Electrocatalytic urea synthesis provides a favorable strategy for conventional energy-consuming urea synthesis,but achieving large-scale catalyst synthesis with high catalytic efficiency remains challenging.Herein,we ...Electrocatalytic urea synthesis provides a favorable strategy for conventional energy-consuming urea synthesis,but achieving large-scale catalyst synthesis with high catalytic efficiency remains challenging.Herein,we developed a simple method for the preparation of a series of FeNi-alloy-based catalysts,named FeNi@nC-T(n represents the content of nanoporous carbon as 1,3,5,7 or 9 g and T=900,950,1000 or 1100°C),for highly performed urea synthesis via NO_(3)−and CO_(2)co-reduction.The FeNi@7C-1000 achieved a high urea yield of 1041.33 mmol h^(−1)gFeNi^(−1)with a Faradaic efficiency of 15.56%at–1.2 V vs.RHE.Moreover,the scale-up synthesized FeNi@7C-950-S(over 140 g per batch)was achieved with its high catalytic performance and high stability maintained.Mechanism investigation illuminated that the Ni and Fe sites catalyze and stabilize the key*CO and*N intermediates and minimize the C–N coupling reaction barriers for highly efficient urea synthesis.展开更多
When checking the ice shape calculation software,its accuracy is judged based on the proximity between the calculated ice shape and the typical test ice shape.Therefore,determining the typical test ice shape becomes t...When checking the ice shape calculation software,its accuracy is judged based on the proximity between the calculated ice shape and the typical test ice shape.Therefore,determining the typical test ice shape becomes the key task of the icing wind tunnel tests.In the icing wind tunnel test of the tail wing model of a large amphibious aircraft,in order to obtain accurate typical test ice shape,the Romer Absolute Scanner is used to obtain the 3D point cloud data of the ice shape on the tail wing model.Then,the batch-learning self-organizing map(BLSOM)neural network is used to obtain the 2D average ice shape along the model direction based on the 3D point cloud data of the ice shape,while its tolerance band is calculated using the probabilistic statistical method.The results show that the combination of 2D average ice shape and its tolerance band can represent the 3D characteristics of the test ice shape effectively,which can be used as the typical test ice shape for comparative analysis with the calculated ice shape.展开更多
文摘Electrocatalytic urea synthesis provides a favorable strategy for conventional energy-consuming urea synthesis,but achieving large-scale catalyst synthesis with high catalytic efficiency remains challenging.Herein,we developed a simple method for the preparation of a series of FeNi-alloy-based catalysts,named FeNi@nC-T(n represents the content of nanoporous carbon as 1,3,5,7 or 9 g and T=900,950,1000 or 1100°C),for highly performed urea synthesis via NO_(3)−and CO_(2)co-reduction.The FeNi@7C-1000 achieved a high urea yield of 1041.33 mmol h^(−1)gFeNi^(−1)with a Faradaic efficiency of 15.56%at–1.2 V vs.RHE.Moreover,the scale-up synthesized FeNi@7C-950-S(over 140 g per batch)was achieved with its high catalytic performance and high stability maintained.Mechanism investigation illuminated that the Ni and Fe sites catalyze and stabilize the key*CO and*N intermediates and minimize the C–N coupling reaction barriers for highly efficient urea synthesis.
基金supported by the AG600 project of AVIC General Huanan Aircraft Industry Co.,Ltd.
文摘When checking the ice shape calculation software,its accuracy is judged based on the proximity between the calculated ice shape and the typical test ice shape.Therefore,determining the typical test ice shape becomes the key task of the icing wind tunnel tests.In the icing wind tunnel test of the tail wing model of a large amphibious aircraft,in order to obtain accurate typical test ice shape,the Romer Absolute Scanner is used to obtain the 3D point cloud data of the ice shape on the tail wing model.Then,the batch-learning self-organizing map(BLSOM)neural network is used to obtain the 2D average ice shape along the model direction based on the 3D point cloud data of the ice shape,while its tolerance band is calculated using the probabilistic statistical method.The results show that the combination of 2D average ice shape and its tolerance band can represent the 3D characteristics of the test ice shape effectively,which can be used as the typical test ice shape for comparative analysis with the calculated ice shape.
