The novel calcium-silicate-hydrate(C-S-H)/paraffin composite phase change materials were synthesized using a discontinuous two-step nucleation method.Initially,the C-S-H precursor is separated and dried,followed by im...The novel calcium-silicate-hydrate(C-S-H)/paraffin composite phase change materials were synthesized using a discontinuous two-step nucleation method.Initially,the C-S-H precursor is separated and dried,followed by immersion in an aqueous environment to transform it into C-S-H.This two-step nucleation approach results in C-S-H with a specific surface area of 497.2 m^(2)/g,achieved by preventing C-S-H foil overlapping and refining its pore structure.When impregnated with paraffin,the novel C-S-H/paraffin composite exhibits superior thermal properties,such as a higher potential heat value of 148.3 J/g and an encapsulation efficiency of 81.6%,outperforming conventional C-S-H.Moreover,the composite material demonstrates excellent cyclic performance,indicating its potential for building thermal storage compared to other paraffin-based composites.Compared with the conventional method,this simple technology,which only adds conversion and centrifugation steps,does not negatively impact preparation costs,the environment,and resource consumption.This study provides valuable theoretical insights for designing thermal storage concrete materials and advancing building heat management.展开更多
The spallation of the concrete slabs or walls resulting from contact detonation constitutes risk to the personnel and equipment inside the structures because of the high speed concrete fragments even though the overal...The spallation of the concrete slabs or walls resulting from contact detonation constitutes risk to the personnel and equipment inside the structures because of the high speed concrete fragments even though the overall structures or structural members are not destroyed completely. Correctly predicting the damage caused by any potential contact detonation can lead to better fortification design to withstand the blast Ioadings. It is therefore of great significance to study the mechanism involved in the spallation of concrete slabs and walls. Existing studies on this topic often employ simplified material models and 1D wave analysis, which cannot reproduce the realistic response in the spallation process. Numerical simulations are therefore carried out under different contact blast Ioadings in the free air using LS-DYNA. Sophisticated concrete and reinforcing bar material models are adopted, taking into account the strain rate effect on both tension and compression. The erosion technique is used to model the fracture and failure of materials under tensile stress. Full processes of the deformation and dynamic damage of reinforced concrete （RC） slabs and plain concrete slabs are thus observed realistically. It is noted that with the increase of quantity of explosive, the dimensions of damage crater increase and the slabs experience four different damage patterns, namely explosive crater, spalling, perforation, and punching. Comparison between the simulation results of plain concrete slabs and those of RC slabs show that reinforcing bars can enhance the integrity and shearing resistance of the slabs to a certain extent, and meanwhile attenuate the ejection velocity and decrease the size of the concrete fragments. Therefore, optimizing reinforcement arrangement can improve the anti-spallation capability of the slabs and walls to a certain extent.展开更多
Projectile made of carbon fiber composite material shell and metal warhead penetrates concrete target at speeds of 336,m/s,447,m/s and 517,m/s.The angles between the perpendicu-lar of target surface and projectile axi...Projectile made of carbon fiber composite material shell and metal warhead penetrates concrete target at speeds of 336,m/s,447,m/s and 517,m/s.The angles between the perpendicu-lar of target surface and projectile axis are 0°and 30°.The thickness of concrete target is 200,mm and the compression strength is 30 MPa.The experimental results indicate that the strength of composite material structure is high.Composite projectile can go through concrete tar-get without fiber segregation and breakage.The percent fill is 18.5% in the composite material projectile.It is about twice as that of metal projectile,if the density of metal is taken as 7.8,g/cm3.Comparing with metal projectile,low-density,high-strength composite material can lessen projec-tile weight,improve charge-weight ratio of detonator and enhance destructive powder.展开更多
Numerical exercises are presented on the thermally induced motion of internally heated beams under various heat transfer and structural boundary conditions. The dynamic displacement and dynamic thermal moment of the b...Numerical exercises are presented on the thermally induced motion of internally heated beams under various heat transfer and structural boundary conditions. The dynamic displacement and dynamic thermal moment of the beam are analyzed taking into consideration that the temperature gradient is independent as well as dependent on the beam displacement. The effect of length to thickness ratio of the beam on the thermally induced vibration is also investigated. The type of boundary conditions has its influence on the magnitude of dynamic displacement and dynamic thermal moment. A sustained thermally induced motion is observed with progress of time when the temperature gradient being evaluated is dependent on the forced convection generated due to beam motion. A finite element method (FEM) is used to solve the structural equation of motion as well as the heat transfer equation.展开更多
To investigate the residual strength of concrete under fatigue loading, experiments were conducted to determine the functional relation between residual strength and the number of cycles. 80 100mm×100mm×100m...To investigate the residual strength of concrete under fatigue loading, experiments were conducted to determine the functional relation between residual strength and the number of cycles. 80 100mm×100mm×100mm specimens of plain concrete were tested under uniaxial compressive fatigue loading. Based on probability distribution of the residual strength of concrete under fatigue loading, the empirical expressions of the residual strength corresponding to the number of cycles were obtained. There is a good correlation between residual strength and residual secant elastic modulus. Thus the relationship between residual secant elastic modulus and the number of cycles is established. A damage variable based on the longitudinal maximum strain is defined, and a good linearity relationship between residual strength and damage is found out.展开更多
