In order to improve the purifying efficiency of RJ6 flux,5%(mass fraction) GdCl3 was introduced into the flux for refining Mg-10Gd-3Y-0.5Zr(GW103K) alloy.The results show that the RJ6 flux containing 5%GdCl3 exhibits ...In order to improve the purifying efficiency of RJ6 flux,5%(mass fraction) GdCl3 was introduced into the flux for refining Mg-10Gd-3Y-0.5Zr(GW103K) alloy.The results show that the RJ6 flux containing 5%GdCl3 exhibits better adsorption ability to nonmetallic inclusions than the one without GdCl3.Moreover,the mechanical,corrosion properties and fluidity of the alloy refined with RJ6 flux and RJ6 flux containing 5%GdCl3 were investigated,respectively.It is found that these properties are improved to a certain degree due to the removal of nonmetallic inclusions in the alloy.Thermodynamic analysis and surface tension experiments indicate that the main reason can be ascribed to the decrease of the surface tension of the flux with 5%GdCl3,which promotes the combination of flux and nonmetallic inclusions.展开更多
An interfacial equation of state based on perturbation theory for surfactant-oil-water system has been developed. By combining the interfacial equation of state with Boudh-Hir and Mansoori's model, a molecular the...An interfacial equation of state based on perturbation theory for surfactant-oil-water system has been developed. By combining the interfacial equation of state with Boudh-Hir and Mansoori's model, a molecular ther-modynamic model has been proposed. The interfacial tension of surfactant-oil-water systems can be calculated from the surface tensions of pure oil and water by this model. The interfacial tension data for sodium dodecyl sulphate-heptane-water system, polyoxyethylene n-octylphenol-heptane-water system and hexadecyl trimethyl ammonium bromide-heptane-water system have been correlated. By using the adjustable parameters obtained, the interfacial tensions of these systems at other temperatures have been predicted. Both the correlated and the predicted values are satisfactory.展开更多
Heat transfer characteristics between the immersed heater and the bed content were studied in the riser of a liquid-solid circulating fluidized bed, whose diameter and height were 0.102 m (ID) and 2.5 m, respectively....Heat transfer characteristics between the immersed heater and the bed content were studied in the riser of a liquid-solid circulating fluidized bed, whose diameter and height were 0.102 m (ID) and 2.5 m, respectively. Effects of liquid velocity, particle size, surface tension of liquid phase and solid circulation rate on the overall heat transfer coefficient were examined. The heat transfer coefficient increased with increasing particle size or solid circulation rate due to the higher potential of particles to contact with the heater surface and promote turbulence near the heater surface. The value of heat transfer coefficient increased gradually with increase in the surface tension of liquid phase, due to the slight increase of solid holdup. The heat transfer coefficient increased with the liquid velocity even in the higher range, due to the solid circulation prevented the decrease in solid holdup, in contrast to that in the conventional liquid-solid fluidized beds. The values of heat transfer coefficient were well correlated in terms of dimensionless groups as well as operating variables.展开更多
The best track data of tropical cyclones (TCs) provided by Regional Specialized Meteorological Center (RSMC) Tokyo for the South China Sea (SCS) from 1977 to 2007 are employed to study the spatiotemporal variations (f...The best track data of tropical cyclones (TCs) provided by Regional Specialized Meteorological Center (RSMC) Tokyo for the South China Sea (SCS) from 1977 to 2007 are employed to study the spatiotemporal variations (for a period of 12 hours) and the rapid (slow) intensification (RI/SI) of TCs with different intensity. The main results are as follows. (1) Over this period, the tropical storms (TSs) and severe tropical storms (STSs) mostly intensify or are steady while the typhoons (TYs) mostly weaken. The stronger a TC is initially, the more observation of its intensification and the less its variability will be; the more observation of its weakening is, the larger its variability will be. (2) The TC intensifies the fastest at 0000 UTC while weakening the fastest at 1200 UTC. (3) In the intensifying state, TSs, STSs, and TYs are mainly active in the northeastern, central-eastern, and central SCS respectively. The weakening cases mainly distribute over waters east off Hainan Island and Vietnam and west off the Philippines. Some cases of TSs and STSs weaken over the central SCS. (4) The RI cases form farther south in contrast to the SI cases. The RI cases are observed in regions where there are weaker vertical shear and easterly components at 200 hPa. The RI cases also have stronger mid-and lower-level warm-core structure and smaller radii of 15.4 m/s winds. The SI cases have slightly higher SST.展开更多
Observation and measurement were conducted to investigate contact angle andits hysteresis on rough surface. The experimental results indicate that the increase in solidsurface roughness enlarges advancing contact angl...Observation and measurement were conducted to investigate contact angle andits hysteresis on rough surface. The experimental results indicate that the increase in solidsurface roughness enlarges advancing contact angle and decreases receding contact angle, resultingin enhanced hysteresis. It was observed that when Young''s contact angle θ_Y 【 90°, as theroughness of solid surface increased the extent of the decrease in receding contact angle exceededthat of the increase in advancing contact angle. Based on the experimental observations, the conceptof hysteresis tension was introduced to describe the contact angle hysteresis behavior on roughsolid surface. The model provides a thoughtful understanding of the physical nature of contact anglehysteresis, in particular an instructive description of the influence of surface roughness on thehysteresis. The prediction of the model is found in quite good agreement with the experimentalobservation and measurement.展开更多
