V2O3 nanoparticles with high surface area have been successfully prepared by a new solvothermal method without using any surfactant and template. The size of V2O3 nanoparticles is mostly equal to 10 nm-30 nm. The high...V2O3 nanoparticles with high surface area have been successfully prepared by a new solvothermal method without using any surfactant and template. The size of V2O3 nanoparticles is mostly equal to 10 nm-30 nm. The highest surface area of obtained V2O3 nanoparticles reaches 49 m2/g. Several kinds of V2O3 catalysts were prepared by different methods. All these V2O3 catalysts obtained thereby showed high catalytic activity for oxidative desulfurization(ODS) reaction by using tert-butyl hydroperoxide as the oxidant. The V2O3 catalyst with a highest ODS activity was obtained under the following conditions: The catalyst was prepared upon using V2O5 as the vanadium source, methanol as the solvent, and oxalic acid as the complexing reagent at a V2O5/oxalic acid molar ratio of 1:2. The process for ODS of dibenzothiophene was carried out under mild conditions(under atmospheric pressure and at a relatively low temperature). The highest ODS activity of the obtained V2O3 nanoparticles can be attributed to their highest surface area.展开更多
基金supported by the National Nature Science Foundation of China (21303088)
文摘V2O3 nanoparticles with high surface area have been successfully prepared by a new solvothermal method without using any surfactant and template. The size of V2O3 nanoparticles is mostly equal to 10 nm-30 nm. The highest surface area of obtained V2O3 nanoparticles reaches 49 m2/g. Several kinds of V2O3 catalysts were prepared by different methods. All these V2O3 catalysts obtained thereby showed high catalytic activity for oxidative desulfurization(ODS) reaction by using tert-butyl hydroperoxide as the oxidant. The V2O3 catalyst with a highest ODS activity was obtained under the following conditions: The catalyst was prepared upon using V2O5 as the vanadium source, methanol as the solvent, and oxalic acid as the complexing reagent at a V2O5/oxalic acid molar ratio of 1:2. The process for ODS of dibenzothiophene was carried out under mild conditions(under atmospheric pressure and at a relatively low temperature). The highest ODS activity of the obtained V2O3 nanoparticles can be attributed to their highest surface area.
