Aluminium alloy is one of the earliest and most widely used superplastic materials.The objective of this work is to review the scientific advances in superplastic Al alloys.Particularly,the emphasis is placed on the m...Aluminium alloy is one of the earliest and most widely used superplastic materials.The objective of this work is to review the scientific advances in superplastic Al alloys.Particularly,the emphasis is placed on the microstructural evolution and deformation mechanisms of Al alloys during superplastic deformation.The evolution of grain structure,texture,secondary phase,and cavities during superplastic flow in typical superplastic Al alloys is discussed in detail.The quantitative evaluation of different deformation mechanisms based on the focus ion beam(FIB)-assisted surface study provides new insights into the superplasticity of Al alloys.The main features,such as grain boundary sliding,intragranular dislocation slip,and diffusion creep can be observed intuitively and analyzed quantitatively.This study provides some reference for the research of superplastic deformation mechanism and the development of superplastic Al alloys.展开更多
In comparison to discrete descriptions of fracture process,the recently proposed phase field methodology averts the numerical tracking strategy of discontinuities in solids,which enables the numerical implement simpli...In comparison to discrete descriptions of fracture process,the recently proposed phase field methodology averts the numerical tracking strategy of discontinuities in solids,which enables the numerical implement simplification.An implicit finite element formulation based on the diffuse phase field is extended for stable and efficient analysis of complex dynamic fracture process in ductile solids.This exhibited formulation is shown to capture entire range of the characteristics of ductile material presenting J2-plasticity,embracing plasticization,cracks initiation,propagation,branching and merging while fulfilling the basic principle of thermodynamics.Herein,we implement a staggered time integration scheme of the dynamic elasto-plastic phase field method into the commercial finite element code.The numerical performance of the present advanced phase field model has been examined through several classic dynamic fracture benchmarks,and in all cases simulation results are in good agreement with the associated experimental data and other numerical results in previous literature.展开更多
The coupling effects of electrical pulse,temperature,strain rate,and strain on the flow behavior and plasticity of 5182-O aluminum alloy were investigated and characterized.The isothermal tensile test and electrically...The coupling effects of electrical pulse,temperature,strain rate,and strain on the flow behavior and plasticity of 5182-O aluminum alloy were investigated and characterized.The isothermal tensile test and electrically-assisted isothermal tensile test were performed at the same temperature,and three typical models were further embedded in ABAQUS/Explicit for numerical simulation to illustrate the electroplastic effect.The results show that electric pulse reduces the deformation resistance but enhances the elongation greatly.The calibration accuracy of the proposed modified Lim−Huh model for highly nonlinear and coupled dynamic hardening behavior is not much improved compared to the modified Kocks−Mecking model.Moreover,the artificial neural network model is very suitable to describe the macromechenical response of materials under the coupling effect of different variables.展开更多
A crystal plasticity finite element model was developed for the drawing deformation of pure copper micro wire,based on rate-dependent crystal plasticity theory.The impact of wire diameter compression ratio on the micr...A crystal plasticity finite element model was developed for the drawing deformation of pure copper micro wire,based on rate-dependent crystal plasticity theory.The impact of wire diameter compression ratio on the micro-mechanical deformation behavior during the wire drawing process was investigated.Results indicate that the internal deformation and slip of the drawn wire are unevenly distributed,forming distinct slip and non-slip zones.Additionally,horizontal strain concentration bands develop within the drawn wire.As the wire diameter compression ratio increases,the strength of the slip systems and the extent of slip zones inside the deformation zone also increase.However,the fluctuating stress state,induced by contact pressure and frictional stress,results in a rough and uneven wire surface and diminishes the stability of the drawing process.展开更多
