Modified refractivity (M) profile is an important parameter to describe the atmospheric refraction environment,as well as a key factor in uniquely evaluating electromagnetic propagation effects.In order to improve the...Modified refractivity (M) profile is an important parameter to describe the atmospheric refraction environment,as well as a key factor in uniquely evaluating electromagnetic propagation effects.In order to improve the model-derived M profile in stable (especially very stable) conditions,three nonlinear similarity functions,namely BH91,CB05,SHEBA07,are introduced in this paper to improve the original Babin_V25 model,and the performances of these modified models are verified based on the hydrometeorological observations from tower platforms,which are finally compared with the original Babin_V25 model and Local_HYQ92 model.Results show that introducing nonlinear similarity functions can significantly improve the model-derived M profile;especially,the newly developed SHEBA07 functions manage to reduce the predicted root mean square (rms) differences of M and M slope (for both 0-5m and 5-40m) by 64.5%,16.6%,and 60.4%,respectively in stable conditions.Unfortunately,this improved method reacts little on the evaporation duct height;in contrast,Local_HYQ92 model is capable of reducing the predicted rms differences of M,M slope (for both 0-5m and 5-40m),and evaporation duct height by 76.7%,40.2%,83.7%,and 58.0% respectively.Finally,a new recommendation is made to apply Local_HYQ92 and Babin_SHEBA07 in very stable conditions considering that M slope is more important than evaporation duct height and absolute M value in uniquely determining electromagnetic propagation effects.展开更多
In this work, photovoltaic properties of the PBDB-T:ITIC based-NF-PSCs were fully optimized and characterized by tuning the morphology of the active layers and changing the device architecture. First, donor/acceptor(D...In this work, photovoltaic properties of the PBDB-T:ITIC based-NF-PSCs were fully optimized and characterized by tuning the morphology of the active layers and changing the device architecture. First, donor/acceptor(D/A) weight ratios were scanned,and then further optimization was performed by using different additives, i.e. 1,8-diiodooctane(DIO), diphenyl ether(DPE),1-chloronaphthalene(CN) and N-methyl-2-pyrrolidone(NMP), on the basis of best D/A ratio(1:1, w/w), respectively. Finally,the conventional or inverted device architectures with different buffer layers were employed to fabricate NF-PSC devices, and meanwhile, the morphology of the active layers was further optimized by controlling annealing temperature and time. As a result,a record efficiency of 11.3% was achieved, which is the highest result for NF-PSCs. It's also remarkable that the inverted NF-PSCs exhibited long-term stability, i.e. the best-performing devices maintain 83% of their initial PCEs after over 4000 h storage.展开更多
基金Key project of the National Natural Science Foundation of China(4083095841005029)the "973" National Basis Research and Development Program of China (2009CB421502)
文摘Modified refractivity (M) profile is an important parameter to describe the atmospheric refraction environment,as well as a key factor in uniquely evaluating electromagnetic propagation effects.In order to improve the model-derived M profile in stable (especially very stable) conditions,three nonlinear similarity functions,namely BH91,CB05,SHEBA07,are introduced in this paper to improve the original Babin_V25 model,and the performances of these modified models are verified based on the hydrometeorological observations from tower platforms,which are finally compared with the original Babin_V25 model and Local_HYQ92 model.Results show that introducing nonlinear similarity functions can significantly improve the model-derived M profile;especially,the newly developed SHEBA07 functions manage to reduce the predicted root mean square (rms) differences of M and M slope (for both 0-5m and 5-40m) by 64.5%,16.6%,and 60.4%,respectively in stable conditions.Unfortunately,this improved method reacts little on the evaporation duct height;in contrast,Local_HYQ92 model is capable of reducing the predicted rms differences of M,M slope (for both 0-5m and 5-40m),and evaporation duct height by 76.7%,40.2%,83.7%,and 58.0% respectively.Finally,a new recommendation is made to apply Local_HYQ92 and Babin_SHEBA07 in very stable conditions considering that M slope is more important than evaporation duct height and absolute M value in uniquely determining electromagnetic propagation effects.
基金supported by the National Basic Research Program(2014CB643501)the National Natural Science Foundation of China(91333204,21325419)the Chinese Academy of Sciences(XDB12030200)
文摘In this work, photovoltaic properties of the PBDB-T:ITIC based-NF-PSCs were fully optimized and characterized by tuning the morphology of the active layers and changing the device architecture. First, donor/acceptor(D/A) weight ratios were scanned,and then further optimization was performed by using different additives, i.e. 1,8-diiodooctane(DIO), diphenyl ether(DPE),1-chloronaphthalene(CN) and N-methyl-2-pyrrolidone(NMP), on the basis of best D/A ratio(1:1, w/w), respectively. Finally,the conventional or inverted device architectures with different buffer layers were employed to fabricate NF-PSC devices, and meanwhile, the morphology of the active layers was further optimized by controlling annealing temperature and time. As a result,a record efficiency of 11.3% was achieved, which is the highest result for NF-PSCs. It's also remarkable that the inverted NF-PSCs exhibited long-term stability, i.e. the best-performing devices maintain 83% of their initial PCEs after over 4000 h storage.
