This paper describes a new method for producing TiCl4 by chloridizing materials of high content CaO and MgO, in which a combined fluidized bed is used as a reactor to avoid agglomeration between particles caused by mo...This paper describes a new method for producing TiCl4 by chloridizing materials of high content CaO and MgO, in which a combined fluidized bed is used as a reactor to avoid agglomeration between particles caused by molten CaCl2 and MgCl2. The combined fluidized bed consists of at least a riser tube and a semi-circulating fluidized bed. Two kinds of high titanium slag, in which the total mass content of CaO and MgO is 2.03% and 9.09% respectively, are employed to examine the anti-agglomeration effect and the conversion of the materials when the temperature ranges are between 923.15K and 1073.15K, gas apparent velocity 0.7--1.1m.s-1, and inlet amount of solid materials is 4.6-7.0kg·h^-1. It is found that the anti-agglomeration effect in the combined fluidized bed is satisfactory and the new method can achieve a TiCl4 production capacity of 14.0-75.4t·m^-2·d^-1 in relation to 25.0-- 40.0t·m^-2·d^-1 from the conventional bubble bed. Furthermore, low-temperature chloridization, for example, at 923K or 973K, can also be used to produce TiCl4 and avoid agglomeration.展开更多
Exo-tetrahydrodicyclopentadiene (exo-TCD) is an important high-energy fuel. Silicotungstic acid (SiW) immobilized on H-type β zeolite (Hβ) at room temperature were used to prepare the Hβ zeolite catalysts wit...Exo-tetrahydrodicyclopentadiene (exo-TCD) is an important high-energy fuel. Silicotungstic acid (SiW) immobilized on H-type β zeolite (Hβ) at room temperature were used to prepare the Hβ zeolite catalysts with different SiW contents. Catalytic performances of the catalysts were investigated during the preparation of exo-TCD via isomerization of endo-tetrahydrodicyclopentadiene (endo-TCD). The properties of catalysts were characterized by XRD, temperature pro- grammed desorption of ammonia (NHa-TPD), FT-IR, and N2-adsorption techniques. SiW was highly dispersed on the surface of Hβ zeolite, and the 10% SiW/Hβ zeolite catalyst had the highest amount of weak acidity among all SiW/Hβ zeolite catalysts. The influence of different factors on isomerization reaction was investigated. At a reaction temperature of 240 ℃, a n(cyclohexane) / n(endo-TCD) ratio of 10, a m(catalyst)/m(endo-TCD) ratio of 0.3, an initial pressure of 1.0 MPa, and a reaction time of 1.5 h in the presence of 10% SiW/Hβ catalyst calcined at 400 ℃, the conversion of endo-TCD reached up to 92.0%, with the yield of exo-TCD equating to 51.0%.展开更多
A solid state synthesis of ultrafine/nanocrystalline WC-10Co composite powders was reported from WO3 , Co3O4 and carbon powders after reduction and carburization at relatively low temperatures in a short time under pu...A solid state synthesis of ultrafine/nanocrystalline WC-10Co composite powders was reported from WO3 , Co3O4 and carbon powders after reduction and carburization at relatively low temperatures in a short time under pure H2 atmosphere. The effects of ball milling time and reaction temperature on the preparation of ultrafine/nanocrystalline WC-Co composite powders were studied using X-ray diffraction and scanning electron microscope (SEM). The results show that fine mixed oxide powders (WO3 , Co3O4 and carbon powders) can be obtained by long time ball milling. Increasing the reaction temperature can decrease the formation of Co3W3C and graphite phases and increase the WC crystallite size. Long-time ball milling and high reaction temperature are favorable to obtain fine and pure composite powders consisting of nanocrystalline WC from WO3 , Co3O4 and carbon powders.展开更多
This article introduces the latest advances achieved by the Sichuan Vinylon Plant in the fields of maintaining the stable operation of acetylene reactors, extending the operating cycle of production equipment, adaptat...This article introduces the latest advances achieved by the Sichuan Vinylon Plant in the fields of maintaining the stable operation of acetylene reactors, extending the operating cycle of production equipment, adaptation to the composition of different natural gas feeds and enlarged scale of production facilities. And a forward-looking idea on next step of technology for manufacture of acetylene from natural gas has been set forth.展开更多