According to the data of the experiment made in mechanical tensile of Polycarbonate in high temperature, experiments were done to polycarbonate sheet by hot gas pressure bulge-forming. It was found that selecting and ...According to the data of the experiment made in mechanical tensile of Polycarbonate in high temperature, experiments were done to polycarbonate sheet by hot gas pressure bulge-forming. It was found that selecting and combination of the processing parameters were vital to the quality. In the experiments and numerical simulation with the software of DYNAFORM, the processing parameters have been studied.The results showed that the method of discontinuous pressure and pressure preservation advantage the forming; when temperature and pressure meet the forming conditions, the longer time of pressure preservation promotes sufficient forming.展开更多
The pullout testing of geosynthetics is essential for studying interface interaction in the soil-reinforcement system. In this paper, a new method for testing interface properties of geotextiles is proposed. The inter...The pullout testing of geosynthetics is essential for studying interface interaction in the soil-reinforcement system. In this paper, a new method for testing interface properties of geotextiles is proposed. The interface frictional characters of two kinds of geotextiles (woven and needle-punched nonwoven) are investigated through pullout test. Nonwoven specimen has more wide variety of displacement along length than that of woven under the same pressure because of their different extensibility. The greater the elongation and deformation of specimens, the more evident the variations of displacement along reinforcement from front to pullout end. The greater the normal pressure, the smaller the displacement of every position along length with the same pullout load. The study focuses on the effects of the tensile modulus and the difference of pullout response between woven and nonwoven geotextiles.展开更多
We prepared cold-setting cement with metakaolin from kaolin dehydrated at 800 ℃ and phosphate, and studied the phase composition, microstructure and setting reaction mechanism of the cementing material by means of in...We prepared cold-setting cement with metakaolin from kaolin dehydrated at 800 ℃ and phosphate, and studied the phase composition, microstructure and setting reaction mechanism of the cementing material by means of infrared spectroscopy, thermogravimetry, X-ray diffraction, and scanning electron microscopy. The metakaolin-phosphate cement is predominantly amorphous, where the phases responsible for chemical setting are mainly amorphous aluminophosphate hydrates. The reactivity of metakaolin depends on the particle size. Metakaolin particles of 1.75 μm in D50 have an acid dissolution index up to 18.45%, and the reaction with phosphate at room temperature to form metakaolin-phosphate cement takes only 6 h. The so obtained cement shows a compressive strength of 92.5 MPa after 7 d and keeps its amorphous phase at 1 000 ℃, demonstrating better bonding and mechanical properties and higher stability at a medium or high temperature.展开更多
基金The National Natural Science Foundation of China(No.52122802,52078126)Jiangsu Provincial Department of Science and Technology Innovation Support Program(No.BK20222004,BZ2022036).
文摘The novel calcium-silicate-hydrate(C-S-H)/paraffin composite phase change materials were synthesized using a discontinuous two-step nucleation method.Initially,the C-S-H precursor is separated and dried,followed by immersion in an aqueous environment to transform it into C-S-H.This two-step nucleation approach results in C-S-H with a specific surface area of 497.2 m^(2)/g,achieved by preventing C-S-H foil overlapping and refining its pore structure.When impregnated with paraffin,the novel C-S-H/paraffin composite exhibits superior thermal properties,such as a higher potential heat value of 148.3 J/g and an encapsulation efficiency of 81.6%,outperforming conventional C-S-H.Moreover,the composite material demonstrates excellent cyclic performance,indicating its potential for building thermal storage compared to other paraffin-based composites.Compared with the conventional method,this simple technology,which only adds conversion and centrifugation steps,does not negatively impact preparation costs,the environment,and resource consumption.This study provides valuable theoretical insights for designing thermal storage concrete materials and advancing building heat management.
基金Supported by the National Defense Preliminary Research Project Fund of Zhejiang University,and Qianjiang Talent Plan.
文摘The spallation of the concrete slabs or walls resulting from contact detonation constitutes risk to the personnel and equipment inside the structures because of the high speed concrete fragments even though the overall structures or structural members are not destroyed completely. Correctly predicting the damage caused by any potential contact detonation can lead to better fortification design to withstand the blast Ioadings. It is therefore of great significance to study the mechanism involved in the spallation of concrete slabs and walls. Existing studies on this topic often employ simplified material models and 1D wave analysis, which cannot reproduce the realistic response in the spallation process. Numerical simulations are therefore carried out under different contact blast Ioadings in the free air using LS-DYNA. Sophisticated concrete and reinforcing bar material models are adopted, taking into account the strain rate effect on both tension and compression. The erosion technique is used to model the fracture and failure of materials under tensile stress. Full processes of the deformation and dynamic damage of reinforced concrete （RC） slabs and plain concrete slabs are thus observed realistically. It is noted that with the increase of quantity of explosive, the dimensions of damage crater increase and the slabs experience four different damage patterns, namely explosive crater, spalling, perforation, and punching. Comparison between the simulation results of plain concrete slabs and those of RC slabs show that reinforcing bars can enhance the integrity and shearing resistance of the slabs to a certain extent, and meanwhile attenuate the ejection velocity and decrease the size of the concrete fragments. Therefore, optimizing reinforcement arrangement can improve the anti-spallation capability of the slabs and walls to a certain extent.
