This study was to analyze the mineral elements in famous tea varieties in Sichuan Province. Eighteen mineral elements in the samples of 13 famous tea varieties in Sichuan Province were measured via related instruments...This study was to analyze the mineral elements in famous tea varieties in Sichuan Province. Eighteen mineral elements in the samples of 13 famous tea varieties in Sichuan Province were measured via related instruments. The results showed, of all the 18 measured samples, that the contents of K, P, S, Ca and Mg were relatively higher（ 〉1 500 mg/kg） in famous tea varieties in Sichuan Province, while those of Ba, Cr, V, Co and Se were relatively lower（ 〈 10 mg/kg） ; compared to common green tea, the famous tea varieties in Sichuan Province contained higher contents of K, Zn, P, Na, Ni, Cu, S, Se and Co（0.38% -115.65% higher than that in common green tea）, and lower contents of Mg, Mn, AI, Ca, V, Rb, Fe and Cr（7.20% -46.67% lower than that in common green tea）; of the 13 tested tea varieties, Hongyanyingchun, Yongchuanxiuya and Qingchengxueya were rich in mineral elements, while Yuchengyunwu and Yuqiancha lacked in mineral elements. The re- suits show that Hongyanyingchun, Yongchuanxiuya and Qingchengxueya are the elites in the famous tea varieties in Sichuan Province.展开更多
To understand the mineral elements in different varieties of tea （ Camellia sinensis）, 17 mineral elements in eight tea varieties including Yunnan Dayezhong, No. 43 Longjing and No. 6 Zaobaijian, were measured. The ...To understand the mineral elements in different varieties of tea （ Camellia sinensis）, 17 mineral elements in eight tea varieties including Yunnan Dayezhong, No. 43 Longjing and No. 6 Zaobaijian, were measured. The results showed that nine elements, such as P, K, Ba, Mn, Cu, were significantly different among varieties, others did not. Black tea varieties usually contain high contents of Cu and K. As a conclusion, mineral elements should be extensively considered in breeding tea varieties.展开更多
An electrochemically reduced graphene oxide sample, ERGO_0.8v, was prepared by electrochemical reduction of graphene oxide （GO） at -0.8 V, which shows unique electrocatalytic activity toward tetracycline （TTC） det...An electrochemically reduced graphene oxide sample, ERGO_0.8v, was prepared by electrochemical reduction of graphene oxide （GO） at -0.8 V, which shows unique electrocatalytic activity toward tetracycline （TTC） detection compared to the ERGO-12v （GO applied to a negative potential of-1.2 V）, GO, chemically reduced GO （CRGO）-modified glassy carbon electrode （GC） and bare GC electrodes. The redox peaks of TTC on an ERGO-0.8v-modifled glass carbon electrode （GC/ERGO-0.8v） were within 0-0.5 V in a pH 3.0 buffer solution with the oxidation peak current correlating well with TTC concentration over a wide range from 0.1 to 160 mg/L Physical characterizations with Fourier transform infrared （FT-IR）, Raman, and X-ray photoelectron spectroscopies （XPS） demonstrated that the oxygen-containing functional groups on GO diminished after the electrochemical reduction at -0.8 V, yet still existed in large amounts, and the defect density changed as new sp2 domains were formed. These changes demonstrated that this adjustment in the number of oxygen-containing groups might be the main factor affecting the electrocatalytic behavior of ERGO. Additionally, the defect density and sp2 domains also exert a profound influence on this behavior. A possible mechanism for the TTC redox reaction at the GC/ERGO-0.8v electrode is also presented. This work suggests that the electrochemical reduction is an effective method to establish new catalytic activities of GO by setting appropriate parameters.展开更多
