Noble metal/titania hollow nanomaterials usually exhibit excellent photocatalytic activity because of their high specific surface area,low density,good surface permeability,strong light-harvesting capacity,and rapid i...Noble metal/titania hollow nanomaterials usually exhibit excellent photocatalytic activity because of their high specific surface area,low density,good surface permeability,strong light-harvesting capacity,and rapid interfacial charge transfer. However,the present preparation methods usually include complicated and multistep procedures,which can cause damage to the hollow nanostructures. In this paper,a facile template-induced synthesis,based on a template-directed deposition and in situ template-sacrificial dissolution,was employed to prepare Ag-modified TiO 2(Ag/TiO 2) hollow octahedra using Ag2 O octahedra as templates and TiF 4 as the precursor. In the synthetic strategy,the shells of TiO 2 hollow octahedra were formed by coating TiO 2 nanoparticles on the surface of Ag2 O templates based on the template-directed deposition. Simultaneously,the Ag2 O templates can be in situ removed by dissolving the Ag2 O octahedral template in HF solution produced via the hydrolysis reaction of TiF 4 in the reaction system. In addition,Ag nanoparticles were deposited on the inside and outside surfaces of TiO 2 shells by effectively using the photosensitive properties of Ag2 O and Ag+ ions under light irradiation,along with the formation of TiO 2 hollow octahedra. The Ag/TiO 2 hollow octahedra exhibited high photocatalytic activity because of their(1) short diffusion distances between photogenerated electrons and holes because of the thin shells of Ag/TiO 2 hollow octahedral,(2) deposition of Ag nanoparticles on the inside and outside surfaces of TiO 2 shells,and(3) rapid interfacial charge transfer between TiO 2 shells and Ag nanoparticles. This work may also provide new insights into preparing other Ag-modified and hollow nanostructured photocatalysts.展开更多
The pollen grain morphology and leaf epiderm shape and microstructural of Rye( Secale cereal ), common wheat and Octoploid Trititrigia were observed with the scanning electron microscope(SEM). The results revealed...The pollen grain morphology and leaf epiderm shape and microstructural of Rye( Secale cereal ), common wheat and Octoploid Trititrigia were observed with the scanning electron microscope(SEM). The results revealed that there were great differences between pollen and leaf epiderm microcosmic morphology in three species. Such characteristics of Octoploid tnticalwere between those of common wheat and Rye. The morphology of pollen grain and leaf epiderm shape counld be used as an index for taxonomy for genera and species, and had somewhat scientif- ic references to identify new multiploid species created by chromosome engineering.展开更多
[Objective] The aim was to study on construction of overall water environment in Xi'an. [Method] The study discussed necessity and basic principles of over-all restoration and construction of "Chang'an Eight Water...[Objective] The aim was to study on construction of overall water environment in Xi'an. [Method] The study discussed necessity and basic principles of over-all restoration and construction of "Chang'an Eight Water" from urban planning, and explored related methods from long term planning and concrete construction approaches. [Result] The study proposed that urban landscape substrates of "Chang' an Eight Water" should be restored based on overall planning about urban water environment, change of linear metabolism, and construction of drainage circulation system. Furthermore, self-circulation and purification of rainfall and sewage could be made use of there in view of present urban water environment. In addition, urban "metabolism" should be restored progressively to improve urban environment with consideration of water catchment, storage, and diversion. [Conclusion] We should take the initiative to catch the special opportunity to build Xi'an into an international metropolis with overall planning, designing and implementation, which will be conducive to reconstruction of water system and pleasant surroundings, and to presentation of urban ecosystem and context in "Chang'an Eight Water", providing many opportunities for urban development.展开更多
