In order to overcome the limitations of traditional microperforated plate with narrow sound absorption bandwidth and a single structure,two multi-cavity composite sound-absorbing materials were designed based on the s...In order to overcome the limitations of traditional microperforated plate with narrow sound absorption bandwidth and a single structure,two multi-cavity composite sound-absorbing materials were designed based on the shape of monoclinic crystals:uniaxial oblique structure(UOS)and biaxial oblique structure(BOS).Through finite element simulation and experimental research,the theoretical models of UOS and BOS were verified,and their sound absorption mechanisms were revealed.At the same time,the influence of multi-cavity composites on sound absorption performance was analyzed based on the theoretical model,and the influence of structural parameters on sound absorption performance was discussed.The research results show that,in the range of 100-2000 Hz,UOS has three sound absorption peaks and BOS has five sound absorption peaks.The frequency range of the half-absorption bandwidth(α>0.5)of UOS and BOS increases by 242% and 229%,respectively.Compared with traditional microperforated sound-absorbing structures,the series and parallel hybrid methods significantly increase the sound-absorbing bandwidth of the sound-absorbing structure.This research has guiding significance for noise control and has broad application prospects in the fields of transportation,construction,and mechanical design.展开更多
According to the characteristics of high-order solitons,compressed picosecond pulses are numerically simulated in the photonic crystal fiber (PCF),by means of split-step Fourier method. The results show that,PCF enabl...According to the characteristics of high-order solitons,compressed picosecond pulses are numerically simulated in the photonic crystal fiber (PCF),by means of split-step Fourier method. The results show that,PCF enables input pulse with lower peak power to form high-order solitons for the purpose of femtosecond pulse-width compression. For example,60- femtosecond pulse width was made for 1-ps initial pulse width only over the distance of 2.2 m.Besides,shorter optimum fiber length for compression and higher compression ratio could be obtained on the premise of pre-chirp technique.展开更多
Three new metal organic frameworks,[Mn^(Ⅲ)_(4)Mn^(Ⅱ)_(8)O_(2)(4-thmpy)_(4)(O_(2)CPh)_(10)(OMe)_(2)(H_(2)O)_(2)]·3CH_(3)OH·4H_(2)O(1),[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)O(4-thmpy)_(4)(O_(2)CPh)_(6)(H_(2)O)_(4)]·CH...Three new metal organic frameworks,[Mn^(Ⅲ)_(4)Mn^(Ⅱ)_(8)O_(2)(4-thmpy)_(4)(O_(2)CPh)_(10)(OMe)_(2)(H_(2)O)_(2)]·3CH_(3)OH·4H_(2)O(1),[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)O(4-thmpy)_(4)(O_(2)CPh)_(6)(H_(2)O)_(4)]·CH_(3)OH·3H_(2)O(2),and[Mn^(Ⅱ)_(4)Ni^(Ⅱ)_(6)O(4-thmpy)_(4)(O_(2)CPh)_(6)(H_(2)O)_(4)]·2CH_(3)OH·2H_(2)O(3),have been successfully synthesized by using 4-[tri-(hydroxymethyl)methyl]pyridine(4-thmpyH_(3))as ligand.Crystal structure analyses show that compound 1 is a disk-like twelve nuclear[Mn^(Ⅲ)_(4)Mn^(Ⅱ)_(8)]0D cluster.Compounds 2 and 3 are isomorphic,and the decanuclear heteronuclear cluster[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)]node in compound 2 can be seen as a hyper-tetrahedron of four coboundary cubic alkanes[Mn^(Ⅱ)Co^(Ⅱ)_(3)O_(4)],then each ten-nuclear heteronuclear cluster[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)]is connected by six 4-thmpy^(3-)with six adjacent decanuclear clusters[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)],forming the NaCl-type 3D topological structure.Magnetic studies showed that there exist antiferromagnetic interactions between metal ions in 1-3.展开更多
A crystal plasticity finite element model was developed for the drawing deformation of pure copper micro wire,based on rate-dependent crystal plasticity theory.The impact of wire diameter compression ratio on the micr...A crystal plasticity finite element model was developed for the drawing deformation of pure copper micro wire,based on rate-dependent crystal plasticity theory.The impact of wire diameter compression ratio on the micro-mechanical deformation behavior during the wire drawing process was investigated.Results indicate that the internal deformation and slip of the drawn wire are unevenly distributed,forming distinct slip and non-slip zones.Additionally,horizontal strain concentration bands develop within the drawn wire.As the wire diameter compression ratio increases,the strength of the slip systems and the extent of slip zones inside the deformation zone also increase.However,the fluctuating stress state,induced by contact pressure and frictional stress,results in a rough and uneven wire surface and diminishes the stability of the drawing process.展开更多
Synthesis of ZSM-5 zeolite typically utilizes small molecule polyamines or quaternary ammonium salts as organic structure guiding agent(OSDA).By contrast,the OSDA-free hydrothermal synthesis system eliminates the use ...Synthesis of ZSM-5 zeolite typically utilizes small molecule polyamines or quaternary ammonium salts as organic structure guiding agent(OSDA).By contrast,the OSDA-free hydrothermal synthesis system eliminates the use of organic templates and the subsequent calcination procedure.This not only reduces the cost of synthesis,but also prevents environmental pollution from the combustion of organic templates,representing an eco-friendly approach.Despite this,literature suggests that even so-called template-free synthesis systems often involve trace amount of organic substances like alcohol.In the present work,a calcined commercial ZSM-5 zeolite was served as seed,with sodium aluminate as aluminum source and silica sol as