AIM: To assess the effects of combined transcatheter arterial chemoembolization (TACE) and percutaneous ethanol ablation (PEA) in patients with large hepatocellular carcinoma (HCC).METHODS: A total of 63 patie...AIM: To assess the effects of combined transcatheter arterial chemoembolization (TACE) and percutaneous ethanol ablation (PEA) in patients with large hepatocellular carcinoma (HCC).METHODS: A total of 63 patients with unresectable large HCC were treated with TACE followed by PEA. The largest dimension of the tumors ranged from 5.3 cm to 17.8 cm. The survival rates, acute effects, toxicity and prognostic factors were analyzed.RESULTS: The cumulative survival rates at 1, 3 and 5 years were 59.4%, 28.4% and 15.8%, respectively (a median survival of 27.7 too). Tumor area was reduced by more than 50% in 30 (47.6%) cases. In 56 cases with increased α-fetoprotein (AFP) values, AFP level was declined by more than 75%. The combined thera- py was generally well tolerated. Only two patients died from variceal bleeding associated with the therapy. The Cox proportional hazards model showed that the num- ber of tumors, the tumor margin and the ethanol dose were independent prognostic factors. CONCLUSION: The combined TACE and PEA therapy is a promising approach for unresectable large HCC.展开更多
Lymph node (LN) metastases from hepatocellular carcinoma (HCC) are considered uncommon. We describe the surgical resection of a solitary para-aortic LN metastasis from HCC. A 65-year-old Japanese man with B-type liver...Lymph node (LN) metastases from hepatocellular carcinoma (HCC) are considered uncommon. We describe the surgical resection of a solitary para-aortic LN metastasis from HCC. A 65-year-old Japanese man with B-type liver cirrhosis was admitted for the evaluation of a liver tumor. He had already undergone radiofrequency ablation, transcatheter arterial chemoembolization, and percutaneous ethanol injection therapy for HCC. Despite treatment, viable regions remained in segments 4 and 8. We performed a right paramedian sectionectomy with partial resection of the left paramedian section of the liver. Six months later, serum concentrations of alpha-fetoprotein (189 ng/mL) and PIVKA-2 (507 mAU/mL) increased. Enhanced com- puted tomography of the abdomen revealed a tumor (20 mm in diameter) on the right side of the abdominal aorta. Fluorine-18 fluorodeoxyglucose positron emission tomography revealed an increased standard uptake value. There was no evidence of recurrence in other regions. Esophagogastroduodenoscopy and colonoscopy revealed no malignant tumor in the gastrointestinal tract. Para-aortic LN metastasis from HCC was thus diagnosed. We performed lymphadenectomy. Histopathological examination revealed that the tumor was largely necrotic, with poorly differentiated HCC on its surface, which confirmed the suspected diagnosis. After 6 mo tumor marker levels were normal, with no evidence of recurrence. Our experience suggests that a solitary para-aortic LN metastasis from HCC can be treated surgically.展开更多
The coordination structure of cupric tartrate(Cu−TA)complex was investigated by ultraviolet−visible(UV-Vis)and liquid chromatography/mass spectrometer(LC-MS)firstly;furthermore,effective coordination configurations an...The coordination structure of cupric tartrate(Cu−TA)complex was investigated by ultraviolet−visible(UV-Vis)and liquid chromatography/mass spectrometer(LC-MS)firstly;furthermore,effective coordination configurations and electronic properties of Cu−TA in aqueous solution were systematically revealed by density functional theory(DFT)calculations.Consistently,Job plots show the possible existence of[Cu(TA)]and[Cu(TA)_(2)]^(2-)at 230 and 255 nm based on UV-Vis results.LC-MS results confirm the existence of the single and high coordination complexes[Cu_(2)(TA)_(2)]^(+),[Cu(TA)_(2)]^(+)and[Cu_(2)(TA)_(3)(H_(2)O)_(2)(OH)_(2)]^(2+).DFT calculation results show that carboxylic oxygen and hydroxyl oxygen of tartaric acid(TA)are preferred sites for Cu(Ⅱ)coordination.[Cu(TA)](1H,3H sites O of TA coordinated with Cu(Ⅱ)),[Cu(TA)_(2)]^(2-)(two 1^(C),2^(H) sites O of TA coordinated with Cu(Ⅱ)),and[Cu(TA)_(3)]^(4-)(three 2H,3H sites O of TA coordinated with Cu(Ⅱ))should be dominant coordination configurations of Cu−TA.The corresponding Gibbs reaction energies are-170.1,-136.2,and-90.2 kJ/mol,respectively.展开更多
To establish bonding stress—slip constitutive model between bars and grout concrete,13 test specimens were employed to study the bonding behavior and the force transfer of bars adhered to grout concrete. The bonding ...To establish bonding stress—slip constitutive model between bars and grout concrete,13 test specimens were employed to study the bonding behavior and the force transfer of bars adhered to grout concrete. The bonding stress development of bars adhered to grout concrete was analyzed. The local bonding stress—slip curve was obtained. Based on the test results,a new bonding stress— slip constitutive model between bars and grout concrete was proposed. The results show that the maximum bonding stress is not influenced by the bar bond length,but it is strengthened when the splitting strength of grout concrete is increased. The model matches the experimental results well,and the regressing coefficient equals 1.7.展开更多