基金Supported by Arm Equipment Exploration Project(No.6130516).
文摘Projectile made of carbon fiber composite material shell and metal warhead penetrates concrete target at speeds of 336,m/s,447,m/s and 517,m/s.The angles between the perpendicu-lar of target surface and projectile axis are 0°and 30°.The thickness of concrete target is 200,mm and the compression strength is 30 MPa.The experimental results indicate that the strength of composite material structure is high.Composite projectile can go through concrete tar-get without fiber segregation and breakage.The percent fill is 18.5% in the composite material projectile.It is about twice as that of metal projectile,if the density of metal is taken as 7.8,g/cm3.Comparing with metal projectile,low-density,high-strength composite material can lessen projec-tile weight,improve charge-weight ratio of detonator and enhance destructive powder.
文摘Numerical exercises are presented on the thermally induced motion of internally heated beams under various heat transfer and structural boundary conditions. The dynamic displacement and dynamic thermal moment of the beam are analyzed taking into consideration that the temperature gradient is independent as well as dependent on the beam displacement. The effect of length to thickness ratio of the beam on the thermally induced vibration is also investigated. The type of boundary conditions has its influence on the magnitude of dynamic displacement and dynamic thermal moment. A sustained thermally induced motion is observed with progress of time when the temperature gradient being evaluated is dependent on the forced convection generated due to beam motion. A finite element method (FEM) is used to solve the structural equation of motion as well as the heat transfer equation.
文摘To investigate the residual strength of concrete under fatigue loading, experiments were conducted to determine the functional relation between residual strength and the number of cycles. 80 100mm×100mm×100mm specimens of plain concrete were tested under uniaxial compressive fatigue loading. Based on probability distribution of the residual strength of concrete under fatigue loading, the empirical expressions of the residual strength corresponding to the number of cycles were obtained. There is a good correlation between residual strength and residual secant elastic modulus. Thus the relationship between residual secant elastic modulus and the number of cycles is established. A damage variable based on the longitudinal maximum strain is defined, and a good linearity relationship between residual strength and damage is found out.
基金Sponsored by the Scientific Research Foundation of Harbin Institute of Technology(Grant No.HIT.2000.65).
文摘According to the data of the experiment made in mechanical tensile of Polycarbonate in high temperature, experiments were done to polycarbonate sheet by hot gas pressure bulge-forming. It was found that selecting and combination of the processing parameters were vital to the quality. In the experiments and numerical simulation with the software of DYNAFORM, the processing parameters have been studied.The results showed that the method of discontinuous pressure and pressure preservation advantage the forming; when temperature and pressure meet the forming conditions, the longer time of pressure preservation promotes sufficient forming.
文摘The pullout testing of geosynthetics is essential for studying interface interaction in the soil-reinforcement system. In this paper, a new method for testing interface properties of geotextiles is proposed. The interface frictional characters of two kinds of geotextiles (woven and needle-punched nonwoven) are investigated through pullout test. Nonwoven specimen has more wide variety of displacement along length than that of woven under the same pressure because of their different extensibility. The greater the elongation and deformation of specimens, the more evident the variations of displacement along reinforcement from front to pullout end. The greater the normal pressure, the smaller the displacement of every position along length with the same pullout load. The study focuses on the effects of the tensile modulus and the difference of pullout response between woven and nonwoven geotextiles.
基金Fankou Cement Company Limited, Dachang Construction Materials under the Contract No. 2004440003050237.
文摘We prepared cold-setting cement with metakaolin from kaolin dehydrated at 800 ℃ and phosphate, and studied the phase composition, microstructure and setting reaction mechanism of the cementing material by means of infrared spectroscopy, thermogravimetry, X-ray diffraction, and scanning electron microscopy. The metakaolin-phosphate cement is predominantly amorphous, where the phases responsible for chemical setting are mainly amorphous aluminophosphate hydrates. The reactivity of metakaolin depends on the particle size. Metakaolin particles of 1.75 μm in D50 have an acid dissolution index up to 18.45%, and the reaction with phosphate at room temperature to form metakaolin-phosphate cement takes only 6 h. The so obtained cement shows a compressive strength of 92.5 MPa after 7 d and keeps its amorphous phase at 1 000 ℃, demonstrating better bonding and mechanical properties and higher stability at a medium or high temperature.
