This paper summarizes the new results on the petrogenesis of Mesozoic granitoids and volcanic rocks in South China. The authors propose that these rocks were formed in time and space as a response to regional tectonic...This paper summarizes the new results on the petrogenesis of Mesozoic granitoids and volcanic rocks in South China. The authors propose that these rocks were formed in time and space as a response to regional tectonic regime change from the continent-continent collision of the Indosinian orogeny within the broad Tethyan orogenic domain in the Early Mesozoic (T1-T3) (Period Ⅰ) to the largely extensional setting as a result of the Yanshanian orogeny genetically associated with the NW-WNW-ward subduction of the paleo-Pacific oceanic lithosphere in the Late Mesozoic (J2-K2) (Period Ⅱ). Of the Period I Indosinian granitoids, the early (T1-T2^1) ones are syn-collisional, and formed in a compressional setting; the late (T2^2-T3) ones are latecollisional, and formed in a locally extensional environment. During the Period Ⅱ Yanshanian magmatism, the Early Yanshanian (J2-J3) granitoid-volcanic rocks, which are distributed mainly in the Nanling Range and in the interior of the South China tectonic block (SCB), are characteristic of rift-type intraplate magmatism, whereas the Late Yanshanian K1 granitoidovolcanic rocks are interpreted as genetically representing active continental margin magmatism. The K2 tholeiitic basalts interlayered with red beds are interpreted as genetically associated with the development of back-arc extensional basins in the interior of the SCB. The Yanshanian granitoid-volcanic rocks are distributed widely in South China, reflecting extensional tectonics within much of the SCB. The extension-induced deep crustal melting and underplating of mantle-derived basaltic melts are suggested as the two principal driving mechanisms for the Yanshanian granitic magmatism in South China.展开更多
The cohesion weakening and friction strengthening(CWFS)model for rock reveals the strength components mobilization process during progressive brittle failure process of rock,which is very helpful in understanding mech...The cohesion weakening and friction strengthening(CWFS)model for rock reveals the strength components mobilization process during progressive brittle failure process of rock,which is very helpful in understanding mechanical properties of rock.However,the used incremental cyclic loading−unloading compression test for the determination of strength components is very complicated,which limits the application of CWFS model.In this paper,incremental cyclic loading−unloading compression test was firstly carried out to study the evolution of deformation and the strength properties of Beishan granite after various temperatures treated under different confining pressures.We found the axial and lateral unloading modulus are closely related to the applied stress and damage state of rock.Based on these findings,we can accurately determine the plastic strain during the entire failure process using conventional tri-axial compression test data.Furthermore,a strength component(cohesive and frictional strength)determination method was developed using conventional triaxial compression test.Using this method,we analyzed the variation of strength mobilization and deformation properties of Beishan granite after various temperatures treated.At last,a non-simultaneous strength mobilization model for thermally treated granite was obtained and verified by numerical simulation,which demonstrated the effectiveness of the proposed strength determination method.展开更多
In China,Beishan granite is chosen as a potential host surrounding rock of a high-level radioactive waste(HLW)repository.For this research,Beishan granite specimens were heated up to 300℃,400℃ and 500℃,respectively...In China,Beishan granite is chosen as a potential host surrounding rock of a high-level radioactive waste(HLW)repository.For this research,Beishan granite specimens were heated up to 300℃,400℃ and 500℃,respectively.And conventional triaxial compression tests were conducted after cooling down the samples.The results show that after 300℃,400℃ and 500℃ heating treatment,the diameter of samples increases by 0.066%,0.143%and 0.409%,respectively,which is a little larger than the axial length changes.Mechanical tests show that peak strength increases slightly with increasing temperature.However,the dilatancy threshold is lower than that observed for samples which have not experienced heating treatment.Peak strain and dilatancy threshold strain show a strong temperature dependence.The higher the temperature,the greater the strain.Furthermore,increasing temperature has negative influence on threshold elastic modulus E_(c) and tangent elastic modulus E_(t).Poisson ratio decreases when temperature increases from 300℃ to 500℃,but it is still larger than that observed for samples which have not experienced heating treatment.In addition,AE monitoring shows a quiet period in the initial loading stage,which proves that the micro cracks are closed during heating and contribute to the increase of peak strength.展开更多
As part of the mosaic of micro-continents within the Central Asian Orogenic Belt(CAOB), the Xing’anAirgin Sum Block(XAB) features increasingly-recognized Meso-Neoproterozoic geological records. However, the origin, t...As part of the mosaic of micro-continents within the Central Asian Orogenic Belt(CAOB), the Xing’anAirgin Sum Block(XAB) features increasingly-recognized Meso-Neoproterozoic geological records. However, the origin, temporal-spatial distribution of ancient materials, and their roles in crust evolution remain to debate. This paper presents an integrated study of zircon U-Pb ages and Hf-O isotopes for Mesoproterozoic and Paleozoic granites from the Erenhot region of central Inner Mongolia, along eastern CAOB. The intrusion of 1450 Ma syenogranite denotes that the Precambrian basement of XAB extends from Sonid Zuoqi westward to Erenhot. The 384 and 281 Ma monzogranites containing Mesoproterozoic xenocrystic zircons possess Proterozoic-dominant two-stage Hf model ages, further suggesting the wide existence of Proterozoic crust beneath western XAB. Cyclic Proterozoic crustal growth and reworking seem to show close linkages with the orogenesis during relevant supercontinent cycles. 1450-1360 Ma juvenile crustal growth at Erenhot and synchronous ancient crust reworking at Sonid Zuoqi and Abagaqi were likely resulted from retreating subduction involved in Columbia breakup, while 1.2-1.0 Ga reworking and 0.9-0.7 Ga growth events within the Erenhot basement might respond to assembly and breakup of Rodinia, respectively. Besides, our work confirms that reworking of Neoproterozoic crust played important roles during Paleozoic multi-stage accretion of CAOB.展开更多
The Qilishan gold deposit is located in the southern Zhaolai gold ore belt in the northwestern Jiaodong region.A total of seven gold ore bodies have been found in the mining area.Linglong gneissic biotite granite and ...The Qilishan gold deposit is located in the southern Zhaolai gold ore belt in the northwestern Jiaodong region.A total of seven gold ore bodies have been found in the mining area.Linglong gneissic biotite granite and the NE trending Lingbei fracture control the output and distribution of the gold deposit.The ore bodies with veined or irregular shape occur in the structural alteration zone.The ore bodies of different sizes are NE trending and SE dipping.The constituent minerals of the ores mainly include pyrite,chalcopyrite,native gold,electrum,argentite,matildite,hematite,quartz and calcite.The ores are characterized by metasomatic dissolution structure,as well as veined and brecciated structures.The ore-forming process is divided into four stages,namely quartz-,pyrite-,polymetallic-and carbonate stages.Study on fluid inclusion shows that the deposit is composed of gas-liquid two-phase inclusions (Ⅰ) and three-phase inclusions containing CO2 (Ⅱ),and that the former dominates.The homogenization temperature is 259.6℃-373.7℃ ; the salinity of three-phase inclusions containing CO2is 5.77%-9.84% (NaCl) ; the salinity of gas-liquid two-phase inclusions is 6.58%-8.54% (NaCl) ; and the estimated ore-forming pressure is 55.2-82.2 MPa.According to the nonlinear relationship between the depth and pressure of the fluid in the fracture zone,the ore-forming depth of the Qilishan gold deposit is calculated as 5.95-7.14 km.It is preliminarily determined that the deposit is a mesophilic and hypothermal gold deposit.展开更多