A novel technology of preparation of felt-metal supported modified polyvinyl alcohol(PVA) ultrafiltration(UF) membrane was invented, which could avoid the blockage of the holes of support layer and the leakage of ...A novel technology of preparation of felt-metal supported modified polyvinyl alcohol(PVA) ultrafiltration(UF) membrane was invented, which could avoid the blockage of the holes of support layer and the leakage of the casting solution through the holes of support layer. Felt-metal supported ferric sulfate modified PVA composite UF membranes were prepared by the innovative technology. The results show that the composite membranes are used to treat 1 000 mg/L oil/water emulsion at trans-membrane pressure from 0.25 to 0.45 MPa, the permeate flux is from 36 to 52 L/(m2·h), and the retention of chemical oxygen demand(COD) is over 92%. The composite membrane resistance increases with the increase of trans-naembrane pressure.展开更多
This paper presents the results obtained for the effluent dewatering properties of anaerobic digestion of secondary sludge (SS) and anaerobic co-digestion of mixture of this sludge with the distillery wastewater (D...This paper presents the results obtained for the effluent dewatering properties of anaerobic digestion of secondary sludge (SS) and anaerobic co-digestion of mixture of this sludge with the distillery wastewater (DW) under thermophilic (55±1 ℃), 5 L of working volume, three parallel lab-scale conditions. Its mixtures were prepared with a DW content of 25%and 50% and the C/N ratios of mixtures are 13.1 and 17.6, respectively. The effluent dewatering properties were evaluated under stable conditions which the biogas yield and the effluent pH were steady. The natural settleability, biogas yield, centrifugal dewatering, centrifugal supernatant turbidity and specific resistance filtration (SRF) were investigated. The results showed that the effluent dewatering properties of anaerobic co-digestion of mixtures between SS and DW were better than that of anaerobic digestion of SS alone. In the anaerobic digestion system with the feed were SS, mixture of SS and a DW content of 25%and 50% in order, the net biogas yield of secondary sludge in ADSA,ADSB and ADSC were 0.42 0.507 and 0.511 m3 biogass/kg.VS.d ; compared with the biogas yield in anaerobic digestion system A (ADSA), the biogas yield in anaerobic digestion system B (ADSB) and anaerobic digestion system C (ADSC) had been increased by more than 20% respectively; the SRF of three digested sludge are(were) from 6.8×10^13, 1. 1×10^13 to 5.1×10^12 m/Kg, natural settling rates of 12 h are 26, 37 and 56% and that of 24 h are 32%, 45% and 59% respectively; the centrifugal dewatering rate of 3 min at speed of 1000 rpm were 16%, 31% and 51% respectively; the turbidity of centrifugal supernatant were 804, 754 and 678FTU simultaneously.展开更多
AIM: To investigate the aspects of liver histology in patients with non-alcoholic steatohepatitis (NASH) who had normal aminotransferase levels. METHODS: Thirty-four patients diagnosed with liver steatosis by ultr...AIM: To investigate the aspects of liver histology in patients with non-alcoholic steatohepatitis (NASH) who had normal aminotransferase levels. METHODS: Thirty-four patients diagnosed with liver steatosis by ultrasonographic examination participated in the study. We compared all non- alcoholic fatty liver disease and NASH cases, according to aminotransferase level, aspartate aminotransferase (AST)/alanine aminotransferase (ALT) ratio and presence of metabolic syndrome. RESULTS: Sixteen of 25 patients with high aminotransferase levels were diagnosed with NASH and nine with simple fatty liver according to liver histology. Among the nine patients with normal aminotransferase levels, seven had NASH and two had simple fatty liver. The patients with normal and high liver enzyme levels had almost the same prevalence of NASH and metabolic syndrome. Liver histology did not reveal any difference according to aminotransferase levels and AST/ALT ratio. CONCLUSION: Aminotransferase levels and AST/AIT ratio do not seem to be reliable predictors for NASH. Despite numerous non-invasive biomarkers, all patients with fatty liver should undergo liver biopsy.展开更多
Objective:We evaluated the microsurgical effects of intratumoral injection ethanol into intracranial tumors,in particular,those with highly vascularized large meningiomas. Methods: Twelve patients presented with large...Objective:We evaluated the microsurgical effects of intratumoral injection ethanol into intracranial tumors,in particular,those with highly vascularized large meningiomas. Methods: Twelve patients presented with large meningioma,anhydrous ethanol was intraoperatively injected at an average volume of 15.4 mL followed by microscopic tumor resection. Results: Tumors in the injected sites became pallor to various extent and sclerous,leading to significantly decreased hemorrhage on the surface and cut. The average intraoperative hemorrhage was 88 mL. Complete tumor resection was achieved in 11 out of 12 patients; however,only 1 patient had 91.6% of the tumor resected. None of these patients had any postoperative complications. Conclusion: Intratumoral injection of anhydrous ethanol is a safe,convenient,and effective approach to diminish intraoperative bleeding for highly vascularized large meningiomas.展开更多