The photocatalytic activity of cobalt octakis（butylthio） porphyrazine（CoPz（BuS）8） was assessed through photodegradation of the dye rhodamine B（RhB） in water under irradiation with a Xe lamp and aerated conditi...The photocatalytic activity of cobalt octakis（butylthio） porphyrazine（CoPz（BuS）8） was assessed through photodegradation of the dye rhodamine B（RhB） in water under irradiation with a Xe lamp and aerated conditions.The photocatalytic activity of CoPz（BuS）8 loaded on Al2O3 or SiO2@Fe3O4nanoparticles or coordinated with an axial azide ligand was also investigated.The results demonstrated that the photocatalytic activity of CoPz（BuS）8 loaded on Al2O3 was higher than that loaded on SiO2@Fe3O4.The kinetic curves of RhB degradation in aqueous solutions at different pH indicated the pseudo first-order kinetics of the reaction.The highest degradation rate for CoPz（BuS）8 loaded Al2O3 at pH = 4 after 160 min was 84.6%.However,the advantages of easier separation and recycling as well as the ability to terminate the reaction at any time for the CoPz（BuS）8 loaded SiO2@Fe3O4 cannot be ignored.When electron-rich NaN3 was coordinated with CoPz（BuS）8 as an axial ligand and loaded on Al2O3,the resulting catalyst produced more active oxygen species such as O2^- and HO· to promote the quicker degradation of RhB than that by the other catalysts.For the N3-coordinated CoPz（BuS）8 loaded on Al2O3,the reactions at pH = 4 and 7 distinctly deviated from first-order kinetics,and the degradation rate reached 77.6%after 80 min at pH = 4.展开更多
Based on the results of field trials and soil and plant measurements, the available silicon contents ofpaddy soils, their relations with the SiO_2 content of rice plant, the relationships between rice yield on theone ...Based on the results of field trials and soil and plant measurements, the available silicon contents ofpaddy soils, their relations with the SiO_2 content of rice plant, the relationships between rice yield on theone hand and the SiO_2 content and SiO_2/N ratio of rice plant on the other, the effects of silicon on riceyield and resistance to diseases and pests and the effective conditions and causes for increasing rice yield inSichuan Basin are expounded in the present paper. The study results show that about one half of the paddysoils developed from yellow soil, purple soil, alluvial soil, etc. in Sichuan Province were insufficient in siliconsupply. Critical values for silicon fertilization were 98 mg kg￣(-1) available Si in the paddy soils and < 112.8gkg￣(-1) SiO_2 in the rice plants. A SiO_2 content of rice plant over 121.6g kg￣(-1) and a SiO_2/N ratio maintainedat about 12 were required for gaining a rice yield of 7500 kg ha￣(-1). The yield increase by silicon fertilizationwas due to the improvement of silicon nutrition in rice plants and the balance of SiO_2/N ratio, and the reasonfor enhanced resistance to diseases and pests was concerned with the inhibition of luxury N absorption andthe raising of plant SiO_2/N ratio. Silicon fertilization tended to balance the uptake of N, P and K by riceplant .展开更多
Two spherically symmetric non-singular black hole solutions in Moiler tetrad theory of gravitation have been obtained. Although the two solutions have the same form of metric （spherically symmetric nonsingular black ...Two spherically symmetric non-singular black hole solutions in Moiler tetrad theory of gravitation have been obtained. Although the two solutions have the same form of metric （spherically symmetric nonsingular black hole）, their energy contents are different. We use another method given by Gibbons and Hawking to calculate the energy content of these solutions. We also obtained different value of energy. Study the requirements of a satisfactory energymomentum complex given by Moiler we find that the second solution, which behaves as 1/√r, is not transformed as a four-vector under Lorentz transformation.展开更多
Investigation of phosphorus (P) sorption-desorption characteristics of drainage ditch sediments is important for better understanding on sediment P transport behaviors in ditches. Surface ditch sediment samples were c...Investigation of phosphorus (P) sorption-desorption characteristics of drainage ditch sediments is important for better understanding on sediment P transport behaviors in ditches. Surface ditch sediment samples were collected from headwater sub-catchment of forestland, sloping cropland, paddy field, and residential area in a representative catchment in the central Sichuan Basin. These sediment samples were used for determination of P sorption-desorption characteristics by a batch equilibrium technique. Results showed that the maximum