Through the octree data structure analysis,a volumetric dataset of closed-cell porous materials is converted into a dataset of hierarchical octree nodes,and then the specific traversal search algorithm on the octree n...Through the octree data structure analysis,a volumetric dataset of closed-cell porous materials is converted into a dataset of hierarchical octree nodes,and then the specific traversal search algorithm on the octree nodes is depicted in details,which is involved in six steps of the volume growth model and one step of the volume decomposition model.Moreover,the conditions of both the proceeding traversal and three possibilities of terminating are given,and the traversal algorithm of completeness is proved from a theoretical perspective.Finally,using a simulated volumetric dataset of columnar pores,the extracting effectiveness of the octree traversal algorithm is verified.The results show that the volume and the distribution information of pores can be successfully extracted by the proposed algorithm,which builds a solid foundation for a more effective performance analysis of porous materials.展开更多
A photocatalyst composed of TiO 2 nanotube arrays(TNTs) and octahedral Cu2 O nanoparticles was fabricated,and its performance in the photocatalytic reduction of CO2 under visible and simulated solar irradiation was ...A photocatalyst composed of TiO 2 nanotube arrays(TNTs) and octahedral Cu2 O nanoparticles was fabricated,and its performance in the photocatalytic reduction of CO2 under visible and simulated solar irradiation was studied. The average nanotube diameter and length was 100 nm and 5 μm,respectively. The different amount of octahedral Cu2 O modified TNTs were obtained by varying electrochemical deposition time. TNTs modified with an optimized amount of Cu2 O nanoparticles exhibited high efficiency in the photocatalysis,and the predominant hydrocarbon product was methane. The methane yield increased with increasing Cu2 O content of the catalyst up to a certain deposition time,and decreased with further increase in Cu2 O deposition time. Insufficient deposition time(5 min) resulted in a small amount of Cu2 O nanoparticles on the TNTs,leading to the disadvantage of harvesting light. However,excess deposition time(45 min) gave rise to entire TNT surface being most covered with Cu2 O nanoparticles with large sizes,inconvenient for the transport of photo-generated carriers. The highest methane yield under simulated solar and visible light irradiation was observed for the catalysts prepared at a Cu2 O deposition time of 15 and 30 min respectively. The morphology,crystallization,photoresponse and electrochemical properties of the catalyst were characterized to understand the mechanism of its high photocatalytic activity. The TNT structure provided abundant active sites for the adsorption of reactants,and promoted the transport of photogenerated carriers that improved charge separation. Modifying the TNTs with octahedral Cu2 O nanoparticles promoted light absorption,and prevented the hydrocarbon product from oxidation. These factors provided the Cu2O-modified TNT photocatalyst with high efficiency in the reduction of CO2,without requiring co-catalysts or sacrificial agents.展开更多
Several catalysts comprising Pt supported on octahedral Fe3O4(Pt/Fe3O4) were prepared by a facile method involving co-precipitation followed by thermal treatment at different temperatures. A variety of characterizat...Several catalysts comprising Pt supported on octahedral Fe3O4(Pt/Fe3O4) were prepared by a facile method involving co-precipitation followed by thermal treatment at different temperatures. A variety of characterization results revealed that this preparation process afforded highly crystalline octahedral Fe3O4 with a uniform distribution of Pt nanoparticles on its surface. The thermal-treatment temperature significantly influenced the redox properties of the Pt/Fe3O4 catalysts. All the Pt/Fe3O4 catalysts were found to be catalytically active and stable for the oxidation of low-concentration formaldehyde(HCHO) with oxygen. The catalyst prepared by thermal treatment at 80 °C(labelled Pt/Fe3O4-80) exhibited the highest catalytic activity, efficiently converting HCHO to CO2 and H2 O under ambient temperature and moisture conditions. The excellent performance of Pt/Fe3O4-80 was mainly attributed to beneficial interactions between the Pt and Fe species that result in the formation a higher density of active interface sites(e.g., Pt-O-FeO x and Pt-OH-FeO x). The introduction of water vapor improves the catalytic activity of the Pt/Fe3O4 catalysts as it participates in a water-assisted dissociation process.展开更多