The Nanling metallogenic belt in South China is characterized by well-developed tungsten-tin mineralization related to multi- ple-aged granitoids. This belt is one of the 5 key prospecting and exploration areas among ...The Nanling metallogenic belt in South China is characterized by well-developed tungsten-tin mineralization related to multi- ple-aged granitoids. This belt is one of the 5 key prospecting and exploration areas among the 19 important metallogenic tar- gets in China. Important progress has been made in recent years in understanding the Nanling granitoids and associated miner- alization, and this paper introduces the latest major findings as follows: (1) there exists a series of Caledonian, Indosinian, and Yanshanian W-Sn-bearing granites; (2) the Sn-bearing Yanshanian granites in the Nanling Range form an NE-SW trending aluminous A-type granite belt that stretches over 350 km. The granites typically belong to the magnetite series, and dioritic micro-granular enclaves with mingling features are very common; (3) the Early Yanshanian Sn- and W-bearing granites pos- sess different petrological and geochemical features to each other: most Sn-bearing granites are metaluminous to weakly per- aluminous biotite (hornblende) granites, with zircon tHe(t) values of ca. -2 to -8, whereas most W-bearing granites are peralu- minous two-mica granites or muscovite granites with CHf(t) values of ca. -8 to -12; (4) based on the petrology and geochemis- try of the W-Sn-bearing granites, mineralogical studies have shown that common minerals such as titanite, magnetite, and bio- tite may be used as indicators for discriminating the mineralizing potential of the Sn-bearing granites. Similarly, W-bearing minerals such as wolframite may indicate the mineralizing potential of the W-bearing granites. Future studies should be fo- cused on examining the internal relationships between the multiple-aged granites in composite bodies, the metallogenic pecu- liarities of multiple-aged W-Sn-bearing granites, the links between melt evolution and highly evolved ore-bearing felsic dykes, and the connections between granite domes and mineralization.展开更多
The dating of the uplift onset of the Huangshan pluton in the southern part of Anhui Province associated with the collision between paleo-Pacific Block and the Eurasian Block is a fundamental issue to better understan...The dating of the uplift onset of the Huangshan pluton in the southern part of Anhui Province associated with the collision between paleo-Pacific Block and the Eurasian Block is a fundamental issue to better understand the uplift mechanisms and the regional tectonic evolution. Х^2 values of seven zircon fission track (ZFF) samples collected from the south part of the Huangshan pluton were all 〈5%. Based on the grain ages of four typical ZFr samples, three thermal overprints ranging in 113-123, 72-95 and 49-66 Ma were distinguished respectively using the binomial peak-fitting method in accordance with the tectonic thermal events after south China shifted into circum-Pacific tectonic region. Apatite fission track (AFT) study of the Huangshan pluton shows ages lie between 15±3 and 56±6 Ma with all Х^2 values 〉5%, and all are significantly younger than their host rock formation ages, indicating that the samples have experienced post-formation thermal history. Based on the AFT resuits and topography characteristics in the Huangshan pluton, three zones with different denudation intensities caused by the differential uplift of the fault blocks were recognized in this paper, indicating that denudation was driven by the increase in elevation significantly. Modeling of the AFT data shows that the earlier cooling phase took place in the early Cenozoic and involved 3.3, 3.8 and 6.0℃/Ma of cooling rates equivalent to the exhumation rates of 90, 104 and 167 m/Ma in different fault blocks. The last phase of cooling took place from -10 Ma with average cooling rate of -5.6℃/Ma, equivalent to average denudation rates of -156 m/Ma. The fission track results imply that the regional compression field plays an important role for the differential exhumation between individual fault blocks of the Huangshan pluton.展开更多
This paper presents a model to simulate the safe behavior of Dagangshan arch dam with a rate-dependency anisotropic damage model. This model considers the damage of asymmetry and anisotropy under cyclic loading of ten...This paper presents a model to simulate the safe behavior of Dagangshan arch dam with a rate-dependency anisotropic damage model. This model considers the damage of asymmetry and anisotropy under cyclic loading of tension and compression, and it is used in the compiled finite element code. The material parameters used in the model can be identified from uniaxial static and dynamic experiments. Thereafter, it is used for analyzing damage and failure patterns of the dam subjected to water pressure and strong earthquakes. The numerical results show that it is necessary to consider both asymmetry between tension and compression and anisotropy of damage. Severe damage regions of the dam reveal brittle and risky positions clearly. Meanwhile damage patterns show the failure trend and safety behaviors of the dam. These results match well with that of the experiments carried out in DUT. The proposed model may be used to predict the damage patterns and potential failure modes of concrete structures like the dam. And the aseismic performance of the dam can be figured out.展开更多
The Qinling orogen is a typical composite orogen for understanding multi-stages of magmatism and orogenic processes. Many studies have been carried out on the magmatic rocks in the Qinling orogen but their petrogenesi...The Qinling orogen is a typical composite orogen for understanding multi-stages of magmatism and orogenic processes. Many studies have been carried out on the magmatic rocks in the Qinling orogen but their petrogenesis is still controversial. This pa- per presents a review of all granitoid rocks based on previous and new studies of geochronology and geochemistry. Four dis- tinct periods of granitoid magmatism, Neoproterozoic (979-711 Ma), Paleozoic (507-400 Ma), Early Mesozoic (250-185 Ma) and Late Mesozoic (160-100 Ma), have been recognized from the Qinling orogen according to zircon U-Pb ages, intrusion as- sociations and deformation, as well as regional geology. The Neoproterozoic granitic rocks consist of three stages at 979-911, 894-815 and 759-711 Ma, respectively, corresponding to strongly deformed S-type, weakly deformed I-type and A-type gran- itoids. They can be interpreted as magmatic occurrences in syn-collisional, post-collisional and extensional settings, respec- tively, in response to old continental terranes of the Neoproterozoic tectonomagmatic events in the old continents of China, such as South China and Tarim cratons. Although this continental terrane would be involved in the Phanerozoic Qinling orog- eny, the Neoproterozoic magmatic rocks are not the products of the Qinling orogenic processes. The Paleozoic magmatic rocks can be classified into three stages at 507-470, 460-422 and 415-400 Ma, respectively. The first-stage magmatism is temporal- ly associated with ultra-high pressure metamorphism in the North Qinling terrane. These magmatic rocks are interpreted as magmatic occurrences in subductional, syn-collisional and post-collisional settings, respectively. The Early Mesozoic mag- matic rocks occur in two stages at 252-185 and 225-200 Ma, respectively. The first-stage granitoids are mainly represented by I-type quartz diorites and granodiorites, and the second stage by granodiorites and monzogranites with the 1- to A-type charac- teristics and some with rapakivi textures. Their emplacement ages and geochemical parameters such as A/CNK, K2O/Na2O ra- tios and εNd(t) values do not show any polarity change in perpendicular to subduction/collision zone. Therefore, all these Early Mesozoic granitoids are unlikely the product of continental subduction as some researchers suggested. Instead, they are plausi- bly related to the subduction of the Mianlue Ocean and the subsequent collision between the South China Craton and the South Qinling terrane. The Late Mesozoic granitoids were emplaced mainly at two stages of 160-130 and 120-100 Ma, and charac- terized by the evolution from I- to I-A- and A-type granitoids. These characteristics are consistent with the granitoid magmatic evolution from contractional to extensional settings during the Jurassic/Cretaceous in eastern China. Accordingly, the Late Mesozoic granitoid rocks in the Qinling orogen probably have a similar petrogenetic mechanism to those of the huge magmatic belt along the western Pacific margin, i.e., intra-continent magmatism related to a far-field effect of the subduction of Paleo-Pacific plate.展开更多