Gegen Qinlian Decoction is one of the commonly used classical prescriptions,which consists of fourherbs:Gegen(Puerariae Lobatae Radix),Huangqin(Scutellariae Radix),Huanglian(Coptidis Rhizoma),and Zhigancao Glycyrrhiza...Gegen Qinlian Decoction is one of the commonly used classical prescriptions,which consists of fourherbs:Gegen(Puerariae Lobatae Radix),Huangqin(Scutellariae Radix),Huanglian(Coptidis Rhizoma),and Zhigancao Glycyrrhizae Radix et Rhizoma Praeparata cum Melle.The clinical application experience of Gegen Qinlian Decoction is as follows:first,according to Zhongjing Zhang's original text,heat distressing the large intestine with unresolved exterior syndrome is theoriginal meaningof Gegen Qinlian Decoction syndrome.In clinical practice,bacillary dysentery,gastrointestinal cold,etc.,belong to simultaneous exterior and interior disease,which are completely consistent with the original meaning of this prescription;second,the clinical digestive system diseases with exuberant heat of the large intestine as the core manifestation cannot be treated merely based on the exterior syndrome;third,due to the interior-exterior relationship between the lung and the large intestine and between the meridians,the use of Gegen(Puerariae Lobatae Radix),Huangqin(Scutellariae Radix),and Huanglian(Coptidis Rhizoma)can make the source of body clear,and the waste qi can be released and thepore can be easily opened,so this prescription can also be used for exogenous fever;fourth,with multidimensional comprehensive understanding of the syndrome,pathogenesis,symptoms and pharmacology,Gegen Qinlian Decoction has also been further applied to the treatment of hypertension,diabetes,etc.展开更多
The elemental composition,heat expansibility and breaking characteristics of limestone have been investigated with the use of an energy spectrum analyzer,a SEM,an optical microscope and an experimental heat swelling p...The elemental composition,heat expansibility and breaking characteristics of limestone have been investigated with the use of an energy spectrum analyzer,a SEM,an optical microscope and an experimental heat swelling power system.The results show that 1) the heat expansibility of limestone has anisotropic properties,and 2) the heat expansion rate in the direction perpendicular to stratification is eight times greater than the rate parallel to stratification.The changes in heat expansibility as a function of heating temperature is essentially coincident with that of swelling and breaking of mineral particles and the appearance of cracks,indicating that the reason for causing the heat expansion of rock are the structural changes of limestone caused by thermal stress,crystal transformation and mineral decomposition.The apparent destruction of limestone under high temperatures is largely characterized by rock stratification breaks.When the limestone is heated beyond a certain limit,the rock destroys into crazed cracks.展开更多
Biological and synthetic surfactants were compared in terms of their ability to reduce interfacial tension, change the thermodynamic characteristics of a pre-conditioned surface, and to modify the rheological properti...Biological and synthetic surfactants were compared in terms of their ability to reduce interfacial tension, change the thermodynamic characteristics of a pre-conditioned surface, and to modify the rheological properties of their respective formulations at two different temperatures. Both classes of suffactants were able to reduce the inteffacial tension of their formulations to a similar level. However, the biosurfactants were more effective than the synthetics surfactants. Biosurfactants also altered the surface properties of stainless steel, rendering it hydrophilic. Microbial adhesion to stainless steel conditioned with biosurfactants was found to be thermodynamically unfavorable for all microbial strains tested. A linear relationship between shear stress and shear rate was obtained across a range of experimental conditions for all surfactant mixtures, indicating that all formulations behaved as Newtonian fluids.展开更多
V-4Cr-4Ti is the leading candidate vanadium alloy for fusion applications as structural material of first wall and blanket. Due to the interaction between Ti and interstitial solutes of C, N, and O, precipitation occu...V-4Cr-4Ti is the leading candidate vanadium alloy for fusion applications as structural material of first wall and blanket. Due to the interaction between Ti and interstitial solutes of C, N, and O, precipitation occurs at elevated temperature. The behavior has been studied in the past few years by short time annealing and results showed that it may greatly affect its mechanical properties Ti-CON type precipitates, appearing at- 700℃ in the solid-solution annealed alloy in high number density and small size, strengthen the alloy significantly and reduce its ductility. As the ductility reduction is in an acceptable level, the strengthening might be utilized for a light and strong vanadium alloy structure. Before a conclusion, uncertainty of its thermal stability should be studied during the high temperature serves. Besides, seldom has been studied for the effect of long time aging on precipitation behavior and tensile properties of the alloy.展开更多
