把握教学本质 培养学科思维——以“微观粒子专题复习”教学为例

化学教师要关注学生的学习过程,通过基于数据和调研进行学情诊断、基于学习问题进行针对性突破、基于能力提升进行拓展延伸,让学生收获知识、发展思维。以“微观粒子专题复习”为例,设计有价值的学习活动,把握教学本质,培养学生的学科思维,立足学科强化育人功能。

Dissipative Particle Dynamics Simulation of Microscopic Properties in Diblock Copolymer Films

Mean-square bond length, root-mean-square end-to-end distance and gyration radius in diblock copolymer films have been studied by dissipative particle dynamics simulations. Results show evident linear trends of any property separately with the thickness of film, the interaction between particles of different types, the repulsion between particle and boundary, except for the dependence of the variations of mean-square bond length on the thickness of film, which exhibits as a wave trend. What＇s more, the varying trends of mean-square bond length and root-mean-square end-to-end distance can correspond to each other. The density distribution of either component in diblock copolymer film can be controlled and adjusted effectively through its interaction with boundary.

Limit Properties of One Dimensional Periodic Hopping Model

One dimensional periodic hopping model is useful to understand the motion of microscopic particles in thermal noise environment. In this research, by formal calculation and based on detailed balance, the explicit expressions of the limits of mean velocity and diffusion constant of this model as the number of internal mechanochemical sates tend to infinity are obtained.These results will be helpful to understand the limit of the one dimensional hopping model.At the same time, the work can be used to get more useful results in continuous form from the corresponding ones obtained by discrete models.

Application of the DEM to screening process:a 3D simulation

The discrete element method(DEM) has been widely used to simulate microscopic interactions between particles.Screening is a deeply complicated process when considering the law of motion for the particles,themselves.In this paper,a numerical model for the study of a particle screening process using the DEM is presented.Special attention was paid to the modeling of a vibrating screen that allows particles to pass through,or to rebound,when approaching the screen surface.Inferences concerning screen length and vibrating frequency as they relate to screening efficiency were studied.The conclusions were:three-dimensional simulation of screening efficiency along the screen length follows an exponential distribution;when the sieve vibrates over a certain frequency range the screening efficiency is stable;and,higher vibration frequencies can improve the handling capacity of the screening machine.

Beginning of a New Revolution of Science ＆ Technology

Modern science and technology is being developed towards destroying human and human calls for a new era of science ＆ technology. Contemporary science is seeing a significant breakthrough and a new revolution of science and technology is beginning. The theoretical basis of the new revolution of science and technology is ＂state space-time＂, ＂the unity of physics and biology＂, ＂thinking motion and automatic organization of the universe＂ and ＂thinking＇s active control＂. The new revolution of science and technology takes material （microscopic particle） science, life （organic and inorganic life） science and thinking science as the fundamental sciences, takes life technology, new information technology, new material technology and new energy technology as the basis of the overall technological system, progresses in all aspects, including life technology, medicine, new material technology, new information technology, new energy technology, new robot technology, new manufacturing technology, laser technology, astronavigation technology, ocean technology, military technology, new educational technology, etc., and at the same time Qigong technology with thinking control as its core will emerge. In the era of life, thinking and Qigong technology, technology proceeds very rapidly, global society and economy develop at a high speed, and globalization is accelerated. Life, thinking and Qigong technologies feature improvement of human internal energy and quality, purify human soul, reduce material desire, and greatly reduce environmental disruption. The overall （thinking and Qigong） technology takes the establishment of the cosmic era of human as its ultimate goal.

Thermodynamic Performance Characteristics of a Brownian Microscopic Heat Engine Driven by Discrete and Periodic Temperature Field

A Brownian microscopic heat engine with a particle hopping on a one-dimensional lattice driven by adiscrete and periodic temperature field in a periodic sawtooth potential is investigated.In order to clarify the underlyingphysical pictures of the heat engine, the heat flow via the potential energy and the kinetic energy of the particles areconsidered simultaneously.Based on describing the jumps among the three states, the expressions of the efficiency andpower output of the heat engine are derived analytically.The general performance characteristic curves are plotted bynumerical calculation.It is found that the power output-efficiency curve is a loop-shaped one, which is similar to onefor a real irreversible heat engine.The influence of the ratio of the temperature of the hot and cold reservoirs and thesawtooth potential on the maximum efficiency and power output is analyzed for some given parameters.When the heatflows via the kinetic energy is neglected, the power output-efficiency curve is an open-shaped one, which is similar to onefor an endroeversible heat engine.