The Zhuxi ore deposit is a super-large scheelite(copper) polymetallic deposit discovered in recent years. It grew above copper/tungsten-rich Neoproterozoic argilloarenaceous basement rocks and was formed in the contac...The Zhuxi ore deposit is a super-large scheelite(copper) polymetallic deposit discovered in recent years. It grew above copper/tungsten-rich Neoproterozoic argilloarenaceous basement rocks and was formed in the contact zone between Yanshanian granites and Carboniferous-Permian limestone. Granites related to this mineralization mainly include equigranular, middle- to coarse-grained granites and granitic porphyries. There are two mineralization types: skarn scheelite(copper) and granite scheelite mineralization. The former is large scale and has a high content of scheelite, whereas the latter is small scale and has a low content of scheelite. In the Taqian-Fuchun Basin, its NW boundary is a thrust fault, and the SE boundary is an angular unconformity with Proterozoic basement. In Carboniferous-Permian rock assemblages, the tungsten and copper contents in the limestone are both very high. The contents of major elements in granitoids do not differ largely between the periphery and the inside of the Zhuxi ore deposit. In both areas, the values of the aluminum saturation index are A/CNK>1.1, and the rocks are classified as potassium-rich strongly peraluminous granites. In terms of trace elements, compared to granites on the periphery of the Zhuxi ore deposit, the granites inside the Zhuxi ore deposit have smaller d Eu values, exhibit a significantly more negative Eu anomaly, are richer in Rb, U, Ta, Pb and Hf, and are more depleted in Ba, Ce, Sr, La and Ti, which indicates that they are highly differentiated S-type granites with a high degree of evolution. Under the influence of fluids, mineralization of sulfides is evident within massive rock formations inside the Zhuxi ore deposit, and the mean SO_3 content is 0.2%. Compared to peripheral rocks, the d Eu and total rare earth element(REE) content of granites inside the Zhuxi ore deposit are both lower, indicating a certain evolutionary inheritance relationship between the granites on the periphery and the granites inside the Zhuxi ore deposit. For peripheral and ore district plutons, U-Pb zircon dating shows an age range of 152–148 Ma. In situ Lu-Hf isotope analysis of zircon in the granites reveals that the calculated e_(Hf)(t) values are all negative, and the majority range from -6 to -9. The T_(DM2) values are concentrated in the range of 1.50–1.88 Ga(peak at 1.75 Ga), suggesting that the granitic magmas are derived from partial melting of ancient crust. This paper also discusses the metallogenic conditions and ore-controlling conditions of the ore district from the perspectives of mineral contents, hydrothermal alteration, and ore-controlling structures in the strata and the ore-bearing rocks. It is proposed that the Zhuxi ore deposit went through a multistage evolution, including oblique intrusion of granitic magmas, skarn mineralization, cooling and alteration, and precipitation of metal sulfides. The mineralization pattern can be summarized as "copper in the east and tungsten in the west, copper at shallow-middle depths and tungsten at deep depths, tungsten in the early stage and copper in the late stage".展开更多
The Mesozoic high-K granitic intrusions from the eastern Dabie Mountains, Central China, can be divided into three superunits namely the Yaohe, Penghe and Huangbai superunits. The Yaohe superunit is compositionally do...The Mesozoic high-K granitic intrusions from the eastern Dabie Mountains, Central China, can be divided into three superunits namely the Yaohe, Penghe and Huangbai superunits. The Yaohe superunit is compositionally dominated by quartz monzonite extending as a band in NW direction which is differently foliated, contains numerous dioritic enclaves and has been dated as 174 Ma. The Penghe superunit, widely distributed in the field, varies in composition but is dominated by quartz monzonitic and granitic rocks, which is massive in structure, has well developed with dioritic enclaves and is aged in 125-127 Ma. The Huangbai superunit is mainly composed of granitic composition which is massive in structure, rarely contains dioritic enclaves and is aged in 120-111 Ma. These three superunits of granitic intrusions can also be clearly distinguished in geochemistry. They have recorded an orogenic process of the Dabie Mountains from the end of regional metamorphism to the overprinting of the circum-Pacific tectonic regime.展开更多
Early Yanshanian(Jurassic) granitoids are widespread in the Nanling Range,South China.Whereas large granitic batholiths commonly crop out in the center of the Nanling Range(corresponding geographically to the central ...Early Yanshanian(Jurassic) granitoids are widespread in the Nanling Range,South China.Whereas large granitic batholiths commonly crop out in the center of the Nanling Range(corresponding geographically to the central and northern parts of Guangdong Province),many small stocks occur in the southern part of Jiangxi Province.Most of the small stocks are associated closely with economically significant rare-metal deposits(W,Sn,Nb,Ta).Here we report the results for biotite granites and two-mica granites from three Yanshanian stocks of the Longyuanba complex.LA-ICPMS U-Pb dating of zircon yields an age of 156.1±2.1 Ma for Xiaomubei biotite granite,and U-Pb zircon dating using SIMS yields an age of 156.7±1.2 Ma for Longyuanba-Chengjiang biotite granite and 156.4±1.3 Ma for Jiangtoudong two-mica granite.Biotite granites are silica-rich(SiO 2 =70%-79%),potassic(K 2 O/Na 2 O>1.9),and peraluminous(ASI=1.05-1.33).Associated samples are invariably enriched in Rb,Th,Pb and LREE,yet depleted in Ba,Nb,Sr,P and Ti,and their REE pattern shows a large fractionation between LREE and HREE((La/Yb) N =10.7-13.5) and a pronounced Eu negative anomaly(δEu=0.28-0.41).Two-mica granite samples are also silica-rich(SiO 2 =75%-79%),potassic(K 2 O/Na 2 O>1.2),and peraluminous(ASI=1.09-1.17).However,in contrast to the biotite granites,they are more enriched in Rb,Th,Pb and extremely depleted in Ba,Nb,Sr,P and Ti,and exhibit nearly flat((La/Yb) N =0.75-1.08) chondrite-normalized REE patterns characterized by strong Eu depletion(δEu=0.02-0.04) and clear tetrad effect(TE 1.3 =1.10-1.14).Biotite granites and two-mica granties have comparable Nd isotopic signatures,and their εNd(t) are concentrated in the 13.0 to 9.6 and 11.5 to 7.7 respectively.Their zircon Hf-O isotopes of both also show similarity(biotite granites:εHf(t)= 10.8-7.9,δ 18 O=7.98‰-8.89‰ and εHf(t)= 13.8 to 9.1,δ 18 O=8.31‰-10.08‰;two-mica granites:εHf(t)= 11.3 to 8.0,δ 18 O=7.91‰-9.77‰).The results show that both biotite and two-mica granites were derived mainly from sedimentary source rocks with a minor contribution from mantle-derived materials.In spite of some S-type characteristics,the biotite granites were formed by fractional crystallization of I-type magma and assimilation of peraluminous sedimentary rocks during their ascent to the surface.Therefore,they belong to highly fractionated I-type granites.Two-mica granites exhibit a tetrad effect in their REE patterns,but share the same isotopic features with the biotite granites,suggesting that they are highly fractionated I-type granites as well.Their Lanthanide tetrad effects may be attributed to the hydrothermal alteration by magmatic fluids that have suffered degassing at late stages.Granitic magmas undergoing fractional crystallization and wall-rock assilimation can generate highly evolved granites with no REE tetrad effect in the uni-phase system.However,in the late-stage of magmatic evolution in the multi-phase system(i.e.,magmatic-hydrothermal system),these magmas also can lead to the highly evolved granites exhibiting mew-shaped REE pattern characterized by tetrad effect as the consequence of melt-fluid and fluid-vapor fractionation,and the resultant autometasomatism.We thus suggest that the REE pattern exhibiting tetrad effect feature is an important indicator of rare metal mineralization in the early Yanshanian time in southern China,implying the metamorphism of the ore fluid.展开更多
