The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most ...The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most probable thermal decomposition mechanism is the three-dimensional diffusion model of Jander equation,and the mechanism code is D3.The activation energy and pre-exponential factor for thermal decomposition of high iron gibbsite ore calculated by the Popescu method are 75.36 kJ/mol and 1.51×10-5 s-（-1）,respectively.The correctness of the obtained mechanism function is validated by the activation energy acquired by the iso-conversional method.Popescu method is a rational and reliable method for the analysis of the thermal decomposition mechanism of high iron gibbsite ore.展开更多
Given the conflicts over the proposed formation mechanisms of Xiashu loess, the question of the provenance of sediments comprising the Xiashu loess in the Yangtze River Delta has not been satisfactorily resolved. In t...Given the conflicts over the proposed formation mechanisms of Xiashu loess, the question of the provenance of sediments comprising the Xiashu loess in the Yangtze River Delta has not been satisfactorily resolved. In this study, the provenance of aeolian sediments of the Yangtze River Delta, China was examined by applying the detrial zircon U–Pb dating technique, Sr–Nd isotopic and trace element compositional analysis. U-Pb dating analysis was conducted on the Xiashu loess at three locations over the Yangtze River Delta, including Huangnishan(HNS) hill, Shengshan(SS) island and the Xuancheng(XC) area. The Xiashu loess and the sediments of the Yangtze River Valley share considerable similarity in their zircon U-Pb age spectra with the same main age peak and comparable age distribution. By contrast, significant differences in the age spectra, existbetween the Xiashu loess and loess deposits of Chinese Loess Plateau(CLP). Coarse grains of the Yangtze River Delta loess may have a proximal material source identical to the sediments from the Yangtze River valley. Sr–Nd isotopic values of the Xiashu loess match those from the northern margin of the Tibetan Plateau. Rare earth element ratios independent of grain size illustrate that the values from loess of the Yangtze River Delta mostly overlap with those of CLP loess. This feature implies that loess from the Yangtze River Delta has a dominant source of distant material similar as the CLP loess. As such, we conclude that multi-proxy analysis of sediments can shed new light on tracing the provenance of aeolian loess in the Yangtze River Delta.展开更多
The construction of Three Gorges Project (TGP) is characterized by large construction scale,high construction intensity and complexity in technology.In view of various technical difficulties such as navigation in cons...The construction of Three Gorges Project (TGP) is characterized by large construction scale,high construction intensity and complexity in technology.In view of various technical difficulties such as navigation in construction period,two river closures,high-intensity concrete and earth-rock construction,high-intensity construction and demolition of RCC (roller compacted concrete) cofferdam in stage III and immediate navigation of double-line five-step shiplock after impoundment of reservoir,the scheme of river diversion during construction is adopted,namely "diversion in 3 stages,open channel navigation and cofferdam power generation".The practice and innovation achievements in river diversion during construction as well as earth-rock and concrete construction are presented emphatically.展开更多
Consolidated-isotropically undrained triaxial compression （CIUC） tests were performed on the reconstituted deep clay from a mine in East China. It was consolidated to maximum stresses in the range of 0.3-2.6 MPa. Th...Consolidated-isotropically undrained triaxial compression （CIUC） tests were performed on the reconstituted deep clay from a mine in East China. It was consolidated to maximum stresses in the range of 0.3-2.6 MPa. The test results show that the stress-strain-strength properties of the clay during undrained shear are significantly stress-dependent. In particular, in the case of high consolidation pressure, the post-peak drop in strength on stress-strain curves and shear plane in soil specimens are more evident, the peak stress ratio and the axial strain at which this ratio was reached are smaller, and the relationship between pore pressure and axial strain is also significantly different from that for the case of low consolidation pressure. The environmental scanning electron microscope observations and micro analysis lead to an understanding of the physical mechanisms underlying the above stress-dependent mechanical behavior. In addition, the CIUC behaviors of the studied clay are discussed in the context of critical state soil mechanics.展开更多
基金Project(51374058)supported by the National Natural Science Foundation of China
文摘The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most probable thermal decomposition mechanism is the three-dimensional diffusion model of Jander equation,and the mechanism code is D3.The activation energy and pre-exponential factor for thermal decomposition of high iron gibbsite ore calculated by the Popescu method are 75.36 kJ/mol and 1.51×10-5 s-（-1）,respectively.The correctness of the obtained mechanism function is validated by the activation energy acquired by the iso-conversional method.Popescu method is a rational and reliable method for the analysis of the thermal decomposition mechanism of high iron gibbsite ore.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41371032, 41671003, 41601189, 41672349)
文摘Given the conflicts over the proposed formation mechanisms of Xiashu loess, the question of the provenance of sediments comprising the Xiashu loess in the Yangtze River Delta has not been satisfactorily resolved. In this study, the provenance of aeolian sediments of the Yangtze River Delta, China was examined by applying the detrial zircon U–Pb dating technique, Sr–Nd isotopic and trace element compositional analysis. U-Pb dating analysis was conducted on the Xiashu loess at three locations over the Yangtze River Delta, including Huangnishan(HNS) hill, Shengshan(SS) island and the Xuancheng(XC) area. The Xiashu loess and the sediments of the Yangtze River Valley share considerable similarity in their zircon U-Pb age spectra with the same main age peak and comparable age distribution. By contrast, significant differences in the age spectra, existbetween the Xiashu loess and loess deposits of Chinese Loess Plateau(CLP). Coarse grains of the Yangtze River Delta loess may have a proximal material source identical to the sediments from the Yangtze River valley. Sr–Nd isotopic values of the Xiashu loess match those from the northern margin of the Tibetan Plateau. Rare earth element ratios independent of grain size illustrate that the values from loess of the Yangtze River Delta mostly overlap with those of CLP loess. This feature implies that loess from the Yangtze River Delta has a dominant source of distant material similar as the CLP loess. As such, we conclude that multi-proxy analysis of sediments can shed new light on tracing the provenance of aeolian loess in the Yangtze River Delta.
文摘The construction of Three Gorges Project (TGP) is characterized by large construction scale,high construction intensity and complexity in technology.In view of various technical difficulties such as navigation in construction period,two river closures,high-intensity concrete and earth-rock construction,high-intensity construction and demolition of RCC (roller compacted concrete) cofferdam in stage III and immediate navigation of double-line five-step shiplock after impoundment of reservoir,the scheme of river diversion during construction is adopted,namely "diversion in 3 stages,open channel navigation and cofferdam power generation".The practice and innovation achievements in river diversion during construction as well as earth-rock and concrete construction are presented emphatically.
基金the National Natural Science Foundation of China，the Ministry of Science and Technology of China
文摘Consolidated-isotropically undrained triaxial compression （CIUC） tests were performed on the reconstituted deep clay from a mine in East China. It was consolidated to maximum stresses in the range of 0.3-2.6 MPa. The test results show that the stress-strain-strength properties of the clay during undrained shear are significantly stress-dependent. In particular, in the case of high consolidation pressure, the post-peak drop in strength on stress-strain curves and shear plane in soil specimens are more evident, the peak stress ratio and the axial strain at which this ratio was reached are smaller, and the relationship between pore pressure and axial strain is also significantly different from that for the case of low consolidation pressure. The environmental scanning electron microscope observations and micro analysis lead to an understanding of the physical mechanisms underlying the above stress-dependent mechanical behavior. In addition, the CIUC behaviors of the studied clay are discussed in the context of critical state soil mechanics.
