The modification of oxide-derived Cu electrode with Ni, Zn, and Au was examined to improve the catalytic activity of COz electroreduction. The experimental results showed that Ni modification increased the Faraday eff...The modification of oxide-derived Cu electrode with Ni, Zn, and Au was examined to improve the catalytic activity of COz electroreduction. The experimental results showed that Ni modification increased the Faraday efficiency of the formation of formic acid and n-propanol. The Faraday effi- ciency relating to the formation of the liquid products was as high as 34.3% at -1.5 V versus the saturated calomel electrode reference potential. In contrast, modification with Zn reduced the for- mic acid formation efficiency but enhanced the alcohol formation efficiency. Finally, modification with Au suppressed the selectivity toward the formation of both formic acid and alcohols.展开更多
Cyclic metallurgical process for separation and recovery of Cr from vanadium precipitated solution by precipitation with PbCO_(3)and leaching with Na_(2)CO_(3)was investigated.The concentration of Cr residue in the so...Cyclic metallurgical process for separation and recovery of Cr from vanadium precipitated solution by precipitation with PbCO_(3)and leaching with Na_(2)CO_(3)was investigated.The concentration of Cr residue in the solution decreases from 2.360 to 0.001 g/L by adding PbCO_(3)into vanadium precipitated solution according to Pb/Cr molar ratio of 2.5,adjusting the pH to 3.0 and stirring for 180 min at 30℃.Then,the precipitates were leached with hot Na_(2)CO_(3)solution to obtain leaching solution containing Na_(2)CrO_(4)and leaching residue containing PbCO_(3).The leaching efficiency of Cr reaches 96.43%by adding the precipitates into 0.5 mol/L Na_(2)CO_(3)solution with the mass ratio of liquid to solid(L/S)of 10:1 mL/g and stirring for 60 min under pH 9.5 at 70℃.After filtration,leaching residue is reused in Cr precipitation and leaching solution is used to circularly leach the Cr precipitates until Na_(2)CrO_(4)approaches the saturation.Finally,the product of Na_(2)CrO_(4)·4H_(2)O is obtained by evaporation and crystallization of leaching solution.展开更多
Porous C‐I codoped carbon nitride materials were synthesized by in‐situ codoping with iodized ionic liquid followed by post‐thermal treatment in air.The effects of doping content of C‐I codoping with different amo...Porous C‐I codoped carbon nitride materials were synthesized by in‐situ codoping with iodized ionic liquid followed by post‐thermal treatment in air.The effects of doping content of C‐I codoping with different amounts of ionic liquid on the structural,optical and photocatalytic properties of the samples were investigated.Characterization results show that more compact interlayer sacking can be achieved by post‐thermal treatment.Combined with C‐I codoping by insertion of ionic liquids,much enlarged surface area but optimized sp2 conjugated heterocyclic structure can be found in the catalysts.Optical and energy band analysis results evidence that the light absorptions especially in visible light region are significantly improved.Although the band gap of porous C‐I codoped samples enlarge because of the generation of porous,the negatively shifted conduction band position thermodynamically supplies stronger motivation for water reduction.Photoelectricity tests reveal that the photo‐induced electron density was increased after C‐I codoping modification.Also,the recombination rate of electron‐hole pairs is remarkably inhibited.The catalysts with moderate C‐I codoing content perform sharply enhanced photocatalytic H2 evolution activity under visible light irradiation.A H2 evolution rate of 168.2μmol/h was achieved and it was more than 9.8 times higher than pristine carbon nitride.This study demonstrates a novel non‐metal doping strategy for synthesis and optimization of polymer semiconductor with gratifying photocatalytic H2 evolution performance from water hydrolysis.展开更多
The study has assessed the denitrification performance of fermented and dark-fermented biosolids as external carbon sources using lab-scaled Sequencing Batch Reactors (SBRs). This was done by adding fermented and da...The study has assessed the denitrification performance of fermented and dark-fermented biosolids as external carbon sources using lab-scaled Sequencing Batch Reactors (SBRs). This was done by adding fermented and dark-fermented biosolids into anoxic zones of two SBRs, and then assessing the change of effluent characteristics comparing to before adding and to a third controlled reactor. The results showed that by adding 150-170 mg rbCOD/L of either of the selected fermented biosolids, almost complete denitrification could be reached for tested SBRs (reduced from initial -20 mg NO3/L to 〈 1 mg NO3/L). Finally, the experiment also found that the impact of NI-I4 components of fermented and dark-fermented biosolids onto the final effluent were much lesser than expected, where only less than 2.5 mg NH4/L were detected in the effluent, much lower than the added 5.0-5.7 mg/L.展开更多
基金supported by the National Natural Science Foundation of China(21573183,21222310,21361140374,21321062)the Funda-mental Research Funds for the Central Universities(20720160045)~~
文摘The modification of oxide-derived Cu electrode with Ni, Zn, and Au was examined to improve the catalytic activity of COz electroreduction. The experimental results showed that Ni modification increased the Faraday efficiency of the formation of formic acid and n-propanol. The Faraday effi- ciency relating to the formation of the liquid products was as high as 34.3% at -1.5 V versus the saturated calomel electrode reference potential. In contrast, modification with Zn reduced the for- mic acid formation efficiency but enhanced the alcohol formation efficiency. Finally, modification with Au suppressed the selectivity toward the formation of both formic acid and alcohols.