Yanshanian magmatisms are intensive in the southern Anhui Province and can be divided into early (152-137 Ma) and late (136-122 Ma) stages. A Yanshanian granitic zone was found to crop out along Qingshan to Changg...Yanshanian magmatisms are intensive in the southern Anhui Province and can be divided into early (152-137 Ma) and late (136-122 Ma) stages. A Yanshanian granitic zone was found to crop out along Qingshan to Changgai areas in the Ttmxi district in Field investigation which has a genetic link with molybdenum multiple metal mineralization. To be a representative syenitic granite in the southern Anhui Province, the Huangshan pluton has not been found so far to have any genetic link with mineralization. Zircon LA-ICP-MS dating indicate that the four granitic bodies from the Qingshan-Changgai zone have concurrent formed ages from 140~:4 to 141~2 Ma, belonging to the Yanshanian early stage magmatism. However, the Huangshan granite is dated to be 12912 Ma, belonging to the Yanshanian late stage magmatism. The Qingshan-Changgai granites show high SiO2 and K20 contents, low P205 contents and middle A12O3 contents and are high-K calc-alkaline series metaluminum I-type granite. These rocks are characterized by enrichments in the large ion lithophile elements and light rare earth elements (REE), depletions in the high field-strength elements, and middle degree negative anomalies of Eu, geochemical features of arc or continent crustal derived magma affinities. These rocks have 87Sr/StSr(t) ratios from 0.7120 to 0.7125,εNd(t) values from -7.24 to -4.38 and zircon εHf(t) values of -4.4 to 6.7, similar to that of the coeval ore-bearing granodiorites in the southern Anhui Province. Integrated geochemical studies indicate that the Yanshanian ore-bearing granodiorites were formed by partial melting of the Meso-Neoproterozoic accreted thickened low crust. Meanwhile, the Qingshan-Changgai granites were formed through a AFC process of plagioclase+amphibole+Shangxi Group of magmas that formed the ore-bearing granodiorites. The Huangshan granites are characterized by high SiOz and K2O contents, moderate Al2O3 contents, seagull shape REE distributed pattern and distinct Eu negative abnormities. Comparing with the Qingshan-Changgai granites, the Huangshan granites show more Ba, Sr, P, and Ti negative abnormities with no Nb and Ta depletions and are high-K calc-alkaline series metaluminum A-type granite, εHr(t) values of the Huangshan granites are from -6.6 to -1.2, similar to that of the early stage ore-bearing granodiorites, indicating that they were also formed by anatexis of the Meso-Neoproterozoic accreted crust, but their magma sources might be residual granulitic crust which ever underwent Yanshanian early stage I-type intermediate-acid magma extraction. Comparing studies on the two stages granites indicate that the early stage granites derived from a relative thickened low crust under a lower temperature condition. Their magma sources were Meso-Neoproterozoic accreted crust which enriched in ore-forming materials and further became more enriched through processes of magma AFC evolution. However, the late stage A-type granites originated from relative shallow crust under a higher temperature condition. Their magma source was depleted in ore-forming materials due to the early stage magma extraction and thus had weak ore-forming capacity. From early to late stage, the magmatisms tectonic setting translated from post-orogenic to anorogenic and the later corresponded to a back-arc extensional setting as increase of the slab subducted angle of the Paleo-Pacific plate.展开更多
On the basis of new paleontological data,the sequence and distributions of the Middle Devonian-Tournaisian rocks on Hainan Island have been sorted out for the first time.The Devonian rocks include the Middle Devonian ...On the basis of new paleontological data,the sequence and distributions of the Middle Devonian-Tournaisian rocks on Hainan Island have been sorted out for the first time.The Devonian rocks include the Middle Devonian Jinbo Formation and the Upper Devonian Changjiang Formation,which are distributed in northwestern Hainan Island.The Jinbo Formation is represented by631 m of littoral facies deposits,and was intruded by the Yanshanian granite in the base.The presence of chitinozoans Eisenackitina caster,Funsochitina pilosa,and Lagenochitina amottensis indicates the Givetian in age.The Changjiang Formation is made up of 140 m of neritic facies rocks,and contains the Famennian conodonts Palmatolepis gracilis sigmoidalis,Polygnathus germanus,and corals Cystophrentis kalaohoensis.The Devonian-Tournaisian transition beds,the lower part of the Jishi Formation,are composed of 61–129 m sandstone and siltstone,with gastropods Euomphalus spp.and brachiopods,and marked by conglomerate with the underlying Devonian rocks.The middle-upper part of the Tournaisian Jishi Formation consists of 100–251 m clastic and carbonate rocks,containing abundant corals Pseudoularinia irregularis,conodonts Siphonodella isosticha,trilobites Weberiphillipsia linguiformis,and brachiopods.On the basis of the occurrence of Xinanosprifer flabellum and Homotoma sp.,the Nanhao Formation in southern Hainan Island is now regarded as the Lower Silurian,instead of the previously designated Lower Carboniferous.It is confirmed that no Carboniferous rocks occurred in the area south to the Gancheng-Wanning Fault.展开更多
文摘This paper summarizes the new results on the petrogenesis of Mesozoic granitoids and volcanic rocks in South China. The authors propose that these rocks were formed in time and space as a response to regional tectonic regime change from the continent-continent collision of the Indosinian orogeny within the broad Tethyan orogenic domain in the Early Mesozoic (T1-T3) (Period Ⅰ) to the largely extensional setting as a result of the Yanshanian orogeny genetically associated with the NW-WNW-ward subduction of the paleo-Pacific oceanic lithosphere in the Late Mesozoic (J2-K2) (Period Ⅱ). Of the Period I Indosinian granitoids, the early (T1-T2^1) ones are syn-collisional, and formed in a compressional setting; the late (T2^2-T3) ones are latecollisional, and formed in a locally extensional environment. During the Period Ⅱ Yanshanian magmatism, the Early Yanshanian (J2-J3) granitoid-volcanic rocks, which are distributed mainly in the Nanling Range and in the interior of the South China tectonic block (SCB), are characteristic of rift-type intraplate magmatism, whereas the Late Yanshanian K1 granitoidovolcanic rocks are interpreted as genetically representing active continental margin magmatism. The K2 tholeiitic basalts interlayered with red beds are interpreted as genetically associated with the development of back-arc extensional basins in the interior of the SCB. The Yanshanian granitoid-volcanic rocks are distributed widely in South China, reflecting extensional tectonics within much of the SCB. The extension-induced deep crustal melting and underplating of mantle-derived basaltic melts are suggested as the two principal driving mechanisms for the Yanshanian granitic magmatism in South China.