In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction (XRD), X-ray fluorescence (XR...In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), Brunauer-Emmett-Teller (BET) and scanning electron microscopy (SEM) methods. It is found that Fe and Ce intercalate into the silicate layers of bentonite successfully. Tetracycline was removed by heterogeneous photo-Fenton reaction using the catalyst in this work. The effects of different reaction systems, hydrogen peroxide concentration, initial pH, catalyst dosage, UV power and introduction of different anions on degradation were investigated in details. The stability of catalyst was investigated through recycling experiment. The results show that removal rate of tetracycline is 98.13% under the conditions of 15 mmol/L H202, 0.50 g/L catalyst dosage, initial pH 3.0, 11 W UV lamp power and 60 min reaction time. However, the removal rate decreases after adding some anions. The hydroxyl radical plays an important role in heterogeneous photo-assisted Fenton degradation of tetracycline. The catalyst is very stable and can be recycled many times.展开更多
A novel deterministic joint remote preparation scheme of arbitrary four-particle genuine entangled state from one sender to either of two receivers is proposed. Two three-particle Green-Horne-Zeilinger (GHZ) states ...A novel deterministic joint remote preparation scheme of arbitrary four-particle genuine entangled state from one sender to either of two receivers is proposed. Two three-particle Green-Horne-Zeilinger (GHZ) states and one four-particle GHZ state are used as the quantum channel. The presented scheme is realized through orthogonal projective mea-surement of the Hadamard transferred basis and recovery operation Ulijk). Some useful and general measurement bases have been con-structed. The classical communication cost of the presented scheme is also calculated. Our analysis confirms the feasibility and validity of the proposed method, and shows that it has a 100% probability of success in preparation of the target quantum state.展开更多
We report a hybrid energy cell that can simultaneously or individually harvest wind, solar, and chemical energies to power some electronic devices. By utilizing the wind driven relative rotations between a polytetrafl...We report a hybrid energy cell that can simultaneously or individually harvest wind, solar, and chemical energies to power some electronic devices. By utilizing the wind driven relative rotations between a polytetrafluoroethylene film and an etched A1 film attached on two acrylic tubes, the fabricated triboelectric nanogenerator (TENG) can deliver an open-circuit voltage of about 90 V, a short-circuit current density of about 0.5 mA/m2, and a maximum power density of 16 mW/m2, which is capable of directly lighting up 20 blue light- emitting-diodes (LEDs). By integrating a TENG, a solar cell, and an electrochemical cell, a hybrid energy cell has been fabricated to simultaneously scavenge three different types of energies. As compared with the individual energy units, the hybrid energy cell exhibited much better performance in charging a capacitor. Moreover, we also demonstrated that the hybrid energies generated can be stored in a Li-ion battery for powering a commercial wind speed sensor and a temperature sensor. This work represents significant progress toward practical applications of hybrid energy cells, providing potential solutions for simul- taneously scavenging wind, solar, and chemical energies.展开更多
An inexpensive material, i.e., tetranuclear zinc(Ⅱ) complex, (Zn40(A/D)6) [AID = 7-azaindolate], was utilized as a cathode buffer in organic photovoltaic (OPV) devices, leading to the improvement of device pe...An inexpensive material, i.e., tetranuclear zinc(Ⅱ) complex, (Zn40(A/D)6) [AID = 7-azaindolate], was utilized as a cathode buffer in organic photovoltaic (OPV) devices, leading to the improvement of device performance. Compared to OPV devices based on a conventional cathode buffer of TPBi (1,3,5-tris(2-N-phenylbenzimidazolyl)benzene), although the freshly prepared devices showed similar performance, when heated to a series of high temperatures under air, the short circuit current and the open circuit voltage of the Zn40(AID)6 devices dropped more slowly, indicating the superiority of using Zn40(AID)6 as a cathode buffer over TPBi in OPV devices.展开更多
基金Supported by the National Natural Science Foundation of China (No.20306030) and China Postdoctoral Science Foundation (No.2003033240).