A new case configuration in R^3, the conjugate-nest consisted of one regular tetrahedron and one regular octahedron is discussed. If the configuration is a central configuration, then all masses of outside layer are e...A new case configuration in R^3, the conjugate-nest consisted of one regular tetrahedron and one regular octahedron is discussed. If the configuration is a central configuration, then all masses of outside layer are equivalent, the masses of inside layer are also equivalent. At the same time the following relation between ρ(r =√3/3ρ is the radius ratio of the sizes) and mass ratio τ=~↑m/m must be satisfied τ=~↑m/m=ρ(ρ+3)(3+2ρ+ρ^2)^-3/2+ρ(-ρ+3)(3-2ρ+ρ^2)^-3/2-4.2^-3/2ρ^-2-^-1ρ^-2/2(1+ρ)(3+2ρ+ρ^2)^-3/2+2(ρ-1)(3-2ρ+ρ^2)^-3/2-4(2√2)^-3ρ, and for any mass ratio τ, when mass ratio r is in the open interval (0, 0.03871633950 ... ), there exist three central configuration solutions(the initial configuration conditions who imply hamagraphic solutions) corresponding radius ratios are r1, r2, and r3, two of them in the interval (2.639300779… , +∞) and one is in the interval (0.7379549890…, 1.490942703… ). when mass ratio τ is in the open interval (130.8164950… , +∞), in the same way there have three corresponding radius ratios, two of them in the interval (0, 0.4211584789... ) and one is in the interval (0.7379549890…, 1.490942703…). When mass ratio τ is in the open interval (0.03871633950…, 130.8164950…), there has only one solution r in the interval (0.7379549890…, 1.490942703… ).展开更多
Orebody-rendering techniques are developed using the marching cubes (MC) algorithm. The shape of an orebody is viv- idly displayed in real time and can be used to guide mining design as well. The MC algorithm has been...Orebody-rendering techniques are developed using the marching cubes (MC) algorithm. The shape of an orebody is viv- idly displayed in real time and can be used to guide mining design as well. The MC algorithm has been improved in two aspects. By analyzing the principles of the MC algorithm, as well as the features of the specific application, improvements were developed to: eliminate ambiguities by using a unified isosurface constructing method in the voxels, and improve the operating efficiency of the MC algorithm by incorporating an octree structure. The analytical results of the examples demonstrate the effectiveness of our proposal.展开更多
The formation mechanism for the body-centred regular octahedral structure of Li7 cluster is proposed. The curve of the total energy versus the separation R between the nucleus at the centre and nuclei at the apexes fo...The formation mechanism for the body-centred regular octahedral structure of Li7 cluster is proposed. The curve of the total energy versus the separation R between the nucleus at the centre and nuclei at the apexes for this structure of Li7 has been calculated by using the method of Gou's modified arrangement channel quantum mechanics (MACQM). The result shows that the curve has a minimal energy of-52.169 73 a.u. at R = 5.06ao. When R approaches infinity, the total energy of seven lithium atoms has the value of-51.996 21 a.u. So the binding energy of Li7 with respect to seven lithium atoms is 0.173 52 a.u. Therefore the binding energy per atom for Li7 is 0.024 79 a.u. or 0.674 eV, which is greater than the binding energy per atom of 0.453 eV for Li2, the binding energy per atom of 0.494 eV for Li3 and the binding energy per atom of 0.632 eV for Li5 calculated previously by us. This means that the Li7 cluster may be formed stably in a body-centred regular octahedral structure with a greater binding energy.展开更多
A series of Ag,Cu and Co-doped manganese oxide octahedral molecular sieves(OMS-2) were synthesized and evaluated to remove nitrogen oxides(NOx) from cigarette mainstream smoke.The three kinds of catalysts were added t...A series of Ag,Cu and Co-doped manganese oxide octahedral molecular sieves(OMS-2) were synthesized and evaluated to remove nitrogen oxides(NOx) from cigarette mainstream smoke.The three kinds of catalysts were added to cigarettes for studying the capabilities of reducing NOx from cigarette mainstream smoke.The catalysis and reduction of NO in laboratory were studied.A mechanism for NOx catalytic reduction from burning cigarettes with the catalysts adding to cigarettes was described.The catalysts show excellent catalytic activity for NOx removal,especially the Ag-doped OMS-2 catalyst.0.5%(mass fraction) Ag-doped OMS-2 catalyst has the best ability to remove NOx from cigarette mainstream smoke.The use of Ag-doped OMS-2 as catalyst for removing carcinogenic compounds from cigarette smoke will be an effective strategy to protect the environment and public health.展开更多