基金Project(41902301)supported by the National Natural Science Foundation of ChinaProject(20201Y185)supported by the Science and Technology Foundation of Guizhou Province,China+2 种基金Project(Z018023)supported by the Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,IRSM,CASProject(201822)supported by the Foundation for Young Talents of Guizhou University,ChinaProject(2017-5402)supported by the Mountain Geohazard Prevention R&D Center of Guizhou Province,China。
文摘The cohesion weakening and friction strengthening(CWFS)model for rock reveals the strength components mobilization process during progressive brittle failure process of rock,which is very helpful in understanding mechanical properties of rock.However,the used incremental cyclic loading−unloading compression test for the determination of strength components is very complicated,which limits the application of CWFS model.In this paper,incremental cyclic loading−unloading compression test was firstly carried out to study the evolution of deformation and the strength properties of Beishan granite after various temperatures treated under different confining pressures.We found the axial and lateral unloading modulus are closely related to the applied stress and damage state of rock.Based on these findings,we can accurately determine the plastic strain during the entire failure process using conventional tri-axial compression test data.Furthermore,a strength component(cohesive and frictional strength)determination method was developed using conventional triaxial compression test.Using this method,we analyzed the variation of strength mobilization and deformation properties of Beishan granite after various temperatures treated.At last,a non-simultaneous strength mobilization model for thermally treated granite was obtained and verified by numerical simulation,which demonstrated the effectiveness of the proposed strength determination method.
基金Projects(52104135, 51674266) supported by the National Natural Science Foundation of ChinaProject supported by the Qingdao Postdoctoral Applied Research Project Foundation,China。
文摘In China,Beishan granite is chosen as a potential host surrounding rock of a high-level radioactive waste(HLW)repository.For this research,Beishan granite specimens were heated up to 300℃,400℃ and 500℃,respectively.And conventional triaxial compression tests were conducted after cooling down the samples.The results show that after 300℃,400℃ and 500℃ heating treatment,the diameter of samples increases by 0.066%,0.143%and 0.409%,respectively,which is a little larger than the axial length changes.Mechanical tests show that peak strength increases slightly with increasing temperature.However,the dilatancy threshold is lower than that observed for samples which have not experienced heating treatment.Peak strain and dilatancy threshold strain show a strong temperature dependence.The higher the temperature,the greater the strain.Furthermore,increasing temperature has negative influence on threshold elastic modulus E_(c) and tangent elastic modulus E_(t).Poisson ratio decreases when temperature increases from 300℃ to 500℃,but it is still larger than that observed for samples which have not experienced heating treatment.In addition,AE monitoring shows a quiet period in the initial loading stage,which proves that the micro cracks are closed during heating and contribute to the increase of peak strength.
基金Projects(41873035,41802053) supported by the National Natural Science Foundation of ChinaProject(ZD2021015) supported by the Science and Technology Project of Hebei Education Department,China+1 种基金Project(SCRM2116) supported by the Opening Foundation of Hebei Key Laboratory of Strategic Critical Mineral Resources,ChinaProject(202045004) supported by the Scientific Research Starting Foundation of Central South University,China。
文摘As part of the mosaic of micro-continents within the Central Asian Orogenic Belt(CAOB), the Xing’anAirgin Sum Block(XAB) features increasingly-recognized Meso-Neoproterozoic geological records. However, the origin, temporal-spatial distribution of ancient materials, and their roles in crust evolution remain to debate. This paper presents an integrated study of zircon U-Pb ages and Hf-O isotopes for Mesoproterozoic and Paleozoic granites from the Erenhot region of central Inner Mongolia, along eastern CAOB. The intrusion of 1450 Ma syenogranite denotes that the Precambrian basement of XAB extends from Sonid Zuoqi westward to Erenhot. The 384 and 281 Ma monzogranites containing Mesoproterozoic xenocrystic zircons possess Proterozoic-dominant two-stage Hf model ages, further suggesting the wide existence of Proterozoic crust beneath western XAB. Cyclic Proterozoic crustal growth and reworking seem to show close linkages with the orogenesis during relevant supercontinent cycles. 1450-1360 Ma juvenile crustal growth at Erenhot and synchronous ancient crust reworking at Sonid Zuoqi and Abagaqi were likely resulted from retreating subduction involved in Columbia breakup, while 1.2-1.0 Ga reworking and 0.9-0.7 Ga growth events within the Erenhot basement might respond to assembly and breakup of Rodinia, respectively. Besides, our work confirms that reworking of Neoproterozoic crust played important roles during Paleozoic multi-stage accretion of CAOB.
基金Supported by Project of Alternative Resources Prospecting in Crisis Mines(No.200623018)
文摘The Qilishan gold deposit is located in the southern Zhaolai gold ore belt in the northwestern Jiaodong region.A total of seven gold ore bodies have been found in the mining area.Linglong gneissic biotite granite and the NE trending Lingbei fracture control the output and distribution of the gold deposit.The ore bodies with veined or irregular shape occur in the structural alteration zone.The ore bodies of different sizes are NE trending and SE dipping.The constituent minerals of the ores mainly include pyrite,chalcopyrite,native gold,electrum,argentite,matildite,hematite,quartz and calcite.The ores are characterized by metasomatic dissolution structure,as well as veined and brecciated structures.The ore-forming process is divided into four stages,namely quartz-,pyrite-,polymetallic-and carbonate stages.Study on fluid inclusion shows that the deposit is composed of gas-liquid two-phase inclusions (Ⅰ) and three-phase inclusions containing CO2 (Ⅱ),and that the former dominates.The homogenization temperature is 259.6℃-373.7℃ ; the salinity of three-phase inclusions containing CO2is 5.77%-9.84% (NaCl) ; the salinity of gas-liquid two-phase inclusions is 6.58%-8.54% (NaCl) ; and the estimated ore-forming pressure is 55.2-82.2 MPa.According to the nonlinear relationship between the depth and pressure of the fluid in the fracture zone,the ore-forming depth of the Qilishan gold deposit is calculated as 5.95-7.14 km.It is preliminarily determined that the deposit is a mesophilic and hypothermal gold deposit.
