The effects of a novel three-step aging process （T76＋T6） on the electrochemical corrosion behavior of 7150 extruded aluminum alloy were evaluated and compared with those of the conventional retrogression and re-agi...The effects of a novel three-step aging process （T76＋T6） on the electrochemical corrosion behavior of 7150 extruded aluminum alloy were evaluated and compared with those of the conventional retrogression and re-aging process （T77）. The open circuit potential （OCP）, cyclic polarization and electrochemical impedance spectra （EIS） of the A1 alloys were measured after treatment in three solutions （3.5% NaCl （mass fraction）; 10 mmol/L NaCl ＋ 0.1 mol/L Na2SO4; 4 mol/L NaCl ＋ 0.5 mol/L KNO3 ＋ 0.1 mol/L HNO3）. The parameters including the corrosion potential, pitting potential, pit transition potential and steepness, and potential differences were extensively discussed to evaluate the corrosion behavior of the Al alloys. The electrochemical and scanning electron microscopy （SEM） data show that compared with the 7150-T77 Al alloy, the T76 ＋ T6 aged 7150 A1 alloy exhibits better resistance to pitting corrosion, inter-granular corrosion （IGC） and exfoliation corrosion, which is attributed to further coarsening and inter-spacing of the grain boundary particles （GBPs） as revealed by transmission electron microscopy. Furthermore, the hardness tests indicate that an attractive combination of strength and corrosion resistance was obtained for the 7150 Al alloy with T76 ＋ T6 treatment.展开更多
Recombinant Escherichia coli BL21 is used to produce human-like collagen. The key constituents of media are optimized using response surface methodology (RSM). Before thermal induction, the highest biomass production ...Recombinant Escherichia coli BL21 is used to produce human-like collagen. The key constituents of media are optimized using response surface methodology (RSM). Before thermal induction, the highest biomass production and the lowest production of some hazardous by-products, especially acetic acid, were obtained in the media containing 0.085 mol·L-1 glucose and 0.019 mol·L-1 nitrogen (carbon-nitrogen ratio, 4.47:1). After thermal induction, when the concentrations of glucose and nitrogen in the media were 0.065 mol·L-1 and 0.017 mol·L-1 , respectively (carbon-nitrogen ratio, 3.82:1), the productivity of human-like collagen per cell was the highest while that of acetic acid was the lowest. The extended analysis showed that the production of lactic acid and propionic acid increased while that of some intermediate acids of the tricarboxylic acid cycle decreased if the dose of glucose increased.展开更多
The circulations off the Changjiang mouth in May and November were simulated by a three dimension numerical model with monthly averaged parameters of dynamic factors in this paper. The area covers the East China Sea (...The circulations off the Changjiang mouth in May and November were simulated by a three dimension numerical model with monthly averaged parameters of dynamic factors in this paper. The area covers the East China Sea (ECS), Yellow Sea and Bohai Sea. Simulated results show that the circulation off the Changjiang mouth in spring and autumn is mainly the Changjiang runoff and Taiwan Warm Current (TWC). The Changjiang discharge is much larger in May than in November, and the wind is westward in May, and southward in November off the Changjiang mouth. The runoff in May branches in three parts, one eastward flows, the other two flow northward and southward along the Subei and Zhejiang coast respectively. The Changjiang diluted water expands eastward off the mouth, and forms a strong salinity front near the mouth. Surface circulation in autumn is similar to that in winter, the runoff southward flows along the coast, and the northward flowing TWC becomes weaker compared to that in spring and summer. The bottom circulations in May and November are mainly the runoffnear the mouth and the TWC offthe mouth, and the runoff and TWC are greater in May than in November.展开更多
The liquid flow on a single-pass sieve distillation tray is simulated with a three-dimensional computational fluid dynamics (CFD) program with the K-ε turbulence model. In the model, a source term SMi is formulatedin...The liquid flow on a single-pass sieve distillation tray is simulated with a three-dimensional computational fluid dynamics (CFD) program with the K-ε turbulence model. In the model, a source term SMi is formulatedin the Navier-Stokes equations to represent the interfacial momentum transfer and another term Sc is added to themass transfer equation as the source of interfacial mass transfer. The simulation provides the detailed informationof the three-dimensional distribution of liquid velocity on the tray, the circulation area and the concentration profilealong the height of liquid layer.展开更多