P sorption capacities (Qm) in the sediments ranged from 159.7 to 263.7 mg/kg, while higher Qm were observed in the ditch sediments from the paddy fields. The Qm was significantly and positively correlated with oxalate-extractable Fe and Al oxides (r=0.97 and 0.98, p < 0.01), clay fraction (r = 0.78, p < 0.05) and organic matter (r = 0.95, p < 0.01). Sediment pH, clay and organic matter influenced the P sorption through amorphous Fe and Al oxides. CaCO3 content was negatively correlated with the Qm (r = -0.83, p < 0.05), implying that saturated CaCO3 (> 50 g/kg) would not increase P sorption capacity in the ditch sediments. The ditch sediments featured a linear desorption curve, suggesting that P release risk would be enhanced with the increase of the P adsorption. The P desorption rate was positively correlated with Olsen P (r = 0.94, p < 0.01), but negatively related to the fine particle-size fractions (r = -0.92, p < 0.01), the sum of the amorphous Fe and Al oxides (r = -0.67, p < 0.05) and the P sorption capacity (r = -0.59, p < 0.05). The ditch sediments from residential area had a higher P release risk than that from the other ditches of forestland, sloping cropland and paddy field. The P sorption index (PSI) derived from single-point measurement was significantly correlated with the P sorption capacity (r = 0.99, p < 0.01), and could be used for estimating Qm as 1.64 times PSI plus 24.0 (Qm = 1.64 PSI + 24.0) for similar sediments with highly calcareous soils and sediments. Ditch cleaning and sediment removal for the ditch in residential area were recommended in this area to reduce the P release risk.展开更多
Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loadin...Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loading Fe-SA catalysts by a simple procedure remains challenging.Herein,we report a high-loading(7.5 wt%)Fe-SA/NPC catalyst prepared by carbon-assisted pyrolysis of metal complexes.Both the nitrogen-doped porous carbon(NPC)support with high specific surface area and ο-phenylenediamine(o-PD)play key roles role in the preparation of high-loading Fe-SA/NPC catalysts.The results of X-ray photoelectron spectroscopy,high-angle annular dark-field scanning transmission electron microscopy,and X-ray absorption fine structure spectroscopy experiments show that the Fe atoms are anchored on the carbon carriers in a single-atom site configuration and coordinated with four of the doped nitrogen atoms of the carbon substrates(Fe-N_(4)).The activities of the Fe-SA/NPC catalysts in the oxygen reduction reaction increased with increasing iron loading.The optimized 250Fe-SA/NPC-800 catalyst exhibited an onset potential 0.97 V of and a half-wave potential of 0.85 V.Our study provides a simple approach for the large-scale synthesis of high-loading single-atom catalysts.展开更多
The unsaturated undisturbed quaternary system middle pleistocene loess,a typical unsaturated soil,often occurs in the implementation of western development strategy.To obtain the shearing strength characteristics of t...The unsaturated undisturbed quaternary system middle pleistocene loess,a typical unsaturated soil,often occurs in the implementation of western development strategy.To obtain the shearing strength characteristics of this unsaturated undisturbed loess,based on the analysis of mineral composition,the triaxial shear test of undisturbed quaternary system middle pleistocene loess under different moisture contents is conducted with the specialized triaxial instrument for unsaturated soil.The test results show that the mainly mineral composition of undisturbed quaternary system middle pleistocene loess is quartz and albite.Under the same confining pressure,the matric suction increases with the decrease of moisture content.The smaller the moisture content,the larger the matric suction;the higher the moisture content,the lower the matric suction.Under the same moisture content,the matric suction increases with the confining pressure and reaches a maximum when the confining pressure is 100 kPa,and then decreases with the increase of confining pressure.This phenomenon is closely related to the grain contact tightness of soil mass under high confining