The current study was carried out to examine the heavy metals (Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and As) concentration in GW (groundwater) samples in the vicinity of distillery spent wash evaporation ponds and RGW (...The current study was carried out to examine the heavy metals (Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and As) concentration in GW (groundwater) samples in the vicinity of distillery spent wash evaporation ponds and RGW (reference groundwater) samples collected 2 km to 3 km away from the source. The study examines the potential health risk caused by consumption of heavy metals to local inhabitants living around distillery spent wash evaporation ponds. HM (heavy metals) concentration was determined by AAS (atomic absorption) and the results were compared with permissible limits of PEPA (pakistan environmental Protection Agency) and WHO (World Health Organization), set for industria effluents and drinking water. The health risk assessment such as CDI (chronic daily intake) and HQ (hazard quotient) were determined on the sources ofHM concentration. The cm of heavy metals in GW were found in following decreasing order Fe, Zn, Mn, Ni, Co, Cu, Cr, Cd, Pb and As. The HQ indexes of HM in the GW samples near the distillery spent wash evaporation ponds was in the order As, C, Ni, Cu, Mn, Zn, Pb and Cr. The results showed that the distillery spent wash is the cause for the change in HM contents of the study area.展开更多
An ionic conductivity prediction equation at low concentration for two acid salts is proposed taking into account the dissociation and association equilibria among ions. The salts considered are sodium and potassium h...An ionic conductivity prediction equation at low concentration for two acid salts is proposed taking into account the dissociation and association equilibria among ions. The salts considered are sodium and potassium hydrogen tartrates. There is no additional parameter of high order terms except for the Onsager's coefficient of limited term in the new equation. Results show a complex conductance of acidic tartrates in aqueous solution. The molar conductivities of metal ions are nearly constant such that the contributions from hydrogen and tartrate ions decrease with concentration, while the molar conductivity of bitartrate ion increases with concentration.展开更多
The kinetics of reductive leaching of manganese from low grade pyrolusite in dilute sulfuric acid in the presence of molasses alcohol wastewater was investigated. The shrinking core model was applied to quantify the e...The kinetics of reductive leaching of manganese from low grade pyrolusite in dilute sulfuric acid in the presence of molasses alcohol wastewater was investigated. The shrinking core model was applied to quantify the effects of reaction parameters on leaching rate. The leaching rate increases with reaction temperature, concentrations of H 2 SO 4 and organic matter in molasses alcohol wastewater increase and ore particle size decreases. The leaching process follows the kinetics of a shrinking core model and the apparent activation energy is 57.5 kJ·mol –1 . The experimental results indicate a reaction order of 0.52 for H2SO4 concentration and 0.90 for chemical oxygen demand (COD) of molasses alcohol wastewater. It is concluded that the reductive leaching of pyrolusite with molasses alcohol wastewater is controlled by the diffusion through the ash/inert layer composed of the associated minerals.展开更多
An innovative internal circulation membrane bioreactor(ICMBR)treating traditional opaque beer brewery wastewater was introduced. Beer wastewater from Tianjin Huarun Brewhouse was taken as the influent. The removal e...An innovative internal circulation membrane bioreactor(ICMBR)treating traditional opaque beer brewery wastewater was introduced. Beer wastewater from Tianjin Huarun Brewhouse was taken as the influent. The removal efficiency of suspended solid, chemical oxygen demand, total nitrogen and ammonia nitrogen were studied with the changeable hard real time design method, organic loading rate and nutrition elements. The average percentage reduction in chemical oxygen demand achieved 90%. The total nitrogen and ammonia nitrogen were also reduced by 90% and 95%, respectively. The results indicate that the outlet of ICMBR meets the requirements of the environment landscape recycling use.展开更多
The binary liquid-liquid equilibrium(LLE) data for salt-containing systems of 1-butanol+water+CaCl2, n-butyl acetate+water+CaCl2 and ethyl acetate+acetic acid+water+CaCl2 were determined and the salt effect was analyz...The binary liquid-liquid equilibrium(LLE) data for salt-containing systems of 1-butanol+water+CaCl2, n-butyl acetate+water+CaCl2 and ethyl acetate+acetic acid+water+CaCl2 were determined and the salt effect was analyzed. The results showed that an obvious salt effect could be identified for the systems of 1-butanol+water+CaCl2 and ethyl acetate+acetic acid+water.展开更多
Nonalcoholic fatty liver disease(NAFLD),defined by excessive liver fat deposition related to the metabolic syndrome,is a leading cause of progressive liver disease,for which accurate non-invasive staging systems and e...Nonalcoholic fatty liver disease(NAFLD),defined by excessive liver fat deposition related to the metabolic syndrome,is a leading cause of progressive liver disease,for which accurate non-invasive staging systems and effective treatments are still lacking.Evidence has shown that increased ferritin levels are associated with the metabolic insulin resistance syndrome,and higher hepatic iron and fat content.Hyperferritinemia and iron stores have been associated with the severity of liver damage in NAFLD,and iron depletion reduced insulin resistance and liver enzymes.Recently,Kowdley et al demonstrated in a multicenter study in 628 adult patients with NAFLD from the NAFLD-clinical research network database with central re-evaluation of liver histology and iron staining that the increased serum ferritin level is an independent predictor of liver damage in patients with NAFLD,and is useful to identify NAFLD patients at risk of non-alcoholic steatohepatitis and advanced fibrosis.These data indicate that incorporation of serum ferritin level may improve the performance of noninvasive scoring of liver damage in patients with NAFLD,and that iron depletion still represents an attractive therapeutic target to prevent the progression of liver damage in these patients.展开更多