Excitation of surface resonance modes and presence of resonance-free hyperbolic modes are two common ways to enhance the near-field radiative energy transport, which can find wide applications in noncontact thermal ma...Excitation of surface resonance modes and presence of resonance-free hyperbolic modes are two common ways to enhance the near-field radiative energy transport, which can find wide applications in noncontact thermal management and energy harvesting.Here, we identify another way to achieve the super-Planckian thermal radiation via hyperbolic surface phonon polaritons(HSPhPs). Based on the fluctuation-dissipation theory, the near-field radiative heat flux between bulk hexagonal boron nitride(hBN) planes with the optical axis perpendicular to the radiative energy flow can be 120 times as large as the blackbody limit for a gap distance of 20 nm. When the film thickness is reduced to 10 nm, the radiative heat flux is found to increase by 26.3%.The underlying mechanism is attributed to the coupling of Type I HSPhPs inside the anisotropic hBN film, which improves the energy transmission coefficient over a broad wavevector space especially for waves with extremely high wavevectors. This work helps to deepen the understanding of near-field radiation between natural hyperbolic materials, and opens a new route to enhance the near-field thermal radiation.展开更多
This study investigated the effect of heat treatment combined with acid and alkali on the angiotensin-I- converting enzyme (ACE) inhibitory activity of peptides derived from bovine casein. The free amino group conte...This study investigated the effect of heat treatment combined with acid and alkali on the angiotensin-I- converting enzyme (ACE) inhibitory activity of peptides derived from bovine casein. The free amino group content, color, and cytotoxicity of the peptides were measured under different conditions. When heated at 100 ℃ in the pH range from 9.0 to 12.0, ACE inhibitory activity was reduced and the appearance of the peptides was significantly darkened. After thermal treatment in the presence of acid and alkali, the free amino group content of ACE inhibitory peptides decreased markedly. High temperature and prolonged heating also resulted in the loss of ACE inhibitory activity, the loss of free amino groups, and the darker coloration of bovine casein-derived peptides. However, ACE inhibitory peptides, within a concentration range of from 0.01 to 0.2 mg/ml, showed no cytotoxicity to Caco-2 and ECV-304 cell lines after heat treatment. This indicated that high temperature and alkaline heat treatment impaired the stability of bovine casein-derived ACE inhibitory peptides.展开更多
Structural and thermal sensitivity of Cu(60-x)Zr(30+x) Ti 10 (x=0,5,and 10 at%) amorphous alloys to the application of tension was investigated. The structural sensitivity to tension decreases with increasing Cu conte...Structural and thermal sensitivity of Cu(60-x)Zr(30+x) Ti 10 (x=0,5,and 10 at%) amorphous alloys to the application of tension was investigated. The structural sensitivity to tension decreases with increasing Cu content. The crystallization enthalpy increases with increasing excess free volume. The characteristic temperatures of the tensile samples can surpass those of the as-cast ones under a critical heating rate which differs in the Cu content. The increase of the excess free volume significantly influences the glass transition and crystallization procedures.展开更多
With the usual definitions for the entropy and the temperature associated with the apparent horizon, we discuss the first law of the thermodynamics on the apparent in the general scalar-tensor theory of gravity with t...With the usual definitions for the entropy and the temperature associated with the apparent horizon, we discuss the first law of the thermodynamics on the apparent in the general scalar-tensor theory of gravity with the kinetic term of the scalar field nonminimally coupling to Einstein tensor. We show the equivalence between the first law of thermodynamics on the apparent horizon and Friedmann equation for the general models, by using a mass-like function which is equal to the Misner-Sharp mass on the apparent horizon. The results further support the universal relationship between the first law of thermodynamics and Friedmann equation.展开更多
基金Project(08XD14020) supported by Program of Shanghai Subject Chief ScientistProject(2007CB613701) supported by the National Basic Research Program of ChinaProject(2009AA033501) supported by High-tech Research and Development Program of China
文摘In order to improve the purifying efficiency of RJ6 flux,5%(mass fraction) GdCl3 was introduced into the flux for refining Mg-10Gd-3Y-0.5Zr(GW103K) alloy.The results show that the RJ6 flux containing 5%GdCl3 exhibits better adsorption ability to nonmetallic inclusions than the one without GdCl3.Moreover,the mechanical,corrosion properties and fluidity of the alloy refined with RJ6 flux and RJ6 flux containing 5%GdCl3 were investigated,respectively.It is found that these properties are improved to a certain degree due to the removal of nonmetallic inclusions in the alloy.Thermodynamic analysis and surface tension experiments indicate that the main reason can be ascribed to the decrease of the surface tension of the flux with 5%GdCl3,which promotes the combination of flux and nonmetallic inclusions.