Microstructure and properties of Al-doped ODS steels prepared by wet-milling and SPS methods

In this paper,15Cr-ODS steels containing 0,1 wt%,2 wt%and 3 wt%Al element were fabricated by combining wet-milling and spark plasma sintering(SPS)methods.The microstructure and mechanical properties of ODS steel were investigated by XRD,SEM,TEM,EBSD and tensile tests.The results demonstrate that the Al addition significantly refines the particle precipitates in the Fe-Cr matrix,leading to the obvious refinement in grain size of matrix and the improvement of mechanical properties.The dispersion particles in ODS steels with Al addition are identified as Al2O3 and Y_(2)Ti_(2)O_(7)nanoparticles,which has a heterogeneous size distribution in the range of 5 nm to 300 nm.Increasing Al addition causes an obvious increase in tensile strength and a decline in elongation.The tensile strength and elongation of 15Cr-ODS steel containing 3 wt%Al are 775.3 MPa and 15.1%,respectively.The existence of Al element improves the corrosion resistance of materials.The ODS steel containing 2 wt%Al shows corrosion potential of 0.39 V and passivation current density of 2.61×10^(−3)A/cm^(2)(1.37 V).This work shows that Al-doped ODS steels prepared by wet-milling and SPS methods have a potential application in structural parts for nuclear system.

Prediction of Thermophoretic Deposition Efficiency of Particles in a Laminar Gas Flow along a Concentric Annulus： A Comparison of Developing and Fully Developed Flows

Thermophoresis is an important mechanism of micro-particle transport due to temperature gradients in the surrounding medium.It has numerous applications,especially in the field of aerosol technology.This study has numerically investigated the thermophoretic deposition efficiency of particles in a laminar gas flow in a concentric annulus using the critical trajectory method.The governing equations are the momentum and energy equations for the gas and the particle equations of motion.The effects of the annulus size,particle diameter,the ratio of inner to outer radius of tube and wall temperature on the deposition efficiency were studied for both developing and fully-developed flows.Simulation results suggest that thermophoretic deposition increases by increasing thermal gradient,deposition distance,and the ratio of inner to outer radius,but decreases with increasing particle size.It has been found that by taking into account the effect of developing flow at the entrance region,higher deposition efficiency was obtained,than fully developed flow.

Evaluating the performance of a WRF microphysics ensemble through comparisons with aircraft observations

observation data obtained in a mesoscale convective system are compared to Weather Research and Forecasting(WRF)model simulations using four microphysics schemes(Morrison,WSM6,P3,SBM)with different complexities.The main purpose of this paper is to assess the performance of the microphysics ensemble in terms of cloud microphysical properties.Results show that although the vertical distributions of liquid water content(LWC)and ice water content(IWC)simulated by the four members are quite different in the convective cloud region,they are relatively uniform in the stratiform cloud region.Overall,the results of the Morrison scheme are very similar to the ensemble average,and both of them are closer to the observations compared to the other schemes.Besides,the authors also note that all members still overpredict the LWC by a factor of 2–8 in some regions,resulting in large deviation between the observation and ensemble average.

Microscopic Mechanism of Large Fluctuation in Odd-Even Differences in Moments of Inertia for Actinide Nuclei

The experimental large fluctuation in odd-even differences in moments ofinertia of deformed actinide nuclei is investigated using the particle-number conserving (PNC)method for treating the cranked shell model with monopole and quadrupole pairing interactions. PNCcalculations show that the large odd-even difference in moments of inertia mainly comes from theinterference contributions j(μv) from particles in high j intruder orbitals μ and v quite near theFermi surface, which have no counterpart in the BCS formalism. The effective monopole andquadrupole pairing interaction strengths are determined to fit the experimental odd-even differencesin binding energies and bandhead moments of inertia. The experimental results for the variation ofmoments of inertia with rotational frequency ω are reproduced well by the PNC calculation. Thenearly identical experimental moments of inertia between ~(236)U(gsb) and ~(238)U(gsb) at lowfrequencies hω ≤ 0.20 MeV are also reproduced quite well.

Nickel composite plating with fly ash as inert particle

The Ni/FA composite plating was realized by electrodeposition with fly ash （FA） as inert particles. The main compositions of FA are 72% SiO2 and 25% A1203 in the size of 3-7 Ixm. Electrodeposition was performed in Watts bath containing FA with concentrations of 5, 20, 50 g/L, current densities of 2 and 4 A/dm2, temperature of 50 ~C and magnetic stirring of 250 r/min. Scanning electron microscope （SEM＋EDX）, electrochemical and mechanical technique were used to study morphology, composition and properties of coating. FA content in deposit is dependent on the FA concentration in solution, as well as the plating parameters. Since FA particles were incorporated in the coating, the mechanical and electrochemical properties of the coating were increased. The microhardness of Ni/FA composite plating reaches HV 430 in comparison with HV 198 of pure Ni coating. It was confirmed by electrochemical measurement that the corrosion resistance of Ni/FA composite coating was higher than that of pure Ni.

Atomic force microscopy study on microstructure of various ranks of coals

As a new technology, Atomil Force Microscopy （AFM） is being used in the research of microscopic structure on coal surface in recent years. By this technology, we can observe the nanoscale pore and crack shape of coal surface, and measure some structural parameters. Different metamorphic grades produce different feature of surface microscopic structure of coal. This paper analyzes the surface microscopic structure of different metamorphic grade coal by AFM. The results show that the coal surface microstructure has a trend from rough to smooth with the increasing of metamorphic grade. The low rank coals contain large or medium pores and the high rank coals contain micro pores. The values of surface morphology characteristic parameters （Sq and Sa） nonlinearly decrease with the increasing coal rank. That is, the coal surface becomes smoother during coalification.