N, O-carboxymethyl chitosan (NOCC) composite nanofiltration (NF) membranes were prepared by coating and cross-linking. The fermentation effluent from a wine factory was treated with the resulting NOCC/polysulfone ...N, O-carboxymethyl chitosan (NOCC) composite nanofiltration (NF) membranes were prepared by coating and cross-linking. The fermentation effluent from a wine factory was treated with the resulting NOCC/polysulfone (PSF) composite NF membranes. The permeate flux and the removal efficiencies of the resulting NF membranes for the color, chemical oxygen demand (CODcr), total organic carbon (TOC), and conductivity of the fermentation effluent were investigated in relation to the driving pressure, the feed flow, and the operation time. The permeate flux and the removal efficiencies were found to increase with the increase of the driving pressure or the feed flow. At 0.40 MPa and ambient temperature the removal efficiencies were 95.5%, 70.7%, 72.6%, and 31.6% for color, CODcr, TOC, and conductivity, respectively. The membrane was found to be stable over a 10-h ooeration for the fermentation effluent treatment.展开更多
In this study,three semipredictive activity coefficient models:Wilson,non-random-two liquid model(NRTL),and universal quasi-chemical model(UNIQUAC),have been used for modeling vapor-liquid equilibrium properties of te...In this study,three semipredictive activity coefficient models:Wilson,non-random-two liquid model(NRTL),and universal quasi-chemical model(UNIQUAC),have been used for modeling vapor-liquid equilibrium properties of ternary mixtures that include substances found in alcoholic distillation processes of wine and musts.In particular,vapor-liquid equilibrium in ternary mixtures containing water + ethanol + congener has been modeled using parameters obtained from binary and ternary mixture data.The congeners are substances that although present in very low concentrations,of the order of part per million,are important enological parameters.The results given by these different models have been compared with literature data and conclusions about the accuracy of the models studied are drawn,recommending the best models for correlating and predicting phase equilibrium properties of this type of mixtures.展开更多
Performances of submerged membrane bioreactor (SMBR) treating brewery wastewater were investigated in this study. With little variation of COD:TN:TP ratio (100:5:1) in influent, SMBR showed high removal effici...Performances of submerged membrane bioreactor (SMBR) treating brewery wastewater were investigated in this study. With little variation of COD:TN:TP ratio (100:5:1) in influent, SMBR showed high removal efficiency ( 〉 90% ) for both COD and NH4^+ - N, and it also showed a strong resistive ability for shock organics loading rate, evidenced by no obvious fluctuation for COD in the effluent when the organics loading rate suddenly increased from 0. 27 g/( gMLSS · d) to 0. 54 g/( gMLSS · d). Comparatively different with the COD removal, TN and TP removal showed a strong correlation with the growth stage of the sludge in SMBR. When the sludge was in the multiplication stage, about 45% of TN was removed and an average removal efficiency of 30% for TP was also observed. However, when the activated sludge was in the steady stage, the removal efficiency for TN decreased to about 30% , whereas, the removal efficiency for TP was very low, and sometimes even below zero. The results of GC/MS indicated that the residual organic matters in the effluent were mainly alkyl hydrocarbon with high molecular weight, and coupling with the results of electroseopic scanning, it is speculated that biomass formed at external and internal membrane fibers played an important role for the removal of small organics.展开更多
As an important geophysical tool,high density electrical technique infers the underground geological structures by processing and inverting the apparent resistivity data.Currently,the false anomalies have been frequen...As an important geophysical tool,high density electrical technique infers the underground geological structures by processing and inverting the apparent resistivity data.Currently,the false anomalies have been frequently occurred in the graph of apparent resistivity pseudo-section or inverted geoelectrical section obtained from high-density electrical technique,and are difficult to remove.In this study,the authors explain the mechanism of the false anomalies and put forward the horizontal differential field method to identify the false anomalies.Based on the analysis of modeling results,this method is applied in the surveying data in Xinlei Quarry of Jiuquan,and the results confirm the effectiveness of the horizontal differential field method.展开更多