基金Supported by the National Nature Science Foundation of China(No.29736170)
文摘An interfacial equation of state based on perturbation theory for surfactant-oil-water system has been developed. By combining the interfacial equation of state with Boudh-Hir and Mansoori's model, a molecular ther-modynamic model has been proposed. The interfacial tension of surfactant-oil-water systems can be calculated from the surface tensions of pure oil and water by this model. The interfacial tension data for sodium dodecyl sulphate-heptane-water system, polyoxyethylene n-octylphenol-heptane-water system and hexadecyl trimethyl ammonium bromide-heptane-water system have been correlated. By using the adjustable parameters obtained, the interfacial tensions of these systems at other temperatures have been predicted. Both the correlated and the predicted values are satisfactory.
基金Supported by Korea Institute of Energy Technology Evaluation and Planning (KETEP)GTL Technology Development Consortium (Korean National Oil Corp., Korea Gas Corp., Daelim Industrial Co. and Hyundai Engineering Co.) under "Energy Efficiency & Resources Programs" of the Ministry of Knowledge Economy, Republic of Korea
文摘Heat transfer characteristics between the immersed heater and the bed content were studied in the riser of a liquid-solid circulating fluidized bed, whose diameter and height were 0.102 m (ID) and 2.5 m, respectively. Effects of liquid velocity, particle size, surface tension of liquid phase and solid circulation rate on the overall heat transfer coefficient were examined. The heat transfer coefficient increased with increasing particle size or solid circulation rate due to the higher potential of particles to contact with the heater surface and promote turbulence near the heater surface. The value of heat transfer coefficient increased gradually with increase in the surface tension of liquid phase, due to the slight increase of solid holdup. The heat transfer coefficient increased with the liquid velocity even in the higher range, due to the solid circulation prevented the decrease in solid holdup, in contrast to that in the conventional liquid-solid fluidized beds. The values of heat transfer coefficient were well correlated in terms of dimensionless groups as well as operating variables.
基金Specialized Project for Forecasters, China Meteorological Administration 2011(CMAYBY2011-041)
文摘The best track data of tropical cyclones (TCs) provided by Regional Specialized Meteorological Center (RSMC) Tokyo for the South China Sea (SCS) from 1977 to 2007 are employed to study the spatiotemporal variations (for a period of 12 hours) and the rapid (slow) intensification (RI/SI) of TCs with different intensity. The main results are as follows. (1) Over this period, the tropical storms (TSs) and severe tropical storms (STSs) mostly intensify or are steady while the typhoons (TYs) mostly weaken. The stronger a TC is initially, the more observation of its intensification and the less its variability will be; the more observation of its weakening is, the larger its variability will be. (2) The TC intensifies the fastest at 0000 UTC while weakening the fastest at 1200 UTC. (3) In the intensifying state, TSs, STSs, and TYs are mainly active in the northeastern, central-eastern, and central SCS respectively. The weakening cases mainly distribute over waters east off Hainan Island and Vietnam and west off the Philippines. Some cases of TSs and STSs weaken over the central SCS. (4) The RI cases form farther south in contrast to the SI cases. The RI cases are observed in regions where there are weaker vertical shear and easterly components at 200 hPa. The RI cases also have stronger mid-and lower-level warm-core structure and smaller radii of 15.4 m/s winds. The SI cases have slightly higher SST.
