Source analysis and ecological risk assessment for heavy metals in the sediments of the Yangshan Deepwater Harbor in autumn and winter

Temporal and spatial variations of concentrations of heavy metals including mercury （Hg）, zinc （Zn）, lead （Pb）, arsenic （As）, copper （Cu）, and cadmium （Cd） in the sediments of the Yangshan Deepwater Harbor were determined based on 6 cruises in autumn and winter, respectively, from 2010 to 2013. The results demonstrated that the overall concentrations of heavy metals were low and distributed in uniform patterns. The concentrations of Hg, Zn, Pb, and Cd in autumn were significantly higher than those in winter with small fluctuations for As and Cu in terms of seasonal variations. Results of factor analysis showed that Pb, Cd, and Zn were derived from inland industrial and shipping discharges as well as the degradation of organic pollutants in marine environment. While agricultural pollutions, cargo shifting and construction debris from reclamation projects contributed to the sources of Cu, As, and Hg. Ecological risk assessment by Mean Sediment Quality Guideline Quotient （SQG-Q） revealed that the degree for eco-risk of the sediments was low-and-moderate in autumn, higher than that in winter. Hg and Cu were the dominant eco-risk factors. The results of Index of geoaccumulation （Igeo） showed that the whole sites of the sea area were barely influenced by Hg, As, Zn, and Pb, and the extents of Cd and Cu contaminations were in low grade. Contamination degree of all the six heavy metals could be ranked as the following： Cd〉Pb〉Zn〉Hg〉As. According to the results of integrated score of factor analysis, the contamination degree for heavy metals in sediments of the Yangshan Deepwater Harbor was low, despite sites No.5, No.4 and No.3, which were heavily contaminated compared with others.

Electrophoretic Analysis of Isozymes and Discussion about Species Differentiation in Three Species of Genus Gymnocypris

By using the method of electrophoresis,three isozymes (lactate dehydrogenase,malate dehydrogenase and esterase) of three species of genus Gymnocypris were described and analyzed from North Tibet in this paper. The results showed that all three isozymes presented interspecific difference and distinct differentiation among individuals in the same population,and there was no electrophorectic difference between males and females. Analysis of relationships among three naked carps indicated a high degree of similarity between G. selincuoensis and G. cuoensis ,whereas low degree between G. selincuoensis and G. namensis . Furthermore,three isozymes presented expression of null alleles,and the duplicate genes of LDH A 2,LDH B 2,s MDH A 2 and m MDH B 2 also expressed in some individuals. Compared to other tetraploid fishes,three naked carps retained more functional duplicate genes and null alleles. This suggests fishes of genus Gymnocypris are at the early stage of evolution after polyploidization than that of fishes of Catostomidae,it directly related to the later time of schizothoracine fishes originate as well as severe environment.

Distribution and ecological evaluation of heavy metals in multi-medium of the Dongzhai Harbor

The distribution characteristics of heavy metals such as Cu, Zn, Pb, Cd, Hg. As in seawater, superficail sediments and several marine organisms of Dongzhai Harbor in Hainan were analyzed. Index methods of the single factor and geo-accumulation were used to assess the pollution degree of heavy metals. The results showed that the heavy metal levels in the seawater of Dongzhai Harbor accorded with the first category of the seawater except Pb, and were much lower than the fishery water quality standard; the concentration of the heavy metal in surface sediments did not exceed the national benchmark of the first-class of marine sediment quality basically, and the superficial sediments were essentially uncontaminated; the heavy metal content in wetland sediments was slightly higher than those in other typical mangrove wetland island of Hainan and marine sediments in Dongzhai Haibor, which indicated this area might has been affected by land-based pollution influence, and this should cause the attention of related departments; the heavy metal concentrations in marine organisms were up to the first category. All were not beyond the standard of non-environmental pollution aquatic products.

Two-sectional struvite formation process for enhanced treatment of copper-ammonia complex wastewater

Mg2＋ and PO43＋ were added into the synthetic wastewater, leading to the dissociation of the complex ions in the wastewater, and resulting in removal of copper and ammonia therein. The effects of agents addition amount, pH, and reaction time on the removal efficiency of copper and ammonia were investigated. In particular, two-sectional struvite formation （TSSF） process was established for copper and ammonia removal. MgCl2 and Na2HPO4 were added by following 90% addition in the first section and remained 10% in the second during the TSSF process. Compared with one sectional struvite formation, TSSF possessed much better performance. Under condition of n（NH3-N）：n（Mg）：n（P）=1：1.2：1.5 （molar ratio）, pH=9, and reaction time of 30 min, the removal efficiencies of copper and ammonia were 98.9% and 99.96%, respectively. The enhanced performance of TSSF is explained by the competition of ammonia by copper？ammonia complexes and struvite. The dissociation of copper-ammonia complexes is further demonstrated by thermodynamic equilibrium analysis, on the basis of calculations and establishment of predominance phases diagram. Moreover, XRD and EDS analyses further confirmed the formation of struvite and precipitation of copper, which prove the transmission of copper and ammonia from liquid phase into solid phase.