silicon source,ensuring an entirely template-free synthesis system.Polycrystalline ZSM-5 aggregates consisted of rod-like nanocrystals were successfully prepared in the completely OSDA-free system.Effects of the Si/Al ratio in ZSM-5 seed,dosage and crystallization conditions such as crystallization temperature and crystallization time on ZSM-5 synthesis were investigated.The results show that a highly crystallinity ZSM-5 aggregate consisting of primary nano-sized crystals less than 100 nm is produced from a gel precursor with 5.6%(in mass)seed after hydrothermal treatment for 48 h.Furthermore,the Si/Al ratio in ZSM-5 seed has little effect on the topological structure and pore structure of the synthesized samples.However,the seeds with a low Si/Al ratio facilitate faster crystallization of zeolite and enhance the acidity,especially the strong acid centers,of the catalyst.The catalytic performance of the synthesized polycrystalline ZSM-5 was evaluated during dehydration of methanol and compared with a commercial reference ZSM-5r.The results exhibit that as compared with the reference catalyst,the fabricated sample has a longer catalytic lifetime(16 h vs 8 h)attributed to its hierarchical pores derived from the loosely packed primary nanoparticles.Additionally,the prepared polycrystalline catalyst also exhibits a higher aromatics selectivity(28.1%-29.8%vs 26.5%).展开更多
The problems associated with vibrations of viaducts and low-frequency structural noise radiation caused by train excitation continue to increase in importance.A new floating-slab track vibration isolator-non-obstructi...The problems associated with vibrations of viaducts and low-frequency structural noise radiation caused by train excitation continue to increase in importance.A new floating-slab track vibration isolator-non-obstructive particle damping-phononic crystal vibration isolator is proposed herein,which uses the particle damping vibration absorption technology and bandgap vibration control theory.The vibration reduction performance of the NOPD-PCVI was analyzed from the perspective of vibration control.The paper explores the structure-borne noise reduction performance of the NOPD-PCVIs installed on different bridge structures under varying service conditions encountered in practical engineering applications.The load transferred to the bridge is obtained from a coupled train-FST-bridge analytical model considering the different structural parameters of bridges.The vibration responses are obtained using the finite element method,while the structural noise radiation is simulated using the frequency-domain boundary element method.Using the particle swarm optimization algorithm,the parameters of the NOPD-PCVI are optimized so that its frequency bandgap matches the dominant bridge structural noise frequency range.The noise reduction performance of the NOPD-PCVIs is compared to the steel-spring isolation under different service conditions.展开更多
Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by...Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by varying the calcination temperature of anatase-TiO_(2).Structural characterizations revealed that a distinct TiO_(x) coating on the Ni nanoparticles(NPs)was evident for Ni/TiO_(2)-700 catalyst due to strong metal-support interaction.It is observed that the TiOx overlayer gradually disappeared as the ratio of rutile/anatase increased,thereby enhancing the exposure of Ni active sites.The exposed Ni sites enhanced visible light absorption and boosted the dissociation capability of CH4,which led to the much elevated catalytic activity for Ni/TiO_(2)-950 in which rutile dominated.Therefore,the catalytic activity of solar-driven DRM reaction was significantly influenced by the rutile/anatase ratio.Ni/TiO_(2)-950,characterized by a predominant rutile phase,exhibited the highest DRM reactivity,with remarkable H_(2) and CO production rates reaching as high as 87.4 and 220.2 mmol/(g·h),respectively.These rates were approximately 257 and 130 times higher,respectively,compared to those obtained on Ni/TiO_(2)-700 with anatase.This study suggests that the optimization of crystal structure of TiO_(2) support can effectively enhance the performance of photothermal DRM reaction.展开更多
基金Project(52202455)supported by the National Natural Science Foundation of ChinaProject(23A0017)supported by the Key Project of Scientific Research Project of Hunan Provincial Department of Education,China。
文摘In order to overcome the limitations of traditional microperforated plate with narrow sound absorption bandwidth and a single structure,two multi-cavity composite sound-absorbing materials were designed based on the shape of monoclinic crystals:uniaxial oblique structure(UOS)and biaxial oblique structure(BOS).Through finite element simulation and experimental research,the theoretical models of UOS and BOS were verified,and their sound absorption mechanisms were revealed.At the same time,the influence of multi-cavity composites on sound absorption performance was analyzed based on the theoretical model,and the influence of structural parameters on sound absorption performance was discussed.The research results show that,in the range of 100-2000 Hz,UOS has three sound absorption peaks and BOS has five sound absorption peaks.The frequency range of the half-absorption bandwidth(α>0.5)of UOS and BOS increases by 242% and 229%,respectively.Compared with traditional microperforated sound-absorbing structures,the series and parallel hybrid methods significantly increase the sound-absorbing bandwidth of the sound-absorbing structure.This research has guiding significance for noise control and has broad application prospects in the fields of transportation,construction,and mechanical design.