Cationic ring opening polymerization of octamethylcyclotetrasiloxane (Da) initiated by acid treated bentonite was investigated. The experimental conditions were chosen on the basis of preliminary experiments.Higher ...Cationic ring opening polymerization of octamethylcyclotetrasiloxane (Da) initiated by acid treated bentonite was investigated. The experimental conditions were chosen on the basis of preliminary experiments.Higher temperature was found beneficial for the reaction process while stirring intensity beyond a certain level showed no obvious effect on the reaction rate. Polymers were characterized by Fourier transform infrared, proton nuclear magnetic resonance (IH-NMR) and gel perneation chromotography. The width of molecular mass distribution was found ranging between 1.2 and 1.4, which is extraordinarlly narrow compared with that of cationic polymerizations reported elsewhere (〉 1.9). The results were believed due to the absence of free proton and counter ion which simplifies the polymerization process and the huge steric hindrance provided by bentonite particles which keeps the propagation of polysiloxane onto the surface of bentonite particles in a much more regular way. A feasible mechanism is proposed and seems to be supported well by experiments. Additionally, from the results of α, ω-dihydrogen terminated polysiloxanes prepared, the possibility of applying this potential environmentally friendly heterogeneous catalyst in industrial polymerization of cyclosiloxanes is anticipated.展开更多
A novel compound [(CH 3CH 2) 4N] 4[(La 12 (OH) 12 MoO 29 )] was synthesized by hydrothermal reaction. The single crystal X ray diffraction shows that the compound crystallized in the monoclinic space group C2/c ; a =2...A novel compound [(CH 3CH 2) 4N] 4[(La 12 (OH) 12 MoO 29 )] was synthesized by hydrothermal reaction. The single crystal X ray diffraction shows that the compound crystallized in the monoclinic space group C2/c ; a =2 5729(4) nm, b =1 4318(1) nm, c =2 1217(4) nm, β =111 56(1)°, V =6 8235(7) nm 3, Z =4, R =0 0751. The basic building blocks of the crystal structure included one MoO 5 hexahedron and twelve LaO 6 octahedra which shared a common edge to form a [(La 12 (OH) 12 MoO 29 )] 4- unit. These units were held together by the [(CH 3CH 2) 4N] + ions.展开更多
The Cu(II) complex with the ligand 2,9-bis(n-2?5?diazaheptanyl)-1,10-phenan- throline (L) has been synthesized and characterized by single-crystal X-ray diffraction. It crys- tallizes in the monoclinic system, space g...The Cu(II) complex with the ligand 2,9-bis(n-2?5?diazaheptanyl)-1,10-phenan- throline (L) has been synthesized and characterized by single-crystal X-ray diffraction. It crys- tallizes in the monoclinic system, space group P21/n with a = 12.549(4), b = 13.544(4), c = 16.767(5) ? = 107.179(5), C22H32Cl2N6CuO8, Mr = 642.98, V = 2722.5(13) 3, Z = 4, Dc = 1.569 g/cm3, ?= 1.056 mm-1, F(000) =1332, the final R = 0.0733 and wR = 0.1581. The X-ray analysis revealed that the Cu(II) ion is coordinated by six nitrogen atoms of the ligand, in which two nitrogen from phenanthroline and another two from the imine groups near phenanthroline are in the equatorial plane while the two from imine groups at the end of both arms in the axial positions. The coordination geometry can be described as a compressed octahedron.展开更多
Abstract:A space-filling polyhedron is a polyhedron which 'tile' space, analogous to the way of certain polygons tiled the plane. The cube is the unique space-filling platonic solid. If we make line connections the...Abstract:A space-filling polyhedron is a polyhedron which 'tile' space, analogous to the way of certain polygons tiled the plane. The cube is the unique space-filling platonic solid. If we make line connections the center with the vertices in the certain cube, the cube is divided into six pyramids. And if we glued six pyramids to the faces of the cube, we obtain a 'rhombic dodecahedron'. Since cubes are packing a space, rhombic dodecahedra are also space-filling polyhedra and a rhombic dodecahedron is divided into two regular tetrahcdra and one regular octahedron. In this study, we present how rhombic dodecahedron can be split into tetrahedra and octahedron. In this process, we can research a variety of divisions of regular polyhedron.展开更多
Based on comparison and analysis on structural cations of montmorillonite in bentonite samples collected from several typical areas in Jilin Province, relationships among type and quantity of interlayer/tetrahedral/oc...Based on comparison and analysis on structural cations of montmorillonite in bentonite samples collected from several typical areas in Jilin Province, relationships among type and quantity of interlayer/tetrahedral/octahedral cations and temperature and activation energy of removal of bound and hydroxyl water were investigated. The results show that the interlayer cations not only play decisive roles on removal temperature of bound water, but also influence dehydroxylation temperature and activation energy of montmorillonite. Type of octahedral cations also has an effect on dehydroxylation process.展开更多