pressure.According to the triaxial test of loess,the sample of loess experiences 4 stages from loading to failure:1) compaction stage;2) compression stage;3) microcrack developing stage;4) shear failure stage.The test sample is of brittle failure(weak softening)under low moisture content and confining pressure.With the decrease of matric suction and the increase of consolidated confining pressure,the stress-strain curve changes from softening type to ideal plastic type.In the shearing strength parameters of unsaturated undisturbed loess,the influence of moisture content on internal friction angle is small,but that on cohesive force is obvious.Therefore,the shearing strength of unsaturated undisturbed loess is higher than that of saturated undisturbed loess and varies with the moisture content.展开更多
文摘This study was to analyze the mineral elements in famous tea varieties in Sichuan Province. Eighteen mineral elements in the samples of 13 famous tea varieties in Sichuan Province were measured via related instruments. The results showed, of all the 18 measured samples, that the contents of K, P, S, Ca and Mg were relatively higher（ 〉1 500 mg/kg） in famous tea varieties in Sichuan Province, while those of Ba, Cr, V, Co and Se were relatively lower（ 〈 10 mg/kg） ; compared to common green tea, the famous tea varieties in Sichuan Province contained higher contents of K, Zn, P, Na, Ni, Cu, S, Se and Co（0.38% -115.65% higher than that in common green tea）, and lower contents of Mg, Mn, AI, Ca, V, Rb, Fe and Cr（7.20% -46.67% lower than that in common green tea）; of the 13 tested tea varieties, Hongyanyingchun, Yongchuanxiuya and Qingchengxueya were rich in mineral elements, while Yuchengyunwu and Yuqiancha lacked in mineral elements. The re- suits show that Hongyanyingchun, Yongchuanxiuya and Qingchengxueya are the elites in the famous tea varieties in Sichuan Province.
基金Supported by Applied Basic Research Development Program of Si-chuanKey Scientific and Technological Project of Tea Breeding Pro-ject in Sichuan Province during Eleventh Five-year Plan~~
文摘To understand the mineral elements in different varieties of tea （ Camellia sinensis）, 17 mineral elements in eight tea varieties including Yunnan Dayezhong, No. 43 Longjing and No. 6 Zaobaijian, were measured. The results showed that nine elements, such as P, K, Ba, Mn, Cu, were significantly different among varieties, others did not. Black tea varieties usually contain high contents of Cu and K. As a conclusion, mineral elements should be extensively considered in breeding tea varieties.
基金supported by the National Natural Science Foundation of China(21007033)the Fundamental Research Funds of Shandong University(2015JC017)~~
文摘An electrochemically reduced graphene oxide sample, ERGO_0.8v, was prepared by electrochemical reduction of graphene oxide （GO） at -0.8 V, which shows unique electrocatalytic activity toward tetracycline （TTC） detection compared to the ERGO-12v （GO applied to a negative potential of-1.2 V）, GO, chemically reduced GO （CRGO）-modified glassy carbon electrode （GC） and bare GC electrodes. The redox peaks of TTC on an ERGO-0.8v-modifled glass carbon electrode （GC/ERGO-0.8v） were within 0-0.5 V in a pH 3.0 buffer solution with the oxidation peak current correlating well with TTC concentration over a wide range from 0.1 to 160 mg/L Physical characterizations with Fourier transform infrared （FT-IR）, Raman, and X-ray photoelectron spectroscopies （XPS） demonstrated that the oxygen-containing functional groups on GO diminished after the electrochemical reduction at -0.8 V, yet still existed in large amounts, and the defect density changed as new sp2 domains were formed. These changes demonstrated that this adjustment in the number of oxygen-containing groups might be the main factor affecting the electrocatalytic behavior of ERGO. Additionally, the defect density and sp2 domains also exert a profound influence on this behavior. A possible mechanism for the TTC redox reaction at the GC/ERGO-0.8v electrode is also presented. This work suggests that the electrochemical reduction is an effective method to establish new catalytic activities of GO by setting appropriate parameters.
