Effect of cetyltrimethylammonium bromide on morphology and porous structure of mesoporous hydroxyapatite

The mesoporous hydroxyapatite （HA） was synthesized by hydrothermal method utilizing cationic surfactant cetyltrimethylammonium bromide （CTAB） as template. The crystalline phase, morphology and porous structure were characterized respectively by different detecting techniques. The results reveal that the particles are highly crystalline hydroxyapatite phase. The surfactant has little influence on the morphology of the crystals, but affects the porous structure obviously. The sample without CTAB has a low surface area not exceeding 33 m^2/g, and no distinct pores can be observed by TEM. While the samples obtained with the surfactant get better parameters. Numerous open-ended pores centered at 2-7 nm spread unequally on the surface of the hydroxyapatite nanorods. The N2 adsorption-desorption experiments show type IV isotherms with distinct hysteresis loops, illustrating the presence of mesoporous structure. When the mole ratio of CTAB to HA is 1：2, the sample has the largest surface area of 97.1 m^2/g and pore volume of 0.466 cm^3/g.

Preparation, Characterization and Photocatalytic Activity of Fe, La Co-doped Nanometer Titanium Dioxide Photocatalysts

A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanate as precursors and glucan as template. Scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption measurement were employed to characterize the morphology, crystal structure and surface structure of the samples. The photo-absorbance of the obtained catalysts was measured by UV-Vis absorption spectroscopy, and the photocatalytic activities of the prepared samples under UV and visible light were estimated by measuring the degradation rate of methyl orange in an aqueous solution. The characterizations indicated that the prepared photocatalysts consisted of anatase phase and possessed high surface area of ca. 163-176 m2/g. It was shown that the Fe and La co-doped nano-TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The synergistic effect of Fe and La co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of co-doped nano-TiO2 was also confirmed, the photocatalytic activity of codoped nano-TiO2 remained above 89.6% of the fresh sample after being used four times.

Preparation, Characterization, Photocatalytic Activity of S and Ag co-Doped Mesoporous Titania Photocatalysts

In order to improve the photocatalytic performance of mesoporous titania under visible light, a series of photocatalysts of S and Ag co-doped mesoporous titania have been successfully prepared by template method using thiourea, AgNO3 and tetrabutyl titanate as precursors and Pluronic P123 （EO20PO70EO20） as template. Scanning electron microscopy （SEM）, X-ray diffraction （XRD）, nitrogen adsorption-desorption measurements, and UV-visible spectroscopy （UV-Vis） were employed to characterize the morphology, crystal structure, surface structure, and optical absorption properties of the samples. The microcrystal of the photocatalysts consisted of anatase phase and was approximately present in the form of spherical particle. The photocatalytic performance was studied by photodegradation methyl orange （MO） in water under UV and visible light irradiation. The calcination temperature and the doping content influenced the photoactivity. In addition, the possibility of cyclic usage of co-doped mesoporous titania was also confirmed, the photocatalytic activity of mesoporous titania remained above 89% of that of the fresh sample after being used four times. It was shown that the co-doped mesoporous titania could be activated by visible light and could thus be potentially applied for the treatment of water contaminated by organic pollutants. The synergistic effect of sulfur and silver co-doping played an important role in improving the photocatalytic activity.

Preparation of Manganese Oxide Hollow Spheres Using pH-responsive Microgels as Templates

Manganese oxide hollow spheres were prepared by a novel and facile approach using pH- responsive microgels as templates. The final products were thoroughly characterized with X-ray powder diffraction, thermogravimetric analysis, scanning electron microscopy, Fourier transform infrared, and transmission electron microscopy. The results reveal that the shell thickness of manganese oxide hollow spheres increased with the dosage of KMnO4, which implies that a controllable and feasible strategy for manganese oxide hollow spheres prepa- ration has been established. Further studies on the microgels template showed some of them had an irreversible swelling/deswelling transition due to the uneven cross-link extent. Based on the results, a probable formation mechanism for the hollow spheres was proposed.

