The non-random two liquids （NRTL） equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies （h^E） and vapour-liquid equilibria （...The non-random two liquids （NRTL） equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies （h^E） and vapour-liquid equilibria （VLE） and the VLE prediction from h^E data. The calculation strategy for properly determining NRTL parameters and the effect of their temperature dependence on the simultaneous correlation of h^E and VLE data and the VLE extrapolation are analysed in detail.展开更多
An equation of state （EOS） for high-pressure liquids, i.e., Tait EOS, is deduced according to isothermal 1 3V compressibility KT= -1/V· （2V/2p）T·.Based on the equation, a generalized EOS for high pressu...An equation of state （EOS） for high-pressure liquids, i.e., Tait EOS, is deduced according to isothermal 1 3V compressibility KT= -1/V· （2V/2p）T·.Based on the equation, a generalized EOS for high pressure-liquids is established by using the reduced state principle and introducing a characteristic parameter-configuration factor ξ. Reasonably satisfactory P-V-T data for many organic compounds, including some polar components, were calculated by using the equation.展开更多
The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative h...The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transfer of falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies.展开更多
A new general equation of state is presented, which can be used to express not only common cubic equations of state, but also quartic equations of state and so on. Main advantage of the new equation over the previous ...A new general equation of state is presented, which can be used to express not only common cubic equations of state, but also quartic equations of state and so on. Main advantage of the new equation over the previous general equations is that it is in simple form, and is easy to manipulate mathematically.展开更多
A new numerical algorithm is presented to simulate the explosion reaction process of mine explosives based on the equation of state, the equation of mass conservation and thermodynamics balance equation of explosion p...A new numerical algorithm is presented to simulate the explosion reaction process of mine explosives based on the equation of state, the equation of mass conservation and thermodynamics balance equation of explosion products. With the affection of reversible reaction of explosion products to explosion reaction equations and thermodynamics parameters considered, the computer program has been developed. The computation values show that computer simulation results are identical with the testing ones.展开更多
According to the construction characteristic of RCC dam cast by layers, three-dimensional finite element relocating mesh method is developed to simulate construction process and compute temperature field. The computat...According to the construction characteristic of RCC dam cast by layers, three-dimensional finite element relocating mesh method is developed to simulate construction process and compute temperature field. The computation model of relocating mesh method is expatiated in detail; based on the thermodynamic properties of RCC materials, the feasibility and error of relocating mesh method are analyzed and demonstrated; The computation results in this article are verified by means of the temperature observation data of certain RCC gravity dam. The results show that the temperature field computed by three-dimensional finite element relocating mesh method can not only ensure the computation precision, but also improve the calculation efficiency greatly. This provides an effective method for simulating construction process and computing temperature field of RCC dam.展开更多
In this paper, the standard k-ε two-equation model is adopted to numerically simulate fully developed fluid flow and heat transfer in a spiral finned tube within a cracking furnace for ethylene manufacturing. By vari...In this paper, the standard k-ε two-equation model is adopted to numerically simulate fully developed fluid flow and heat transfer in a spiral finned tube within a cracking furnace for ethylene manufacturing. By variable transformation, the original 3-D problem is converted into a 2-D problem in spiral coordinates. The algorithm of SIMPLEC is used to study the fully developed fluid flow and heat transfer in the spiral finned tube at constant periphery temperature and constant axial heat flux. The computed results agree pretty well with the experimental data obtained from the industry. Further studies on the fluid flows and temperature profiles at different Reynolds numbers within straight and spiral finned tubes are conducted and the mechanisms involved are explored. It is found that with the spiral finned tube, pressure drop increases to a great extent whereas heat transfer tends to be decreased.展开更多
The reliable information about interface energetics of organic materials, especially the energy level alignment at organic heterostructures is of pronounced importance for unraveling the photon harvesting and charge s...The reliable information about interface energetics of organic materials, especially the energy level alignment at organic heterostructures is of pronounced importance for unraveling the photon harvesting and charge separation process in organic photovoltaic(OPV) cells. This article provides an overview of interface energetics at typical planar and mixed donor-acceptor heterostructures, perovskite/organic hybrid interfaces, and their contact interfaces with charge collection layers. The substrate effect on energy level offsets at organic heterostructures and the processes that control and limit the OPV operation are presented. Recent efforts on interface engineering with electrical doping are also discussed.展开更多
基金Supported by Deutsche Forschungsgemeinschaft(DFG) (LE 886/4-1)
文摘The non-random two liquids （NRTL） equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies （h^E） and vapour-liquid equilibria （VLE） and the VLE prediction from h^E data. The calculation strategy for properly determining NRTL parameters and the effect of their temperature dependence on the simultaneous correlation of h^E and VLE data and the VLE extrapolation are analysed in detail.