文摘According to the characteristics of high-order solitons,compressed picosecond pulses are numerically simulated in the photonic crystal fiber (PCF),by means of split-step Fourier method. The results show that,PCF enables input pulse with lower peak power to form high-order solitons for the purpose of femtosecond pulse-width compression. For example,60- femtosecond pulse width was made for 1-ps initial pulse width only over the distance of 2.2 m.Besides,shorter optimum fiber length for compression and higher compression ratio could be obtained on the premise of pre-chirp technique.
基金the National Natural Science Foundation of China(21873018)Foundation of the Education Department of Jilin Province(111099108)Jilin Provincial Research Center of Advanced Energy Materials(Northeast Normal University)for financial support
文摘Three new metal organic frameworks,[Mn^(Ⅲ)_(4)Mn^(Ⅱ)_(8)O_(2)(4-thmpy)_(4)(O_(2)CPh)_(10)(OMe)_(2)(H_(2)O)_(2)]·3CH_(3)OH·4H_(2)O(1),[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)O(4-thmpy)_(4)(O_(2)CPh)_(6)(H_(2)O)_(4)]·CH_(3)OH·3H_(2)O(2),and[Mn^(Ⅱ)_(4)Ni^(Ⅱ)_(6)O(4-thmpy)_(4)(O_(2)CPh)_(6)(H_(2)O)_(4)]·2CH_(3)OH·2H_(2)O(3),have been successfully synthesized by using 4-[tri-(hydroxymethyl)methyl]pyridine(4-thmpyH_(3))as ligand.Crystal structure analyses show that compound 1 is a disk-like twelve nuclear[Mn^(Ⅲ)_(4)Mn^(Ⅱ)_(8)]0D cluster.Compounds 2 and 3 are isomorphic,and the decanuclear heteronuclear cluster[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)]node in compound 2 can be seen as a hyper-tetrahedron of four coboundary cubic alkanes[Mn^(Ⅱ)Co^(Ⅱ)_(3)O_(4)],then each ten-nuclear heteronuclear cluster[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)]is connected by six 4-thmpy^(3-)with six adjacent decanuclear clusters[Mn^(Ⅱ)_(4)Co^(Ⅱ)_(6)],forming the NaCl-type 3D topological structure.Magnetic studies showed that there exist antiferromagnetic interactions between metal ions in 1-3.
基金the National Natural Science Foundation of China(Nos.U21A2051,52173297,52071133)the R&D Projects of Henan Academy of Sciences of China(No.220910009)+2 种基金the Key R&D and Promotion Projects of Henan Province of China(No.212102210441)the Joint Fund of Henan Science and Technology R&D Plan of China(No.222103810037)the Zhongyuan Scholar Workstation Funded Project of China(No.214400510028).
文摘A crystal plasticity finite element model was developed for the drawing deformation of pure copper micro wire,based on rate-dependent crystal plasticity theory.The impact of wire diameter compression ratio on the micro-mechanical deformation behavior during the wire drawing process was investigated.Results indicate that the internal deformation and slip of the drawn wire are unevenly distributed,forming distinct slip and non-slip zones.Additionally,horizontal strain concentration bands develop within the drawn wire.As the wire diameter compression ratio increases,the strength of the slip systems and the extent of slip zones inside the deformation zone also increase.However,the fluctuating stress state,induced by contact pressure and frictional stress,results in a rough and uneven wire surface and diminishes the stability of the drawing process.