Abstract The study on the catalysis of ionic liquids for alkylation of benzene with 1-octadecene to synthesize LAB (linear alkylbenzenes) was performed. The results showed that the most important factor that governe...Abstract The study on the catalysis of ionic liquids for alkylation of benzene with 1-octadecene to synthesize LAB (linear alkylbenzenes) was performed. The results showed that the most important factor that governed the conversion of olefin and selectivity of LAB was reaction temperature. Moreover, the effects of different ionic liquids and molar ratio of benzene to 1-octadecene on the conversion and selectivity were obviously in different degrees. The reaction temperature, molar ratio of benzene to 1-octadecene and the amount of catalyst were lower, compared with the traditional reaction technologies. The experimental results demonstrated that the ionic liquid had higher activity at 30℃, with over 98% selectivity of monoalkylbenzene and 100% conversion of the olefin at the molar ratio 0.08 of FeCl3 in ionic liquid to 1-octadecene and 10 for benzene to 1-octadecene.展开更多
基金supported by the National Natural Science Foundation of China(5120839621277107+5 种基金21477094and 51472192)the Program for New Century Excellent Talents in University(NCET-13-0944)the Fundamental Research Funds for the Central Universities(WUT 2014-1a-0032014-VII-037and 2015IB002)~~
文摘Noble metal/titania hollow nanomaterials usually exhibit excellent photocatalytic activity because of their high specific surface area,low density,good surface permeability,strong light-harvesting capacity,and rapid interfacial charge transfer. However,the present preparation methods usually include complicated and multistep procedures,which can cause damage to the hollow nanostructures. In this paper,a facile template-induced synthesis,based on a template-directed deposition and in situ template-sacrificial dissolution,was employed to prepare Ag-modified TiO 2(Ag/TiO 2) hollow octahedra using Ag2 O octahedra as templates and TiF 4 as the precursor. In the synthetic strategy,the shells of TiO 2 hollow octahedra were formed by coating TiO 2 nanoparticles on the surface of Ag2 O templates based on the template-directed deposition. Simultaneously,the Ag2 O templates can be in situ removed by dissolving the Ag2 O octahedral template in HF solution produced via the hydrolysis reaction of TiF 4 in the reaction system. In addition,Ag nanoparticles were deposited on the inside and outside surfaces of TiO 2 shells by effectively using the photosensitive properties of Ag2 O and Ag+ ions under light irradiation,along with the formation of TiO 2 hollow octahedra. The Ag/TiO 2 hollow octahedra exhibited high photocatalytic activity because of their(1) short diffusion distances between photogenerated electrons and holes because of the thin shells of Ag/TiO 2 hollow octahedral,(2) deposition of Ag nanoparticles on the inside and outside surfaces of TiO 2 shells,and(3) rapid interfacial charge transfer between TiO 2 shells and Ag nanoparticles. This work may also provide new insights into preparing other Ag-modified and hollow nanostructured photocatalysts.
文摘The pollen grain morphology and leaf epiderm shape and microstructural of Rye( Secale cereal ), common wheat and Octoploid Trititrigia were observed with the scanning electron microscope(SEM). The results revealed that there were great differences between pollen and leaf epiderm microcosmic morphology in three species. Such characteristics of Octoploid tnticalwere between those of common wheat and Rye. The morphology of pollen grain and leaf epiderm shape counld be used as an index for taxonomy for genera and species, and had somewhat scientif- ic references to identify new multiploid species created by chromosome engineering.
文摘[Objective] The aim was to study on construction of overall water environment in Xi'an. [Method] The study discussed necessity and basic principles of over-all restoration and construction of "Chang'an Eight Water" from urban planning, and explored related methods from long term planning and concrete construction approaches. [Result] The study proposed that urban landscape substrates of "Chang' an Eight Water" should be restored based on overall planning about urban water environment, change of linear metabolism, and construction of drainage circulation system. Furthermore, self-circulation and purification of rainfall and sewage could be made use of there in view of present urban water environment. In addition, urban "metabolism" should be restored progressively to improve urban environment with consideration of water catchment, storage, and diversion. [Conclusion] We should take the initiative to catch the special opportunity to build Xi'an into an international metropolis with overall planning, designing and implementation, which will be conducive to reconstruction of water system and pleasant surroundings, and to presentation of urban ecosystem and context in "Chang'an Eight Water", providing many opportunities for urban development.