Organic biomass is an attractive feedstock for second generation alcohol production. Wild-type strains of the genus Candida showed capabilities different to produce alcohol fermenting a carbohydrates mixture (synthet...Organic biomass is an attractive feedstock for second generation alcohol production. Wild-type strains of the genus Candida showed capabilities different to produce alcohol fermenting a carbohydrates mixture (synthetic medium), individually and in co-culture. Therefore, the main objective of this work was to evaluate the capability of Candida wild-type strains isolated from termite gut and rumen liquid, to ferment the most commonly carbohydrates presented in citrus residues, individually and in co-culture to alcohol production. C Tropicalis (LR4) presented higher percentage of carbohydrate consumption (74.20% ± 4.60%), alcohol production (44.53 ± 0.01 gLl) and maximal alcohol productivity (6.40 ± 0.01 gL-l day) than C Glabrata (T1). Co-culture schemas, CC1 (LR4: 60%; TI: 40%) and CC3 (first LR4 alone and 2 days later T1) presented the highest alcohol production (45.20 ± 1.30 gL-1 and 46.80 ± 2.60 gL-1, respectively). Maximal alcohol productivity was obtained with CC2 (LR4: 80%; TI: 20%) and CC3 schemas, 7.70 ± 0.29 gL-1 day and 7.80 ± 0.44 gL-l day, respectively. The results suggest the usefulness of these wild-type strains in co-culture as an alternative to alcohol production from carbohydrates mixtures at concentrations commonly found in citrus waste.展开更多
基金Supported by Guangdong Provincial Science and Technology Project,China,No.2008B030301127
文摘AIM: To assess the effects of combined transcatheter arterial chemoembolization (TACE) and percutaneous ethanol ablation (PEA) in patients with large hepatocellular carcinoma (HCC).METHODS: A total of 63 patients with unresectable large HCC were treated with TACE followed by PEA. The largest dimension of the tumors ranged from 5.3 cm to 17.8 cm. The survival rates, acute effects, toxicity and prognostic factors were analyzed.RESULTS: The cumulative survival rates at 1, 3 and 5 years were 59.4%, 28.4% and 15.8%, respectively (a median survival of 27.7 too). Tumor area was reduced by more than 50% in 30 (47.6%) cases. In 56 cases with increased α-fetoprotein (AFP) values, AFP level was declined by more than 75%. The combined thera- py was generally well tolerated. Only two patients died from variceal bleeding associated with the therapy. The Cox proportional hazards model showed that the num- ber of tumors, the tumor margin and the ethanol dose were independent prognostic factors. CONCLUSION: The combined TACE and PEA therapy is a promising approach for unresectable large HCC.
文摘Lymph node (LN) metastases from hepatocellular carcinoma (HCC) are considered uncommon. We describe the surgical resection of a solitary para-aortic LN metastasis from HCC. A 65-year-old Japanese man with B-type liver cirrhosis was admitted for the evaluation of a liver tumor. He had already undergone radiofrequency ablation, transcatheter arterial chemoembolization, and percutaneous ethanol injection therapy for HCC. Despite treatment, viable regions remained in segments 4 and 8. We performed a right paramedian sectionectomy with partial resection of the left paramedian section of the liver. Six months later, serum concentrations of alpha-fetoprotein (189 ng/mL) and PIVKA-2 (507 mAU/mL) increased. Enhanced com- puted tomography of the abdomen revealed a tumor (20 mm in diameter) on the right side of the abdominal aorta. Fluorine-18 fluorodeoxyglucose positron emission tomography revealed an increased standard uptake value. There was no evidence of recurrence in other regions. Esophagogastroduodenoscopy and colonoscopy revealed no malignant tumor in the gastrointestinal tract. Para-aortic LN metastasis from HCC was thus diagnosed. We performed lymphadenectomy. Histopathological examination revealed that the tumor was largely necrotic, with poorly differentiated HCC on its surface, which confirmed the suspected diagnosis. After 6 mo tumor marker levels were normal, with no evidence of recurrence. Our experience suggests that a solitary para-aortic LN metastasis from HCC can be treated surgically.
基金the National Key Research and Development Program of China(No.2019YFC0408303)the Natural Science Foundation of Hunan Province,China(No.2021JJ20069)+2 种基金the Changsha Science and Technology Project,China(Nos.kq2106016,kq2009005)Higher Education Discipline Innovation Project(111 Project),China(No.B14034)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2021zzts0887).
文摘The coordination structure of cupric tartrate(Cu−TA)complex was investigated by ultraviolet−visible(UV-Vis)and liquid chromatography/mass spectrometer(LC-MS)firstly;furthermore,effective coordination configurations and electronic properties of Cu−TA in aqueous solution were systematically revealed by density functional theory(DFT)calculations.Consistently,Job plots show the possible existence of[Cu(TA)]and[Cu(TA)_(2)]^(2-)at 230 and 255 nm based on UV-Vis results.LC-MS results confirm the existence of the single and high coordination complexes[Cu_(2)(TA)_(2)]^(+),[Cu(TA)_(2)]^(+)and[Cu_(2)(TA)_(3)(H_(2)O)_(2)(OH)_(2)]^(2+).DFT calculation results show that carboxylic oxygen and hydroxyl oxygen of tartaric acid(TA)are preferred sites for Cu(Ⅱ)coordination.[Cu(TA)](1H,3H sites O of TA coordinated with Cu(Ⅱ)),[Cu(TA)_(2)]^(2-)(two 1^(C),2^(H) sites O of TA coordinated with Cu(Ⅱ)),and[Cu(TA)_(3)]^(4-)(three 2H,3H sites O of TA coordinated with Cu(Ⅱ))should be dominant coordination configurations of Cu−TA.The corresponding Gibbs reaction energies are-170.1,-136.2,and-90.2 kJ/mol,respectively.
