三唑-1-苄基-4-基)丙酸,收率分别是76%、62%和68%,产物结构经核磁共振波谱、质谱、红外光谱进行了表征。1,2,3-三唑氨基酸衍生物含双功能螯合基团,是很有潜力的fac-[188Re(CO)3(H2O)3]+放射性标记配体。

Grafting of Poly（lauryl acrylate） onto Nano-silica by ‘Click Chemistry’

Poly（n-alkyl acrylate） with long side groups,namely,poly（lauryl acrylate）（PLA） was synthesized by reversible addition-fragmentation chain transfer（RAFT） polymerization,and the trithioester terminal groups were converted to thiol by reducing reaction.Grafting of the obtained polymer onto nano-silica modified with 3-（methacryloxy）propyl-trimethoxysilane（SiO2-MPS） was conducted by thiol-ene ‘click chemistry＇.PLA was characterized by proton nuclear magnetic resonance（1H NMR） and gel permeation chromatography（GPC）.Fourier transform infrared（FTIR） spectrometry and thermogravimetric analysis（TGA） were used to demonstrate the grafting reaction,and the grafted hairy nano-silica（SiO2-g-PLA） was viewed under a transmission electron microscope（TEM）.According to TGA,grafting ratio and grafting density of SiO2-g-PLA are 30.27％ and 0.013 chain/nm2,respectively.The static water contact angle of SiO2-g-PLA is （80.10±2.97）°,which ensures its hydrophobicity.Dispersion experiment was carried out to confirm its dispersibility in mixed solvents,indicating its potential application in coatings or composites.

国外化学原理教材介绍——以Zumdahl的Chemistry(10th edition)为例

Zumdahl夫妇和DeCoste合著的Chemistry是一本在国内外广受赞誉的化学原理类教材。本文以此教材为例,介绍了国外化学原理类的教材。Chemistry这本教材内容既有广度同时也具有深度,具有可读性强、适用面广和拓展性强的特点。教材编写紧扣其培养学生化学思维和知识应用能力的基本理念,在内容和形式设计上运用了多种策略培养学生分析解决问题的能力和批判性思维能力。

国外无机化学教材的研究——以Housecroft&Sharpe的Inorganic Chemistry(5th edition)为例

Catherine Housecroft和Alan G.Sharpe合著的Inorganic Chemistry是一本经历了时间检验的经典教材,其内容涵盖了无机化学的基础原理、元素化学、生物无机化学以及这些知识在催化、工业生产和材料等领域的应用。本文希望通过对该教材的介绍及其与国内教材的编写内容和排版等的对照分析,为国内无机化学的教材编写提供一些有价值的参考,同时为从事无机化学教学的教师提供一个选择参考教材的选项。

Click chemistry approach to functionalize two-dimensional macromolecules of graphene oxide nanosheets

A facile "click chemistry" approach to functionalize 2D macromolecules of graphene oxide nanosheets with poly(ethylene glycol) of different molecular weights,polystyrene,palmitic acid and various amino acids was presented.FTIR,TGA,Raman spectroscopy,XPS,XRD,TEM,AFM and SEM were utilized to characterize the products.High degree of functionalization was achieved on the flat surfaces of graphene oxide,affording polymer-grafted 2D brushes and amino acids-immobilized nanosheets,which show improved solubility in organic solvents.The click chemistry strategy reported herein provides a facile and general method for functionalization of graphene oxide with macromolecules and desired biomolecules.

Development of Cardanol-Based Polyol via Click Chemistry and Crosslinking with Melamine Formaldehyde Resin for Coating Applications

The research work presented in this article deals with the synthesis of cardanol-based polyol and its curing with hexabutoxymethyl melamine(HBMM)for application in coatings.Cardanol-based polyol was prepared via thiol-ene click reaction using thioglycerol.Unsaturation present in the long chain of cardanol was successfully utilized to synthesize polyol via thiol-ene coupling.The reaction was carried out between cardanol and thioglycerol in the presence of Irgacure 184(photoinitiator)and 1,8-Diazabicyclo[5.4.0]undec-7-ene(catalyst)under UV light for 12 h at 80°C.After completion of the reaction,one mole of thioglycerol was successfully added across the double bond of a fatty chain of cardanol and confirmed by Fourier transform infrared spectroscopy(FTIR)and proton nuclear magnetic resonance spectroscopy and hydroxyl and iodine values were determined.Furthermore,the polyol thus prepared was cured with commercial HBMM in various proportions,such as 1:0.6,1:0.8 and 1:1,on an equivalent basis.The coatings were then characterized for mechanical,chemical,optical,thermal and anticorrosive properties.It was observed that coatings exhibited excellent performance properties as compared to that of its acrylic counterpart.

基于伪虎鲸click信号的主动声呐探测信号低截获性分析

为解决现代主动声呐易暴露的问题,提出以伪虎鲸click信号作为主动声呐发射信号波形进行探测,以实现声呐的低截获性。首先通过宽带模糊函数分析了伪虎鲸click信号的分辨性能;然后通过仿真对比单双基地声呐探测模型下,伪虎鲸click信号与常规主动声呐信号的截获因子,验证了其低截获性。结果表明,伪虎鲸click信号三维宽带模糊函数呈现理想的“图钉型”,时延分辨力达到7.644×10^(-6) s,频移分辨力达到7.405 Hz,具有良好的分辨性能;伪虎鲸click信号的截获因子在−4.887~−17.6 dB之间,始终小于0 dB,且远低于常规主动声呐信号,具有优异的低截获性能。伪虎鲸click信号作为声呐发射信号可实现有效与低截获性的声呐探测。