基金The National Basic Research Program of China(973Program)(No.2006CB601202)
文摘Through the octree data structure analysis,a volumetric dataset of closed-cell porous materials is converted into a dataset of hierarchical octree nodes,and then the specific traversal search algorithm on the octree nodes is depicted in details,which is involved in six steps of the volume growth model and one step of the volume decomposition model.Moreover,the conditions of both the proceeding traversal and three possibilities of terminating are given,and the traversal algorithm of completeness is proved from a theoretical perspective.Finally,using a simulated volumetric dataset of columnar pores,the extracting effectiveness of the octree traversal algorithm is verified.The results show that the volume and the distribution information of pores can be successfully extracted by the proposed algorithm,which builds a solid foundation for a more effective performance analysis of porous materials.
基金supported by the National Natural Science Foundation of China(2137704421573085)+5 种基金the Key Project of Natural Science Foundation of Hubei Province(2015CFA037)Wuhan Planning Project of Science and Technology(2014010101010023)Self-determined Research Funds of CCNU from the Colleges’Basic Research and Operation of MOE(CCNU15ZD007CCNU15KFY005)China Postdoctoral Science Foundation(2015M572187)Hubei Provincial Department of Education(D20152702)~~
文摘A photocatalyst composed of TiO 2 nanotube arrays(TNTs) and octahedral Cu2 O nanoparticles was fabricated,and its performance in the photocatalytic reduction of CO2 under visible and simulated solar irradiation was studied. The average nanotube diameter and length was 100 nm and 5 μm,respectively. The different amount of octahedral Cu2 O modified TNTs were obtained by varying electrochemical deposition time. TNTs modified with an optimized amount of Cu2 O nanoparticles exhibited high efficiency in the photocatalysis,and the predominant hydrocarbon product was methane. The methane yield increased with increasing Cu2 O content of the catalyst up to a certain deposition time,and decreased with further increase in Cu2 O deposition time. Insufficient deposition time(5 min) resulted in a small amount of Cu2 O nanoparticles on the TNTs,leading to the disadvantage of harvesting light. However,excess deposition time(45 min) gave rise to entire TNT surface being most covered with Cu2 O nanoparticles with large sizes,inconvenient for the transport of photo-generated carriers. The highest methane yield under simulated solar and visible light irradiation was observed for the catalysts prepared at a Cu2 O deposition time of 15 and 30 min respectively. The morphology,crystallization,photoresponse and electrochemical properties of the catalyst were characterized to understand the mechanism of its high photocatalytic activity. The TNT structure provided abundant active sites for the adsorption of reactants,and promoted the transport of photogenerated carriers that improved charge separation. Modifying the TNTs with octahedral Cu2 O nanoparticles promoted light absorption,and prevented the hydrocarbon product from oxidation. These factors provided the Cu2O-modified TNT photocatalyst with high efficiency in the reduction of CO2,without requiring co-catalysts or sacrificial agents.
文摘Several catalysts comprising Pt supported on octahedral Fe3O4(Pt/Fe3O4) were prepared by a facile method involving co-precipitation followed by thermal treatment at different temperatures. A variety of characterization results revealed that this preparation process afforded highly crystalline octahedral Fe3O4 with a uniform distribution of Pt nanoparticles on its surface. The thermal-treatment temperature significantly influenced the redox properties of the Pt/Fe3O4 catalysts. All the Pt/Fe3O4 catalysts were found to be catalytically active and stable for the oxidation of low-concentration formaldehyde(HCHO) with oxygen. The catalyst prepared by thermal treatment at 80 °C(labelled Pt/Fe3O4-80) exhibited the highest catalytic activity, efficiently converting HCHO to CO2 and H2 O under ambient temperature and moisture conditions. The excellent performance of Pt/Fe3O4-80 was mainly attributed to beneficial interactions between the Pt and Fe species that result in the formation a higher density of active interface sites(e.g., Pt-O-FeO x and Pt-OH-FeO x). The introduction of water vapor improves the catalytic activity of the Pt/Fe3O4 catalysts as it participates in a water-assisted dissociation process.