文摘Observation and measurement were conducted to investigate contact angle andits hysteresis on rough surface. The experimental results indicate that the increase in solidsurface roughness enlarges advancing contact angle and decreases receding contact angle, resultingin enhanced hysteresis. It was observed that when Young''s contact angle θ_Y 【 90°, as theroughness of solid surface increased the extent of the decrease in receding contact angle exceededthat of the increase in advancing contact angle. Based on the experimental observations, the conceptof hysteresis tension was introduced to describe the contact angle hysteresis behavior on roughsolid surface. The model provides a thoughtful understanding of the physical nature of contact anglehysteresis, in particular an instructive description of the influence of surface roughness on thehysteresis. The prediction of the model is found in quite good agreement with the experimentalobservation and measurement.
基金supported by the Project of Traditional Chinese Medicine Academic School Inheritance Workshop Construction of the National Administration of Traditional Chinese Medicine-YanjingLiu's Typhoid Fever School InheritanceWorkshop(LPGZS 2019-01)Projectof Chinese Medicine Master Inheritance Workshop of National Administration of Traditional Chinese Medicine-Qingguo Wang Inheritance Workshaop(2014011)the Sixth Batch of National Chinese Medicine Senior Experts Academic Experience Inheritance Project of National Administration of Traditional Chinese Medicine(2017-01).
文摘Gegen Qinlian Decoction is one of the commonly used classical prescriptions,which consists of fourherbs:Gegen(Puerariae Lobatae Radix),Huangqin(Scutellariae Radix),Huanglian(Coptidis Rhizoma),and Zhigancao Glycyrrhizae Radix et Rhizoma Praeparata cum Melle.The clinical application experience of Gegen Qinlian Decoction is as follows:first,according to Zhongjing Zhang's original text,heat distressing the large intestine with unresolved exterior syndrome is theoriginal meaningof Gegen Qinlian Decoction syndrome.In clinical practice,bacillary dysentery,gastrointestinal cold,etc.,belong to simultaneous exterior and interior disease,which are completely consistent with the original meaning of this prescription;second,the clinical digestive system diseases with exuberant heat of the large intestine as the core manifestation cannot be treated merely based on the exterior syndrome;third,due to the interior-exterior relationship between the lung and the large intestine and between the meridians,the use of Gegen(Puerariae Lobatae Radix),Huangqin(Scutellariae Radix),and Huanglian(Coptidis Rhizoma)can make the source of body clear,and the waste qi can be released and thepore can be easily opened,so this prescription can also be used for exogenous fever;fourth,with multidimensional comprehensive understanding of the syndrome,pathogenesis,symptoms and pharmacology,Gegen Qinlian Decoction has also been further applied to the treatment of hypertension,diabetes,etc.
基金Project 50574037 supported by the National Natural Science Foundation of China
文摘The elemental composition,heat expansibility and breaking characteristics of limestone have been investigated with the use of an energy spectrum analyzer,a SEM,an optical microscope and an experimental heat swelling power system.The results show that 1) the heat expansibility of limestone has anisotropic properties,and 2) the heat expansion rate in the direction perpendicular to stratification is eight times greater than the rate parallel to stratification.The changes in heat expansibility as a function of heating temperature is essentially coincident with that of swelling and breaking of mineral particles and the appearance of cracks,indicating that the reason for causing the heat expansion of rock are the structural changes of limestone caused by thermal stress,crystal transformation and mineral decomposition.The apparent destruction of limestone under high temperatures is largely characterized by rock stratification breaks.When the limestone is heated beyond a certain limit,the rock destroys into crazed cracks.
文摘Biological and synthetic surfactants were compared in terms of their ability to reduce interfacial tension, change the thermodynamic characteristics of a pre-conditioned surface, and to modify the rheological properties of their respective formulations at two different temperatures. Both classes of suffactants were able to reduce the inteffacial tension of their formulations to a similar level. However, the biosurfactants were more effective than the synthetics surfactants. Biosurfactants also altered the surface properties of stainless steel, rendering it hydrophilic. Microbial adhesion to stainless steel conditioned with biosurfactants was found to be thermodynamically unfavorable for all microbial strains tested. A linear relationship between shear stress and shear rate was obtained across a range of experimental conditions for all surfactant mixtures, indicating that all formulations behaved as Newtonian fluids.