基金supported by National Natural Science Foundation of China (20977115, 21272281)Natural Science Foundation of Hubei Province (2014CFB919)the Science and Technology Plan Innovation Team of Wuhan City (2015070504020220)~~
文摘The photocatalytic activity of cobalt octakis（butylthio） porphyrazine（CoPz（BuS）8） was assessed through photodegradation of the dye rhodamine B（RhB） in water under irradiation with a Xe lamp and aerated conditions.The photocatalytic activity of CoPz（BuS）8 loaded on Al2O3 or SiO2@Fe3O4nanoparticles or coordinated with an axial azide ligand was also investigated.The results demonstrated that the photocatalytic activity of CoPz（BuS）8 loaded on Al2O3 was higher than that loaded on SiO2@Fe3O4.The kinetic curves of RhB degradation in aqueous solutions at different pH indicated the pseudo first-order kinetics of the reaction.The highest degradation rate for CoPz（BuS）8 loaded Al2O3 at pH = 4 after 160 min was 84.6%.However,the advantages of easier separation and recycling as well as the ability to terminate the reaction at any time for the CoPz（BuS）8 loaded SiO2@Fe3O4 cannot be ignored.When electron-rich NaN3 was coordinated with CoPz（BuS）8 as an axial ligand and loaded on Al2O3,the resulting catalyst produced more active oxygen species such as O2^- and HO· to promote the quicker degradation of RhB than that by the other catalysts.For the N3-coordinated CoPz（BuS）8 loaded on Al2O3,the reactions at pH = 4 and 7 distinctly deviated from first-order kinetics,and the degradation rate reached 77.6%after 80 min at pH = 4.
文摘Based on the results of field trials and soil and plant measurements, the available silicon contents ofpaddy soils, their relations with the SiO_2 content of rice plant, the relationships between rice yield on theone hand and the SiO_2 content and SiO_2/N ratio of rice plant on the other, the effects of silicon on riceyield and resistance to diseases and pests and the effective conditions and causes for increasing rice yield inSichuan Basin are expounded in the present paper. The study results show that about one half of the paddysoils developed from yellow soil, purple soil, alluvial soil, etc. in Sichuan Province were insufficient in siliconsupply. Critical values for silicon fertilization were 98 mg kg￣(-1) available Si in the paddy soils and < 112.8gkg￣(-1) SiO_2 in the rice plants. A SiO_2 content of rice plant over 121.6g kg￣(-1) and a SiO_2/N ratio maintainedat about 12 were required for gaining a rice yield of 7500 kg ha￣(-1). The yield increase by silicon fertilizationwas due to the improvement of silicon nutrition in rice plants and the balance of SiO_2/N ratio, and the reasonfor enhanced resistance to diseases and pests was concerned with the inhibition of luxury N absorption andthe raising of plant SiO_2/N ratio. Silicon fertilization tended to balance the uptake of N, P and K by riceplant .
文摘Two spherically symmetric non-singular black hole solutions in Moiler tetrad theory of gravitation have been obtained. Although the two solutions have the same form of metric （spherically symmetric nonsingular black hole）, their energy contents are different. We use another method given by Gibbons and Hawking to calculate the energy content of these solutions. We also obtained different value of energy. Study the requirements of a satisfactory energymomentum complex given by Moiler we find that the second solution, which behaves as 1/√r, is not transformed as a four-vector under Lorentz transformation.