Relation between Atmospheric Deposition and Accumulation of Heavy Metals in Rice in Mining Areas of Guangxi

Firstly, the concept, sources and damage of atmospheric deposition were introduced, and then the relation between atmospheric deposition and accumulation of heavy metals in rice in Guangxi was analyzed to provide reference for the implementation of effective risk early warning of pollution from heavy metal deposition and safe production of rice in mining areas of Guangxi.

Treatment of Organic Wastewater Containing Cr^(3+) by a Novel Complex Process of Electrodeposition and Biofilm

A novel complex process of electrodeposition and biofilm is utilized to treat organic wastewater containing Cr 3+, and its purifying mechanism is also described in this article. In details, organic materials in wastewater are consumed as nutritious source by biofilm composed of microorganism and EPS (extracellular polysaccharide substance). While one part of heavy metal ions, such as Cr 3+, is removed by electrodeposition, the other part is adsorbed on biofilm. In contrast, experimental data of single electrodeposition or biofilm process are listed. Further, the kinetic curves of microbes cultivated or microbes acclimated by Cr 3+ to degrade glucose are provided,too. In conclusion, the experimental results indicate that initial wastewater consists of C 6H 12O 6 (500 mg·L -1), Cr 3+ (10 mg·L -1), after treated with the complex process, concentrations of C 6H 12O 6 and Cr 3+ are on the scale of 15-20 mg·L -1, and less than 1 mg·L -1, respectively. Purified water can meet the standards of industrial reused water.

Analysis on Grain Traits and Sedimentation Value of Wheat Genotype Heng 9966, Its Parents and Their Closely Related Varieties

[Objective] 7 indictors of wheat genotype Heng 9966, its parents and their closely related varieties were analyzed based on the 1000-grain weight, sedimentation value and traits of selected grains in DUS test, so as to provide references for the protection of variety intellectual property. [Method] Testing comparison and statistical analysis were conducted to the dormant seeds of winter wheat genotype 9966, parents of Liangxing 99 and Liangxing 96 aw well as the closely related variety of the parents, Jimai 22. [Result] Heng 9966 showed a difference of 2 codes in 1000-grain weight and sedimentation value from the above-mentioned 3 genotypes, and the variant analysis reached the extremely significant level of 0.01. And it also showed extremely significant difference at the level of 0.01 with Liangxing 66 in grain length, with Liangxing 66 and Jimai 22 in grain width, with Liangxing 66 in grain area, with Liangxing 66 and Jimai 22 in grain perimeter. [Conclusion] Heng 9966 had significant distinctness from its parents and their closely related variety, and grain shape can be used as a reference indicator for variety distinctness for the protection of variety intellectual property.

Solubility Model of Thiamine Nitrate During Recrystallization Process

The concentration variations of all key components were investigated during recrystallization process of thiamine nitrate, and a mathematic model that is used to show the solubility variations of thiamine nitrate was constructed in this paper. Comparing the predicted values with those experimental results, it was concluded that the model well reflected the solubility variations of thiamine nitrate during recrystallization process. The proposed model was important to study the nucleation process and crystal growth process during recrystallization process, and also provided a beneficial method to study the solubility variations of solute during such precipita- tion process.

哲学的诗化诘问:论小海诗歌中的时间

小海的诗歌表现时间形式非常有意味,其“绝对化的时间”“静止的时间”和“沉重的时间”所支撑的艺术空间充溢着哲学之思。“绝对化的时间”,即“理想的时间”,是探索生命本源的时间,是一种假设的时间,在小海的诗歌中呈现的形式是对自然的眷恋与打量。“静止的时间”,即“现实的时间”,是书写生存状态的时间。“沉重的时间”是一种“纠结”与过渡的时间,是一种等待填充的时间,也是充满矛盾和张力的暧昧不明的时间,其显形需要借助某种“中介物”实现。三种时间交相辉映,共同建构了小海诗歌的审美空间。