文摘This paper describes a new method for producing TiCl4 by chloridizing materials of high content CaO and MgO, in which a combined fluidized bed is used as a reactor to avoid agglomeration between particles caused by molten CaCl2 and MgCl2. The combined fluidized bed consists of at least a riser tube and a semi-circulating fluidized bed. Two kinds of high titanium slag, in which the total mass content of CaO and MgO is 2.03% and 9.09% respectively, are employed to examine the anti-agglomeration effect and the conversion of the materials when the temperature ranges are between 923.15K and 1073.15K, gas apparent velocity 0.7--1.1m.s-1, and inlet amount of solid materials is 4.6-7.0kg·h^-1. It is found that the anti-agglomeration effect in the combined fluidized bed is satisfactory and the new method can achieve a TiCl4 production capacity of 14.0-75.4t·m^-2·d^-1 in relation to 25.0-- 40.0t·m^-2·d^-1 from the conventional bubble bed. Furthermore, low-temperature chloridization, for example, at 923K or 973K, can also be used to produce TiCl4 and avoid agglomeration.
文摘Exo-tetrahydrodicyclopentadiene (exo-TCD) is an important high-energy fuel. Silicotungstic acid (SiW) immobilized on H-type β zeolite (Hβ) at room temperature were used to prepare the Hβ zeolite catalysts with different SiW contents. Catalytic performances of the catalysts were investigated during the preparation of exo-TCD via isomerization of endo-tetrahydrodicyclopentadiene (endo-TCD). The properties of catalysts were characterized by XRD, temperature pro- grammed desorption of ammonia (NHa-TPD), FT-IR, and N2-adsorption techniques. SiW was highly dispersed on the surface of Hβ zeolite, and the 10% SiW/Hβ zeolite catalyst had the highest amount of weak acidity among all SiW/Hβ zeolite catalysts. The influence of different factors on isomerization reaction was investigated. At a reaction temperature of 240 ℃, a n(cyclohexane) / n(endo-TCD) ratio of 10, a m(catalyst)/m(endo-TCD) ratio of 0.3, an initial pressure of 1.0 MPa, and a reaction time of 1.5 h in the presence of 10% SiW/Hβ catalyst calcined at 400 ℃, the conversion of endo-TCD reached up to 92.0%, with the yield of exo-TCD equating to 51.0%.
基金Projects(50823006, 51021063, 51271152) supported by the National Natural Science Foundation of ChinaProject(NCET-10-0842)supported by the Program for New Century Excellent Talents in Universities of China
文摘A solid state synthesis of ultrafine/nanocrystalline WC-10Co composite powders was reported from WO3 , Co3O4 and carbon powders after reduction and carburization at relatively low temperatures in a short time under pure H2 atmosphere. The effects of ball milling time and reaction temperature on the preparation of ultrafine/nanocrystalline WC-Co composite powders were studied using X-ray diffraction and scanning electron microscope (SEM). The results show that fine mixed oxide powders (WO3 , Co3O4 and carbon powders) can be obtained by long time ball milling. Increasing the reaction temperature can decrease the formation of Co3W3C and graphite phases and increase the WC crystallite size. Long-time ball milling and high reaction temperature are favorable to obtain fine and pure composite powders consisting of nanocrystalline WC from WO3 , Co3O4 and carbon powders.
文摘This article introduces the latest advances achieved by the Sichuan Vinylon Plant in the fields of maintaining the stable operation of acetylene reactors, extending the operating cycle of production equipment, adaptation to the composition of different natural gas feeds and enlarged scale of production facilities. And a forward-looking idea on next step of technology for manufacture of acetylene from natural gas has been set forth.