Combining the genetic algorithms with artificial neural networks for optimization of board allocating

This paper introduced the Genetic Algorithms (GAs) and Artificial Neural Networks (ANNs), which have been widely used in optimization of allocating. The combination way of the two optimizing algorithms was used in board allocating of furniture production. In the experiment, the rectangular flake board of 3650 mm 1850 mm was used as raw material to allocate 100 sets of Table Bucked. The utilizing rate of the board reached 94.14 % and the calculating time was only 35 s. The experiment result proofed that the method by using the GA for optimizing the weights of the ANN can raise the utilizing rate of the board and can shorten the time of the design. At the same time, this method can simultaneously searched in many directions, thus greatly in-creasing the probability of finding a global optimum.

Numerical analysis of coupled finite element with element-free Galerkin in sheet flexible-die forming

A numerical method for coupled deformation between sheet metal and flexible-die was proposed. Based on the updated Lagrangian （UL） formulation, the elastoplastic deformation of sheet metal was analyzed with finite element method （FEM） and the bulk deformation of flexible-die was analyzed with element-free Galerkin method （EFGM）. The frictional contact between sheet metal and flexible-die was treated by the penalty function method. The sheet elastic flexible-die bulging process was analyzed with the FEM-EFGM program for coupled deformation between sheet metal and bulk flexible-die, called CDSB-FEM-EFGM for short. Compared with finite element code DEFORM-2D and experiment results, the CDSB-FEM-EFGM program is feasible. This method provides a suitable numerical method to analyze sheet flexible-die forming.

Synthesis of spinel LiMn_(2)O_(4) microspheres with durable high rate capability

Spinel LiMn2O4 microspheres with durable high rate capability were synthesized by a facile route using spherical MnCO3 precursors as the self-supported templates, combined with the calcinations of LiNO3 at 700 °C for 8 h. The spherical MnCO3 precursors were obtained from the control of the crystallizing process of Mn2＋ ions and NH4HCO3 in aqueous solution. The effects of the mole ratio of the raw materials, reaction time, and reaction temperature on the morphology and yield of the MnCO3 were investigated. The as-synthesized MnCO3 and LiMn2O4 microspheres were characterized by powder X-ray diffractometry （XRD） and scanning electron microscopy （SEM）. Galvanostatic charge/discharge tests indicate that the spinel LiMn2O4 microspheres deliver a discharge capacity of 90 mA-h/g at 10C rate show good capacity retention capability （75% of their initial capacity after 800 cycles at 10C rate）. The durable high rate capability suggests that the as-synthesized LiMn2O4 microspheres are promising cathode materials for high power lithium ion batteries.

Synthesis of mesoporous carbon as electrode material for supercapacitor by modified template method

The pore structures and electrochemical performances of mesoporous carbons prepared by silica sol template method as electrode material for supercapacitor were investigated. The mean pore size and mass specific capacitance of the mesoporous carbons increase with the increase of mass ratio of silica sol to carbon source （glucose）. A modified template method, combining silica sol template method and ZnCl2 chemical activation method, was proposed to improve the mass specific capacitance of the mesoporous carbon with an improved BET surface area. The correlation of rate capability and pore structure was studied by constant current discharge and electrochemical impedance spectroscopy. A commercially available microporous carbon was used for comparison. The result shows that mesoporous carbon with a larger pore size displays a higher rate capability. Mesoporous carbon synthesized by modified template method has both high mass specific capacitance and good rate capability.