基金Project(2006BAJ03A01-05) supported by National Science and Technology Pillar Program during the 11th Five-Year Plan Period of ChinaProject (JG200705) supported by Key Laboratory of Structural Engineering of Shenyang Jianzhu University, China
文摘To establish bonding stress—slip constitutive model between bars and grout concrete,13 test specimens were employed to study the bonding behavior and the force transfer of bars adhered to grout concrete. The bonding stress development of bars adhered to grout concrete was analyzed. The local bonding stress—slip curve was obtained. Based on the test results,a new bonding stress— slip constitutive model between bars and grout concrete was proposed. The results show that the maximum bonding stress is not influenced by the bar bond length,but it is strengthened when the splitting strength of grout concrete is increased. The model matches the experimental results well,and the regressing coefficient equals 1.7.
文摘A novel technology of preparation of felt-metal supported modified polyvinyl alcohol(PVA) ultrafiltration(UF) membrane was invented, which could avoid the blockage of the holes of support layer and the leakage of the casting solution through the holes of support layer. Felt-metal supported ferric sulfate modified PVA composite UF membranes were prepared by the innovative technology. The results show that the composite membranes are used to treat 1 000 mg/L oil/water emulsion at trans-membrane pressure from 0.25 to 0.45 MPa, the permeate flux is from 36 to 52 L/(m2·h), and the retention of chemical oxygen demand(COD) is over 92%. The composite membrane resistance increases with the increase of trans-naembrane pressure.
文摘This paper presents the results obtained for the effluent dewatering properties of anaerobic digestion of secondary sludge (SS) and anaerobic co-digestion of mixture of this sludge with the distillery wastewater (DW) under thermophilic (55±1 ℃), 5 L of working volume, three parallel lab-scale conditions. Its mixtures were prepared with a DW content of 25%and 50% and the C/N ratios of mixtures are 13.1 and 17.6, respectively. The effluent dewatering properties were evaluated under stable conditions which the biogas yield and the effluent pH were steady. The natural settleability, biogas yield, centrifugal dewatering, centrifugal supernatant turbidity and specific resistance filtration (SRF) were investigated. The results showed that the effluent dewatering properties of anaerobic co-digestion of mixtures between SS and DW were better than that of anaerobic digestion of SS alone. In the anaerobic digestion system with the feed were SS, mixture of SS and a DW content of 25%and 50% in order, the net biogas yield of secondary sludge in ADSA,ADSB and ADSC were 0.42 0.507 and 0.511 m3 biogass/kg.VS.d ; compared with the biogas yield in anaerobic digestion system A (ADSA), the biogas yield in anaerobic digestion system B (ADSB) and anaerobic digestion system C (ADSC) had been increased by more than 20% respectively; the SRF of three digested sludge are(were) from 6.8×10^13, 1. 1×10^13 to 5.1×10^12 m/Kg, natural settling rates of 12 h are 26, 37 and 56% and that of 24 h are 32%, 45% and 59% respectively; the centrifugal dewatering rate of 3 min at speed of 1000 rpm were 16%, 31% and 51% respectively; the turbidity of centrifugal supernatant were 804, 754 and 678FTU simultaneously.
文摘AIM: To investigate the aspects of liver histology in patients with non-alcoholic steatohepatitis (NASH) who had normal aminotransferase levels. METHODS: Thirty-four patients diagnosed with liver steatosis by ultrasonographic examination participated in the study. We compared all non- alcoholic fatty liver disease and NASH cases, according to aminotransferase level, aspartate aminotransferase (AST)/alanine aminotransferase (ALT) ratio and presence of metabolic syndrome. RESULTS: Sixteen of 25 patients with high aminotransferase levels were diagnosed with NASH and nine with simple fatty liver according to liver histology. Among the nine patients with normal aminotransferase levels, seven had NASH and two had simple fatty liver. The patients with normal and high liver enzyme levels had almost the same prevalence of NASH and metabolic syndrome. Liver histology did not reveal any difference according to aminotransferase levels and AST/ALT ratio. CONCLUSION: Aminotransferase levels and AST/AIT ratio do not seem to be reliable predictors for NASH. Despite numerous non-invasive biomarkers, all patients with fatty liver should undergo liver biopsy.
文摘Objective:We evaluated the microsurgical effects of intratumoral injection ethanol into intracranial tumors,in particular,those with highly vascularized large meningiomas. Methods: Twelve patients presented with large meningioma,anhydrous ethanol was intraoperatively injected at an average volume of 15.4 mL followed by microscopic tumor resection. Results: Tumors in the injected sites became pallor to various extent and sclerous,leading to significantly decreased hemorrhage on the surface and cut. The average intraoperative hemorrhage was 88 mL. Complete tumor resection was achieved in 11 out of 12 patients; however,only 1 patient had 91.6% of the tumor resected. None of these patients had any postoperative complications. Conclusion: Intratumoral injection of anhydrous ethanol is a safe,convenient,and effective approach to diminish intraoperative bleeding for highly vascularized large meningiomas.