Polyamide/polyethylene(PA/PE)microplastics were injected into soil containing sulfamethoxazole(SMX)to investigate their combined effects on SMX removal,soil enzyme activity,and microbial communities.The results show t...Polyamide/polyethylene(PA/PE)microplastics were injected into soil containing sulfamethoxazole(SMX)to investigate their combined effects on SMX removal,soil enzyme activity,and microbial communities.The results show that both PA and PE transiently increase SMX removal and inhibite the stimulation of microbial species diversity by SMX.The effect of PE is more significant.Meanwhile,PE combined with SMX increases the relative abundances of Actinobacteria and Pseudomonas,while PA combined with SMX decreases the relative abundances of Nocardioides and Streptomyces.In addition,PA/PE combined with SMX can increase dehydrogenase,urease,ammonia monooxygenase,and nitrate reductase activities in the soil while inhibiting the activity of laccase.Compared with PA combined with SMX,the activities of dehydrogenase,urease,ammonia monooxygenase,and laccase of PE combined with SMX increase by 9.82%,10.41%,8.07%,and 5.47%,while the activities of nitrate reductase and neutral phosphatase decrease by 1.47%and 6.78%.展开更多
The microstructures and hot tensile behaviors of ZK30 alloys subjected to single-and multi-pass friction stir processing(FSP)were systematically investigated.Following single-pass FSP(S-FSP),coarse grains underwent re...The microstructures and hot tensile behaviors of ZK30 alloys subjected to single-and multi-pass friction stir processing(FSP)were systematically investigated.Following single-pass FSP(S-FSP),coarse grains underwent refinement to 1−2μm,with a distinct basal texture emerging in the stir zone(SZ).Additionally,second-phase particles were fragmented,dispersed,and partially dissolved.Multi-pass FSP(M-FSP)further enhanced the homogeneity of the microstructure,reduced texture intensity differences,and decreased the fraction of second-phase particles by 50%.Both S-FSP and M-FSP SZs demonstrated superplasticity at strain rates below 1×10^(−3)s^(−1)and at temperatures of 250−350℃.The S-FSP SZ exhibited an elongation of 390%at 250℃and 1×10^(−4)s^(−1),while the M-FSP SZ achieved an elongation of 406%at 350℃and 1×10^(−3)s^(−1).The superplastic deformation of SZ was co-dominated by grain boundary sliding(GBS)and the solute-drag mechanism in S-FSP and mainly by GBS in M-FSP.展开更多
The microstructure and mechanical properties of ZK60 Mg alloy were investigated under different solution treatments and artificial aging conditions. When as-cast ZK60 alloy was solution treated at 400 ℃for 10 h and a...The microstructure and mechanical properties of ZK60 Mg alloy were investigated under different solution treatments and artificial aging conditions. When as-cast ZK60 alloy was solution treated at 400 ℃for 10 h and artificially aged at 150 ℃, the volume fraction of precipitates increased with the aging time up to 30 h. When the as-cast ZK60 alloy was solution treated at 400 ℃ for 10 h and artificially aged at 200 ℃ for 15 20 h, the volume fraction of precipitates reached a peak value. Tensile test at room temperature showed that a high density of the second phase precipitates was beneficial to improving the strength and elongation. Solution treatment at 400 ℃ for 10 h and artificial aging at 150 ℃ for 30 h is considered the optimum heat treatment condition to obtain a good combination of strength and ductility.展开更多
Warm tensile tests for aluminum alloy 7022 sheet are held at different temperatures and strain rates. The range of temperature is 293-773 K and that of the strain rate is 0. 001-0.1 s^-1. The warm tensile properties,r...Warm tensile tests for aluminum alloy 7022 sheet are held at different temperatures and strain rates. The range of temperature is 293-773 K and that of the strain rate is 0. 001-0.1 s^-1. The warm tensile properties,relations among temperature,strain rate,and the flow stress are discussed. Constitutive equations under the warm tension are obtained based on revised Hooke law and Grosman equation. It is concluded that flow stress declines with the increase of the temperature and the decrease of the strain rates. The elongation percentage increases with the increase of the temperature and the decrease of strain rate.展开更多