基金supported jointly by the CAS Action Plan for the Development of Western China (Grant No. KZCX2-XB3-09)the Key Project in the National Science and Technology Pillar Program of China (Grant No. 2011BAD31B03)
文摘Investigation of phosphorus (P) sorption-desorption characteristics of drainage ditch sediments is important for better understanding on sediment P transport behaviors in ditches. Surface ditch sediment samples were collected from headwater sub-catchment of forestland, sloping cropland, paddy field, and residential area in a representative catchment in the central Sichuan Basin. These sediment samples were used for determination of P sorption-desorption characteristics by a batch equilibrium technique. Results showed that the maximum P sorption capacities (Qm) in the sediments ranged from 159.7 to 263.7 mg/kg, while higher Qm were observed in the ditch sediments from the paddy fields. The Qm was significantly and positively correlated with oxalate-extractable Fe and Al oxides (r=0.97 and 0.98, p < 0.01), clay fraction (r = 0.78, p < 0.05) and organic matter (r = 0.95, p < 0.01). Sediment pH, clay and organic matter influenced the P sorption through amorphous Fe and Al oxides. CaCO3 content was negatively correlated with the Qm (r = -0.83, p < 0.05), implying that saturated CaCO3 (> 50 g/kg) would not increase P sorption capacity in the ditch sediments. The ditch sediments featured a linear desorption curve, suggesting that P release risk would be enhanced with the increase of the P adsorption. The P desorption rate was positively correlated with Olsen P (r = 0.94, p < 0.01), but negatively related to the fine particle-size fractions (r = -0.92, p < 0.01), the sum of the amorphous Fe and Al oxides (r = -0.67, p < 0.05) and the P sorption capacity (r = -0.59, p < 0.05). The ditch sediments from residential area had a higher P release risk than that from the other ditches of forestland, sloping cropland and paddy field. The P sorption index (PSI) derived from single-point measurement was significantly correlated with the P sorption capacity (r = 0.99, p < 0.01), and could be used for estimating Qm as 1.64 times PSI plus 24.0 (Qm = 1.64 PSI + 24.0) for similar sediments with highly calcareous soils and sediments. Ditch cleaning and sediment removal for the ditch in residential area were recommended in this area to reduce the P release risk.
文摘Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loading Fe-SA catalysts by a simple procedure remains challenging.Herein,we report a high-loading(7.5 wt%)Fe-SA/NPC catalyst prepared by carbon-assisted pyrolysis of metal complexes.Both the nitrogen-doped porous carbon(NPC)support with high specific surface area and ο-phenylenediamine(o-PD)play key roles role in the preparation of high-loading Fe-SA/NPC catalysts.The results of X-ray photoelectron spectroscopy,high-angle annular dark-field scanning transmission electron microscopy,and X-ray absorption fine structure spectroscopy experiments show that the Fe atoms are anchored on the carbon carriers in a single-atom site configuration and coordinated with four of the doped nitrogen atoms of the carbon substrates(Fe-N_(4)).The activities of the Fe-SA/NPC catalysts in the oxygen reduction reaction increased with increasing iron loading.The optimized 250Fe-SA/NPC-800 catalyst exhibited an onset potential 0.97 V of and a half-wave potential of 0.85 V.Our study provides a simple approach for the large-scale synthesis of high-loading single-atom catalysts.
基金Project(51108485)supported by the National Natural Science Foundation of ChinaProject(20110191120033)supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China+1 种基金Projects(106112013CDJZR200001,CDJZR12200012)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(cstc2013jcyjA30005)supported by the Natural Science Foundation of Chongqing,China
文摘The unsaturated undisturbed quaternary system middle pleistocene loess,a typical unsaturated soil,often occurs in the implementation of western development strategy.To obtain the shearing strength characteristics of this unsaturated undisturbed loess,based on the analysis of mineral composition,the triaxial shear test of undisturbed quaternary system middle pleistocene loess under different moisture contents is conducted with the specialized triaxial instrument for unsaturated soil.The test results show that the mainly mineral composition of undisturbed quaternary system middle pleistocene loess is quartz and albite.Under the same confining pressure,the matric suction increases with the decrease of moisture content.The smaller the moisture content,the larger the matric suction;the higher the moisture content,the lower the matric suction.Under the same moisture content,the matric suction increases with the confining pressure and reaches a maximum when the confining pressure is 100 kPa,and then decreases with the increase of confining pressure.This phenomenon is closely related to the grain contact tightness of soil mass under high confining pressure.According to the triaxial test of loess,the sample of loess experiences 4 stages from loading to failure:1) compaction stage;2) compression stage;3) microcrack developing stage;4) shear failure stage.The test sample is of brittle failure(weak softening)under low moisture content and confining pressure.With the decrease of matric suction and the increase of consolidated confining pressure,the stress-strain curve changes from softening type to ideal plastic type.In the shearing strength parameters of unsaturated undisturbed loess,the influence of moisture content on internal friction angle is small,but that on cohesive force is obvious.Therefore,the shearing strength of unsaturated undisturbed loess is higher than that of saturated undisturbed loess and varies with the moisture content.