基金Projects(51134007,51201186)supported by the National Natural Science Foundation of ChinaProject(51327902)supported by the Major Research Equipment Development,China+1 种基金Projects(2012CB619502,2010CB731701)supported by the National Basic Research Program of ChinaProject(12JJ6040)supported by the Natural Science Foundation of Hunan Province,China
文摘The effects of a novel three-step aging process （T76＋T6） on the electrochemical corrosion behavior of 7150 extruded aluminum alloy were evaluated and compared with those of the conventional retrogression and re-aging process （T77）. The open circuit potential （OCP）, cyclic polarization and electrochemical impedance spectra （EIS） of the A1 alloys were measured after treatment in three solutions （3.5% NaCl （mass fraction）; 10 mmol/L NaCl ＋ 0.1 mol/L Na2SO4; 4 mol/L NaCl ＋ 0.5 mol/L KNO3 ＋ 0.1 mol/L HNO3）. The parameters including the corrosion potential, pitting potential, pit transition potential and steepness, and potential differences were extensively discussed to evaluate the corrosion behavior of the Al alloys. The electrochemical and scanning electron microscopy （SEM） data show that compared with the 7150-T77 Al alloy, the T76 ＋ T6 aged 7150 A1 alloy exhibits better resistance to pitting corrosion, inter-granular corrosion （IGC） and exfoliation corrosion, which is attributed to further coarsening and inter-spacing of the grain boundary particles （GBPs） as revealed by transmission electron microscopy. Furthermore, the hardness tests indicate that an attractive combination of strength and corrosion resistance was obtained for the 7150 Al alloy with T76 ＋ T6 treatment.
基金Supported by the National High Technology Research and Development Program of China （2006AA02Z246 2007AA03Z456） the National Natural Science Foundation of China （20776119 21076169）+4 种基金 Xi’an Research and Development Program（CX0735） the Scientific Research Program of Shaanxi Provincial Department of Education China （07JK417 07JC16 JG08181） the Natural Science Foundation of Shaanxi Province （2010JQ2012） the Specialized Research Fund for the Doctoral Program of Higher Education of China （20096101120023 20096101110014） Shaanxi Key Subject Program China
文摘Recombinant Escherichia coli BL21 is used to produce human-like collagen. The key constituents of media are optimized using response surface methodology (RSM). Before thermal induction, the highest biomass production and the lowest production of some hazardous by-products, especially acetic acid, were obtained in the media containing 0.085 mol·L-1 glucose and 0.019 mol·L-1 nitrogen (carbon-nitrogen ratio, 4.47:1). After thermal induction, when the concentrations of glucose and nitrogen in the media were 0.065 mol·L-1 and 0.017 mol·L-1 , respectively (carbon-nitrogen ratio, 3.82:1), the productivity of human-like collagen per cell was the highest while that of acetic acid was the lowest. The extended analysis showed that the production of lactic acid and propionic acid increased while that of some intermediate acids of the tricarboxylic acid cycle decreased if the dose of glucose increased.
文摘The circulations off the Changjiang mouth in May and November were simulated by a three dimension numerical model with monthly averaged parameters of dynamic factors in this paper. The area covers the East China Sea (ECS), Yellow Sea and Bohai Sea. Simulated results show that the circulation off the Changjiang mouth in spring and autumn is mainly the Changjiang runoff and Taiwan Warm Current (TWC). The Changjiang discharge is much larger in May than in November, and the wind is westward in May, and southward in November off the Changjiang mouth. The runoff in May branches in three parts, one eastward flows, the other two flow northward and southward along the Subei and Zhejiang coast respectively. The Changjiang diluted water expands eastward off the mouth, and forms a strong salinity front near the mouth. Surface circulation in autumn is similar to that in winter, the runoff southward flows along the coast, and the northward flowing TWC becomes weaker compared to that in spring and summer. The bottom circulations in May and November are mainly the runoffnear the mouth and the TWC offthe mouth, and the runoff and TWC are greater in May than in November.
基金Supported by Visiting Scholar Foundation of Key Lab in Tianjin University.
文摘The liquid flow on a single-pass sieve distillation tray is simulated with a three-dimensional computational fluid dynamics (CFD) program with the K-ε turbulence model. In the model, a source term SMi is formulatedin the Navier-Stokes equations to represent the interfacial momentum transfer and another term Sc is added to themass transfer equation as the source of interfacial mass transfer. The simulation provides the detailed informationof the three-dimensional distribution of liquid velocity on the tray, the circulation area and the concentration profilealong the height of liquid layer.