Template-free hydrothermal synthesis and gas-sensitivity of hollow-structured Cu_(0.3)Co_(2.7)O_(4) microspheres

Hollow-structured Cu_(0.3)Co_(2.7)O_(4) microspheres have been synthesized by a simple one-pot template-free hydrothermal method with copper sulfate,cobalt acetate and ammonia as raw materials.The products were characterized by powder X-ray diffraction,energy dispersive X-ray analysis,selected area electron diffraction,high-resolution transmission electron microscopy,scanning electron microscopy and BET measurements.The research results show that the hollow Cu_(0.3)Co_(2.7)O_(4) microspheres consist of single-crystalline nanocubes with the diameter of about 20 nm.The formation mechanism of hollow Cu_(0.3)Co_(2.7)O_(4) microspheres is suggested as Ostwald ripening in a solid-solution-solid process,and Cu_(0.3)Co_(2.7)O_(4) microspheres are mesoporous containing two pore sizes of 3.3 and 5.9 nm.The as-prepared Cu_(0.3)Co_(2.7)O_(4) sensors have optimal gas responses to 50×10^(−6) mg/m^(3) C_(2)H_(5)OH at 190℃.

Preparation and characterization of monodisperse zirconia spherical nanometer powder via lamellar liquid crystal template method

Cubic phase spherical zirconia nano-powder was prepared by a direct template route in the lamellar liquid crystal formed by polyoxyethylene tert-octylphenyl ether(Triton X-100)/sodium dodecyl sulfate(SDS)/H_2O.The precursor powder and zirconia powder were characterized by XRD,FT-IR,TG/DSC,TEM,and SEM methods.Results show that the stability of the lamellar liquid crystal is controlled by NH_3·H_2O concentration.The size of nanoparticles is greatly affected by NH_3·H_2O and ZrOCl_2·8H_2O concentrations.The zirconia nanoparticles show narrow particle size distribution of 10-30 nm.

A novel algorithm for a rotation invariant template matching

A novel algorithm for a rotation invariant template matching is proposed when the fluctuating scope of the rotation angle is limited within the region of [-20°,20°]. The matching candidates are selected using a computationally low cost improved correlation algorithm. "AND" operation is adopted to reduce the computational cost. Therefore the algorithm improves the matching speed consumedly. The simulation results verify the efficiency of the proposed method. Moreover,when the size of reference image is fixed,the advantage of this time-saving algorithm is more obvious as the increase of the size of the real time image. The matching speed of the proposed method is over 20 times faster than the speed of the two-level pyramid decomposing accelerating method.

Research on the measurement of belt speed by video in coal mine based on improved template matching algorithm

In order to improve the intelligence of video monitoring system of belt and make up the deficiency of higher failure rate and bad real-time performance in the traditional systems of measurement of belt speed, according to the fact that the light of coal mine is uneven, the strength of light changes greatly, the direction of belt movement is constant, and the position of camera was fixed, various algorithms of speed measurement by video were studied, and algorithm for template matching based on sum of absolute differences （SAD） and correlation coefficient was proposed and improved, besides, the tracking of feature regions was realized. Then, a camera calibration method using the invariance of the cross-ratio was adopted and the real-time measurement of belt speed by the hardware platform based on DM642 was realized. Finally, experiment results show that this method not only has advantages of high precision and strong anti-jamming capability but also can real-time reflect the changes of belt speed, so it has a comprehensive applicability.

Galerkin solution of Winkler foundation-based irregular Kirchhoff plate model and its application in crown pillar optimization

Irregular plates are very common structures in engineering,such as ore structures in mining.In this work,the Galerkin solution to the problem of a Kirchhoff plate lying on the Winkler foundation with two edges simply supported and the other two clamped supported is derived.Coordinate transformation technique is used during the solving process so that the solution is suitable to irregular shaped plates.The mechanical model and the solution proposed are then used to model the crown pillars between two adjacent levels in Sanshandao gold mine,which uses backfill method for mining operation.After that,an objective function,which takes security,economic profits and filling effect into consideration,is built to evaluate design proposals.Thickness optimizations for crown pillars are finally conducted in both conditions that the vertical stiffness of the foundation is known and unknown.The procedure presented in the work provides the guidance in thickness designing of complex shaped crown pillars and the preparation of backfill materials,thus to achieve the best balance between security and profits.