Preparation of novel chiral stationary phase based on click chemistry for ligand exchange chromatography

按化学被使用使到修改叠氮化物的硅石胶化上导出的 l 脯氨酸不能调动给新奇 chiral 静止阶段(作为 click-CSP 表示了) 为 ligand 交换层析。发达协议联合运作的简洁，特别温和的条件和高表面装载的好处。enantioselectivity &#x3b1；一些， click-CSP 上的 dl 氨基的酸被发现在从 1.13 ～ 3.46 的范围。一些 dl 氨基的酸和稳定性学习的色析法的分辨率坚定地为准备 chiral 说明按化学的潜力为 ligand 交换的静止阶段层析。

SYNTHESIS OF A HYPERBRANCHED POLY(AROYLARYLENE) CONTAINING TRIAZOLE AND FLUORENE FUNCTIONALITIES BY CLICK CHEMISTRY AND METAL-FREE,REGIOSELECTIVE POLYCYCLOTRIMERIZATION

A new bis(aroylacetylene) containing tfiazole and fluorene moieties is synthesized by click chemistry. Polycyclotrimerization of the monomer is catalyzed by piperidine in refluxed dioxane,furnishing a regioregular poly(aroylarylene) in a satisfactory yield.The hyperbranched structure of the polymer is characterized spectroscopically with satisfactory results.The polymer enjoys no metal detriment and is soluble in common organic solvents such as tetrahydrofuran (THF),chloroform,dichloromethane (DCM),and N,N-...

Cardanol-Based Polyurethane Coatings via Click Chemistry:An Eco-friendly Approach

This research work discloses the preparation of polyurethane coatings from cardanol modified using thiolene chemistry,wherein unsaturated long alkyl chain of cardanol was successfully utilized via thiol-ene click reaction to synthesize polyol.For this purpose,cardanol and thioglycerol was reacted in the presence of Irgacure 184(photoinitiator)and 1,8-Diazabicyclo[5.4.0]undec-7-ene(catalyst)and exposed to UV light for 12 h at 80℃.One mole of thioglycerol was successfully added across the double bond of fatty chain of cardanol and confirmed by chemical and spectroscopic analysis.Further,the polyol thus prepared was cured with various polyisocyanates,viz.,N-75(HDI based),L-67/BA(TDI based),Z-4470(IPDI based)and corresponding polyurethane coatings were developed.The coatings were then analyzed for mechanical,chemical,optical,thermal and anticorrosive properties.It was observed that cardanol-based PU coatings exhibited excellent mechanical,chemical and thermal and anticorrosive properties as compared to that of commercial acrylic-PU coatings.

基于SCIE的有关“Click chemistry”研究论文分析

依据Web of Science平台下的SCIE数据库中2001-2014年间有关"Click chemistry"的论文数据和文献计量方法,从发表年份、国家、机构、期刊和研究方向等进行聚类分析,研究"Click chemistry"自首次提出后的研究发展情况。结果表明,美国发表相关论文的数量和质量均位居世界第一。中国的发文量排名第二,但是论文质量和世界先进水平仍有一定差距。

Intrinsic Self-Healing Chemistry for Next-Generation Flexible Energy Storage Devices

The booming wearable/portable electronic devices industry has stimulated the progress of supporting flexible energy storage devices.Excellent performance of flexible devices not only requires the component units of each device to maintain the original performance under external forces,but also demands the overall device to be flexible in response to external fields.However,flexible energy storage devices inevitably occur mechanical damages(extrusion,impact,vibration)/electrical damages(overcharge,over-discharge,external short circuit)during longterm complex deformation conditions,causing serious performance degradation and safety risks.Inspired by the healing phenomenon of nature,endowing energy storage devices with self-healing capability has become a promising strategy to effectively improve the durability and functionality of devices.Herein,this review systematically summarizes the latest progress in intrinsic self-healing chemistry for energy storage devices.Firstly,the main intrinsic self-healing mechanism is introduced.Then,the research situation of electrodes,electrolytes,artificial interface layers and integrated devices based on intrinsic self-healing and advanced characterization technology is reviewed.Finally,the current challenges and perspective are provided.We believe this critical review will contribute to the development of intrinsic self-healing chemistry in the flexible energy storage field.

Integrated interface configuration by in-situ interface chemistry enabling uniform lithium deposition in all-solid-state lithium metal batteries

All-solid-state lithium metal batteries(ASSLMBs)are considered as one of the ultimate goals for the development of energy storage systems due to their high energy density and high safety.However,the mismatching of interface transport kinetics as well as interfacial instability induces the growth of lithium dendrite and thus,leads to severe degradation of battery electrochemical performances.Herein,an integrated interface configuration(IIC)consisting of in-situ generated Li I interphase and Li-Ag alloy anode is proposed through in-situ interface chemistry.The IIC is capable of not only regulating charge transport kinetics but also synchronously stabilizing the lithium/electrolyte interface,thereby achieving uniform lithium platting.Therefore,Li||Li symmetric cells with IIC achieve a critical current density of up to 1.6 mA cm^(-2)and achieve stable cycling over 1600 hours at a high current density of 0.5 mA cm^(-2).Moreover,a high discharge capacity of 140.1 mA h g-1at 0.1 C is also obtained for the Li(Ni_(0.6)Co_(0.2)Mn_(0.2))O_(2)(NCM622)full battery with a capacity retention of 65.6%after 300 cycles.This work provides an effective method to synergistically regulate the interface transport kinetics and inhibit lithium dendrite growth for high-performance ASSLMBs.