An orthogonal test was conducted to investigate the influence of technical parameters of squeeze casting on the strength and ductility of AISigCu3 alloys. The experimental results showed that when the forming pressure...An orthogonal test was conducted to investigate the influence of technical parameters of squeeze casting on the strength and ductility of AISigCu3 alloys. The experimental results showed that when the forming pressure was higher than 65 MPa, the strength (ab) of A1Si9Cu3 alloys decreased with the forming pressure and pouring temperature increasing, whereas ab increased with the increase of filling velocity and mould preheating temperature. The ductility (6) by alloy was improved by increasing the forming pressure and filling velocity, but decreased with pouring temperature increasing. When the mould preheating temperature increased, the ductility increased first, and then decreased. Under the optimized parameters of pouring temperature 730 ℃, forming pressure 75 MPa, filling velocity 0.50 m/s, and mould preheating temperature 220 ℃, the tensile strength, elongation, and hardness of A1Si9Cu3 alloys obtained in squeeze casting were improved by 16.7%, 9.1%, and 10.1%, respectively, as compared with those of sand castings.展开更多
Microstructure and tensile behaviors of AZ31 magnesium alloy prepared by friction stir processing(FSP) were investigated.The results show that microstructure of the AZ31 hot-rolled plate with an average grain size o...Microstructure and tensile behaviors of AZ31 magnesium alloy prepared by friction stir processing(FSP) were investigated.The results show that microstructure of the AZ31 hot-rolled plate with an average grain size of 92.0 μm is refined to 11.4 μm after FSP.The FSP AZ31 alloy exhibits excellent plasticity at elevated temperature,with an elongation to failure of 1050% at 723 K and a strain rate of 5×10-4 s-1.The elongation of the FSP material is 268% at 723 K and 1×10-2 s-1,indicating that high strain rate superplasticity could be achieved.On the other hand,the hot-rolled base material,which has a coarse grain structure,possesses no superplasticity under the experimental conditions.展开更多
Chinese bamboo flour was chemically modified by acetylation with acetic anhydride by using trichloroacetic acid as an activation agent and the optimized condition for acetylation of bamboo flour was determined as the ...Chinese bamboo flour was chemically modified by acetylation with acetic anhydride by using trichloroacetic acid as an activation agent and the optimized condition for acetylation of bamboo flour was determined as the trichloroacetic acid amount 6.0 g per 1.5-g bamboo flour, ultrasosonication duration 40 min and the reaction time 1 h at 65℃. The composition, microstructure and thermal behavior of acetylated bamboo flour were preliminarily characterized by FT-IR, DSC and SEM etc. The acetylated bamboo flour can be molded into sheets at 130℃ and 10 MPa, indicating the modified bamboo flour possesses thermalplastic performance.展开更多
文摘Aluminium alloy is one of the earliest and most widely used superplastic materials.The objective of this work is to review the scientific advances in superplastic Al alloys.Particularly,the emphasis is placed on the microstructural evolution and deformation mechanisms of Al alloys during superplastic deformation.The evolution of grain structure,texture,secondary phase,and cavities during superplastic flow in typical superplastic Al alloys is discussed in detail.The quantitative evaluation of different deformation mechanisms based on the focus ion beam(FIB)-assisted surface study provides new insights into the superplasticity of Al alloys.The main features,such as grain boundary sliding,intragranular dislocation slip,and diffusion creep can be observed intuitively and analyzed quantitatively.This study provides some reference for the research of superplastic deformation mechanism and the development of superplastic Al alloys.
基金supported by the Na⁃tional Natural Science Foundation of China(No.12302176).
文摘In comparison to discrete descriptions of fracture process,the recently proposed phase field methodology averts the numerical tracking strategy of discontinuities in solids,which enables the numerical implement simplification.An implicit finite element formulation based on the diffuse phase field is extended for stable and efficient analysis of complex dynamic fracture process in ductile solids.This exhibited formulation is shown to capture entire range of the characteristics of ductile material presenting J2-plasticity,embracing plasticization,cracks initiation,propagation,branching and merging while fulfilling the basic principle of thermodynamics.Herein,we implement a staggered time integration scheme of the dynamic elasto-plastic phase field method into the commercial finite element code.The numerical performance of the present advanced phase field model has been examined through several classic dynamic fracture benchmarks,and in all cases simulation results are in good agreement with the associated experimental data and other numerical results in previous literature.
基金the financial supports from the National Natural Science Foundation of China(Nos.52075423,U2141214).