基金NSF of China(10231010)NSF of Chongqing EducationCommittee(071105)NSF of SXXYYB(070X)
文摘A new case configuration in R^3, the conjugate-nest consisted of one regular tetrahedron and one regular octahedron is discussed. If the configuration is a central configuration, then all masses of outside layer are equivalent, the masses of inside layer are also equivalent. At the same time the following relation between ρ(r =√3/3ρ is the radius ratio of the sizes) and mass ratio τ=~↑m/m must be satisfied τ=~↑m/m=ρ(ρ+3)(3+2ρ+ρ^2)^-3/2+ρ(-ρ+3)(3-2ρ+ρ^2)^-3/2-4.2^-3/2ρ^-2-^-1ρ^-2/2(1+ρ)(3+2ρ+ρ^2)^-3/2+2(ρ-1)(3-2ρ+ρ^2)^-3/2-4(2√2)^-3ρ, and for any mass ratio τ, when mass ratio r is in the open interval (0, 0.03871633950 ... ), there exist three central configuration solutions(the initial configuration conditions who imply hamagraphic solutions) corresponding radius ratios are r1, r2, and r3, two of them in the interval (2.639300779… , +∞) and one is in the interval (0.7379549890…, 1.490942703… ). when mass ratio τ is in the open interval (130.8164950… , +∞), in the same way there have three corresponding radius ratios, two of them in the interval (0, 0.4211584789... ) and one is in the interval (0.7379549890…, 1.490942703…). When mass ratio τ is in the open interval (0.03871633950…, 130.8164950…), there has only one solution r in the interval (0.7379549890…, 1.490942703… ).
基金Projects 20020008006 supported by the Exclusive Research Foundation for Doctoral Programs by Ministry of Education of China2006BAK04B04 by the National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science & Technology of China
文摘Orebody-rendering techniques are developed using the marching cubes (MC) algorithm. The shape of an orebody is viv- idly displayed in real time and can be used to guide mining design as well. The MC algorithm has been improved in two aspects. By analyzing the principles of the MC algorithm, as well as the features of the specific application, improvements were developed to: eliminate ambiguities by using a unified isosurface constructing method in the voxels, and improve the operating efficiency of the MC algorithm by incorporating an octree structure. The analytical results of the examples demonstrate the effectiveness of our proposal.
基金The project supported by National Natural Science Foundation of China under Grant No. 19974027
文摘The formation mechanism for the body-centred regular octahedral structure of Li7 cluster is proposed. The curve of the total energy versus the separation R between the nucleus at the centre and nuclei at the apexes for this structure of Li7 has been calculated by using the method of Gou's modified arrangement channel quantum mechanics (MACQM). The result shows that the curve has a minimal energy of-52.169 73 a.u. at R = 5.06ao. When R approaches infinity, the total energy of seven lithium atoms has the value of-51.996 21 a.u. So the binding energy of Li7 with respect to seven lithium atoms is 0.173 52 a.u. Therefore the binding energy per atom for Li7 is 0.024 79 a.u. or 0.674 eV, which is greater than the binding energy per atom of 0.453 eV for Li2, the binding energy per atom of 0.494 eV for Li3 and the binding energy per atom of 0.632 eV for Li5 calculated previously by us. This means that the Li7 cluster may be formed stably in a body-centred regular octahedral structure with a greater binding energy.
文摘A series of Ag,Cu and Co-doped manganese oxide octahedral molecular sieves(OMS-2) were synthesized and evaluated to remove nitrogen oxides(NOx) from cigarette mainstream smoke.The three kinds of catalysts were added to cigarettes for studying the capabilities of reducing NOx from cigarette mainstream smoke.The catalysis and reduction of NO in laboratory were studied.A mechanism for NOx catalytic reduction from burning cigarettes with the catalysts adding to cigarettes was described.The catalysts show excellent catalytic activity for NOx removal,especially the Ag-doped OMS-2 catalyst.0.5%(mass fraction) Ag-doped OMS-2 catalyst has the best ability to remove NOx from cigarette mainstream smoke.The use of Ag-doped OMS-2 as catalyst for removing carcinogenic compounds from cigarette smoke will be an effective strategy to protect the environment and public health.
基金Supported by the National Natural Science Foundation of China (No.20576117)
文摘Cationic ring opening polymerization of octamethylcyclotetrasiloxane (Da) initiated by acid treated bentonite was investigated. The experimental conditions were chosen on the basis of preliminary experiments.Higher temperature was found beneficial for the reaction process while stirring intensity beyond a certain level showed no obvious effect on the reaction rate. Polymers were characterized by Fourier transform infrared, proton nuclear magnetic resonance (IH-NMR) and gel perneation chromotography. The width of molecular mass distribution was found ranging between 1.2 and 1.4, which is extraordinarlly narrow compared with that of cationic polymerizations reported elsewhere (〉 1.9). The results were believed due to the absence of free proton and counter ion which simplifies the polymerization process and the huge steric hindrance provided by bentonite particles which keeps the propagation of polysiloxane onto the surface of bentonite particles in a much more regular way. A feasible mechanism is proposed and seems to be supported well by experiments. Additionally, from the results of α, ω-dihydrogen terminated polysiloxanes prepared, the possibility of applying this potential environmentally friendly heterogeneous catalyst in industrial polymerization of cyclosiloxanes is anticipated.
