Ternary Ag/AgC l/BiO IO3 composite photocatalysts are prepared by a facile method. Enhanced visible-light absorption and charge carrier separation are achieved after the introduction of Ag/AgC l particles into BiO IO3...Ternary Ag/AgC l/BiO IO3 composite photocatalysts are prepared by a facile method. Enhanced visible-light absorption and charge carrier separation are achieved after the introduction of Ag/AgC l particles into BiO IO3 systems,as revealed by ultraviolet-visible diffuse-reflectance spectrometry,photocurrent response and electrochemical impedance spectroscopy. The Ag/AgC l/BiO IO3 composites are applied to the visible-light photocatalytic oxidization of NO in air and exhibit an enhanced activity for NO removal in comparison with Ag/AgC l and pure BiO IO3. A possible photocatalytic mechanism for Ag/AgC l/BiO IO3 is proposed,which is related to the surface plasmon resonance effects of Ag metal and the effective carrier separation ability of BiO IO3. This work provides insight into the design and preparation of BiO IO3-based materials with enhanced visible-light photocatalysis ability.展开更多
Proposed new cubic equation of state is more accurate than others in result and simple in form. The equation has been tried with 23 pure compounds including both polar and non-polar compounds. Experimental values of t...Proposed new cubic equation of state is more accurate than others in result and simple in form. The equation has been tried with 23 pure compounds including both polar and non-polar compounds. Experimental values of these compounds collected from various journals were compared with proposed model and found to be more accurate than other widely used cubic equations of state like SRK and Peng Robinson. The form of current EOS best suits to PVT data and total error is almost halved for a set of experimental data in the most cases.展开更多
基金supported by the National Natural Science Foundation of China(5147807051108487)the Science and Technology Project from Chongqing Education Commission(KJ1400617)~~
文摘Ternary Ag/AgC l/BiO IO3 composite photocatalysts are prepared by a facile method. Enhanced visible-light absorption and charge carrier separation are achieved after the introduction of Ag/AgC l particles into BiO IO3 systems,as revealed by ultraviolet-visible diffuse-reflectance spectrometry,photocurrent response and electrochemical impedance spectroscopy. The Ag/AgC l/BiO IO3 composites are applied to the visible-light photocatalytic oxidization of NO in air and exhibit an enhanced activity for NO removal in comparison with Ag/AgC l and pure BiO IO3. A possible photocatalytic mechanism for Ag/AgC l/BiO IO3 is proposed,which is related to the surface plasmon resonance effects of Ag metal and the effective carrier separation ability of BiO IO3. This work provides insight into the design and preparation of BiO IO3-based materials with enhanced visible-light photocatalysis ability.
文摘Proposed new cubic equation of state is more accurate than others in result and simple in form. The equation has been tried with 23 pure compounds including both polar and non-polar compounds. Experimental values of these compounds collected from various journals were compared with proposed model and found to be more accurate than other widely used cubic equations of state like SRK and Peng Robinson. The form of current EOS best suits to PVT data and total error is almost halved for a set of experimental data in the most cases.