文摘V-4Cr-4Ti is the leading candidate vanadium alloy for fusion applications as structural material of first wall and blanket. Due to the interaction between Ti and interstitial solutes of C, N, and O, precipitation occurs at elevated temperature. The behavior has been studied in the past few years by short time annealing and results showed that it may greatly affect its mechanical properties Ti-CON type precipitates, appearing at- 700℃ in the solid-solution annealed alloy in high number density and small size, strengthen the alloy significantly and reduce its ductility. As the ductility reduction is in an acceptable level, the strengthening might be utilized for a light and strong vanadium alloy structure. Before a conclusion, uncertainty of its thermal stability should be studied during the high temperature serves. Besides, seldom has been studied for the effect of long time aging on precipitation behavior and tensile properties of the alloy.
基金the startup fund from Nanjing University of Aeronautics and Astronautics (Grant No. 90YAH16057)
文摘Excitation of surface resonance modes and presence of resonance-free hyperbolic modes are two common ways to enhance the near-field radiative energy transport, which can find wide applications in noncontact thermal management and energy harvesting.Here, we identify another way to achieve the super-Planckian thermal radiation via hyperbolic surface phonon polaritons(HSPhPs). Based on the fluctuation-dissipation theory, the near-field radiative heat flux between bulk hexagonal boron nitride(hBN) planes with the optical axis perpendicular to the radiative energy flow can be 120 times as large as the blackbody limit for a gap distance of 20 nm. When the film thickness is reduced to 10 nm, the radiative heat flux is found to increase by 26.3%.The underlying mechanism is attributed to the coupling of Type I HSPhPs inside the anisotropic hBN film, which improves the energy transmission coefficient over a broad wavevector space especially for waves with extremely high wavevectors. This work helps to deepen the understanding of near-field radiation between natural hyperbolic materials, and opens a new route to enhance the near-field thermal radiation.
基金supported by the Innovative Research Team of Higher Education of Heilongjiang Province(No.2010td11)the National Natural Science Foundation of China(No.31000801)+1 种基金the National Key Technology R&D Program of China during the 12th Five-Year Plan Period(No.2013BAD18B06)the 2009 Doctoral Science Research of Northeast Agricultural University,China
文摘This study investigated the effect of heat treatment combined with acid and alkali on the angiotensin-I- converting enzyme (ACE) inhibitory activity of peptides derived from bovine casein. The free amino group content, color, and cytotoxicity of the peptides were measured under different conditions. When heated at 100 ℃ in the pH range from 9.0 to 12.0, ACE inhibitory activity was reduced and the appearance of the peptides was significantly darkened. After thermal treatment in the presence of acid and alkali, the free amino group content of ACE inhibitory peptides decreased markedly. High temperature and prolonged heating also resulted in the loss of ACE inhibitory activity, the loss of free amino groups, and the darker coloration of bovine casein-derived peptides. However, ACE inhibitory peptides, within a concentration range of from 0.01 to 0.2 mg/ml, showed no cytotoxicity to Caco-2 and ECV-304 cell lines after heat treatment. This indicated that high temperature and alkaline heat treatment impaired the stability of bovine casein-derived ACE inhibitory peptides.
基金the National Natural Science Foundation (Grant No. 50874045)the Scientific Research Fund of the Hunan Provincial Education Department (Grant No. 10A044)
文摘Structural and thermal sensitivity of Cu(60-x)Zr(30+x) Ti 10 (x=0,5,and 10 at%) amorphous alloys to the application of tension was investigated. The structural sensitivity to tension decreases with increasing Cu content. The crystallization enthalpy increases with increasing excess free volume. The characteristic temperatures of the tensile samples can surpass those of the as-cast ones under a critical heating rate which differs in the Cu content. The increase of the excess free volume significantly influences the glass transition and crystallization procedures.
基金supported by the National Natural Science Foundation of China(Grant Nos.11175270 and 11475065)the Program for New Century Excellent Talents in University(Grant No.NCET-12-0205)
文摘With the usual definitions for the entropy and the temperature associated with the apparent horizon, we discuss the first law of the thermodynamics on the apparent in the general scalar-tensor theory of gravity with the kinetic term of the scalar field nonminimally coupling to Einstein tensor. We show the equivalence between the first law of thermodynamics on the apparent horizon and Friedmann equation for the general models, by using a mass-like function which is equal to the Misner-Sharp mass on the apparent horizon. The results further support the universal relationship between the first law of thermodynamics and Friedmann equation.