文摘The coupling effects of electrical pulse,temperature,strain rate,and strain on the flow behavior and plasticity of 5182-O aluminum alloy were investigated and characterized.The isothermal tensile test and electrically-assisted isothermal tensile test were performed at the same temperature,and three typical models were further embedded in ABAQUS/Explicit for numerical simulation to illustrate the electroplastic effect.The results show that electric pulse reduces the deformation resistance but enhances the elongation greatly.The calibration accuracy of the proposed modified Lim−Huh model for highly nonlinear and coupled dynamic hardening behavior is not much improved compared to the modified Kocks−Mecking model.Moreover,the artificial neural network model is very suitable to describe the macromechenical response of materials under the coupling effect of different variables.
基金the National Natural Science Foundation of China(Nos.U21A2051,52173297,52071133)the R&D Projects of Henan Academy of Sciences of China(No.220910009)+2 种基金the Key R&D and Promotion Projects of Henan Province of China(No.212102210441)the Joint Fund of Henan Science and Technology R&D Plan of China(No.222103810037)the Zhongyuan Scholar Workstation Funded Project of China(No.214400510028).
文摘A crystal plasticity finite element model was developed for the drawing deformation of pure copper micro wire,based on rate-dependent crystal plasticity theory.The impact of wire diameter compression ratio on the micro-mechanical deformation behavior during the wire drawing process was investigated.Results indicate that the internal deformation and slip of the drawn wire are unevenly distributed,forming distinct slip and non-slip zones.Additionally,horizontal strain concentration bands develop within the drawn wire.As the wire diameter compression ratio increases,the strength of the slip systems and the extent of slip zones inside the deformation zone also increase.However,the fluctuating stress state,induced by contact pressure and frictional stress,results in a rough and uneven wire surface and diminishes the stability of the drawing process.
基金Jiangsu Provincial Key Research and Development Program(No.BE2022831).
文摘Polyamide/polyethylene(PA/PE)microplastics were injected into soil containing sulfamethoxazole(SMX)to investigate their combined effects on SMX removal,soil enzyme activity,and microbial communities.The results show that both PA and PE transiently increase SMX removal and inhibite the stimulation of microbial species diversity by SMX.The effect of PE is more significant.Meanwhile,PE combined with SMX increases the relative abundances of Actinobacteria and Pseudomonas,while PA combined with SMX decreases the relative abundances of Nocardioides and Streptomyces.In addition,PA/PE combined with SMX can increase dehydrogenase,urease,ammonia monooxygenase,and nitrate reductase activities in the soil while inhibiting the activity of laccase.Compared with PA combined with SMX,the activities of dehydrogenase,urease,ammonia monooxygenase,and laccase of PE combined with SMX increase by 9.82%,10.41%,8.07%,and 5.47%,while the activities of nitrate reductase and neutral phosphatase decrease by 1.47%and 6.78%.
基金supported by Hebei Natural Science Foundation,China (No.E2020203158)Hebei Provincial Department of Human Resources and Social Security,China (No.E2020100006)。
文摘The microstructures and hot tensile behaviors of ZK30 alloys subjected to single-and multi-pass friction stir processing(FSP)were systematically investigated.Following single-pass FSP(S-FSP),coarse grains underwent refinement to 1−2μm,with a distinct basal texture emerging in the stir zone(SZ).Additionally,second-phase particles were fragmented,dispersed,and partially dissolved.Multi-pass FSP(M-FSP)further enhanced the homogeneity of the microstructure,reduced texture intensity differences,and decreased the fraction of second-phase particles by 50%.Both S-FSP and M-FSP SZs demonstrated superplasticity at strain rates below 1×10^(−3)s^(−1)and at temperatures of 250−350℃.The S-FSP SZ exhibited an elongation of 390%at 250℃and 1×10^(−4)s^(−1),while the M-FSP SZ achieved an elongation of 406%at 350℃and 1×10^(−3)s^(−1).The superplastic deformation of SZ was co-dominated by grain boundary sliding(GBS)and the solute-drag mechanism in S-FSP and mainly by GBS in M-FSP.