Treatment of Organic Wastewater Containing Cr3+ by a Novel Complex Process of Electrodeposition and Biofilm

A novel complex process of electrodeposition and biofilm is utilized to treat organic wastewater containing Cr 3+, and its purifying mechanism is also described in this article. In details, organic materials in wastewater are consumed as nutritious source by biofilm composed of microorganism and EPS (extracellular polysaccharide substance). While one part of heavy metal ions, such as Cr 3+, is removed by electrodeposition, the other part is adsorbed on biofilm. In contrast, experimental data of single electrodeposition or biofilm process are listed. Further, the kinetic curves of microbes cultivated or microbes acclimated by Cr 3+ to degrade glucose are provided,too. In conclusion, the experimental results indicate that initial wastewater consists of C 6H 12O 6 (500 mg·L -1), Cr 3+ (10 mg·L -1), after treated with the complex process, concentrations of C 6H 12O 6 and Cr 3+ are on the scale of 15-20 mg·L -1, and less than 1 mg·L -1, respectively. Purified water can meet the standards of industrial reused water.

Evaluation of PS-DInSAR technology for subsidence monitoring caused by repeated mining in mountainous area

The high resolution Terra SAR-X dataset was employed with DIn SAR and persistent scatterer interferometry（PSI） technique for subsidence monitoring in a mountainous area. For DInS AR technique, the generally used SRTM and relief-DEM, which was derived from aerial topographic map, were used to evaluate the influence of external DEM. The results show that SRTM could not fully compensate the complex topography of the research area. The corner reflectors installed during the acquisition of SAR dataset were used to estimate the accuracy of geocoding. The terrain corrected geocoding results based on relief-DEM were much better than using SRTM, with the root mean square error（RMSE） being 6.35 m in X direction and 11.65 m in Y direction（both in UTM projection）, around one pixel of the multilooked intensity image to be geocoded. For PSI technique, the results from time-series analysis of multi-baseline differential interferograms were integrated to restrict only persistent scatterer candidates near the boundary of subsiding area for regression analysis. The results demonstrate that PSI can refine the boundary of subsidence, which could then be used to derive some angular parameters to help people to learn the law of subsidence caused by repeated excavation in this area.

Characteristics of gravity anomalies and prediction of volcanosedimentary boron deposit distribution in the Xiongba area,Tibet

Volcanosedimentary boron deposits are present within Tertiary lacustrine sediments and volcanic rocks in Xiongba, Tibet. Boron deposits are characterized by low density relative to country rocks; thus, it is possible to locate them by gravity measurements. We conducted a 1：50000 high-precision gravity survey in the Xiongba area, Tibet, and obtained the Bouguer and residual gravity anomalies. We analyzed fault systems and the distribution of sedimentary and volcanic rocks and their relation to the volcanosedimentary boron deposits. The processing of the gravity data revealed local gravity variations and fault structures. We applied preferential downward continuation and wavelet transform to the gravity data, and in conjunction with geological data, we predicted the distribution of volcanosedimentary boron deposits.

Characteristics of Heavy Metals and Their Evaluation in Sediments from Middle and Lower Reaches of the Huaihe River

We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy metals (Cr,Cu,Zn,Cd and Pb). The average concentrations of Cr,Cu,Zn,Cd and Pb of the 18 sampling locations were re-spectively 56.1,22.2,70.0,0.17 and 20.4 μg/g. Compared with their background values,the average concentrations of Zn and Cu in sediment samples from the Huaihe River were slightly higher,while the average concentrations of Cr and Pb were slightly lower. The concentration of Cd in all sediment samples was higher than its background value,while the average concentration of Cd in all sediment samples was about twice the amount of the background value. The concen-tration of the five heavy metals was lower than that of the Yangtze River. A correlation analysis revealed that heavy metals have similar geochemical feautures. The geo-accumulation index (Igeo) was used to evaluate the degree of pollu-tion of the Huaihe River sediments. The index reveals that the sediment samples are largely ranked from zero pollution to no to medium pollution.

