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基于葫芦脲[8]包结增强供体-受体作用构筑“刚-柔”型超分子共聚物 被引量:3
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作者 樊煜 林沨 +2 位作者 徐晓娜 徐甲强 赵新 《高分子学报》 SCIE CAS CSCD 北大核心 2017年第1期80-85,共6页
设计合成了一种缺电性的刚性棒状超分子单体,在葫芦脲(CB[8])存在下,它与富电性的柔性单体受CB[8]包结增强的供体-受体作用驱动在水中共组装形成"刚-柔"(rod-coil)型超分子共聚物.运用核磁共振滴定实验、紫外-可见光谱、二维... 设计合成了一种缺电性的刚性棒状超分子单体,在葫芦脲(CB[8])存在下,它与富电性的柔性单体受CB[8]包结增强的供体-受体作用驱动在水中共组装形成"刚-柔"(rod-coil)型超分子共聚物.运用核磁共振滴定实验、紫外-可见光谱、二维扩散排序核磁共振谱(DOSY)、动态光散射(DLS)以及透射电子显微镜(TEM)等对超分子聚合物的形成及其结构进行了证实和表征,并发现该超分子共聚物在低浓度下采取伸展的线形构象,当浓度增加到一定程度后其线形骨架发生卷曲,转变为颗粒状团聚结构. 展开更多
关键词 超分子共聚物 葫芦脲[8] 供体-受体作用 “刚-柔”型
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A unified approach to type synthesis of both rigid and flexure parallel mechanisms 被引量:8
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作者 YU JingJun LI ShouZhong +2 位作者 PEI Xu BI ShuSheng ZONG GuangHua 《Science China(Technological Sciences)》 SCIE EI CAS 2011年第5期1206-1219,共14页
Type synthesis of both rigid and compliant parallel mechanisms has become a hot issue in the field of mechanisms and robotics research in recent years. A unified approach to type synthesis of the two classes of mechan... Type synthesis of both rigid and compliant parallel mechanisms has become a hot issue in the field of mechanisms and robotics research in recent years. A unified approach to type synthesis of the two classes of mechanisms, however, has not been referred and investigated up to date. Based on the state-of-art analysis for several major type synthesis approaches related to rigid and compliant mechanisms, respectively, it proves feasible to establish a unified methodology for type synthesis of these two classes of mechanisms. That is a synthesis philosophy in terms of the hierarchy mapping between mathematic, physical, and mechanical building blocks in the framework of screw theory, as addressed in this paper. The key point of the proposed method lies in establishing the mapping among three different building blocks (i.e. geometric building block, kinematic or constraint building block, and mechanical building block). As a result, it makes the whole type synthesis process simple and visible. By using the proposed method, two examples are taken to verify the effectiveness for the type synthesis of both rigid and flexure mechanisms. The content of this paper may provide a theoretical frame for constructing a visualized algorithm or software about the unified type synthesis (or conceptual design) of both rigid and flexure parallel mechanisms. 展开更多
关键词 type synthesis flexure mechanism parallel mechanism screw system building block
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