基金Project(2009BB4215)supported by the Natural Science Foundation Project of CQ CSTC, ChinaProject(20090191120013)supported by the PhD Programs Foundation of Ministry of Education of China+2 种基金Project(50725413)supported by the National Natural Science Foundation of ChinaProject(2007CB613704)supported by the National Basic Research Program of ChinaProject(CDJZR10 13 00 01)supported by the Fundamental Research Funds for the Central Universities, China
文摘The microstructure and mechanical properties of ZK60 Mg alloy were investigated under different solution treatments and artificial aging conditions. When as-cast ZK60 alloy was solution treated at 400 ℃for 10 h and artificially aged at 150 ℃, the volume fraction of precipitates increased with the aging time up to 30 h. When the as-cast ZK60 alloy was solution treated at 400 ℃ for 10 h and artificially aged at 200 ℃ for 15 20 h, the volume fraction of precipitates reached a peak value. Tensile test at room temperature showed that a high density of the second phase precipitates was beneficial to improving the strength and elongation. Solution treatment at 400 ℃ for 10 h and artificial aging at 150 ℃ for 30 h is considered the optimum heat treatment condition to obtain a good combination of strength and ductility.
基金Supported by the National Natural Science Foundation of China (50772095)the Graduate Innovation Foundation of Jiangsu Province (CX09B-073Z)~~
文摘Warm tensile tests for aluminum alloy 7022 sheet are held at different temperatures and strain rates. The range of temperature is 293-773 K and that of the strain rate is 0. 001-0.1 s^-1. The warm tensile properties,relations among temperature,strain rate,and the flow stress are discussed. Constitutive equations under the warm tension are obtained based on revised Hooke law and Grosman equation. It is concluded that flow stress declines with the increase of the temperature and the decrease of the strain rates. The elongation percentage increases with the increase of the temperature and the decrease of strain rate.
基金Project(11C26211304055) supported by Small to Medium Enterprise Innovation Fund
文摘An orthogonal test was conducted to investigate the influence of technical parameters of squeeze casting on the strength and ductility of AISigCu3 alloys. The experimental results showed that when the forming pressure was higher than 65 MPa, the strength (ab) of A1Si9Cu3 alloys decreased with the forming pressure and pouring temperature increasing, whereas ab increased with the increase of filling velocity and mould preheating temperature. The ductility (6) by alloy was improved by increasing the forming pressure and filling velocity, but decreased with pouring temperature increasing. When the mould preheating temperature increased, the ductility increased first, and then decreased. Under the optimized parameters of pouring temperature 730 ℃, forming pressure 75 MPa, filling velocity 0.50 m/s, and mould preheating temperature 220 ℃, the tensile strength, elongation, and hardness of A1Si9Cu3 alloys obtained in squeeze casting were improved by 16.7%, 9.1%, and 10.1%, respectively, as compared with those of sand castings.
基金Project (2009Z2-D811) supported by Guangzhou Science and Technology Development Program, ChinaProject (2009ZM0264) supported by the Fundamental Research Funds for the Central Universities, China
文摘Microstructure and tensile behaviors of AZ31 magnesium alloy prepared by friction stir processing(FSP) were investigated.The results show that microstructure of the AZ31 hot-rolled plate with an average grain size of 92.0 μm is refined to 11.4 μm after FSP.The FSP AZ31 alloy exhibits excellent plasticity at elevated temperature,with an elongation to failure of 1050% at 723 K and a strain rate of 5×10-4 s-1.The elongation of the FSP material is 268% at 723 K and 1×10-2 s-1,indicating that high strain rate superplasticity could be achieved.On the other hand,the hot-rolled base material,which has a coarse grain structure,possesses no superplasticity under the experimental conditions.
基金Fujian Province science and technology office (2007F5030)(in part) National Natural Scince Foundation of China (grant 50473063)
文摘Chinese bamboo flour was chemically modified by acetylation with acetic anhydride by using trichloroacetic acid as an activation agent and the optimized condition for acetylation of bamboo flour was determined as the trichloroacetic acid amount 6.0 g per 1.5-g bamboo flour, ultrasosonication duration 40 min and the reaction time 1 h at 65℃. The composition, microstructure and thermal behavior of acetylated bamboo flour were preliminarily characterized by FT-IR, DSC and SEM etc. The acetylated bamboo flour can be molded into sheets at 130℃ and 10 MPa, indicating the modified bamboo flour possesses thermalplastic performance.