Evaluation of mixed-mode stress intensity factors by extended finite element method

Extended finite element method （XFEM） implementation of the interaction integral methodology for evaluating the stress intensity factors （SIF） of the mixed-mode crack problem is presented. A discontinuous function and the near-tip asymptotic function are added to the classic finite element approximation to model the crack behavior. Two-state integral by the superposition of actual and auxiliary fields is derived to calculate the SIFs. Applications of the proposed technique to the inclined centre crack plate with inclined angle from 0° to 90° and slant edge crack plate with slant angle 45°, 67.5° and 90° are presented, and comparisons are made with closed form solutions. The results show that the proposed method is convenient, accurate and computationallv efficient.

Research of multi-channel impulse noise detection algorithms based on template

Attenuating the undesired audio noise generated by impulse noise,such as shot and scream of brakes,is specially useful for real-time audio recording of TV or broadcasting live report.On the basis of impulse noise detection algorithms based on template,this paper improves the method of establishing the template by using multiple microphones to pick up noise corrupted signals and impulse noises in the environment.The universal of thresholds is found and a detection algorithm with slope as the characteristic is proposed by comparing a variety of feature extraction algorithms.The proposed algorithm gets a significant improvement in testing speed and accuracy,which means it is suitable for real-time processing of audio signals.

Joint detection method of pornographic images with skin-like color background

A novel approach is proposed to automatically detect pomographic images with skin-like color background on the Intemet using the locations of human faces and bodies. It has two separate skin-color detection steps： the first one is to quickly detect the potential human skin-color regions; and the second one is to use an off-the-shelf face detector to locate a human face and then apply hypothesis testing based on series of assumptions which take into account the face-height ratio, body orientation and modem photograph composition common sense, etc. After that, a template matching method is used to further discriminate normal images or pornographic ones. Experimental results show that the proposed method has high precision and real time speed.

Adaptive template filter method for image processing based on immune genetic algorithm

To preserve the original signal as much as possible and filter random noises as many as possible in image processing,a threshold optimization-based adaptive template filtering algorithm was proposed.Unlike conventional filters whose template shapes and coefficients were fixed,multi-templates were defined and the right template for each pixel could be matched adaptively based on local image characteristics in the proposed method.The superiority of this method was verified by former results concerning the matching experiment of actual image with the comparison of conventional filtering methods.The adaptive search ability of immune genetic algorithm with the elitist selection and elitist crossover(IGAE) was used to optimize threshold t of the transformation function,and then combined with wavelet transformation to estimate noise variance.Multi-experiments were performed to test the validity of IGAE.The results show that the filtered result of t obtained by IGAE is superior to that of t obtained by other methods,IGAE has a faster convergence speed and a higher computational efficiency compared with the canonical genetic algorithm with the elitism and the immune algorithm with the information entropy and elitism by multi-experiments.

L~∞-Error Estimate of a Nonconfoming Rectangular Plate Element

In this paper,a nonconforming rectangular plate element,the modified incomplete biquadratic plate element,is considered. The asympotic optimal L~∞-error estimate is obtained for the plate bending problem. This proof is based on the method of regularized Green's function and 'the trick of auxiliary element'.

AUTOMATIC TARGET RECOGNITION OF RADAR HRRP BASED ON HIGH ORDER CENTRAL MOMENTS FEATURES

The paper addresses the problem of target recognition using High-resolution Radar Range Profiles(HRRP).A novel approach of feature extraction and dimension reduction based on extended high order central moments is proposed in order to reduce the dimension of range profiles.Features extracted from radar HRRPs are normalized and smoothed,and then comparative analysis of the similar approaches is done.The range profiles are obtained by step frequency technique using the two-dimensional backscatters distribution data of four different aircraft models.The template matching method by nearest neighbor rules,which is based on the theory of kernel methods for pattern analysis,is used to classify and identify the range profiles from four different aircrafts.Numerical simulation results show that the proposed approach can achieve good performance of stability,shift independence and higher recognition rate.It is helpful for real-time identification and the engineering implements of automatic target recognition using HRRP.The number of required templates could be reduced con-siderably while maintaining an equivalent recognition rate.