基金supported by National Natural Science Foundation of China(Grant Nos.41230315,40730423)Ministry of Science and Technology(Grant No.2012CB416704)China National Geological Survey Bureau(Grant No.12120113067300)
文摘The Nanling metallogenic belt in South China is characterized by well-developed tungsten-tin mineralization related to multi- ple-aged granitoids. This belt is one of the 5 key prospecting and exploration areas among the 19 important metallogenic tar- gets in China. Important progress has been made in recent years in understanding the Nanling granitoids and associated miner- alization, and this paper introduces the latest major findings as follows: (1) there exists a series of Caledonian, Indosinian, and Yanshanian W-Sn-bearing granites; (2) the Sn-bearing Yanshanian granites in the Nanling Range form an NE-SW trending aluminous A-type granite belt that stretches over 350 km. The granites typically belong to the magnetite series, and dioritic micro-granular enclaves with mingling features are very common; (3) the Early Yanshanian Sn- and W-bearing granites pos- sess different petrological and geochemical features to each other: most Sn-bearing granites are metaluminous to weakly per- aluminous biotite (hornblende) granites, with zircon tHe(t) values of ca. -2 to -8, whereas most W-bearing granites are peralu- minous two-mica granites or muscovite granites with CHf(t) values of ca. -8 to -12; (4) based on the petrology and geochemis- try of the W-Sn-bearing granites, mineralogical studies have shown that common minerals such as titanite, magnetite, and bio- tite may be used as indicators for discriminating the mineralizing potential of the Sn-bearing granites. Similarly, W-bearing minerals such as wolframite may indicate the mineralizing potential of the W-bearing granites. Future studies should be fo- cused on examining the internal relationships between the multiple-aged granites in composite bodies, the metallogenic pecu- liarities of multiple-aged W-Sn-bearing granites, the links between melt evolution and highly evolved ore-bearing felsic dykes, and the connections between granite domes and mineralization.
基金supported by National Natural Science Foundation of China(Grant Nos.40772134)Open Research Program of the State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences(Grant No.200643)
文摘The dating of the uplift onset of the Huangshan pluton in the southern part of Anhui Province associated with the collision between paleo-Pacific Block and the Eurasian Block is a fundamental issue to better understand the uplift mechanisms and the regional tectonic evolution. Х^2 values of seven zircon fission track (ZFF) samples collected from the south part of the Huangshan pluton were all 〈5%. Based on the grain ages of four typical ZFr samples, three thermal overprints ranging in 113-123, 72-95 and 49-66 Ma were distinguished respectively using the binomial peak-fitting method in accordance with the tectonic thermal events after south China shifted into circum-Pacific tectonic region. Apatite fission track (AFT) study of the Huangshan pluton shows ages lie between 15±3 and 56±6 Ma with all Х^2 values 〉5%, and all are significantly younger than their host rock formation ages, indicating that the samples have experienced post-formation thermal history. Based on the AFT resuits and topography characteristics in the Huangshan pluton, three zones with different denudation intensities caused by the differential uplift of the fault blocks were recognized in this paper, indicating that denudation was driven by the increase in elevation significantly. Modeling of the AFT data shows that the earlier cooling phase took place in the early Cenozoic and involved 3.3, 3.8 and 6.0℃/Ma of cooling rates equivalent to the exhumation rates of 90, 104 and 167 m/Ma in different fault blocks. The last phase of cooling took place from -10 Ma with average cooling rate of -5.6℃/Ma, equivalent to average denudation rates of -156 m/Ma. The fission track results imply that the regional compression field plays an important role for the differential exhumation between individual fault blocks of the Huangshan pluton.
基金supported by the National Natural Science Foundation of China (Grant Nos. 90510017 and 50878123)the National Basic Research Program of China (Grant No. 2007CB714104 )+1 种基金the Innovative Project for Postdoctor of Shandong Province (Grant No. 200803037)the Research Project of SUST Spring Bud (Grant No. 2008AZZ107)
文摘This paper presents a model to simulate the safe behavior of Dagangshan arch dam with a rate-dependency anisotropic damage model. This model considers the damage of asymmetry and anisotropy under cyclic loading of tension and compression, and it is used in the compiled finite element code. The material parameters used in the model can be identified from uniaxial static and dynamic experiments. Thereafter, it is used for analyzing damage and failure patterns of the dam subjected to water pressure and strong earthquakes. The numerical results show that it is necessary to consider both asymmetry between tension and compression and anisotropy of damage. Severe damage regions of the dam reveal brittle and risky positions clearly. Meanwhile damage patterns show the failure trend and safety behaviors of the dam. These results match well with that of the experiments carried out in DUT. The proposed model may be used to predict the damage patterns and potential failure modes of concrete structures like the dam. And the aseismic performance of the dam can be figured out.
基金supported by the National Natural Science Foundation of China(Grant Nos.40872054,41172062 and 41430209)the National Key Basic Science Research Project of China(Grant Nos.2009CB825006 and 2009CB825003)+1 种基金China Geological Survey(Grant Nos.1212010012012,12120113094000,1212011120135 and 1212010811033)Development Project of Innovative Team,Northwest University
文摘The Qinling orogen is a typical composite orogen for understanding multi-stages of magmatism and orogenic processes. Many studies have been carried out on the magmatic rocks in the Qinling orogen but their petrogenesis is still controversial. This pa- per presents a review of all granitoid rocks based on previous and new studies of geochronology and geochemistry. Four dis- tinct periods of granitoid magmatism, Neoproterozoic (979-711 Ma), Paleozoic (507-400 Ma), Early Mesozoic (250-185 Ma) and Late Mesozoic (160-100 Ma), have been recognized from the Qinling orogen according to zircon U-Pb ages, intrusion as- sociations and deformation, as well as regional geology. The Neoproterozoic granitic rocks consist of three stages at 979-911, 894-815 and 759-711 Ma, respectively, corresponding to strongly deformed S-type, weakly deformed I-type and A-type gran- itoids. They can be interpreted as magmatic occurrences in syn-collisional, post-collisional and extensional settings, respec- tively, in response to old continental terranes of the Neoproterozoic tectonomagmatic events in the old continents of China, such as South China and Tarim cratons. Although this continental terrane would be involved in the Phanerozoic Qinling orog- eny, the Neoproterozoic magmatic rocks are not the products of the Qinling orogenic processes. The Paleozoic magmatic rocks can be classified into three stages at 507-470, 460-422 and 415-400 Ma, respectively. The first-stage magmatism is temporal- ly associated with ultra-high pressure metamorphism in the North Qinling terrane. These magmatic rocks are interpreted as magmatic occurrences in subductional, syn-collisional and post-collisional settings, respectively. The Early Mesozoic mag- matic rocks occur in two stages at 252-185 and 225-200 Ma, respectively. The first-stage granitoids are mainly represented by I-type quartz diorites and granodiorites, and the second stage by granodiorites and monzogranites with the 1- to A-type charac- teristics and some with rapakivi textures. Their emplacement ages and geochemical parameters such as A/CNK, K2O/Na2O ra- tios and εNd(t) values do not show any polarity change in perpendicular to subduction/collision zone. Therefore, all these Early Mesozoic granitoids are unlikely the product of continental subduction as some researchers suggested. Instead, they are plausi- bly related to the subduction of the Mianlue Ocean and the subsequent collision between the South China Craton and the South Qinling terrane. The Late Mesozoic granitoids were emplaced mainly at two stages of 160-130 and 120-100 Ma, and charac- terized by the evolution from I- to I-A- and A-type granitoids. These characteristics are consistent with the granitoid magmatic evolution from contractional to extensional settings during the Jurassic/Cretaceous in eastern China. Accordingly, the Late Mesozoic granitoid rocks in the Qinling orogen probably have a similar petrogenetic mechanism to those of the huge magmatic belt along the western Pacific margin, i.e., intra-continent magmatism related to a far-field effect of the subduction of Paleo-Pacific plate.