文摘The current study was carried out to examine the heavy metals (Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and As) concentration in GW (groundwater) samples in the vicinity of distillery spent wash evaporation ponds and RGW (reference groundwater) samples collected 2 km to 3 km away from the source. The study examines the potential health risk caused by consumption of heavy metals to local inhabitants living around distillery spent wash evaporation ponds. HM (heavy metals) concentration was determined by AAS (atomic absorption) and the results were compared with permissible limits of PEPA (pakistan environmental Protection Agency) and WHO (World Health Organization), set for industria effluents and drinking water. The health risk assessment such as CDI (chronic daily intake) and HQ (hazard quotient) were determined on the sources ofHM concentration. The cm of heavy metals in GW were found in following decreasing order Fe, Zn, Mn, Ni, Co, Cu, Cr, Cd, Pb and As. The HQ indexes of HM in the GW samples near the distillery spent wash evaporation ponds was in the order As, C, Ni, Cu, Mn, Zn, Pb and Cr. The results showed that the distillery spent wash is the cause for the change in HM contents of the study area.
基金Supported by the National Natural Science Foundation of China(No.29736170)
文摘An ionic conductivity prediction equation at low concentration for two acid salts is proposed taking into account the dissociation and association equilibria among ions. The salts considered are sodium and potassium hydrogen tartrates. There is no additional parameter of high order terms except for the Onsager's coefficient of limited term in the new equation. Results show a complex conductance of acidic tartrates in aqueous solution. The molar conductivities of metal ions are nearly constant such that the contributions from hydrogen and tartrate ions decrease with concentration, while the molar conductivity of bitartrate ion increases with concentration.
基金Supported by the National Natural Science Foundation of China (20866001) the Natural Science Foundation of GuangxiProvince (0832035)
文摘The kinetics of reductive leaching of manganese from low grade pyrolusite in dilute sulfuric acid in the presence of molasses alcohol wastewater was investigated. The shrinking core model was applied to quantify the effects of reaction parameters on leaching rate. The leaching rate increases with reaction temperature, concentrations of H 2 SO 4 and organic matter in molasses alcohol wastewater increase and ore particle size decreases. The leaching process follows the kinetics of a shrinking core model and the apparent activation energy is 57.5 kJ·mol –1 . The experimental results indicate a reaction order of 0.52 for H2SO4 concentration and 0.90 for chemical oxygen demand (COD) of molasses alcohol wastewater. It is concluded that the reductive leaching of pyrolusite with molasses alcohol wastewater is controlled by the diffusion through the ash/inert layer composed of the associated minerals.
基金Supported by Liaoning Foundation for Science and Technology Cooperation Between Government and University.
文摘An innovative internal circulation membrane bioreactor(ICMBR)treating traditional opaque beer brewery wastewater was introduced. Beer wastewater from Tianjin Huarun Brewhouse was taken as the influent. The removal efficiency of suspended solid, chemical oxygen demand, total nitrogen and ammonia nitrogen were studied with the changeable hard real time design method, organic loading rate and nutrition elements. The average percentage reduction in chemical oxygen demand achieved 90%. The total nitrogen and ammonia nitrogen were also reduced by 90% and 95%, respectively. The results indicate that the outlet of ICMBR meets the requirements of the environment landscape recycling use.
文摘The binary liquid-liquid equilibrium(LLE) data for salt-containing systems of 1-butanol+water+CaCl2, n-butyl acetate+water+CaCl2 and ethyl acetate+acetic acid+water+CaCl2 were determined and the salt effect was analyzed. The results showed that an obvious salt effect could be identified for the systems of 1-butanol+water+CaCl2 and ethyl acetate+acetic acid+water.
基金Supported by First Università degli Studi di Milano 2007,2008,to Valenti L and Fargion SRicerca corrente Ospedale Maggiore Policlinico 2006 and 2008,to Valenti L and FargionSCentro per lo Studio delle Malattie del Fegato e del Metabolismo
文摘Nonalcoholic fatty liver disease(NAFLD),defined by excessive liver fat deposition related to the metabolic syndrome,is a leading cause of progressive liver disease,for which accurate non-invasive staging systems and effective treatments are still lacking.Evidence has shown that increased ferritin levels are associated with the metabolic insulin resistance syndrome,and higher hepatic iron and fat content.Hyperferritinemia and iron stores have been associated with the severity of liver damage in NAFLD,and iron depletion reduced insulin resistance and liver enzymes.Recently,Kowdley et al demonstrated in a multicenter study in 628 adult patients with NAFLD from the NAFLD-clinical research network database with central re-evaluation of liver histology and iron staining that the increased serum ferritin level is an independent predictor of liver damage in patients with NAFLD,and is useful to identify NAFLD patients at risk of non-alcoholic steatohepatitis and advanced fibrosis.These data indicate that incorporation of serum ferritin level may improve the performance of noninvasive scoring of liver damage in patients with NAFLD,and that iron depletion still represents an attractive therapeutic target to prevent the progression of liver damage in these patients.