基金Supported by the National Natural Science Foundation of China(No.2 0 1710 10 )
文摘A novel compound [(CH 3CH 2) 4N] 4[(La 12 (OH) 12 MoO 29 )] was synthesized by hydrothermal reaction. The single crystal X ray diffraction shows that the compound crystallized in the monoclinic space group C2/c ; a =2 5729(4) nm, b =1 4318(1) nm, c =2 1217(4) nm, β =111 56(1)°, V =6 8235(7) nm 3, Z =4, R =0 0751. The basic building blocks of the crystal structure included one MoO 5 hexahedron and twelve LaO 6 octahedra which shared a common edge to form a [(La 12 (OH) 12 MoO 29 )] 4- unit. These units were held together by the [(CH 3CH 2) 4N] + ions.
基金This work was supported by the National Natural Science Foundation of China (No. 20371028)and Natural Science Foundation of Tianjin (No. 023605811)
文摘The Cu(II) complex with the ligand 2,9-bis(n-2?5?diazaheptanyl)-1,10-phenan- throline (L) has been synthesized and characterized by single-crystal X-ray diffraction. It crys- tallizes in the monoclinic system, space group P21/n with a = 12.549(4), b = 13.544(4), c = 16.767(5) ? = 107.179(5), C22H32Cl2N6CuO8, Mr = 642.98, V = 2722.5(13) 3, Z = 4, Dc = 1.569 g/cm3, ?= 1.056 mm-1, F(000) =1332, the final R = 0.0733 and wR = 0.1581. The X-ray analysis revealed that the Cu(II) ion is coordinated by six nitrogen atoms of the ligand, in which two nitrogen from phenanthroline and another two from the imine groups near phenanthroline are in the equatorial plane while the two from imine groups at the end of both arms in the axial positions. The coordination geometry can be described as a compressed octahedron.
文摘Abstract:A space-filling polyhedron is a polyhedron which 'tile' space, analogous to the way of certain polygons tiled the plane. The cube is the unique space-filling platonic solid. If we make line connections the center with the vertices in the certain cube, the cube is divided into six pyramids. And if we glued six pyramids to the faces of the cube, we obtain a 'rhombic dodecahedron'. Since cubes are packing a space, rhombic dodecahedra are also space-filling polyhedra and a rhombic dodecahedron is divided into two regular tetrahcdra and one regular octahedron. In this study, we present how rhombic dodecahedron can be split into tetrahedra and octahedron. In this process, we can research a variety of divisions of regular polyhedron.
文摘Based on comparison and analysis on structural cations of montmorillonite in bentonite samples collected from several typical areas in Jilin Province, relationships among type and quantity of interlayer/tetrahedral/octahedral cations and temperature and activation energy of removal of bound and hydroxyl water were investigated. The results show that the interlayer cations not only play decisive roles on removal temperature of bound water, but also influence dehydroxylation temperature and activation energy of montmorillonite. Type of octahedral cations also has an effect on dehydroxylation process.
基金Supported by the National Natural Science Foundation of China (No.20276038) and Beijing Natural Science Foundation (No.2052010).
文摘Abstract The study on the catalysis of ionic liquids for alkylation of benzene with 1-octadecene to synthesize LAB (linear alkylbenzenes) was performed. The results showed that the most important factor that governed the conversion of olefin and selectivity of LAB was reaction temperature. Moreover, the effects of different ionic liquids and molar ratio of benzene to 1-octadecene on the conversion and selectivity were obviously in different degrees. The reaction temperature, molar ratio of benzene to 1-octadecene and the amount of catalyst were lower, compared with the traditional reaction technologies. The experimental results demonstrated that the ionic liquid had higher activity at 30℃, with over 98% selectivity of monoalkylbenzene and 100% conversion of the olefin at the molar ratio 0.08 of FeCl3 in ionic liquid to 1-octadecene and 10 for benzene to 1-octadecene.