基金supported by the National Basic Research Program of China(Grant No.2012CB416701)National Natural Science Foundation of China(Grant Nos.41330208+3 种基金41572200)National Science and Technology Support Program(Grant No.2011BAB04B02)the Jiangxi Geological Exploration Fund(Grant No.20100112)Jiangxi Science and Technology Project(Grant No.20122BBG70068)
文摘The Zhuxi ore deposit is a super-large scheelite(copper) polymetallic deposit discovered in recent years. It grew above copper/tungsten-rich Neoproterozoic argilloarenaceous basement rocks and was formed in the contact zone between Yanshanian granites and Carboniferous-Permian limestone. Granites related to this mineralization mainly include equigranular, middle- to coarse-grained granites and granitic porphyries. There are two mineralization types: skarn scheelite(copper) and granite scheelite mineralization. The former is large scale and has a high content of scheelite, whereas the latter is small scale and has a low content of scheelite. In the Taqian-Fuchun Basin, its NW boundary is a thrust fault, and the SE boundary is an angular unconformity with Proterozoic basement. In Carboniferous-Permian rock assemblages, the tungsten and copper contents in the limestone are both very high. The contents of major elements in granitoids do not differ largely between the periphery and the inside of the Zhuxi ore deposit. In both areas, the values of the aluminum saturation index are A/CNK>1.1, and the rocks are classified as potassium-rich strongly peraluminous granites. In terms of trace elements, compared to granites on the periphery of the Zhuxi ore deposit, the granites inside the Zhuxi ore deposit have smaller d Eu values, exhibit a significantly more negative Eu anomaly, are richer in Rb, U, Ta, Pb and Hf, and are more depleted in Ba, Ce, Sr, La and Ti, which indicates that they are highly differentiated S-type granites with a high degree of evolution. Under the influence of fluids, mineralization of sulfides is evident within massive rock formations inside the Zhuxi ore deposit, and the mean SO_3 content is 0.2%. Compared to peripheral rocks, the d Eu and total rare earth element(REE) content of granites inside the Zhuxi ore deposit are both lower, indicating a certain evolutionary inheritance relationship between the granites on the periphery and the granites inside the Zhuxi ore deposit. For peripheral and ore district plutons, U-Pb zircon dating shows an age range of 152–148 Ma. In situ Lu-Hf isotope analysis of zircon in the granites reveals that the calculated e_(Hf)(t) values are all negative, and the majority range from -6 to -9. The T_(DM2) values are concentrated in the range of 1.50–1.88 Ga(peak at 1.75 Ga), suggesting that the granitic magmas are derived from partial melting of ancient crust. This paper also discusses the metallogenic conditions and ore-controlling conditions of the ore district from the perspectives of mineral contents, hydrothermal alteration, and ore-controlling structures in the strata and the ore-bearing rocks. It is proposed that the Zhuxi ore deposit went through a multistage evolution, including oblique intrusion of granitic magmas, skarn mineralization, cooling and alteration, and precipitation of metal sulfides. The mineralization pattern can be summarized as "copper in the east and tungsten in the west, copper at shallow-middle depths and tungsten at deep depths, tungsten in the early stage and copper in the late stage".
基金the National Natural Science Foundation of China (Grant No. 49772104) and the Mapping Projects Scaled on 1/50000 from the Ministry of Geology and Mineral Resources of China.
文摘The Mesozoic high-K granitic intrusions from the eastern Dabie Mountains, Central China, can be divided into three superunits namely the Yaohe, Penghe and Huangbai superunits. The Yaohe superunit is compositionally dominated by quartz monzonite extending as a band in NW direction which is differently foliated, contains numerous dioritic enclaves and has been dated as 174 Ma. The Penghe superunit, widely distributed in the field, varies in composition but is dominated by quartz monzonitic and granitic rocks, which is massive in structure, has well developed with dioritic enclaves and is aged in 125-127 Ma. The Huangbai superunit is mainly composed of granitic composition which is massive in structure, rarely contains dioritic enclaves and is aged in 120-111 Ma. These three superunits of granitic intrusions can also be clearly distinguished in geochemistry. They have recorded an orogenic process of the Dabie Mountains from the end of regional metamorphism to the overprinting of the circum-Pacific tectonic regime.