基金the Special Funds for Major State Basic Research Program of China(2003CB615706)
文摘N, O-carboxymethyl chitosan (NOCC) composite nanofiltration (NF) membranes were prepared by coating and cross-linking. The fermentation effluent from a wine factory was treated with the resulting NOCC/polysulfone (PSF) composite NF membranes. The permeate flux and the removal efficiencies of the resulting NF membranes for the color, chemical oxygen demand (CODcr), total organic carbon (TOC), and conductivity of the fermentation effluent were investigated in relation to the driving pressure, the feed flow, and the operation time. The permeate flux and the removal efficiencies were found to increase with the increase of the driving pressure or the feed flow. At 0.40 MPa and ambient temperature the removal efficiencies were 95.5%, 70.7%, 72.6%, and 31.6% for color, CODcr, TOC, and conductivity, respectively. The membrane was found to be stable over a 10-h ooeration for the fermentation effluent treatment.
基金Supported by the Direction of Research of the University of La Serena-Chile (220-2-05 and 220-2-21)the National Council for Scientific and Technological Research,CONICYT (FONDECYT 3020020)
文摘In this study,three semipredictive activity coefficient models:Wilson,non-random-two liquid model(NRTL),and universal quasi-chemical model(UNIQUAC),have been used for modeling vapor-liquid equilibrium properties of ternary mixtures that include substances found in alcoholic distillation processes of wine and musts.In particular,vapor-liquid equilibrium in ternary mixtures containing water + ethanol + congener has been modeled using parameters obtained from binary and ternary mixture data.The congeners are substances that although present in very low concentrations,of the order of part per million,are important enological parameters.The results given by these different models have been compared with literature data and conclusions about the accuracy of the models studied are drawn,recommending the best models for correlating and predicting phase equilibrium properties of this type of mixtures.
文摘Performances of submerged membrane bioreactor (SMBR) treating brewery wastewater were investigated in this study. With little variation of COD:TN:TP ratio (100:5:1) in influent, SMBR showed high removal efficiency ( 〉 90% ) for both COD and NH4^+ - N, and it also showed a strong resistive ability for shock organics loading rate, evidenced by no obvious fluctuation for COD in the effluent when the organics loading rate suddenly increased from 0. 27 g/( gMLSS · d) to 0. 54 g/( gMLSS · d). Comparatively different with the COD removal, TN and TP removal showed a strong correlation with the growth stage of the sludge in SMBR. When the sludge was in the multiplication stage, about 45% of TN was removed and an average removal efficiency of 30% for TP was also observed. However, when the activated sludge was in the steady stage, the removal efficiency for TN decreased to about 30% , whereas, the removal efficiency for TP was very low, and sometimes even below zero. The results of GC/MS indicated that the residual organic matters in the effluent were mainly alkyl hydrocarbon with high molecular weight, and coupling with the results of electroseopic scanning, it is speculated that biomass formed at external and internal membrane fibers played an important role for the removal of small organics.
文摘As an important geophysical tool,high density electrical technique infers the underground geological structures by processing and inverting the apparent resistivity data.Currently,the false anomalies have been frequently occurred in the graph of apparent resistivity pseudo-section or inverted geoelectrical section obtained from high-density electrical technique,and are difficult to remove.In this study,the authors explain the mechanism of the false anomalies and put forward the horizontal differential field method to identify the false anomalies.Based on the analysis of modeling results,this method is applied in the surveying data in Xinlei Quarry of Jiuquan,and the results confirm the effectiveness of the horizontal differential field method.
文摘Organic biomass is an attractive feedstock for second generation alcohol production. Wild-type strains of the genus Candida showed capabilities different to produce alcohol fermenting a carbohydrates mixture (synthetic medium), individually and in co-culture. Therefore, the main objective of this work was to evaluate the capability of Candida wild-type strains isolated from termite gut and rumen liquid, to ferment the most commonly carbohydrates presented in citrus residues, individually and in co-culture to alcohol production. C Tropicalis (LR4) presented higher percentage of carbohydrate consumption (74.20% ± 4.60%), alcohol production (44.53 ± 0.01 gLl) and maximal alcohol productivity (6.40 ± 0.01 gL-l day) than C Glabrata (T1). Co-culture schemas, CC1 (LR4: 60%; TI: 40%) and CC3 (first LR4 alone and 2 days later T1) presented the highest alcohol production (45.20 ± 1.30 gL-1 and 46.80 ± 2.60 gL-1, respectively). Maximal alcohol productivity was obtained with CC2 (LR4: 80%; TI: 20%) and CC3 schemas, 7.70 ± 0.29 gL-1 day and 7.80 ± 0.44 gL-l day, respectively. The results suggest the usefulness of these wild-type strains in co-culture as an alternative to alcohol production from carbohydrates mixtures at concentrations commonly found in citrus waste.