Distribution and Accumulation Characteristics of Heavy Metals in Sediments in Southern Sea Area of Huludao City, China

The southern sea area of the Huludao City, Liaoning Province might be polluted by heavy metals because it is close to the Jinzhou Bay, one of the heaviest sea area polluted by heavy metals in China. The undisturbed modem sediment core can be used to analyze the accumulation and source of the pollutants using 137Cs and 21pbex. Thirty-five samples of surface sediment and two core sedi- ments were collected from the southern sea area of Huludao City. The concentrations of copper （Cu）, lead （Pb）, chrome （Cr）, zinc （Zn）, arsenic （As） and mercury （Hg） in the surface sediments as well as Cu, Pb, Zn, Cr, 137Cs and 2~~pbex in the core sediments were deter- mined to research the spatial distribution and accumulation characteristics, and to analyze the sources and the potential risks of heavy metals. The results show that the pollution levels of Zn and Hg are serious, and 26 stations are at moderate or heavy ecological risks. The concentrations of the heavy metals increase from east to west, as well as from open sea to offshore marine area. The concentrations of heavy metals are not high in the sediments adjacent to the Jinzhou Bay, and the influence caused by the seawater exchange with the Jinzhou Bay is little. The concentrations of the heavy metals in the core sediments show low-high-low characteristic, and it coincides with the pollution history of Huludao City. The atmospheric deposition of heavy metals from the Huludao Zinc Plant is likely to be the main source of pollution without direct discharge of wastewater. The high concentrations of heavy metals appear on the upper sediment of 20 cm. The shallow sediment with high heavy metal contents might be exposed to surface when it was disturbed by the ocean engineering and big storm surge, then cause risk to the safety of aouaculture and human honlthy.

Superposition model for analyzing the dynamic ground subsidence in mining area of thick loose layer

The dynamic ground subsidence due to underground mining is a complicated time-dependent and rate- dependent process. Based. on the theory of rock rheology and probability integral method, this study developed the superposltlOn model for the prediction and analysis of the ground dynamic subsidence in mining area of thick !oose layer. The model consists of two parts （the prediction of overlying bedrock and the prediction of thick loose layer）. The overlying bedrock is regarded as visco-elastic beam, of which the dynamic subsidence is predicted by the Kelvin visco-elastic rheological model. The thick loose layer is regarded as random medium, and the ground dynamic subsidence, is predicted by the probability integral model. At last, the two prediction models are vertically stacked in the same coordinate system, and the bedrock dynamic subsidence is regarded as a variable mining thickness input into the prediction model of ground dynamic subsidence. The prediction results obtained were compared w^th actual movement and deformation data from Zhao I and Zhao II mine, central China. The agreement of the prediction results with the. field measurements.show that the superposition model （SM） is more satisfactory and the formulae obtained are more effective than the classical single probability Integral model（SPIM）, and thus can be effectively used for predicting the ground dynamic subsidence in mining area of thick loose layer.

Heavy metal research in lacustrine sediment:a review

Heavy metals are released into environment from a wide range of natural and anthropogenic sources. Aquatic ecosystems are normally at the receiving end and in many cases, with lakes as intermediaries. Lacustrine sediments are important sinks for heavy metals and play a significant role in enrichment and remobilization of heavy metals in aquatic systems. Therefore, characteristics of heavy metal in lacustrine sediments become one of the important issues in environmental sciences. Progress in heavy metal research of lake sediments since late 1980s is reviewed comprehensively in this paper from over 100. The Highlights are placed on the establishment of aquatic sediment quality guidelines, references chemical speciation of heavy metals, heavy metal transport mechanisms in lakes, and high-resolution study of lake borehole cores. Meanwhile, suggestions for heavy metal research in lacustrine sediment in the future are proposed, including such issues as using integrated approaches to assess aquatic ecosystem, modem lake dynamic process, high-resolution evolutionary sequence and spatial differentiation of environments and international lake database, which should be referential to the promotion of research on heavy metal in aquatic system.

Assessment of heavy metals in sediment in a heavily polluted urban river in the Chaohu Basin, China

The Nanfei River （Anhui Province, China） is a severely polluted urban river that flows into Chaohu Lake. In the present study, sediments were collected from the river and analyzed for their heavy metal contents. Multivariate statistics and the fuzzy comprehensive assessment method were used to determine the sources of pollution, the current pollution status, and spatial and temporal variations in heavy metal pollution in sediments. The concentrations of arsenic （As）, cadmium （Cd）, chromium （Cr）, copper （Cu）, mercury （Hg）, nickel （Ni）, lead （Pb）, and zinc （Zn） in sediments ranged from 5.67-113, 0.08-40.2, 41.6-524, 15.5-460, 0.03-4.84, 13.5-180, 18.8-250, and 47.9-1 996 mg/kg, and the average concentrations of each metal were 1.7, 38.7, 1.8, 5.5, l 8.8, 1.3, 2.5, and 11.1 times greater than the background values, respectively. Multivariate statistical analysis demonstrated that Hg, Cu, Cr, Cd, and Ni may have originated from industrial activities, whereas As and Pb came from agricultural activities. The fuzzy comprehensive assessment method, based on the fuzzy mathematics theory, was used to obtain a detailed assessment of the sediment quality in the Nanfei River watershed. The results indicated that the pollution was moderate in the downstream tributaries of the Nianbu and Dianbu Rivers, but was severe in the main channel of the Nanfei River and in the upstream tributaries of the Sill and Banqiao Rivers. Therefore, sediments in the Nanfei River watershed are heavily polluted and urgent measures should be taken to remedy the status.

