The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral co...The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral correction technique （MSASC）. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu（Ⅱ） or Ni（Ⅱ）and AABB. The binding ratio of AABB to CTAB was 1：2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB：Cu and AABB：Ni were 1：1 and 1：2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.展开更多
Hexagonal and triangular monodisperse Fe3O4 nanosheets have been synthesized via a two-step microemulsion solvothermal approach in which uniform Fe3O4 nanoparticles are first prepared and then these hydrophobic nanocr...Hexagonal and triangular monodisperse Fe3O4 nanosheets have been synthesized via a two-step microemulsion solvothermal approach in which uniform Fe3O4 nanoparticles are first prepared and then these hydrophobic nanocrystals are dispersed in a uniform microemulsion environment as ＂seeds＂ for further re-growth through a secondary solvothermal process. The growth of anisotropic morphologies has been explained by the presence and orientation of twin planes in the face-centered cubic Fe3O4 which direct the shape of the growing particles. In particular, reentrant grooves resulting from twin planes are favorable sites for the addition of adatoms, leading to anisotropic growth. Triangular nanosheets are believed to contain one twin face which directs the growth of the primary particles in two dimensions. Hexagonal nanosheets are believed to contain two parallel planes that allow the growth edges to regenerate one another. The growth mechanism is evidenced by the analysis of high-resolution transmission electron microscopy （HRTEM） results and the as-prepared Fe3O4 nanoparticles have been shown to be an effective catalyst in the synthesis of quinoxaline.展开更多
Based on the layer-by-layer self-assembly of positively charged cetyltrimethylammonium bromide （CTAB） wrapped gold na- norods （AuNRs） and negatively charged superoxide dismutase （SOD） from their aqueous solution...Based on the layer-by-layer self-assembly of positively charged cetyltrimethylammonium bromide （CTAB） wrapped gold na- norods （AuNRs） and negatively charged superoxide dismutase （SOD） from their aqueous solutions on cysteine modified gold electrode （Cys/Au）, a third generation electrochemical biosensor （（SOD/AuNRs）2/Cys/Au） for superoxide anion （02＂-） was developed. The two layers assembly of SOD/AuNRs can significantly enhance the direct electron transfer between SOD and the electrode. The functional enzymatic activities of the SOD offer an electrochemical approach to the determination of 02＂-. In the reductive regions, the proposed sensor exhibits excellent analytical performances, such as wide linear range （200 nM to 0.2 mM O2-）, low detection limit （100 nM O2-）, high sensitivity （22.11 nA cm-2 μM-1）, short response time （less than 5 s）, good stability and reproducibility, while no obvious interferences are caused by commonly met interfering species including hydrogen peroxide （H202）, uric acid （UA） and ascorbic acid （AA）.展开更多
文摘The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral correction technique （MSASC）. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu（Ⅱ） or Ni（Ⅱ）and AABB. The binding ratio of AABB to CTAB was 1：2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB：Cu and AABB：Ni were 1：1 and 1：2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.
基金This work was supported by the National Natural Science Foundation ol： China （Nos. 20901069, 50873093, and 21271156） and the Henan Province Scientific and Technological Research Program （No. 092102210054）.
文摘Hexagonal and triangular monodisperse Fe3O4 nanosheets have been synthesized via a two-step microemulsion solvothermal approach in which uniform Fe3O4 nanoparticles are first prepared and then these hydrophobic nanocrystals are dispersed in a uniform microemulsion environment as ＂seeds＂ for further re-growth through a secondary solvothermal process. The growth of anisotropic morphologies has been explained by the presence and orientation of twin planes in the face-centered cubic Fe3O4 which direct the shape of the growing particles. In particular, reentrant grooves resulting from twin planes are favorable sites for the addition of adatoms, leading to anisotropic growth. Triangular nanosheets are believed to contain one twin face which directs the growth of the primary particles in two dimensions. Hexagonal nanosheets are believed to contain two parallel planes that allow the growth edges to regenerate one another. The growth mechanism is evidenced by the analysis of high-resolution transmission electron microscopy （HRTEM） results and the as-prepared Fe3O4 nanoparticles have been shown to be an effective catalyst in the synthesis of quinoxaline.
基金supported by the National Natural Science Foundation of China (20805013, 20905024&21075031)the National Basic Research Program of China (2009CB421601 & 2011CB911002)the Natural Science Foundation of Hunan Province (09JJ4006 & 09JJ4007)
文摘Based on the layer-by-layer self-assembly of positively charged cetyltrimethylammonium bromide （CTAB） wrapped gold na- norods （AuNRs） and negatively charged superoxide dismutase （SOD） from their aqueous solutions on cysteine modified gold electrode （Cys/Au）, a third generation electrochemical biosensor （（SOD/AuNRs）2/Cys/Au） for superoxide anion （02＂-） was developed. The two layers assembly of SOD/AuNRs can significantly enhance the direct electron transfer between SOD and the electrode. The functional enzymatic activities of the SOD offer an electrochemical approach to the determination of 02＂-. In the reductive regions, the proposed sensor exhibits excellent analytical performances, such as wide linear range （200 nM to 0.2 mM O2-）, low detection limit （100 nM O2-）, high sensitivity （22.11 nA cm-2 μM-1）, short response time （less than 5 s）, good stability and reproducibility, while no obvious interferences are caused by commonly met interfering species including hydrogen peroxide （H202）, uric acid （UA） and ascorbic acid （AA）.