基金The authors are grateful for the financial supports from the National Natural Science Foundation of China(No.51974369)NSFC-STINT(No.52111530192)+1 种基金Postgraduate Research Innovation Project of Central South University,China(No.2019zzts244)the Open Sharing Fund for the Large-scale Instruments and Equipments of Central South University,China(No.CSUZC202029).
文摘Cyclic metallurgical process for separation and recovery of Cr from vanadium precipitated solution by precipitation with PbCO_(3)and leaching with Na_(2)CO_(3)was investigated.The concentration of Cr residue in the solution decreases from 2.360 to 0.001 g/L by adding PbCO_(3)into vanadium precipitated solution according to Pb/Cr molar ratio of 2.5,adjusting the pH to 3.0 and stirring for 180 min at 30℃.Then,the precipitates were leached with hot Na_(2)CO_(3)solution to obtain leaching solution containing Na_(2)CrO_(4)and leaching residue containing PbCO_(3).The leaching efficiency of Cr reaches 96.43%by adding the precipitates into 0.5 mol/L Na_(2)CO_(3)solution with the mass ratio of liquid to solid(L/S)of 10:1 mL/g and stirring for 60 min under pH 9.5 at 70℃.After filtration,leaching residue is reused in Cr precipitation and leaching solution is used to circularly leach the Cr precipitates until Na_(2)CrO_(4)approaches the saturation.Finally,the product of Na_(2)CrO_(4)·4H_(2)O is obtained by evaporation and crystallization of leaching solution.
基金the National Natural Science Foundation of China(21503096,21407067)the Natural Science Foundation of Jiangsu Province(BK20140506)~~
文摘Porous C‐I codoped carbon nitride materials were synthesized by in‐situ codoping with iodized ionic liquid followed by post‐thermal treatment in air.The effects of doping content of C‐I codoping with different amounts of ionic liquid on the structural,optical and photocatalytic properties of the samples were investigated.Characterization results show that more compact interlayer sacking can be achieved by post‐thermal treatment.Combined with C‐I codoping by insertion of ionic liquids,much enlarged surface area but optimized sp2 conjugated heterocyclic structure can be found in the catalysts.Optical and energy band analysis results evidence that the light absorptions especially in visible light region are significantly improved.Although the band gap of porous C‐I codoped samples enlarge because of the generation of porous,the negatively shifted conduction band position thermodynamically supplies stronger motivation for water reduction.Photoelectricity tests reveal that the photo‐induced electron density was increased after C‐I codoping modification.Also,the recombination rate of electron‐hole pairs is remarkably inhibited.The catalysts with moderate C‐I codoing content perform sharply enhanced photocatalytic H2 evolution activity under visible light irradiation.A H2 evolution rate of 168.2μmol/h was achieved and it was more than 9.8 times higher than pristine carbon nitride.This study demonstrates a novel non‐metal doping strategy for synthesis and optimization of polymer semiconductor with gratifying photocatalytic H2 evolution performance from water hydrolysis.
文摘The study has assessed the denitrification performance of fermented and dark-fermented biosolids as external carbon sources using lab-scaled Sequencing Batch Reactors (SBRs). This was done by adding fermented and dark-fermented biosolids into anoxic zones of two SBRs, and then assessing the change of effluent characteristics comparing to before adding and to a third controlled reactor. The results showed that by adding 150-170 mg rbCOD/L of either of the selected fermented biosolids, almost complete denitrification could be reached for tested SBRs (reduced from initial -20 mg NO3/L to 〈 1 mg NO3/L). Finally, the experiment also found that the impact of NI-I4 components of fermented and dark-fermented biosolids onto the final effluent were much lesser than expected, where only less than 2.5 mg NH4/L were detected in the effluent, much lower than the added 5.0-5.7 mg/L.