Crayfish Shell Waste as Safe Biosorbent for Removal of Cu^(2+)and Pb^(2+)from Synthetic Wastewater

Crayfish shell is an abundant natural waste and is also a potential biosorbent for pollutants,especially,heavy metals.In this study,the safety of the use of crayfish shell as a biosorbent was first assessed by release experiments involving primary heavy metal ions,such as Cu^(2+),Zn^(2+),and Cr^(3+),in aqueous solution under different environmental conditions.The release concentrations of heavy metals were dependent on pH,ionic strength,and humic acid;and the maximum release concentrations of heavy metals were still lower than the national standard.Specifically,Cu^(2+) and Pb^(2+) removal by crayfish shell in synthetic wastewater was investigated.The removal process involved biosorption,precipitation,and complexation,and the results indicate that crayfish shell is an excellent biosorbent for Cu^(2+) and Pb^(2+) removal.The precipitation step is particularly dependent on Ca species,pH,and temperature.The maximum removal capacities of Pb^(2+) and Cu^(2+) were 676.20 and 119.98 mg/g,respectively.The related precipitates and the generated complex products include Cu_(2)CO_(3)(OH)_(2),Ca_(2)CuO_(3),CuCO_(3),Pb_(2)CO_(3)(OH)_(2),CaPb_(3)O_(4),and PbCO_(3).

Characteristics and formation of high quality reservoirs in sediment gravity flows of Gangzhong area,Huanghua depression

Reservoirs can be developed in the sediment gravity flows.However,high quality reservoirs are found widespread in sediment gravity flows of Gangzhong area,Huanghua depression,Bohai Bay Basin,East China.Characteristics and formation of these reservoirs are key problems to be solved.Through comprehensive analysis of thin section petrography,scanning electron microscopy and X-ray diffraction,two distinct rules were obtained.1) These high quality reservoirs have apparent characteristics:lithology consists mainly of medium-fine grained sands; moderately-well sorted and rounded; intergranular pores dominating >70% of the entire pores,surface per unit pore volume reaches 15%; average porosity is 21% and average permeability is 55×10-3 μm2.2) Types of sedimentary microfacies and dissolution strongly control on the formation of high quality reservoirs.Main channels and sandy braided bars have the best reservoir properties.Because that sediments are mainly medium-fine grained sands in high-energy environments.The favorable primary porosity and permeability may promote calcite cementation and help to produce more secondary pores.Besides,at the depth of 2500-3200 m,basically matching threshold of oil generation,organic acid expelled when organic matter became mature,and H+ released during clay mineral transformation.These both result in the dissolution of calcite cements and create large volume pores,then physical properties improve correspondingly.Moreover,deep hydrothermal fluid intrusion may also have impacts on the development of secondary pores.

Comparison of Different Extraction Approaches for Heavy Metal Partitioning in Sediment Samples

Three extraction methods, ultrasonic assisted extraction (USE), microwave assisted extraction (MSE), and conventional single extraction (CSE), in conjunction with the modified three-stage BCR sequential extraction procedure (SEP) were applied to examine the contents of Cd, Cu, Cr, Ni, Pb and Zn from lake sediment samples, to know whether these techniques can reduce extraction time and improve reproducibility. The SEP and developed alternative single extrac- tion methods were validated by the analysis of certified reference material BCR 601. By the use of optimized sonication and microwave conditions, steps 1, 2 and 3 of the BCR sequential extraction methods (excluding the hydrogen peroxide digestion in step 3, which was not performed with sonication and microwave) could be completed in 15-30 min and 60- 150 s, respectively. The recoveries of total extractable metal contents in BCR 601, obtained by three single extractions ranged from 93.3%-102%, 88.9%-104% and 81.2%-96.2% for CSE, USE and MSE, respectively. The precision of the single extraction methods was found in the range of 3.7%-9.4% for all metals (n = 6).