基金Project(51004053)supported by National Natural Science Foundation of ChinaProject(2009J01033)supported by Natural Science Foundation of Fujian Province,China+2 种基金Project(3502Z20116008)supported by the Science and Technology Research Project of Xiamen City,ChinaProject(JA11146)supported by Program for Fostering Distinguished Young Scholars in University of Fujian Province,ChinaProject(2011B003)supported by the Foundation for Young Professors of Jimei University,China
文摘In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), Brunauer-Emmett-Teller (BET) and scanning electron microscopy (SEM) methods. It is found that Fe and Ce intercalate into the silicate layers of bentonite successfully. Tetracycline was removed by heterogeneous photo-Fenton reaction using the catalyst in this work. The effects of different reaction systems, hydrogen peroxide concentration, initial pH, catalyst dosage, UV power and introduction of different anions on degradation were investigated in details. The stability of catalyst was investigated through recycling experiment. The results show that removal rate of tetracycline is 98.13% under the conditions of 15 mmol/L H202, 0.50 g/L catalyst dosage, initial pH 3.0, 11 W UV lamp power and 60 min reaction time. However, the removal rate decreases after adding some anions. The hydroxyl radical plays an important role in heterogeneous photo-assisted Fenton degradation of tetracycline. The catalyst is very stable and can be recycled many times.
基金supported by the National Natural Science Foundation of China under Grants No. 61100205, No. 61100208the Project of the Fundamental Research Funds for the Central Universities under Grant No. 2013RC0307
文摘A novel deterministic joint remote preparation scheme of arbitrary four-particle genuine entangled state from one sender to either of two receivers is proposed. Two three-particle Green-Horne-Zeilinger (GHZ) states and one four-particle GHZ state are used as the quantum channel. The presented scheme is realized through orthogonal projective mea-surement of the Hadamard transferred basis and recovery operation Ulijk). Some useful and general measurement bases have been con-structed. The classical communication cost of the presented scheme is also calculated. Our analysis confirms the feasibility and validity of the proposed method, and shows that it has a 100% probability of success in preparation of the target quantum state.
文摘We report a hybrid energy cell that can simultaneously or individually harvest wind, solar, and chemical energies to power some electronic devices. By utilizing the wind driven relative rotations between a polytetrafluoroethylene film and an etched A1 film attached on two acrylic tubes, the fabricated triboelectric nanogenerator (TENG) can deliver an open-circuit voltage of about 90 V, a short-circuit current density of about 0.5 mA/m2, and a maximum power density of 16 mW/m2, which is capable of directly lighting up 20 blue light- emitting-diodes (LEDs). By integrating a TENG, a solar cell, and an electrochemical cell, a hybrid energy cell has been fabricated to simultaneously scavenge three different types of energies. As compared with the individual energy units, the hybrid energy cell exhibited much better performance in charging a capacitor. Moreover, we also demonstrated that the hybrid energies generated can be stored in a Li-ion battery for powering a commercial wind speed sensor and a temperature sensor. This work represents significant progress toward practical applications of hybrid energy cells, providing potential solutions for simul- taneously scavenging wind, solar, and chemical energies.
基金supported by the National Natural Science Foundation of China(20974046,61077021,61076016)New Century Excellent Talents funding from Ministry of Education in China(NCET-08-0697)National Basic Research Program of China(973 Program,2009CB930600)
文摘An inexpensive material, i.e., tetranuclear zinc(Ⅱ) complex, (Zn40(A/D)6) [AID = 7-azaindolate], was utilized as a cathode buffer in organic photovoltaic (OPV) devices, leading to the improvement of device performance. Compared to OPV devices based on a conventional cathode buffer of TPBi (1,3,5-tris(2-N-phenylbenzimidazolyl)benzene), although the freshly prepared devices showed similar performance, when heated to a series of high temperatures under air, the short circuit current and the open circuit voltage of the Zn40(AID)6 devices dropped more slowly, indicating the superiority of using Zn40(AID)6 as a cathode buffer over TPBi in OPV devices.