基金National Natural Science Foundation of China(U19B2003,21706177,21975174)Foundation Supported by China Petroleum&Chemical Corporation(121014-2)。
文摘Synthesis of ZSM-5 zeolite typically utilizes small molecule polyamines or quaternary ammonium salts as organic structure guiding agent(OSDA).By contrast,the OSDA-free hydrothermal synthesis system eliminates the use of organic templates and the subsequent calcination procedure.This not only reduces the cost of synthesis,but also prevents environmental pollution from the combustion of organic templates,representing an eco-friendly approach.Despite this,literature suggests that even so-called template-free synthesis systems often involve trace amount of organic substances like alcohol.In the present work,a calcined commercial ZSM-5 zeolite was served as seed,with sodium aluminate as aluminum source and silica sol as silicon source,ensuring an entirely template-free synthesis system.Polycrystalline ZSM-5 aggregates consisted of rod-like nanocrystals were successfully prepared in the completely OSDA-free system.Effects of the Si/Al ratio in ZSM-5 seed,dosage and crystallization conditions such as crystallization temperature and crystallization time on ZSM-5 synthesis were investigated.The results show that a highly crystallinity ZSM-5 aggregate consisting of primary nano-sized crystals less than 100 nm is produced from a gel precursor with 5.6%(in mass)seed after hydrothermal treatment for 48 h.Furthermore,the Si/Al ratio in ZSM-5 seed has little effect on the topological structure and pore structure of the synthesized samples.However,the seeds with a low Si/Al ratio facilitate faster crystallization of zeolite and enhance the acidity,especially the strong acid centers,of the catalyst.The catalytic performance of the synthesized polycrystalline ZSM-5 was evaluated during dehydration of methanol and compared with a commercial reference ZSM-5r.The results exhibit that as compared with the reference catalyst,the fabricated sample has a longer catalytic lifetime(16 h vs 8 h)attributed to its hierarchical pores derived from the loosely packed primary nanoparticles.Additionally,the prepared polycrystalline catalyst also exhibits a higher aromatics selectivity(28.1%-29.8%vs 26.5%).
基金Project(51978585)supported by the National Natural Science Foundation,ChinaProject(2022YFB2603404)supported by the National Key Research and Development Program,China+1 种基金Project(U1734207)supported by the High-speed Rail Joint Fund Key Projects of Basic Research,ChinaProject(2023NSFSC1975)supported by the Sichuan Nature and Science Foundation Innovation Research Group Project,China。
文摘The problems associated with vibrations of viaducts and low-frequency structural noise radiation caused by train excitation continue to increase in importance.A new floating-slab track vibration isolator-non-obstructive particle damping-phononic crystal vibration isolator is proposed herein,which uses the particle damping vibration absorption technology and bandgap vibration control theory.The vibration reduction performance of the NOPD-PCVI was analyzed from the perspective of vibration control.The paper explores the structure-borne noise reduction performance of the NOPD-PCVIs installed on different bridge structures under varying service conditions encountered in practical engineering applications.The load transferred to the bridge is obtained from a coupled train-FST-bridge analytical model considering the different structural parameters of bridges.The vibration responses are obtained using the finite element method,while the structural noise radiation is simulated using the frequency-domain boundary element method.Using the particle swarm optimization algorithm,the parameters of the NOPD-PCVI are optimized so that its frequency bandgap matches the dominant bridge structural noise frequency range.The noise reduction performance of the NOPD-PCVIs is compared to the steel-spring isolation under different service conditions.
基金The project was supported by the National Key R&D Program of China(2021YFF0500702)Natural Science Foundation of Shanghai(22JC1404200)+3 种基金Program of Shanghai Academic/Technology Research Leader(20XD1404000)Natural Science Foundation of China(U22B20136,22293023)Science and Technology Major Project of Inner Mongolia(2021ZD0042)the Youth Innovation Promotion Association of CAS。
文摘Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by varying the calcination temperature of anatase-TiO_(2).Structural characterizations revealed that a distinct TiO_(x) coating on the Ni nanoparticles(NPs)was evident for Ni/TiO_(2)-700 catalyst due to strong metal-support interaction.It is observed that the TiOx overlayer gradually disappeared as the ratio of rutile/anatase increased,thereby enhancing the exposure of Ni active sites.The exposed Ni sites enhanced visible light absorption and boosted the dissociation capability of CH4,which led to the much elevated catalytic activity for Ni/TiO_(2)-950 in which rutile dominated.Therefore,the catalytic activity of solar-driven DRM reaction was significantly influenced by the rutile/anatase ratio.Ni/TiO_(2)-950,characterized by a predominant rutile phase,exhibited the highest DRM reactivity,with remarkable H_(2) and CO production rates reaching as high as 87.4 and 220.2 mmol/(g·h),respectively.These rates were approximately 257 and 130 times higher,respectively,compared to those obtained on Ni/TiO_(2)-700 with anatase.This study suggests that the optimization of crystal structure of TiO_(2) support can effectively enhance the performance of photothermal DRM reaction.