文摘An equation of state （EOS） for high-pressure liquids, i.e., Tait EOS, is deduced according to isothermal 1 3V compressibility KT= -1/V· （2V/2p）T·.Based on the equation, a generalized EOS for high pressure-liquids is established by using the reduced state principle and introducing a characteristic parameter-configuration factor ξ. Reasonably satisfactory P-V-T data for many organic compounds, including some polar components, were calculated by using the equation.
基金Supported by the National Natural Science Foundation of China (No. 59995550-3) and Science Funds from the Ministry of Education (No. 97000357).
文摘The interfacial evaporative heat transfer was included in the semi-empirical study of the heat transfer for the falling liquid film flow. The investigations showed that, the inclusion of the interfacial eveiporative heat transfer in the turbulent model would lower the predicted convective heat transfer coefficient. Predictions of the new model resulted in a prominent deviation from that predictions of the normal model in the case of large mass flow rate and low wall heat flux. This deviation will be decreased with increasing wall heat flux, such that it will be asymptotic zero at very high wall heat flux. Predictions of the new model agreed well with the current experimental measurements. This study has verified that the Reynolds number is not the sole crucial parameter for heat transfer of falling liquid film flow, and wall heat flux will be another important independent parameter. This result is consistent with our previous studies.
文摘A new general equation of state is presented, which can be used to express not only common cubic equations of state, but also quartic equations of state and so on. Main advantage of the new equation over the previous general equations is that it is in simple form, and is easy to manipulate mathematically.
文摘A new numerical algorithm is presented to simulate the explosion reaction process of mine explosives based on the equation of state, the equation of mass conservation and thermodynamics balance equation of explosion products. With the affection of reversible reaction of explosion products to explosion reaction equations and thermodynamics parameters considered, the computer program has been developed. The computation values show that computer simulation results are identical with the testing ones.
文摘According to the construction characteristic of RCC dam cast by layers, three-dimensional finite element relocating mesh method is developed to simulate construction process and compute temperature field. The computation model of relocating mesh method is expatiated in detail; based on the thermodynamic properties of RCC materials, the feasibility and error of relocating mesh method are analyzed and demonstrated; The computation results in this article are verified by means of the temperature observation data of certain RCC gravity dam. The results show that the temperature field computed by three-dimensional finite element relocating mesh method can not only ensure the computation precision, but also improve the calculation efficiency greatly. This provides an effective method for simulating construction process and computing temperature field of RCC dam.
文摘In this paper, the standard k-ε two-equation model is adopted to numerically simulate fully developed fluid flow and heat transfer in a spiral finned tube within a cracking furnace for ethylene manufacturing. By variable transformation, the original 3-D problem is converted into a 2-D problem in spiral coordinates. The algorithm of SIMPLEC is used to study the fully developed fluid flow and heat transfer in the spiral finned tube at constant periphery temperature and constant axial heat flux. The computed results agree pretty well with the experimental data obtained from the industry. Further studies on the fluid flows and temperature profiles at different Reynolds numbers within straight and spiral finned tubes are conducted and the mechanisms involved are explored. It is found that with the spiral finned tube, pressure drop increases to a great extent whereas heat transfer tends to be decreased.
基金supported by the National Basic Research Program of China (2014CB932600)the National Natural Science Foundation of China (91433116, 11474214)+2 种基金Jiangsu Science and Technology Department (BK20140053)Bureau of Science and Technology of Suzhou Municipality (SYG201525, ZXG201422)the project of the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
文摘The reliable information about interface energetics of organic materials, especially the energy level alignment at organic heterostructures is of pronounced importance for unraveling the photon harvesting and charge separation process in organic photovoltaic(OPV) cells. This article provides an overview of interface energetics at typical planar and mixed donor-acceptor heterostructures, perovskite/organic hybrid interfaces, and their contact interfaces with charge collection layers. The substrate effect on energy level offsets at organic heterostructures and the processes that control and limit the OPV operation are presented. Recent efforts on interface engineering with electrical doping are also discussed.