基金supported by the Chinese Academy of Sciences(Grant Nos.KZCX1-YW-15-2 and GIGCAS-135Y234151001)the Ministry of Science and Technology(Grant No. 2007CB411403)+1 种基金National Natural Science Foundation of China (Grant Nos.40973025 and 41173039)contribution No.1655 from GIGCAS
文摘Early Yanshanian(Jurassic) granitoids are widespread in the Nanling Range,South China.Whereas large granitic batholiths commonly crop out in the center of the Nanling Range(corresponding geographically to the central and northern parts of Guangdong Province),many small stocks occur in the southern part of Jiangxi Province.Most of the small stocks are associated closely with economically significant rare-metal deposits(W,Sn,Nb,Ta).Here we report the results for biotite granites and two-mica granites from three Yanshanian stocks of the Longyuanba complex.LA-ICPMS U-Pb dating of zircon yields an age of 156.1±2.1 Ma for Xiaomubei biotite granite,and U-Pb zircon dating using SIMS yields an age of 156.7±1.2 Ma for Longyuanba-Chengjiang biotite granite and 156.4±1.3 Ma for Jiangtoudong two-mica granite.Biotite granites are silica-rich(SiO 2 =70%-79%),potassic(K 2 O/Na 2 O>1.9),and peraluminous(ASI=1.05-1.33).Associated samples are invariably enriched in Rb,Th,Pb and LREE,yet depleted in Ba,Nb,Sr,P and Ti,and their REE pattern shows a large fractionation between LREE and HREE((La/Yb) N =10.7-13.5) and a pronounced Eu negative anomaly(δEu=0.28-0.41).Two-mica granite samples are also silica-rich(SiO 2 =75%-79%),potassic(K 2 O/Na 2 O>1.2),and peraluminous(ASI=1.09-1.17).However,in contrast to the biotite granites,they are more enriched in Rb,Th,Pb and extremely depleted in Ba,Nb,Sr,P and Ti,and exhibit nearly flat((La/Yb) N =0.75-1.08) chondrite-normalized REE patterns characterized by strong Eu depletion(δEu=0.02-0.04) and clear tetrad effect(TE 1.3 =1.10-1.14).Biotite granites and two-mica granties have comparable Nd isotopic signatures,and their εNd(t) are concentrated in the 13.0 to 9.6 and 11.5 to 7.7 respectively.Their zircon Hf-O isotopes of both also show similarity(biotite granites:εHf(t)= 10.8-7.9,δ 18 O=7.98‰-8.89‰ and εHf(t)= 13.8 to 9.1,δ 18 O=8.31‰-10.08‰;two-mica granites:εHf(t)= 11.3 to 8.0,δ 18 O=7.91‰-9.77‰).The results show that both biotite and two-mica granites were derived mainly from sedimentary source rocks with a minor contribution from mantle-derived materials.In spite of some S-type characteristics,the biotite granites were formed by fractional crystallization of I-type magma and assimilation of peraluminous sedimentary rocks during their ascent to the surface.Therefore,they belong to highly fractionated I-type granites.Two-mica granites exhibit a tetrad effect in their REE patterns,but share the same isotopic features with the biotite granites,suggesting that they are highly fractionated I-type granites as well.Their Lanthanide tetrad effects may be attributed to the hydrothermal alteration by magmatic fluids that have suffered degassing at late stages.Granitic magmas undergoing fractional crystallization and wall-rock assilimation can generate highly evolved granites with no REE tetrad effect in the uni-phase system.However,in the late-stage of magmatic evolution in the multi-phase system(i.e.,magmatic-hydrothermal system),these magmas also can lead to the highly evolved granites exhibiting mew-shaped REE pattern characterized by tetrad effect as the consequence of melt-fluid and fluid-vapor fractionation,and the resultant autometasomatism.We thus suggest that the REE pattern exhibiting tetrad effect feature is an important indicator of rare metal mineralization in the early Yanshanian time in southern China,implying the metamorphism of the ore fluid.
基金supported by the State Key R&D Project of China(Grant No.2016YFC0600203)the National Natural Science Foundation of China(Grant No.41672052,41272074)
文摘Yanshanian magmatisms are intensive in the southern Anhui Province and can be divided into early (152-137 Ma) and late (136-122 Ma) stages. A Yanshanian granitic zone was found to crop out along Qingshan to Changgai areas in the Ttmxi district in Field investigation which has a genetic link with molybdenum multiple metal mineralization. To be a representative syenitic granite in the southern Anhui Province, the Huangshan pluton has not been found so far to have any genetic link with mineralization. Zircon LA-ICP-MS dating indicate that the four granitic bodies from the Qingshan-Changgai zone have concurrent formed ages from 140~:4 to 141~2 Ma, belonging to the Yanshanian early stage magmatism. However, the Huangshan granite is dated to be 12912 Ma, belonging to the Yanshanian late stage magmatism. The Qingshan-Changgai granites show high SiO2 and K20 contents, low P205 contents and middle A12O3 contents and are high-K calc-alkaline series metaluminum I-type granite. These rocks are characterized by enrichments in the large ion lithophile elements and light rare earth elements (REE), depletions in the high field-strength elements, and middle degree negative anomalies of Eu, geochemical features of arc or continent crustal derived magma affinities. These rocks have 87Sr/StSr(t) ratios from 0.7120 to 0.7125,εNd(t) values from -7.24 to -4.38 and zircon εHf(t) values of -4.4 to 6.7, similar to that of the coeval ore-bearing granodiorites in the southern Anhui Province. Integrated geochemical studies indicate that the Yanshanian ore-bearing granodiorites were formed by partial melting of the Meso-Neoproterozoic accreted thickened low crust. Meanwhile, the Qingshan-Changgai granites were formed through a AFC process of plagioclase+amphibole+Shangxi Group of magmas that formed the ore-bearing granodiorites. The Huangshan granites are characterized by high SiOz and K2O contents, moderate Al2O3 contents, seagull shape REE distributed pattern and distinct Eu negative abnormities. Comparing with the Qingshan-Changgai granites, the Huangshan granites show more Ba, Sr, P, and Ti negative abnormities with no Nb and Ta depletions and are high-K calc-alkaline series metaluminum A-type granite, εHr(t) values of the Huangshan granites are from -6.6 to -1.2, similar to that of the early stage ore-bearing granodiorites, indicating that they were also formed by anatexis of the Meso-Neoproterozoic accreted crust, but their magma sources might be residual granulitic crust which ever underwent Yanshanian early stage I-type intermediate-acid magma extraction. Comparing studies on the two stages granites indicate that the early stage granites derived from a relative thickened low crust under a lower temperature condition. Their magma sources were Meso-Neoproterozoic accreted crust which enriched in ore-forming materials and further became more enriched through processes of magma AFC evolution. However, the late stage A-type granites originated from relative shallow crust under a higher temperature condition. Their magma source was depleted in ore-forming materials due to the early stage magma extraction and thus had weak ore-forming capacity. From early to late stage, the magmatisms tectonic setting translated from post-orogenic to anorogenic and the later corresponded to a back-arc extensional setting as increase of the slab subducted angle of the Paleo-Pacific plate.
基金supported by National Natural Science Foundation of China(Grant Nos.40772022,41172025)China Geological Survey Project(Grant Nos.1212011120116,1212011220517)
文摘On the basis of new paleontological data,the sequence and distributions of the Middle Devonian-Tournaisian rocks on Hainan Island have been sorted out for the first time.The Devonian rocks include the Middle Devonian Jinbo Formation and the Upper Devonian Changjiang Formation,which are distributed in northwestern Hainan Island.The Jinbo Formation is represented by631 m of littoral facies deposits,and was intruded by the Yanshanian granite in the base.The presence of chitinozoans Eisenackitina caster,Funsochitina pilosa,and Lagenochitina amottensis indicates the Givetian in age.The Changjiang Formation is made up of 140 m of neritic facies rocks,and contains the Famennian conodonts Palmatolepis gracilis sigmoidalis,Polygnathus germanus,and corals Cystophrentis kalaohoensis.The Devonian-Tournaisian transition beds,the lower part of the Jishi Formation,are composed of 61–129 m sandstone and siltstone,with gastropods Euomphalus spp.and brachiopods,and marked by conglomerate with the underlying Devonian rocks.The middle-upper part of the Tournaisian Jishi Formation consists of 100–251 m clastic and carbonate rocks,containing abundant corals Pseudoularinia irregularis,conodonts Siphonodella isosticha,trilobites Weberiphillipsia linguiformis,and brachiopods.On the basis of the occurrence of Xinanosprifer flabellum and Homotoma sp.,the Nanhao Formation in southern Hainan Island is now regarded as the Lower Silurian,instead of the previously designated Lower Carboniferous.It is confirmed that no Carboniferous rocks occurred in the area south to the Gancheng-Wanning Fault.