Elaborate Architecture of the Hierarchical Hen＇s Eggshell

Eggshells are one of the most common and well-studied biomaterials in nature and exhibit unique properties of gas conduction. However, the morphologies of eggshells at the submicro-/nano-scale and their impact on eggshell functions remain unclear. In this work, the architecture of hen＇s eggshell at different length scales has been systematically investigated by scanning electron microscopy （SEM） and environmental SEM （ESEM）. It is found that the skeleton of calcium carbonate （CaCO3） has hierarchical structures at nano- to micro-scales： primary nano-particles of -10 Fain loosely congregate giving a porous and rough texture, and compose the upper-level morphologies including submicro spheres, nano-rods, rhombohedral-cleavage pattern and slices, which are elaborately arranged in a surface layer, palisade layer and mammillary layer along the radial direction. Accordingly, the pore system exhibits a three-level hierarchy, namely nano-scale pores （between nano-rods and primary nano-particles）, submicro-scale pores （＂bubble pores＂） and micro-scale pores （opening of ＂gas pores＂）. Further investigation shows that hen＇s eggshell regulates gas conduction through adjusting the sizes and numbers of submicro-scale ＂bubble pores＂. Based on our observations, a new description of hen＇s eggshell is presented, which amends the conventional view of micro-scale, straight and permeating ＂gas pores＂, and reveals the role of hierarchical pores in gas conduction and contamination resistance.

Large Eddy Simulation of Micro-Particles Transport with Different Mass Flow Rate in Turbulent Planar Jet Flow

The motion of micro-particles with different mass flow rate in the planer turbulent jet flow has been simulated, using LES method to obtain the flow vorticity evolution and Lagrangian method to track micro-particles. The re- suits showed that when the flow rate is small, the particles more likely to present in the vortex periphery, the dis- tribution pattern is similar to the flow pattern. When the flow rate is high, some particles will escape from the mo- tion region to the original static region, so that in the jet region, particles are relatively evenly distributed. When the flow field is full developed, the particles average concentration in the y direction affected by the mass flow rate relative slightly, the normalized mean particles concentrations at different flow rate were similar to Gaussian shape.

Study of dynamic hydrophobicity of micro-structured hydrophobic surfaces and lotus leaves

The dynamic wetting characteristics of water droplets on silicon wafers with microscale regular pillars structures and fresh lotus leaves are investigated experimentally.We measured the static contact angle,contact angle hysteresis,and roll-off angle of water droplets on both of these superhydrophobic surfaces with a high speed contact angle meter.The dynamic contact angles and internal velocity distribution of water droplets on superhydrophobic surfaces were studied with a high-speed camera system and a particle image velocimetry (PIV) system,respectively.We found that the acceleration of water droplets when they slide off lotus leaves is greater than that of water droplets sliding off the silicon wafers with microscale pillar structures although the static contact angles of water droplets on lotus leaves are slightly smaller than those on the silicon wafers.The reason is that water droplets sliding off lotus leaves have smaller contact angle hysteresis and larger slip velocities.These results indicate that the dynamic contact angle hysteresis and sliding acceleration of liquid droplets are more suitable for reflecting the hydrophobicity of material surfaces compared with static contact angles.Our experiments also show that lotus leaves with multiscale micro/nanostructures have stronger hydrophobicity and self-cleaning properties compared with the micro-structured superhydrophobic surfaces.

An effective description of a periodic one-dimensional hopping model

The periodic one-dimensional hopping model is useful for studying the motion of microscopic particles in the thermal noise environment. Based on the explicit formulations of mean velocity, mean first passage time and effective diffusion constant, a general N internal states or even infinite internal states model can be approximated by a one state model that retains the basic properties of the original process. This effective description aids the analysis of biochemical and biophysical problems. This effective description also implies that, to some extent, many processes can be well described by simple two-state models, or even one-state models.

Effect of cold working and annealing on microstructure and properties of powder metallurgy high entropy alloy

An equiatomic CoCrFeNiMn high entropy alloy （HEA） was produced by powder metallurgy method. Cold rolling followed by subsequent annealing was conducted to further optimize the microstructure and mechanical properties. The results show that the SPSed CoCrFeNiMn HEA has an equiaxed single fcc phase microstructrue. Cold rolling results in extensive dislocation pile-up and twinning within the grains. The 80% cold-rolled alloy shows very high yield strength of 1292 MPa, but a limited elongation of 3%. Subsequent annealing produces recrystallization and precipitation of fine a particles with particle size of 30-100 nm. The annealed alloy has a yield strength of 540 MPa, which is about two to three times of the cast CoCrFeNiMn HEA, while still maintains a high tensile ductility of 41%. The improvement of the tensile properties is caused by the grain boundary strengthening, solid solution strengthening, and precipitation strengthening.